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Investigation of gravity influence on EOR and CO_(2) geological storage based on pore-scale simulation

Petroleum Science 2024年第2期21卷 987-1001页

作者： Yong-Mao Hao Gui-Cheng Wu Zong-Fa li Zhong-Hui Wu Yong-Quan Sun Ran liu xing-xing li Bo-Xin Pang Nan li Key Laboratory of Unconventional Oil&Gas Development(China University of Petroleum(East China)) Ministry of EducationQingdao266580ShandongChina School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580ShandongChina School of Petroleum Engineering Yangtze UniversityWuhan430100HubeiChina Dongsheng Jinggong Petroleum Development Group Co. LtdShengli Oilfield CompanySINOPECDongying257001ShandongChina

Gravity assistance is a critical factor influencing CO_(2)-Oil mixing and miscible flow during EOR and CO_(2)geological *** on the Navier-Stokes equation,component mass conservation equation,and fluid property-composition relationship,a mathematical model for pore-scale CO_(2) injection in oilsaturated porous media was developed in this *** model can reflect the effects of gravity assistance,component diffusion,fluid density variation,and velocity change on EOR and CO_(2) *** nonhomogeneous porous media,the gravity influence and large density difference help to minimize the velocity difference between the main flow path and the surrounding area,thus improving the oil recovery and CO_(2) *** CO_(2) injection angles and oil-CO_(2) density differences can increase the oil recovery by 22.6% and 4.2%,respectively,and increase CO_(2) storage by 37.9% and 4.7%,*** diffusion facilitates the transportation of the oil components from the low-velocity region to the main flow path,thereby reducing the oil/CO_(2) concentration difference within the porous *** diffusion can increase oil recovery and CO_(2) storage by 5.7% and 6.9%,*** addition,combined with the component diffusion,a low CO_(2) injection rate creates a more uniform spatial distribution of the oil/CO_(2) component,resulting in increases of 9.5% oil recovery and 15.7% CO_(2) storage,*** study provides theoretical support for improving the geological CO_(2) storage and EOR processes.

关键词： Gravity Flow simulation CO_(2)-oil mixing Enhanced oil recovery(EOR) Geological storage

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Challenges in li-ion battery high-voltage technology and recent advances in high-voltage electrolytes

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Journal of Energy Chemistry 2024年第4期91卷 73-98页

作者： Jianguo liu Baohui li Jinghang Cao Xiao xing Gan Cui Shandong Key Laboratory of Oil&Gas Storage and Transportation Safety College of Pipeline and Civil EngineeringChina University of Petroleum(East China)Qingdao 266580ShandongChina

The electrolyte directly contacts the essential parts of a lithium-ion battery,and as a result,the electrochemical properties of the electrolyte have a significant impact on the voltage platform,charge discharge capacity,energy density,service life,and rate discharge *** raising the voltage at the charge/discharge plateau,the energy density of the battery is ***,this causes transition metal dissolution,irreversible phase changes of the cathode active material,and parasitic electrolyte oxidation *** article presents an overview of these concerns to provide a clear explanation of the issues involved in the development of electrolytes for high-voltage lithium-ion ***,solidstate electrolytes enable various applications and will likely have an impact on the development of batteries with high energy *** is necessary to improve the high-voltage performance of electrolytes by creating solvents with high thermal stabilities and high voltage resistance and additives with superior film forming performance,multifunctional capabilities,and stable lithium *** offer suggestions for the future development of high-energy lithium-ion batteries,we conclude by offering our own opinions and insights on the current development of lithium-ion batteries.

关键词： lithium-ion battery High voltage Electrolyte additive Solid electrolyte

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Impact of the Political Risk on Food Reserve Ratio:Evidence Across Countries

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Journal of Systems Science & Complexity 2024年第5期37卷 2071-2103页

作者： xing Kai li Shang YANG Xiaoguang School of Economics&Management Nanchang University Department of Statistics and Data Science National University of Singapore Academy of Mathematics and Systems Science Chinese Academy of Sciences University of Chinese Academy of Sciences

Using an unbalanced panel data covering 75 countries from 1991 to 2019, the authors explore how the political risk impacts on food reserve ratio. The empirical findings show that an increasing political risk negatively affects food reserve ratio, and the same effects hold for both internal risk and external risk. Moreover, the authors find that the increasing external or internal risks both negatively affect food production and food exports, but external risk does not significantly impact food imports and it positively impacts food consumption, while internal risk negatively impacts food imports and food consumption. The results suggest that most governments have difficulty raising subsequent food reserve ratios in face of an increasing political risk, no matter if it is an internal risk or an external risk although the mechanisms behind the impacts are different.

关键词： External risk food reserve ratio internal risk political risk

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Targeting neuroinflammation in Alzheimer's disease:from mechanisms to clinical applications

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Neural Regeneration Research 2023年第4期18卷 708-715页

作者： Zi-Zhen Si Chen-Jun Zou Xi Mei Xiao-Fang li Hu Luo Yao Shen Jun Hu xing-xing li Lun Wu Yu liu Pharmacy Department The Affiliated Hospital of Medical SchoolNingbo UniversityNingboZhejiang ProvinceChina Department of Physiology and Pharmacology School of MedicineNingbo UniversityNingboZhejiang ProvinceChina Department of Geriatric Psychiatry Ningbo Kangning HospitalNingboZhejiang ProvinceChina Key Laboratory Office of Sleep Medicine Ningbo Kangning HospitalNingboZhejiang ProvinceChina Department of Psychology Collage of Teacher EducationNingbo UniversityNingboZhejiang ProvinceChina Department of Preventive Medicine School of MedicineNingbo UniversityNingboZhejiang ProvinceChina

Alzheimer’s disease is characterized by sustained neuroinflammation leading to memory loss and cognitive *** past decade has witnessed tremendous efforts in Alzheimer’s disease research;however,no effective treatment is available to prevent disease *** increasing body of evidence suggests that neuroinflammation plays an important role in Alzheimer’s disease pathogenesis,alongside the classical pathological hallmarks such as misfolded and aggregated proteins(e.g.,amyloid-beta and tau).Firstly,this review summarized the clinical and pathological characteristics of Alzheimer’s ***,we outlined key aspects of glial cell-associated inflammation in Alzheimer’s disease pathogenesis and provided the latest evidence on the roles of microglia and astrocytes in Alzheimer’s disease ***,we revealed the double-edged nature of inflammatory cytokines and inflammasomes in Alzheimer’s *** addition,the potential therapeutic roles of innate immunity and neuroinflammation for Alzheimer’s disease were also discussed through these *** the final section,the remaining key problems according to the current research status were discussed.

关键词： Alzheimer’s disease astrocytes immune signaling inflammatory cytokines microglia neuroinflammation neurotoxicity therapeutic strategies

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li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable li metal anode

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Chinese Chemical Letters 2024年第10期35卷 447-451页

作者： Zihao Wang Jing Xue Zhicui Song Jianxiong xing Ajun Zhou Jianmin Ma Jingze li School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China School of Mathematics and Physics Weinan Normal UniversityWeinan 714099China School of Chemistry TiangongUniversityTianjin 300387China Huzhou Key Laboratory of Smart and Clean Energy Yangtze Delta Region Institute(Huzhou)University of Electronic Science and Technology of ChinaHuzhou313001China

Constructing a smart polymer film with favorable lithium(li)transport capability and mechanical flexibility for suppressing li dendrite growth is an effective ***,the porosity and the swelling of the polymer membrane cannot completely prevent liquid electrolyte from sweeping through the artificial protection film,severely deteriorating the cyclic ***,we propose a defectfree hybrid film that consists of li+conductive lithium polyacrylate(liPAA)polymer interface layer and li-Zn alloy patch to tackle the critical problems of traditional polymer composite passivation *** pinhole leaks of the polymer matrix are self-filled by li-Zn alloy patches,enhancing the integrity of liPAA ***,a defect-free hybrid film is nailed flat against the li metal anode,exhibiting extraordinary stability in the liquid electrolyte and enabling perfect protection *** facile strategy produces a promising anode for next generation li batteries.

关键词： limetal anode Patch li-Zn alloy liPAA Hybrid film

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Cage-confinement synthesis of MoC nanoclusers as efficient sulfiphilic and lithiophilic regulator for superior li–S batteries

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Rare Metals 2024年第2期43卷 624-634页

作者： xing-Yuan Zhang Mei-Na Lei Shan Tian Jian-Gan Wang State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi’an710072China

High-energy-density li-S batteries are subjected to serious sulfur deactivation and short cycle lifetime caused by undesirable polysulfide shuttle effect and frantic lithium dendrite *** this work,a controllable cage-confinement strategy to fabricate molybdenum carbide(MoC)nanoclusters as a high-efficient sulfiphilic and lithiophilic regulator to mitigate the formidable issues of li-S batteries is *** sub-2 nm MoC nanoclusters not only guarantee robust chemisorption and fast electrocatalytic conversion of polysulfides to enhance the sulfur electrochemistry,but also homogenize li^(+) flux to suppress the lithium dendrite *** a consequence,the MoC-modified separator endows the batteries with boosted reaction kinetics,promoted sulfur utilization,and improved cycling stability.A reversible capacity of 701 mAh·g^(−1) at a high rate of 5.0C and a small decay rate of 0.076%per cycle at 1.0C over 600 cycles are *** study offers a rational route for design and synthesis of bifunctional nanoclusers with both sulfiphilicity and lithiophilicity for high-performance li-S batteries.

关键词： li-S batteries Nanocluster Electrocatalyst Polysulfide shuttle li dendrites

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LPCS Ni-Zn-Al_(2)O_(3) Intermediate Layer Enhanced SPS NiCr-Cr_(3)C_(2) Coating with Higher Corrosion and Wear Resistances

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Journal of Wuhan University of Technology(Materials Science) 2024年第1期39卷 188-195页

作者：白杨 li Yan xing Lukuo li Xiangbo WANG Zhenhua State Key Laboratory of Marine Coatings Marine Chemical Research Institute Co.Ltd.Qingdao 266071China College of Mechanical and Electrical Engineering University of China Petroleum(East China)Qingdao 266580China Science and Technology on Marine Corrosion and Protection Laboratory Luoyang Ship Materials Research InstituteQingdao 266101China

The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel *** intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) *** friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,*** with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was *** results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.

关键词： low-pressure cold spray NiCr-Cr_(3)C_(2)coating wear behavior salt fog corrosion

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Fullerenes and derivatives as electrocatalysts: Promises and challenges

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Green Energy & Environment 2024年第1期9卷 7-27页

作者： Kun Guo Ning li lipiao Bao xing Lu State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

Carbon-based metal-free nanomaterials are promising alternatives to precious metals as electrocatalysts of key energy storage and conversion *** paramount signiﬁcance are the establishment of design principles by understanding the catalytic mechanisms and identifying the active *** from sp2-conjugated graphene and carbon nanotube,fullerene possesses unique characteristics that are growingly being discovered and exploited by the electrocatalysis *** instance,the well-deﬁned atomic and molecular structures,the good electron afﬁnity to tune the electronic structures of other substances,the intermolecular self-assembly into superlattices,and the on-demand chemical modiﬁcation have endowed fullerene with incomparable advantages as electrocatalysts that are otherwise not applicable to other carbon *** increasing studies are being reported on this intriguing topic,it is necessary to provide a state-of-the-art overview of the recent *** review takes such an initiative by summarizing the promises and challenges in the electrocatalytic applications of fullerene and its *** content is structured according to the composition and structure of fullerene,including intact fullerene(e.g.,fullerene composite and superlattices)and fullerene derivatives(e.g.,doped,endohedral,and disintegrated fullerene).The synthesis,characterization,catalytic mechanisms,and deﬁciencies of these fullerene-based materials are explicitly *** conclude it by sharing our perspectives on the key aspects that future efforts shall consider.

关键词： Fullerene Fullerene derivative Metal-free catalyst Structural defect Electrocatalyst

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Study on concentration distribution and detonation characteristics for non-axisymmetric fuel dispersal

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Defence Technology（防务技术） 2024年第1期31卷 484-495页

作者： linghui Zeng Zhongqi Wang xing Chen Jianping li State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing100081China College of Environment and Chemical Engineering Sichuan University of Science&EngineeringZigong643000China

The study of non-axisymmetric fuel dispersal and detonation can provide reference for the prevention of industrial cloud explosion accidents and the design of fuel air explosive(FAE).The concentration and detonation fields of 85 kg cylindrical and fan-shaped fuel are investigated by experiments and numerical simulations.A dynamic model of the whole process for fuel dispersal and detonation is *** concentration distribution of fuel is used as the initial condition to calculate the detonation stage,thus solving the initial value problem of detonation *** phase and component changes of fuel cloud at different locations are *** fuel cloud is divided into directions of 0°,90°,135°and 180°.The results show that the maximum cloud radius is 20.94 m in 135°and the minimum is 12.04 m in 0°.The diameter of the detonation fireball is 53.6 m,and the peak temperature is 3455 *** highest peak overpressure is 3.44 MPa in 0°and the lowest is 2.97 MPa in 135°.The proportion of liquid phase in 0°is22.90%,and the fuel loss is 11.8% and 9% higher than that in 135°and cylindrical charge,*** stable propagation distance of blast wave in 135°is 42.50% longer than 0°and 28.37% longer than cylindrical charge.

关键词： Fuel dispersal Concentration distribution Detonation characteristic Fuel loss Numerical simulation

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Experimental investigation of spectral evolution in flash radiation by hypervelocity impact on aluminum plates

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Defence Technology（防务技术） 2024年第7期37卷 96-110页

作者： xing Chen Yonggang Lu Zhiwen li Zhonghua Cui Institute of Systems Engineering China Academy of Engineering PhysicsMianyang 621900SichuanChina Chongqing Qianwei Technology Group Co. LtdChongqing 401121China

In this study,a series of hypervelocity impact tests were carried out based on a two-stage light gas gun,and the sequence spectrum and radiation evolution data of the impact products under different impact conditions were *** diameter of the projectile is 3-5 mm,the impact velocity is 3.13-6.58 km/s,and the chamber pressure is 0.56-990 *** spectrum of ejected debris cloud in the 250-310 nm band were obtained using a transient spectral measurement system and a multi-channel radiometer measurement *** test results reveal that the flash radiation intensity increases as a power function with the kinetic energy of the ***,the peak value of the line spectrum decreases as the chamber vacuum degree increases,while the radiation width gradually *** line spectrum in the spectral characterization curve corresponds to the ejected debris clouds splitting phase,which does not produce significant line spectrum during material fragmentation and is dominated by the continuum spectrum produced by blackbody *** will appear one or three characteristic peaks in the flash radiation time curve,the first and second peaks correspond to the penetration phase and the third peak corresponds to the expansion phase of the ejected debris clouds on the time scale,the first and second peaks are more sensitive to the chamber vacuum degree,and when the pressure is higher than 99 Pa,the first and second characteristic peaks will *** radiant heat attenuation of the flash under different impact conditions is significantly different,the attenuation exponent has a power function relationship with the impact velocity and the chamber vacuum degree,while the attenuation exponent has a linear relationship with the diameter of the projectile,the specific expression of the attenuation exponent is obtained by *** findings from this research can serve as a valuable reference for remote diagnostic technologies based on flash radiation characte

关键词： Hypervelocity impact Flash radiation Evolution Spectral characteristics Damage evaluation

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