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Interfaces engineering of heterostructured Ni Co P/Ni Fe LDH@CC for attaining high catalytic activity in long-lasting rechargeable Zn–air batteries

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Rare Metals 2024年第10期43卷 4961-4972页

作者： Xiao-Lin Hu Ji-chuan Fan Xiang Li Zhen-Kun Wu Yuan-yi Li Chao-he Xu School of Science Chongqing Key Laboratory of New Energy Storage Materials and DevicesChongqing University of Technology JINSHAN Science&Technology (Group) Co. Ltd. National Engineering Research Center for Magnesium Alloys Chongqing University College of Aerospace Engineering Chongqing University

Zinc-air batteries (ZABs) offer tremendous potential in various industries and daily life due to their excellent energy density,safety and ***,the practical application of ZABs has been severely hindered by challenges such as high low round-trip efficiencies and overpotential,primarily attributed to the inherent sluggish kinetics in the oxygen evolution reaction(OER) of air *** address these issues effectively and economically,heterojunction engineering accompanied by interfacial chemistry emerges as an ideal approach to designing efficient OER ***,a novel heterogeneous interfacial chemical structure,namely NiCoP/NiFe LDH (layered double hydroxide),needle-like NiCoP and NiFe LDH nanosheets were assembled from cores and shells,***,the NiCoP/NiFe LDH-based ZABs have an exceptionally long cycle life of 238 h,far superior to Pt/C+Ir/C batteries (～97 h).Theoretical calculations and experimental results demonstrate that NiCoP/NiFe LDH possesses tunable interfacial chemistry,demonstrating significant electronic,coordination,geometric and synergistic *** enhancements dramatically improve the active site density,intrinsic activity and electrochemical durability of the *** summary,this work provides a solid foundation for the development of costeffective OER electrocatalysts for electrochemical energy devices.

关键词： Coupling effects Interface catalysis Oxygen evolution reaction Theoretical simulation Zinc–air batteries

Optical responses of metallic plasmonic arrays under the localized excitation

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Nano Research 2024年第3期17卷 1571-1577页

作者： Sen Yan Hao Ma yi-Fan Bao Maofeng Cao chuan Liu Kaifeng Zhang Xiaowei Wu Jianbo he Xiang Wang Bin Ren State Key Laboratory of Physical chemistry of Solid Surfaces Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(IKKEM) Xiamen 361005China Research&Development Group HitachiLtd.Yokohama 244-0817KanagawaJapan department of Electronic Science and Engineering Kyoto UniversityKyoto 615-8510Japan

The metallic plasmonic array that can support both propagating surface plasmon polaritons(PSPPs)and localized surface plasmon resonance(LSPR)possesses rich optical properties and remarkable optical performance,making it a powerful platform for applications in photonics,chemistry,and *** practical applications,the excitation spot is usually smaller than the area of metal *** is thus imperative to address“how many array units are enough?”towards a rational design of plasmonic ***,we employed focused ion beam(FIB)to precisely fabricate a series of plasmonic array structures with increased unit *** utilizing photoluminescence(PL)and surface-enhanced Raman spectroscopy(SERS),we found that the array units outside the excitation spot still have a significant impact on the optical response within the *** with the numerical simulation,we found that the boundary of the finite array leads to the loss of PSPP outside the excitation point,which subsequently affects the coupling of PSPP and LSPR in the excitation spot,leading to variations in PL and SERS *** on the findings,we further tuned the LSPR mode of the metal arrays by electrodeposition to obtain strong near-field enhancement without any influence on the PSPP *** work advances the understanding of near-field and far-field optical behavior in finite-size array structures and provides guidance for designing highly-efficient photonic devices.

关键词： plasmonic periodic array finite-size effects dark field scattering surface-enhanced Raman spectroscopy(SERS)

Fine Sand and Clay Sediment Acoustic Properties of the Novel Sediment Sample from the Arabian Sea:Experimental Investigations and Biot−Stoll Model Validation

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China Ocean Engineering 2024年第1期38卷 169-180页

作者： Shahabuddin SHAIKH HUANG yi-wang ZHANG Ze-chuan Habib Hussain ZUBERI National Key Laboratory of Underwater Acoustic Technology and College of Underwater Acoustic Engineering Harbin Engineering UniversityHarbin 150001China

The present study explores the physical and acoustic characteristics of fine sand and clay in novel seabed marine sediments from of Pakistan coastline of the Arabian *** measured physical parameters included mean grain size,mass density,bulk density,salinity,porosity,permeability,pore size and mineralogical *** properties,including sound speed and attenuation,in the high frequency range of 90-170 kHz were analyzed.A controlled laboratory setup with the acoustic transmission method and Fourier transform techniques was utilized to examine the sound propagation and absorption of novel seabed *** standard deviation of mean sound speed in fresh water was 0.75 m/s,and attenuation was observed in the range of 0.43 to 0.61 dB/*** mean sound velocity in sand and clay varied from 1706 to 1709 m/s and 1602 to 1608 m/s,*** average attenuation was observed at 80 to 93 dB/m in sandy sediments and from 31.8 to 38.6 dB/m in clayey *** velocity variation within sandy sediment is low,consistent with expected results,and smaller than the predicted ***,clay sediment exhibited a positive linear correlation and low sound speed *** increased linearly with frequency for both ***,the laboratory results were validated by using the Biot−Stoll *** dispersion of sound speed in sandy and clayey sediments was consistent with the predictions of the Biot−Stoll *** attenuation aligned more with Biot−Stoll model predictions due to improved permeability,tortuosity and pore size parameter fitting.

关键词： physical and acoustic characteristics marine sediments sound speed attenuation Biot−Stoll model

Evaluation on cutting performance of novel PDC cutter for pipe jacking machine

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Underground Space 2024年第1期14卷 34-52页

作者： Long-chuan Deng yi-Xiang Yuan Xiao-Zhao Li Qian-Wei Zhuang Chi Zhang yi-Wei Chen School of Earth Sciences and Engineering Nanjing UniversityNanjingJiangsu 210023China Shanghai Tunnel Engineering Co.Ltd. Shanghai 200232China State Key Laboratory for Geomechanics and Deep Underground Engineering China University of Mining and TechnologyXuzhouJiangsu 221116China School of Mechanics and Engineering Science Shanghai UniversityShanghai 200444China

It is inevitable to cut reinforced concrete(RC)appeared in cross passage of city metro by cutting tools when constructing in densely populated *** previous cutters employed to cut RC are insufficient and easily damaged,so a new polycrystalline diamond compact(PDC)cutter is used to solve this *** on the theoretical analysis of cutting mechanism,both circular and tapered PDC cutters with cutting edge angle of 90and negative front rack angle of 10are used to cut *** peeling and breaking patterns of cutting concrete are proposed,the nodular and grainy chips are the preferred modes in cutting steel *** LS-DYNA is employed to investigate the cutting performance in *** simulation results show that the average and peak cutting forces increase with the growth of penetration depth,cutting speed,and roundness,and subsequently the recommended penetration depth less than 1.2 mm is obtained to cut RC due to the existence of steel ***,the linear cutting platform is adopted to investigate the force ability and damage state of PDC *** is concluded that the cutting force increases abruptly and fluctuates heavily when cutting the coarse *** patterns occurred in both numerical and experimental results are generally ***,the steel bar is pulled out and the PDC cutter is damaged at the penetration depth of 0.8 mm,while a good cut occurs at the penetration depth of 0.3 *** tapered PDC cutter with a relatively low cutting force is prone to be broken compared with circular PDC *** is suggested that the circular PDC cutter at the penetration depth of 0.3 mm should be used to cut RC in practical engineering.

关键词： PDC cutter RC Pipe jacking machine Linear cutting tests Damage and wear LS-DYNA

Hot Compression Behavior and Tensile Property of a Novel Ni-Co-Based Superalloy Prepared by Electron Beam Smelting Layered Solidification Technology

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Acta Metallurgica Sinica(English Letters) 2024年第2期37卷 283-292页

作者： Yong-Chao Gai Rui Zhang chuan-Yong Cui Zi-Jian Zhou yi Tan yi-Zhou Zhou Xiao-Feng Sun Key Laboratory of Materials Modification by Laser Ionand Electron Beams(Ministry of Education)School of Materials Science and EngineeringDalian University of TechnologyDalian116024China Shi-Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China

The hot compression behavior and tensile strength after compression of a new Ni-Co-based superalloy produced using electron beam smelting layered(EBSL)solidification technology were *** compression tests were performed at temperatures of 1120℃and 1150℃,with strain rates of 1 s^(-1) and 0.01 s^(-1),reaching a true strain of *** strength was evaluated at room *** results revealed that this EBSL technology accelerates dynamic recrystallization(DRX),without compromising the strength of alloy.A significant correlation between the volume fraction of DRX and the strain rate was observed,with higher fractions at lower strain rates,leading to higher tensile ***,at the same strain rate,the specimens compressed at 1120℃exhibited higher tensile strength due to undissolvedγ′*** solution and aging heat treatment,the alloy maintained high tensile *** results suggested that the EBSL Ni-Co-based superalloy offers excellent prospects for practical applications.

关键词： Ni-Co-based superalloy Hot deformation Electron beam smelting Tensile strength

Enhancing MXene-based supercapacitors:Role of synthesis and 3D architectures

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Journal of Energy chemistry 2024年第4期91卷 1-26页

作者： Wen Siong Poh Wen Jie yiang Wee-Jun Ong Pau Loke Show chuan yi Foo School of Energy and Chemical Engineering Xiamen University MalaysiaSelangor Darul EhsanMalaysia&College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005FujianChina Kelip-kelip!Center of Excellence for Light Enabling Technologies Xiamen University MalaysiaSelangor Darul Ehsan 43900Malaysia Center of Excellence for NaNo Energy&Catalysis Technology(CONNECT) Xiamen University MalaysiaSelangor Darul Ehsan 43900Malaysia department of Chemical Engineering Khalifa UniversityShakhbout Bin Sultan St-Zone 1Abu DhabiUnited Arab Emirates Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou UniversityWenzhou 325035ZhejiangChina department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of Nottingham MalaysiaJalan Broga43500 SemenyihSelangor Darul EhsanMalaysia department of Sustainable Engineering Saveetha School of EngineeringSIMATSChennai 602105India

MXene has been the limelight for studies on electrode active materials,aiming at developing supercapacitors with boosted energy density to meet the emerging influx of wearable and portable electronic *** its various desirable properties including intrinsic flexibility,high specific surface area,excellent metallic conductivity and unique abundance of surface functionalities,its full potential for electrochemical performance is hindered by the notorious restacking phenomenon of MXene *** to its two-dimensional(2D)nature and surface functional groups,inevitable Van der Waals interactions drive the agglomeration of nanosheets,ultimately reducing the exposure of electrochemically active sites to the electrolyte,as well as severely lengthening electrolyte ion transport *** a result,energy and power density deteriorate,limiting the application versatility of MXene-based *** 3D architectures using 2D nanosheets presents as a straightforward yet ingenious approach to mitigate the fatal flaws of ***,the sheer number of distinct methodologies reported,thus far,calls for a systematic review that unravels the rationale behind such 3D MXene structural ***,this review aims to serve this purpose while also scrutinizing the structure–property relationship to correlate such structural modifications to their ensuing electrochemical performance ***,the physicochemical properties of MXene play fundamental roles in determining the effective charge storage capabilities of 3D MXene-based *** largely depends on different MXene synthesis techniques and synthesis condition variations,hence,elucidated in this review as ***,the challenges and perspectives for achieving viable commercialization of MXene-based supercapacitor electrodes are highlighted.

关键词： MXene 3D architectures Synthesis design Supercapacitor Energy storage

Electro-reductive carboxylation of acyclic C(sp^(3))–C(sp^(3))bonds in aromatic hydrocarbons with CO_(2)

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Science China chemistry 2024年第10期67卷 3366-3372页

作者： chuan-Kun Ran Quan Qu Yang-yi Tao yi-Fei Chen Li-Li Liao Jian-heng Ye Da-Gang Yu Key Laboratory of Green chemistry&Technology of Ministry of Education College of ChemistrySichuan UniversityChengdu 610064China West China School of Public health and West China Fourth Hospital Sichuan UniversityChengdu 610064China

Despite the recent advances in the selective functionalization of C–C bonds in specific substrates,cleavage and functionalization of C–C bonds in acyclic substrates,such as ethane derivatives,remains *** contrast to the well-developed functionalization of one carbon fragment after C–C bond cleavage,herein,we report a novel electro-reductive carboxylation of C(sp^(3))–C(sp^(3))bond in multi-aryl ethanes with carbon dioxide(CO_(2))by utilizing both carbon ***,this reaction exhibits an atom-,step-economic approach for the synthesis of carboxylic acids,fulfilling principal aspirations of organic ***,this method features mild reaction conditions,broad substrate scope,and good functional group *** and asymmetric substrates bearing primary,secondary,or tertiary C(sp^(3))–C(sp^(3))bonds are all amenable to this strategy,enabling one or two structurally different carboxylic acids to be facilely constructed at the same *** investigations indicate that carbanions might be the key intermediates in this reaction,which could be captured by CO_(2)efficiently.

关键词： carbon dioxide electrochemistry C(sp^(3))–C(sp^(3))bonds cleavage reductive carboxylation

Does type 1 diabetes serve as a protective factor against inflammatory bowel disease:A Mendelian randomization study

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World Journal of Diabetes 2024年第7期15卷 1551-1561页

作者： Ke-Ke Tong Yun-Feng Yu Xin-Yu Yang Jing-yi Wu Rong Yu chuan-chuan Tan The First Hospital of Hunan university of Chinese Medicine Changsha 410007Hunan ProvinceChina School of Traditional Chinese Medicine Hunan University of Chinese MedicineChangsha 410208Hunan ProvinceChina The Third Hospital Zhejiang Chinese Medical UniversityHangzhou 310005Zhejiang ProvinceChina

BACKGROUND The impact of type 1 diabetes(T1D)on inflammatory bowel disease(IBD)remains *** To analyze the causal relationship between T1D and IBD using Mendelian randomization(MR).METHODS Single nucleotide polymorphisms were sourced from FinnGen for T1D,IBD,ulcerative colitis(UC)and Crohn’s disease(CD).Inverse variance-weighted,MREgger,and weighted median tests were used to assess exposure-outcome *** MR-Egger intercept was used to assess horizontal ***’s Q and leave-one-out method were used to analyze heterogeneity and sensitivity,*** Our MR analysis indicated that T1D was associated with a reduced risk of IBD[odds ratio(OR):0.959;95%confidence interval(CI):0.938-0.980;P1]and UC(OR:0.960;95%CI:0.929-0.992;P=0.015),with no significant association observed in terms of CD risk(OR:0.966;95%CI:0.913-1.022;P=0.227).The MR-Egger intercept showed no horizontal pleiotropy(P>0.05).Cochran’s Q and leave-one-out sensitivity analyses showed that the results were not heterogeneous(P>0.05)and were *** This MR analysis suggests that T1D serves as a potential protective factor against IBD and UC but is independent of CD.

关键词： Type 1 diabetes Inflammatory bowel disease Ulcerative colitis Crohn’s disease Mendelian randomization

Displacement-pressure biparametrically regulated softness sensory system for intraocular pressure monitoring

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National Science Review 2024年第6期11卷 159-168页

作者： Yu Cheng yifei Zhan Fangyi Guan Junli Shi Jingxiao Wang yi Sun Muhammad Zubair Cunjiang Yu chuan Fei Guo department of Materials Science and Engineering Southern University of Science and Technology department of Engineering Science and Mechanics Pennsylvania State University department of Biomedical Engineering Pennsylvania State University department of Materials Science and Engineering Materials Research Institute Pennsylvania State University

High intraocular pressure(IOP) is one of the high-risk pathogenic factors of glaucoma. Existing methods of IOP measurement are based on the direct interaction with the cornea. Commercial ophthalmic tonometers based on snapshot measurements are expensive, bulky, and their operation requires trained *** contact lenses are easy to use, but they may block vision and cause infection. here, we report a sensory system for IOP assessment that uses a soft indentor with two asymmetrically deployed iontronic flexible pressure sensors to interact with the eyelid-eyeball in an eye-closed situation. Inspired by human fingertip assessment of softness, the sensory system extracts displacement-pressure information for soft evaluation, achieving high accuracy IOP monitoring(>96%). We further design and custom-make a portable and wearable ophthalmic tonometer based on the sensory system and demonstrate its high efficacy in IOP screening. This sensory system paves a way towards cost-effective, robust, and reliable IOP monitoring.

关键词： intraocular pressure tonometer deep learning softness iontronic sensor