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Interfacial modulation of bifunctional electrolyte additive engineering for dendrite-free and robust lithium metal anode

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Journal of Energy Chemistry 2024年第10期97卷 120-127,I0003页

作者： Mahammad Rafi Shaik yongmin Park young-Kwang jung Won Bin Im Division of Materials Science and Engineering Hanyang University222Wangsimni-roSeongdongguSeoul 0473Republic of Kor Department of Chemical Engineering and Biotechnology University of CambridgeCambridge CB3 OASUK

Anode materials for rechargeable electric car batteries are obtained from Li-metal owing to their extremely high specific capacity and low redox ***,safety concerns related to dendrite formation on the anode surface caused by the uneven distribution of Li-ions during the discharge process interfere with the use of Li-metal in industrial *** this study,methyl vinyl sulfone(MVS),a sulfone-based functional electrolyte additive,is used in an additive engineering strategy to control Lielectrolyte interactions and address the aforementioned *** dendrite growth may be restricted,and transition metal degradation on the surface of the cathode can be reduced by the MVS-derived functional electrolyte additive interfacial *** electrochemical performance of an ethylene carbonate/dimethyl carbonate(EC/DMC)+1 wt% MVS Li-metal anode of a Li||Li symmetric cell exhibits remarkable cycle stability,maintaining a low overvoltage for over 750 h at 1 mA cm^(-2),and capacity of 1 mA h cm^(-2).Additionally,LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) full cells with the MVS additive exhibit enhanced electrochemical stability for 250 cycles at a current density of 100 mA g^(-1).This study provides an innovative approach for stabilizing the metal-electrolyte interfacial layer that may be used for practical applications in metal-based rechargeable batteries.

关键词： Lithium rechargeable battery Dendrite-free Electrolyte additive Bifunctional electrolyte Interfacial layer

Current status and recent advances on the use of ultrasonography in pediatric rheumatic diseases

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World Journal of Pediatrics 2020年第1期16卷 52-59页

作者： Li-Xia Zou Mei-Ping Lu Lawrence Kwok Leung jung Department of Rheumatology Immunology and Allergy Children's HospitalZhejiang University School of Medicine57 Zhugan LaneHangzhou 310003China Division of Rheumatology Children's National Medical Center in Washington D.C.111 Michigan Avenue NWWashingtonD.C.20010USA

Background Ultrasonography has become a useful tool in the clinical rheumatology settings in the last two decades,but its use has only recently been explored by pediatric *** aim of this article is to review the literature on the current status and recent advances on the use of ultrasound in pediatric rheumatic *** sources We have retrieved and reviewed the relevant articles from MEDLINE/PubMed databases published so far,on the applications of ultrasound in juvenile idiopathic arthritis(JIA),systemic lupus erythematosus,dermatomyositis,enthesitis,Sjogren's syndrome,and other rheumatic *** addition,articles on novel ultrasound imaging technology of potential use in pediatric rheumatology are also *** In JIA,ultrasound can be used to detect subclinical synovitis,to improve the classification of patients in JIA subtypes,to capture early articular damage,to monitor treatment response,and to guide intraarticular *** is also considered useful in other rheumatic disorders for the evaluation of musculoskeletal symptoms,assessment of parotid gland pathology,and measurement of skin thickness and *** ultrasound techniques developed to augment the functionality of ultrasonography may also be applicable in pediatric rheumatic *** Ultrasound shows great promise in the assessment and management of children with rheumatologic ***,standardization and validation of ultrasound in healthy children and in patients with rheumatic diseases are still needed.

关键词： Dermatomyositis Juvenile arthritis Lupus Pediatric rheumatic diseases Sonoelastography Ultrasound

Customized 3D-printed occluders enabling the reproduction of consistent and stable heart failure in swine models

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Bio-Design and Manufacturing 2021年第4期4卷 833-841页

作者： han B.Kim Seungman jung hyukjin Park Doo S.Sim Munki Kim Sanskrita Das youngkeun Ahn Myung h.Jeong Jinah Jang young J.hong Division of Cardiology Chonnam National University Medical SchoolGwangjuRepublic of Korea School of Interdisciplinary Bioscience and Bioengineering Pohang University of Science and TechnologyPohangRepublic of Korea Department of Creative IT Engineering Pohang University of Science and TechnologyPohangRepublic of Korea Department of Mechanical Engineering Pohang University of Science and TechnologyPohangRepublic of Korea

Reproducibility of clinical output is important when investigating therapeutic efficacy in pre-clinical animal *** to its physiological relevance,a swine myocardial infarction(MI)model has been widely used to evaluate the effectiveness of stem cells or tissue-engineered constructs for ischemic heart *** methods are used to induce MI in the swine ***,it is difficult,using these approaches,to obtain a similar level of functional outcomes from a group of animals due to interpersonal variation,leading to increased experimental ***,in order to minimize human intervention,we developed an approach to use a customized occluder that has dimensional similarities with that of the coronary artery of animals in the case of the swine *** carried out angiography to measure the diameter of the middle left anterior descending artery of each individual animal to fabricate the customized occluder using a 3D-printing *** fabricated occluder contained a central hole smaller than that of the targeted middle left anterior descending artery to mimic an atherosclerotic coronary artery that has an approximately 20%blocked ***,the 3D-printed occluder can provide continuous blood flow through the central pore,indicating a high survival rate(88%)of up to 28 days *** method showed the possibility of creating consistent myocardial infarction induction as compared to the conventional representative closed-chest method(50%survival rate),thus highlighting how our method can have a profound effect on accelerating reliable experiments for developing new therapeutic approaches to ischemic heart diseases.

关键词： 3D bioprinting Myocardial infarction Ischemic heart failure Swine model Left anterior descending artery

Electrochemical Water Splitting:Bridging the Gaps Between Fundamental Research and Industrial Applications

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Energy & Environmental Materials 2023年第5期6卷 22-42页

作者： hainan Sun Xiaomin Xu hyunseung Kim WooChul jung Wei Zhou Zongping Shao Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Korea WA School of Mines:Minerals Energy and Chemical Engineering(WASM-MECE) Curtin UniversityPerthWestern Australia 6102Australia State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China

Electrochemical water splitting represents one of the most promising technologies to produce green hydrogen,which can help to realize the goal of achieving carbon *** substantial efforts on a laboratory scale have been made for understanding fundamental catalysis and developing high-performance electrocatalysts for the two half-reactions involved in water electrocatalysis,much less attention has been paid to doing relevant research on a larger *** example,few such researches have been done on an industrial ***,we review the very recent endeavors to bridge the gaps between fundamental research and industrial applications for water *** begin by introducing the fundamentals of electrochemical water splitting and then present comparisons of testing protocol,figure of merit,catalyst of interest,and manufacturing cost for laboratory and industry-based water-electrolysis *** attention is paid to tracking the surface reconstruction process and identifying real catalytic species under different testing conditions,which highlight the significant distinctions of corresponding electrochemical reconstruction *** in catalyst designs for industry-relevant water electrolysis are also summarized,which reveal the progress of moving the practical applications forward and accelerating synergies between material science and *** and challenges of electrocatalyst design strategies are proposed finally to further bridge the gaps between lab-scale research and large-scale electrocatalysis applications.

关键词： electrocatalyst design electrochemical water splitting gaps and bridges laboratory scale and industrial scale

Clostridium difficile infection aggravates colitis in interleukin 10-deficient mice

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World Journal of Gastroenterology 2014年第45期20卷 17084-17091页

作者： Mi Na Kim Seong-Joon Koh jung Mogg Kim Jong Pil Im hyun Chae jung Joo Sung Kim Seoul National University healthcare System Gangnam Center Seoul National University Hospital Department of Internal Medicine Seoul National University Boramae Hospital Seoul National University College of Medicine Department of Microbiology Hanyang University College of Medicine Department of Internal Medicine Liver Research Institute Seoul National University College of Medicine

AIM: To investigate the effect of Clostridium difficile (C. difficile) infection in an interleukin 10-deficient (IL-10-/-) mouse model of inflammatory bowel disease.

关键词： Clostridium difficile Inflammatory bowel disease Interleukin 10-deficient mice Interferon-γ Colitis

Copper foam-derived electrodes as efficient electrocatalysts for conventional and hybrid water electrolysis

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Materials Reports(Energy) 2022年第2期2卷 3-20页

作者： hainan Sun hyunseung Kim Sanzhao Song WooChul jung Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon34141Republic of Korea Wenzhou Institute University of Chinese Academy of SciencesWenzhouZhejiang325001China

Electrochemical water splitting has been demonstrated as a promising technology for the renewable generation of green hydrogen from *** the extensive progress in materials science,one particular challenge for further development towards industrial application lies in the rational design and exploitation of efficient and cost-effective materials,especially oxygen evolution reaction(OER)electrocatalysts at the *** addition,attempts to replace the OER with other more oxidizable anode reactions are being evaluated as a groundbreaking strategy for generating hydrogen at lower potentials and reducing overall energy costs while producing valuable chemicals *** with Fe/Co/Ni-based compounds,Cu-based materials have not received extensive research attention for electrode designs despite their high conductivity and abundant earth *** this review,combining with the advantages of a three-dimensional network structure of metal foams,we summarize recent progress on Cu foam(CF)-derived materials as efficient electrocatalysts towards pure water electrolysis and hybrid water *** advantages of CF and design strategies to enhance the electrocatalytic activity and operational durability are presented *** design and fabrication strategies are then highlighted and the structure-activity relationship is also ***,we propose challenges and perspectives on self-supported electrodes beyond CF-derived materials.

关键词： Conventional water electrolysis hybrid water electrolysis Cu foam Electrocatalysts hydrogen production Value-added chemicals

Advanced electrocatalysts with unusual active sites for electrochemical water splitting

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InfoMat 2024年第1期6卷 65-82页

作者： hainan Sun Xiaomin Xu hyunseung Kim Zongping Shao WooChul jung Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology(KAIST)DaejeonRepublic of Korea WA School of Mines:Minerals Energy and Chemical Engineering(WASM-MECE) Curtin UniversityPerthWestern AustraliaAustralia

Electrochemical water splitting represents a promising technology for green hydrogen *** design advanced electrocatalysts,it is crucial to identify their active sites and interpret the relationship between their structures and *** extensively studied as electrocatalysts include noble-metal-based(e.g.,Ru,Ir,and Pt)and non-noble-metal-based(e.g.,3d transition metals)***,advancements in characterization techniques and theoretical calculations have revealed novel and unusual active *** present review highlights the latest achievements in the discovery and identification of various unconventional active sites for electrochemical water splitting,with a focus on state-of-the-art strategies for determining true active sites and establishing structure–activity ***,we discuss the remaining challenges and future perspectives for the development of next-generation electrocatalysts with unusual active *** presenting a fresh perspective on the unconventional reaction sites involved in electrochemical water splitting,this review aims to provide valuable guidance for the future study of electrocatalysts in industrial applications.

关键词： electrochemical water splitting hydrogen evolution reaction oxygen evolution reaction structure–activity relationship unusual active sites

Synergistic Effect of Core/Shell‑Structured Composite Fibers:Efficient Recovery of Rare‑Earth Elements from Spent NdFeB Permanent Magnets

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Advanced Fiber Materials 2024年第6期6卷 1729-1745页

作者： youngkyun jung yun Lee Su‑Jin yoon Jae‑Woo Choi Center for Water Cycle Research Korea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea Department of Chemical and Biological Engineering Korea UniversitySeoul 02841Republic of Korea Department of Energy and Environment Technology KIST SchoolKorea University of Science and TechnologySeoul 02792Republic of Korea

NdFeB magnets are third-generation permanent magnets that are employed as indispensable components in various ***,rare-earth elements(REEs)such as Dy and Nd must be efficiently recovered from end-of-life magnets to enable resource circulation and reinforce unstable supply *** that end,this paper reports synergistically performing core/shell-structured composite fibers(CSCFs)containing sodium polyacrylate and nanoporous zeolitic imidazolate framework-8(NPZIF-8)nanocrystals as a readily recoverable adsorbent with an exceptional REE-adsorbing *** CSCF core forms an NPZIF-8 nanocrystal shell on the fiber surface as well as draws REEs using its dense sodium carboxylate groups into the NPZIF-8 nanocrystal lattice with high specific surface *** CSCFs exhibit significantly higher maximum adsorption capacities(468.60 and 435.13 mg·g-1)and kinetic rate constants(2.02 and 1.92 min-1)for the Nd3+and Dy3+REEs than those of previously reported REE ***,the simple application of the CSCFs to an adsorption reactor considerably mitigates the adsorbent-shape-induced pressure drop,thereby directly influencing the energy efficiency of the ***,the high REE-recovery ability,tractability,and recyclability of the CSCFs offers a pragmatic pathway to achieving cost-effective REE ***,this study provides new insights into designing synergistically performing core/shell architectures for feasible REE recovery.

关键词： Core/shell structures Fibrous adsorbents Synergistic adsorption Metal resource recovery Pressure drop Rare-earth elements

Effects of homogenization temperature on microstructure and mechanical properties of high-speed-extruded Mg–5Bi–3Al alloy

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Journal of Magnesium and Alloys 2022年第10期10卷 2833-2846页

作者： Jae Won Cha Sang-Cheol Jin Jae-Gil jung Sung hyuk Park School of Materials Science and Engineering Kyungpook National University80 DaehakroDaegu 41566Republic of Korea Advanced Metals Division Korea Institute of Materials ScienceChangwon 51508Republic of Korea

This study investigates the effects of billet homogenization temperature on the dynamic recrystallization behavior during high-speed extrusion and resultant microstructure and tensile properties of the Mg–5Bi–3Al(BA53,wt%)*** billets homogenized at 350 and450℃(350h and 450h billets)are extruded at a high speed of 69 m/*** 350h billet has a relatively smaller grain size and a higher abundance of fine Mg3Bi2particles compared to the 450h *** extrusion of the 350h billet,enhanced dynamic recrystallization occurs as a result of its finer grains and abundance of particles,while the growth of recrystallized grains is suppressed by the grain-boundary pinning effect of ***,the extruded 350h material is characterized by smaller grains,relatively greater number of Mg3Bi2particles,and a higher internal strain energy than the extruded 450h *** tensile strength of the extruded 350h material is higher than that of the extruded 450h material owing to stronger grain-boundary hardening,particle hardening,and strain hardening *** extruded 350h material also exhibits a higher tensile elongation as its smaller grains inhibit the formation of crack-inducing undesirable twins during *** results from this study demonstrate that a decrease in the homogenization temperature from 450 to 350℃leads to improved strength and ductility in the high-speed-extruded BA53 material.

关键词： Mg–Bi–Al alloy high-speed extrusion homogenization Dynamic recrystallization Tensile properties