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Heat distribution model under hydrogen-rich low-carbon conditions in blast furnace

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Journal of Iron and Steel Research(International) 2024年第3期31卷 584-594页

作者： Gang wang Jun Xu Kun He Zhong-ping Zou Hao Bai School of Metallurgy and Ecological Engineering University of Science and Technology BeijingBeijing 100083China CISDI Low-Carbon Blast Furnace Research Office MCC Low-Carbon Technology Research InstituteChongqing 401122China

Low carbon development of blast furnaces is one of the key technological directions in the current development of *** to the differences in the physical and chemical properties of hydrogen and carbon,hydrogen-rich media entering a blast furnace will change the heat distribution,thus affecting the stability of ***,a heat distribution model was proposed to study the temperature distribution in a blast furnace,simultaneously considering gas-solid heat exchange,slag and iron melting,and chemical *** model was used to analyze the temperature distribution of a 2300 m^(3) blast furnace and was verified via comparison with actual production ***,the effects of the injection rate of hydrogen-rich media,H2 concentration,and oxygen enrichment rate of the blast on the temperature distribution were *** indicated that the increase in the injection rate of the hydrogen-rich media decreased the amount of direct reduction and led to an increase in the furnace ***,an increase in the oxygen enrichment rate led to a decrease in the furnace temperature,but could reduce the solid fuel ratio,while the change in H2 concentration had less effect on the temperature *** combination of hydrogen-rich media injection and the increase in the oxygen enrichment rate would help to adjust the temperature distribution to the same level as the conventional blast furnace conditions.

关键词： Heat distribution Blast furnace Low-carbon condition Hydrogen enrichment Calculation model

Fabrication of Molecularly Imprinted Electrospun Nanofibers with Mono-amidoxime Functional Ligand for Efficient Decontamination of Toxic Organophosphates

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Chinese Journal of Polymer Science 2024年第4期42卷 446-456页

作者： Lan wang Peng Jiang ya-Lin Niu Jun-Peng Cao Tian-Ying Guo Key Laboratory of Functional Polymer Materials Ministry of EducationInstitute of Polymer ChemistryCollege of Chemistry and Frontier Science Center for the Creation of New Organic SubstancesNankai UniversityTianjin300071China

There is an urgent imperative to discover practical and efficacious artificial catalysts for the expeditious decontamination of toxic organophosphates. Herein, we propose a novel molecularly imprinted approach utilizing electrospun fiber scaffolds. Specifically, an amidoxime-based functional polymer (PMAOX) has been synthesized, which contains amidoxime groups that can act as nucleophiles and ligands for the formation of catalytic active sites. This polymer was blended with polyacrylonitrile (PAN), a well-processable material, to prepare a nanofiber mat using electrospinning techniques. Then, the amidoxime side groups on fiber surface were further cross-linked after the molecular coordination of templates to complete the molecularly imprinting process. This approach can not only enhance the content of functional molecularly imprinted polymers without affecting structural stability, but also combines surface MI technology to fully expose and leverage the advantages of active sites. The as prepared molecularly imprinted electrospun nanofibers MIF-Zn-PMAOX/PAN-6/4 catalyzes the degradation of paraoxon with a half-life of 32 min, and MIF-Ag-PMAOX/PAN catalyzes the degradation of parathion with a half-life of 18 min. The maximum catalytic rate evidence rate enhancements nearly 3700-fold of the self-hydrolysis. Thus, the mono-amidoxime based molecularly imprinted fibers demonstrate the versatility and superiority as self-detoxifying for organophosphates.

关键词： Organophosphateshydrolysis Electrospinning Molecular imprinting

Hierarchical Fe3O4@C nanofoams derived from metal-organic frameworks for high-performance lithium storage

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Rare Metals 2020年第9期39卷 1072-1081页

作者： Huan-Huan Li Ashwani Saini Ru-Yu Xu Nan wang Xiao-Xin Lv ya-ping wang Tao yang Long Chen Hao-Bin Jiang Automotive Engineering Research Institute Jiangsu UniversityZhenjiang 212013China School of Material Science and Engineering Jiangsu UniversityZhenjiang 212013China Jiangsu Chunlan Clean Energy Research Institute Co. Ltd.Taizhou 225300China

A facile method was employed to in situ prepare hierarchical mesoporous Fe3O4@C nanofoams through pyrolysis of a post-treated MIL-53(Fe)*** carbon network-encapsulated ultrasmall and uniform Fe3O4 octahedrons can be obtained by controlling the pyrolysis *** unique artificial shows the excellent lithium storage performance.A reversible discharge capacity of 861.9 mAh·g-1 is observed at 0.1 A·g-1after 300 *** at a high current density of 1 A·g-1,the reversible discharge capacity can still reach 605.2 mAh·g-1 after 500 *** rate capability is also observed,as the specific discharge capacities are833.6,729.9,666.8,643.6 and 635.6 mAh·g-1 at current density of 0.2,0.5,0.8,1.0 and 1.2 A·g-1,*** attractive electrochemical performance of Fe3 O4@C nanofoams should be attributed to the hierarchical foamlike structure,which can effectively relieve the volume change during the lithiation/delithiation process and facilitate fast lithium-ion and electron transport.

关键词： Lithium-ion battery Anode material Fe3O4 Metal-organic framework Thermal treatment

Recent progress on rapid diagnosis of COVID-19 by point-of-care testing platforms

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Chinese Chemical Letters 2024年第3期35卷 66-75页

作者： ya-Nan Tang Dingding Jiang Xuejun wang Yunqi Liu Dacheng Wei State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200433China Institute of Molecular Materials and Devices Fudan UniversityShanghai 200433China

The outbreak of COVID-19 has drawn great attention around the ***-CoV-2 is a highly infectious virus with occult transmission by many mutations and a long incubation *** particular,the emergence of asymptomatic infections has made the epidemic even more ***,early diagnosis and timely management of suspected cases are essential measures to control the spread of the *** simple,portable,and accurate diagnostic techniques for SARS-CoV-2 is the key to epidemic *** advantages of point-of-care testing technology make it play an increasingly important role in viral detection and *** review summarizes the point-of-care testing platforms developed by nucleic acid detection,immunological detection,and nanomaterial-based biosensors ***,this paper provides a prospect for designing future highly accurate,cheap,and convenient SARS-CoV-2 diagnostic technology.

关键词： COVID-19 Point-of-care testing platforms Nucleic acid detection Asymptomatic infection Biosensors

Study on the dynamic mechanical properties of winding-block axial structure considering short circuit strain rate effect

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High Voltage 2024年第2期9卷 380-390页

作者： Xinyu wang ping wang Jianghai Geng Zikang Zhang Fangcheng Lü Shuguo Gao Hebei Provincial Key Laboratory of Power Transmission Equipment Security Defense North China Electric Power UniversityBaodingChina State Grid Hebei Electric Power Research Institute ShijiazhuangChina

Transformers may suffer multiple short-circuit impacts during long-term operation,and axial instability is one of the typical types of serious accidents caused by short-circuit *** axial instability form of the winding-block structure is analysed,and the dynamic solution of the winding short-circuit electromagnetic force is obtained by estab-lishing the three-dimensional magnetic-circuit-force multi-physical field coupling simulation *** influence of strain rate on the cushion block constitutive equation is corrected,and the modified model is verified by short-circuit impact test and quasi-static *** research results show that for 110 kV 31.5 MVA transformers,the maximum electromagnetic axial resultant force of winding is 363.16 kN,and the ultimate tilt force is 1214.2 *** pre-tightening force configuration is accordingly recom-mended to range from 363.16 to 608.28 kN,which is narrowed by 18.49%compared with the static calculation method;Meanwhile,adding a logarithmic strain rate correction term to the classical constitutive equation of the cushion block can achieve a good correction of the stress-strain relationship with the coefficient of determination above 0.99,and the cushion block has a larger elastic modulus under high strain rate *** research results provide an important theoretical reference for the axial stability structure of transformers.

关键词： axial correction structure

Hydrazone derivatives in agrochemical discovery and development

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Chinese Chemical Letters 2024年第3期35卷 104-113页

作者： ya wang Shengxin Guo Lijiao Yu Wei Zhang Zhenchao wang Yonggui Robin Chi Jian Wu National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityHuaxi DistrictGuiyang 550025China Division of Chemistry&Biological Chemistry School of Physical&Mathematical SciencesNanyang Technological UniversitySingapore 637371Singapore

As a common active substructure,hydrazone has attracted increasing attention and is considered essential for pesticide *** has been widely regarded as a potential insecticidal,antibacterial,antifungal,antiviral,and herbicidal *** this review,we highlight the pesticide versatility of hydrazone fragments and provide a comprehensive summary of the biological activity,structure-activity relationship analysis(SARs),and primary mechanism of their *** profile is expected to give valuable information for discovering new pesticides.

关键词： Hydrazone Agrochemicals Biological activity Structure-activity relationship Preliminary mechanism

Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

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Chemical Research in Chinese Universities 2024年第3期40卷 462-474页

作者： wang Chengbin LI ping CHEN Dehong ZHANG Ruiyong wang Lei ZONG Lingbo College of Chemistry and Molecular Engineering Qingdao University of Science and TechnologyQingdao 266042P.R.China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042P.R.China Key Laboratory of Marine Environmental Corrosion and Bio-fouling Institute of OceanologyChinese Academy of SciencesQingdao 266071P.R.China

Single-atom catalysts (SACs) have garnered extensive attention in the field of catalysis due to their exceptional inherent reaction activity, optimal utilization of metal atoms, etc. Controlled synthesis plays a crucial role in elucidating the structure-activity relationship of SACs. This paper reviews various synthetic strategies for SACs, encompassing defect engineering, metal-organic frameworks (MOFs) pyrolysis, and ion exchange. With specific examples, the significance of constructing catalysts at the atomic level is discussed, aiming to comprehensively understand the synthetic strategies of SACs. Finally, it addresses the challenges and prospects associated with controlled synthesis techniques for SACs as well as their future applications.

关键词： Single-atom catalyst Synthetic strategy Carbon support Oxygen reduction reaction

Synthesis and electrochemical properties of a chiral silyl-substituted tetrathiafulvalene derivative

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Chinese Chemical Letters 2014年第4期25卷 579-582页

作者： Guo-Qi Liang Zhong-Bao Zhang Hong-Qi Li ya-ping wang Chun-Ying Xian College of Chemistry Chemical Engineering and BiotechnologyDonghua University

A new chiral tetrathiafulvalene （TTF） derivative and related silyl-substituted 1,3-dithiole-2-（thi）one compounds were synthesized and characterized by 1H NMR, 13C NMR, MS and IR spectra. Single crystal structure of the silyl-substituted 1,3-dithiole-2-one revealed the high degree of conjugation of the five- membered ring moiety in the compound. The electrochemical properties of the new TTF derivative were studied by cyclic voltammetry and the results indicated that the electron-donating ability of the chiral TI＂F derivative was similar to that of BEDT-TTF. The AE value for the new TTF derivative was smaller than those for TTF and BEDT-TrF, indicative of decreased Coulombic repulsion in the dicationic redox state. Formation of charge-transfer （CT） complex between the new donor and electron acceptor 2,3-dichloro-5,6-dicvano-1,4-benzocluinone （DDO） was demonstrated.

关键词： Tetrathiafulvalene Chiral Silyl Electrochemistry

Bi2S3 nanofiber bunch for highly efficient CO2 electroreduction to formate at low overpotential

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Rare Metals 2024年第7期43卷 3391-3399页

作者： Li wang Wen-Ke Gui Shan Jiang Liang wang Jian-ping yang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua University Centre for Catalysis and Clean Energy Griffith UniversityGold Coast Campus

Electrochemical conversion of CO2into valuable chemicals represents a promising strategy to alleviate the environmental issues caused by excessive CO2levels in the *** this work,Bi2S3with different morphologies have b... 详细信息

关键词： Carbon dioxide