Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

作     者：WANG Chengbin LI Ping CHEN Dehong ZHANG Ruiyong WANG Lei ZONG Lingbo 

作者机构：College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042P.R.China College of Materials Science and EngineeringQingdao University of Science and TechnologyQingdao 266042P.R.China Key Laboratory of Marine Environmental Corrosion and Bio-foulingInstitute of OceanologyChinese Academy of SciencesQingdao 266071P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2024年第40卷第3期

页      面：462-474页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(No.52172208) the Taishan Scholar Young Talent Program,China(No.tsqn202306216) the Taishan Scholar Talent Program,China(No.ts20190402) 

主　　题：Single-atom catalyst Synthetic strategy Carbon support Oxygen reduction reaction 

摘      要：Single-atom catalysts (SACs) have garnered extensive attention in the field of catalysis due to their exceptional inherent reaction activity, optimal utilization of metal atoms, etc. Controlled synthesis plays a crucial role in elucidating the structure-activity relationship of SACs. This paper reviews various synthetic strategies for SACs, encompassing defect engineering, metal-organic frameworks (MOFs) pyrolysis, and ion exchange. With specific examples, the significance of constructing catalysts at the atomic level is discussed, aiming to comprehensively understand the synthetic strategies of SACs. Finally, it addresses the challenges and prospects associated with controlled synthesis techniques for SACs as well as their future applications.