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Journal of Wuhan University of technology(Materials science) 2024年第5期39卷 1214-1222页

作者： xiong Kun SHANG Xiaopeng LI Hongyan WANG Dan Zhengzhou Lutong Highway Construction Co. Ltd.Zhengzhou 450052China (Special Glass key lab of Hainan Province)&(State key laboratory of Marine Resource Utilization in South China Sea) Hainan UniversityHaikou 570228China Department of Architectural Engineering Shandong Urban Construction Vocational CollegeJinan 250103China (State key laboratory of High Performance Civil Engineering Materials Jiangsu Sobute New Materials Co.Ltd.)&(School of Material Science and EngineeringSoutheast UniversityNanjing 211189China)

Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and product evolution for CO_(2)curing at various water-to-solid *** pure minerals were synthesized and subject to CO_(2)curing in this study to make an in-depth understanding for the carbonation properties of cement-based *** showed that the optimum water-to-solid ratios of C_(3)S,β-C_(2)S,C_(3)A and C_(4)AF were 0.25,0.15,0.30 and 0.40 for carbonation,corresponding to 2 h carbonation degree of 38.5%,38.5%,24.2%,and 21.9%,*** produced calcite duringβ-C_(2)S carbonation decreased as the water-to-solid ratio increased,with an increase in content of metastable CaCO_(3)of vaterite and *** thermodynamic stability of CaCO_(3)produced during carbonation was C_(3)A>C_(4)AF>β-C_(2)S>C_(3)*** carbonation degree of Portland cement was predicted based on the results of pure minerals and the composition of cement,and the error of predicted production of CaCO_(3)was only 1.1%,which provides a potential method to predict carbonation properties of systems with a complex mineral composition.

关键词： accelerated carbonation portland cement calcium carbonate water-to-solid ratio

Effect of Powder Particle Size on the Properties and Microstructure of Ti(C,N)-Based Cermet

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Rare Metals 2001年第1期20卷 47-51页

作者： Yong Zheng, Weihao xiong (key State laboratory of Die technology, Huazhong University of science and technology, Wuhan 430074, China) Huazhong Univ Sci & Technol Key State Lab Die Technol Wuhan 430074 Peoples R China

The influence of raw powder particle size on the properties and microstructures of Ti (C, N)-based cermets has been studied. The conclusions are as follows: The microstructures of cermets were composed of two kinds of grains, the one with black cores surrounded by obvious rim structures, and the other whose cores were white with unconspicuous rim structures and adhesive phase. In the cermet made from fine powders, the amount of grains with white cores was much more than that in cermet made from coarse powders. In addition, their properties were also much better.

关键词： Ti(C, N)-based cermet powder particle size property microstructure

Constrained oscillation of a bubble subjected to shock wave in microvessel

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Progress in Natural science:Materials International 2009年第9期19卷 1109-1117页

作者： Farong Gao, Caihua xiong *, Youlun xiong Institute of Rehabilitation and Medical Robotics, State key lab of Digital Manufacturing Equipment and technology, School of Mechanical science and Engineering, Huazhong University of science and technology, Wuhan 430074, China [a]Institute of Rehabilitation and Medical Robotics State Key Lab of Digital Manufacturing Equipment and Technology School of Mechanical Science and Engineering Huazhong University of Science and Technology Wuhan 430074 China

A three-phase coupled model of the gasliquid-solid oscillation system is established to analyze the oscillation characteristics of a bubble inside a micro blood vessel with various radii and its shape changes with different interface boundaries. The results show that unlike the spherical symmetric oscillation in an unbounded fluid, the oscillating bubble has significant asymmetric characteristics under the constraint of a fiexible microvessel, especially while its radius reduces to the same order of magnitude as that of the bubble. Moreover, the variation of microbubble motion, whether the geometric shape or oscillation feature, exhibits obvious differences in the micro blood vessel compared with the rigid wall. The reasons behind these phenomena are analyzed in this paper. The conclusions have significant importance in the understanding of the mechanism of microvessel injury in ultrasound therapy.

关键词： Asymmetric oscillation Microbubble Shock wave Micro blood vessel Boundary effects

Ballistic performance of spaced multi-ply soft fabrics: Experimental and numerical investigation

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Defence technology（防务技术） 2024年第4期34卷 143-155页

作者： Zhongwei Zhang Xiaoning yang Yuan Lin Ziming xiong Yuhang Xiang Yi Zhou Mingyang Wang State key laboratory of Explosion&Impact and Disaster Prevention&Mitigation Army Engineering University of PLANanjing 210007China School of Mechanical Engineering Nanjing University of Science&TechnologyNanjing 210007China State key laboratory of New textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China Postdoctoral Station of Civil Engineering Army Engineering University of PLANanjing 210007China

It has been reported that the ply gap influences the ballistic resistance of spaced multi-ply fabric systems,but its working mechanism was not well-understood. This paper reports the experimental and numerical approaches and results of an investigation on the mechanisms that enable the improved ballistic performance of spaced multi-ply systems. Penetration tests were performed over a range of impact velocities ranging from 200 m/s to 400 m/s. The results confirmed that the ply gap is beneficial to the energy absorption capability of the systems. This is because the front plies tend to absorb more energy when they are not immediately constrained by the rear plies. During a ballistic event, the gap relieves the reflection of the compressive pulse, prolonging the projectile engagement time with the front plies;on the other hand, the rear plies become increasingly less active in dissipating energy as the gap *** the gap is sufficiently widened to avoid any interference between the plies before the failure of the front ply, the responses of the whole system no longer vary. It was also found that the ballistic performance of the spaced systems is influenced by ply thickness, impact velocity, and the stacking order of the ply gap.

关键词： Energy absorption capability Ply gap Ballistic performance The front ply The rear ply

Protein hydrogels for biomedical applications

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Biosurface and Biotribology 2024年第3期10卷 106-131页

作者： Xinyi Wang Yue Hou xiong Lu Chaoming Xie yanan Jiang Institute of Biomedical Engineering College of MedicineSouthwest Jiaotong UniversityChengduSichuanChina key lab of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengduSichuanChina Obesity and Metabolism Medicine-Engineering Integration laboratory Department of General SurgeryThe Third People's Hospital of ChengduThe Affiliated Hospital of Southwest Jiaotong UniversityChengduSichuanChina

Hydrogels,characterised as highly hydrophilic three-dimensional polymer networks,have gained increasing attention due to their unique physicochemical properties,finding applications in various *** polymer hydrogels exhibit higher biocompatibility and biodegradability compared to traditional synthetic polymer ***,being the principal materials of natural polymer hydrogels,bear numerous modifiable functional *** resultant hydrogel possesses responsiveness,adjustable degradability,and underway as an excellent *** common raw materials used to construct protein hydrogels are *** terms of comparing natural polymer hydrogels with traditional synthetic polymer hydrogels,the authors conduct a detailed analysis and comparison,highlighting the advantages of natural polymer hydrogels in terms of biocompatibility and biodegradability,and summarising their *** authors also address the limitations of various protein hydrogels and list existing strengthening cross-linking strategies,proposing new insights to overcome the application limits of protein ***,the applications of protein hydrogels in drug delivery,biosensing,bio-inks and tissue engineering are *** authors conclude by summarising the current challenges faced by protein hydrogels and prospecting its future development.

关键词： biomaterials biomedical application

Positron Annihilation Study on TiC Powders

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Rare Metals 2001年第2期20卷 91-94页

作者： Yaobo Hu, Weihao xiong, Zhi Mei, Kun Cui (National key laboratory of Dieie & Mould technology, Huazhong University of science & technology, Wuhan 430074, China) Huazhong Univ Sci & Technol Natl Key Lab Die & Mould Technol Wuhan 430074 Peoples R China

By means of the positron annihilation technique (PAT), superfine TiC powders obtained by ball-milling process were characterized. The results showed that there was a clear correlation between the change in TiC powders and that in the PAT parameters. In the high energy ball-milling process, TiC powders were severely deformed, which caused large increase in the amount of defects and severe distortion of lattice. On the other hand, the extreme refinement of grain size of powders resulted in the increase of grain boundary area and enhancement of system free energy. The spacing between deformed domains in 96 h milled samples is somewhat smaller than those in 48 h milled samples, indicating the size of Type II defects in 96 h milled samples is somewhat smaller than that in 48 h milled samples.

关键词： positron annihilation technique TiC powders defects lifetime lattice

Bimolecular reduction of carbon dioxide: double synthons for alkynes trifunctionalization

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science China Chemistry 2024年第3期67卷 841-847页

作者： Wenfang xiong Xiaobin Tan Hongjian Liu Baiyao Zhu Jinwu Zhao Jianxiao Li Chaorong Qi Huanfeng Jiang School of Pharmacy Guangdong Medical UniversityDongguan 523808China key lab of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China

Carbon dioxide reduction, as a sustainable and versatile strategy for the access of chemical fuels, has attracted increasing attention and enormous efforts have been devoted to it in recent years. However, employing carbon dioxide as double synthons via bimolecular reduction remains challenging. Here, by leveraging the bimolecular reduction of carbon dioxide to carbonyl and methyl respectively, we describe a Pd-catalyzed trifunctionalization of alkynes with aryl iodide for the first time and showcase its advantages on the formation of various β-diketones and their application in the constructing of heterocyclic compounds with important biological activity, including pyrimidine, oxazole, pyrazole.

关键词： carbon dioxide bimolecular reduction trifunctionalization double synthons

Bimetallic NiCoP catalysts anchored on phosphorus-doped lignin-based carbon for robust oxygen evolution performance

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Rare Metals 2024年第7期43卷 3084-3095页

作者： Ling-Ying-Zi xiong Bo-Wen Liu Lei Du Yue-Kuan Zhou Xu-Liang Lin Huan Wang Guangdong Engineering technology Research Center for Sensing Materials&Devices Guangzhou Key Laboratory of Sensing Materials&DevicesSchool of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou 510006China School of Chemical Engineering and Light Industry Guangdong University of TechnologyGuangzhou 510006China Guangdong Provincial laboratory of Chemistry and Fine Chemical Engineering Jieyang Center Jieyang 515200China Sustainable Energy and Environment Thrust Function HubThe Hong Kong University of Science and Technology(Guangzhou)Guangzhou 511400China Division of Emerging Interdisciplinary Areas Department of Mechanical and Aerospace EngineeringThe Hong Kong University of Science and TechnologyHong Kong 999077China State key lab of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640China

Oxygen evolution reaction(OER)catalysts are the key core materials that determine the performance of fuel cells,metal-air batteries,electrolytic water decomposition,and other *** this work,a green lignin-based non-precious metal OER catalyst was prepared by a simple ***,c arboxylated lignin was used to complex Ni and Co in situ,and then they were placed with sodium hypophosphite in the same tube furnace for upstream and downstream high-temperature calcination to construct a lignin carbon-based Ni-Co bimetallic OER catalyst(NiCoP@C).The synthesized catalyst is a porous bimetallic phosphide with a three-dimensional network structure and high-density electrochemical active ***@C exhibited favorable catalytic activity for the oxygen evolution reaction(OER)with overpotential of 280 mV at 10 mA·cm~(-2)and a Tafel slope of 77 mV·dec~(-1).Additionally,it exhibited remarkable durability during *** functional theory(DFT)calculations revealed that by leveraging the distinctive structure of transition metal phosphide nanoparticles incorporated into a reticulated substrate,the NiCoP@C catalyst offered an increased number of active sites for OER catalysis,significantly enhancing its stability during practical *** present study broadens the utilization pathways of biomass to"turn waste into treasure,"aligning the development concept of green sustainable development.

关键词： Oxygen evolution reaction Lignin Carbon-based catalyst Nickel-cobalt bimetal Metal phosphide

Effect of oxide interactions on chromium speciation transformation during simulated municipal solid waste incineration

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Journal of Environmental sciences 2024年第8期142卷 11-20页

作者： Guodong Zhao Chong Tian Peidong Wu Xuguang Zhang Zhikang Wang Xiaoxiang Chen Zhuo xiong Yongchun Zhao Junying Zhang State key laboratory of Coal Combustion School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Power and Mechanical Engineering Wuhan UniversityWuhan 430072China National Environmental Protection Engineering technology Center for Trace Elements Pollution Control and Low Carbon Utilization of Coal Huazhong University of Science and TechnologyWuhan 430074China School of Environmental Engineering Wuhan Textile UniversityWuhan 430200China

Chromium released during municipal solid waste incineration(MSWI)is toxic and *** removal of chromium from simulated MSWI flue gas by four sorbents(CaO,bamboo charcoal(BC),powdered activated carbon(PAC),and Al_(2)O_(3))and the effects of four oxides(SiO_(2),Al_(2)O_(3),Fe_(2)O_(3),and CaO)on chromium speciation transformationwere *** results showed that the removal rates of total Cr by the four sorbents were Al_(2)O_(3)

关键词： Cr(Ⅵ)reduction Cr(Ⅲ)oxidation Alkali oxides Acidic oxides Municipal solid waste incineration