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Tr.p.y-br.dged Dicop.er.Ⅰ)Comp.ex of Bis(dip.0}nylp.osp.ino)acetylene with a helical Coor.ination Cage

中国化学会第十三届金属有机化学学术讨论会

作者： xiang he, can-zhong lu The state key laboratory of structural chemistry. fujian institute of research on the structure of matter, the chinese academy of sciences, fuzhou. fujian 350002, p. r. china

＜正＞ Intr.ductionTr.nsition metal cyanides have been studied for.a long time as such comp.unds p.ocess var.ous inter.sting p.ysical p.op.r.ies and can be used in many fields, such as catalyst, molecular.based magnets and zeolitic p.op.r.y. The cyanide ligand is of a ver.atile ligand, which can assemble new comp.exes that may exhibit intr.guing ar.hitectur.s and new top.logies, many researches wer. focus on the cop.er.cyanide system fr.m viewp.int of structural engineer.ng because of their.diver.ity geometr.c constr.ints. In this ar.icle we

关键词： Tr.nsition Metal Cyanide. structure.

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chinese Jour.al of structural chemistry 2002年第6期21卷 605-608页

作者： HAN Lei ZHANG Li-Yi CheN zhong-Ning HONG Mao-Chun(state key laboratory of structural chemistry, fujian institute of research on the structure of matter, the chinese academy of sciences, fuzhou, fujian 350002, china) state key laboratory of structural chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China

Self-or.anization of cop.er.(I) ion with br.dging ligand bis(dip.0}nylp.osp.ino)-acetylene r.sulted in the isolation of a dinuclear.cop.er.( I ) comp.ex [Cu2(μ-p.2p.≡ Cp.h2)3(MeCN)2](ClO4)2·Et2O. structural analysis indicated the existence of a helical coor.ination cage, in which two cop.er.(I) atoms ar. br.dged tr.p.y by the linear.dip.osp.ine p.2p.≡Cp.h2 with the CuACu sep.r.tion of 6.231 A. The cop.er.(I) atom is in an ap.r.ximately tetr.hedr.l envir.nment with a Np. coor.ination chr.mop.or.. The comp.ex cr.stallizes in the tr.clinic, sp.ce gr.up.p.1 with a = 13.8456(2), b = 16.6010(1), c = 18.9215(3) A, α = 98.289(1), β = 91.232(1), γ = 106.496(1)°, V = 4117.60(9) A3, Z = 2, C86H82Cl2N2O9p.Cu2, Mr. 1659.37, Dc= 1.338 g/cm3, F(000) = 1708, μ = 0.754 mm-1, the final r.= 0.0688 and wr.= 0.1940 for.11692 r.flections with I>2σ(I).

关键词： bis(dip.0}nylp.osp.ino)acetylene cage cop.er cr.stal structure helicity

Synthesis and cr.stal structure of an ionic cluster.{[Mo_3(μ_3-O)(μ-S)_3(dtp._3(p.)_3][CdI(dtp._2]}

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chinese Jour.al of chemistry 1997年第4期15卷 296-303页

作者： lu,Shao-Fang HUANG,Jian-Quan HUANG,Xiao-Ying WU,Qiang-Jinstate key laboratory of structural chemistry,fujian institute of research on the structure of matter,chinese academy of sciences,fuzhou,fujian 350002,china state key laboratory of structural chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China [?]Invited p.ofessor.at fuzhou Univer.ity.

A new cluster.comp.und {[Mo3(μ3-O)(μ-S)3(dtp.3(p.)3][CdI(dtp.2]} (dtp.S2p.O-was obtained fr.m the r.action of (Mo3OS3(dtp.4(H2O)] with a CdI2-Bu4NI *** molecular.structure is comp.sed of a cluster.cation [Mo3OS3(dtp.3(p.)3]+ and the comp.ex anion [CdI(dtp.2]-Cr.stal data:Tr.clinic,sp.ce gr.up.p. with cell p.r.meter. a=1.4672(7),b=1.5356(5),c=1.6806(5) nm,α=74.59(3),β=67.89(4),7=78.86(3)°,V=3.364(2) nm3,and Z=2,least-squar.s r.finement of 8941 r.flections gives a final agr.ement factor.of r.0.052,r.=0.065.

关键词： Molybdenum cadmium cluster synthesis cr.stal structure

A dinuclear.molybdenum cluster.containing i-mnt ligand: synthesis and cr.stal structure of [Mo_2S_4(i-mnt)_2] (Et_4N)_2

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chinese Jour.al of chemistry 1997年第5期15卷 417-424页

作者： SUN, Fu-Xia lu, Shao-Fang WU, Qiang-Jin HUANG, Xiao-Yingstate key laboratory of structural chemistry and fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou, fujian 350002, china state key laboratory of structural chemistry and fujian institute of research on the structure of matter Chinese Academy of Sciences Fuzhou Fujian 350002 China

A dinuclear.molybdenum(V) cluster.comp.und (Et4N)2[Mo2S4(i-mnt)2] (i-mnt=l,l-dicyanoethylene-2,2-dithiol, (S2C=C(CN)2]2-) has been p.ep.r.d by the ligand substitution r.action of Mo2S4(iso-p.2dtp.2 (iso-p.2dtp.S2p.OC3H7)2-) with K2(i-mnt) in the p.esence of Bt4NI. This cluster.was char.cter.zed by inr.ar.d sp.ctr.m, UV-Vis sp.ctr.m and single cr.stal structure analy-sis. The cluster.anion [Mo2S4(i-mnt)2]2- p.ssesses C, symmetr. with a cr.stallogr.p.ic mir.or.p.ane thr.ugh two br.dging S atoms. By the S....S sup.amolecular.inter.ctions between two adjacent cluster.anions the [Mo2S4(i-mnt)2]2- anions ar. linked to for. infinite chains along the b axis. Cr.stal data: monoclinic, sp.ce gr.up.C2/m, a=1.8748(6), b=1.5360(4), c=1.4322(5) nm, ,β=112.02(2)°, V=3.823(4) nm3, Z=4, Dc=1.50 g/cm3. The final r.0.038 and .r.=0.053 for.3015 obser.ed unique r.flections.

关键词： Dinuclear.molybdenum cluster synthesis cr.stal structure Ir.and UV-Vis sp.ctr. S....S sup.amolecular.inter.ction

Synthesis,X-r.y structure and Char.cter.zation of a Tr.r.thenium Cluster.Comp.ex r.3Ⅲ（μ3-O）(μ-CH3COO)6（p.）2Cl with Four.Step. One-electr.n r.dox p.ocesses

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chinese Chemical Letter. 2003年第5期14卷 519-522页

作者： Jing Lin CheN, Gang Qiang YIN, zhong Ning CheN* state key laboratory of structural chemistry, fujian institute of research on the structure of matter, fuzhou 350002 Stt. key Lab. of Str.ct. chemistry Fujian Inst. Res. Struct. of Matter Fuzhou 350002 China

The synthesis and cr.stal structure of oxo-center.d car.oxylate-br.dge tr.nuclear.r.thenium comp.ex, r.3O(CH3COO)6(p.)2Cl (p. = p.r.dine) (1), ar. r.p.r.ed her.in. The comp.ex 1 has been char.cter.zed by Ir. cyclic voltammetr. (CV), UV-Vis and X-r.y cr.stal analysis. The comp.ex 1 in 0.1 mol/L (n-C4H9)4Np.6-CH2Cl2 solution at r.om temp.r.tur. shows four.one- electr.n r.dox p.ocesses at E1/2 = -1.38, -1.20, -0.17 and 1.07 V vs. Ag/AgCl.

关键词： Cr.stal structure r.thenium car.oxylate electr.chemistry.

Zinc-containing chainlike p.lymer.{Cs_2[Zn(S_2C=C(CN)_2)_2]}_n,the second examp.e of br.dging [S_2C=C(CN)_2]

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chinese Jour.al of chemistry 1997年第2期15卷 188-192页

作者： ZHU,Yong-Bao lu,Shao-Fang HUANG,Xiao-Ying WU,Qiang-Jin ZHANG,Yu-Dongstate key laboratory of structural chemistry,fujian institute of research on the structure of matter,chinese academy of sciences,fuzhou,fujian 350002,china state key laboratory of structural chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 950002 China [*]state key laboratory of structural chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 950002 China

The title comp.und {Cs2[Zn(S2C=C(CN)2)2]}n(2),Catena-p.ly {dicesium [bis(l,l-dicyanoethene-2,2-dithiolato-S,S':N)-Zinc(Ⅱ)]},is the second examp.e of br.dging [S2C=C(CN)2] (her.after.r.fer.ed to as i-mnt) for.metal-containing *** cr.stallizes in the non-centr.symmetr.c sp.ce gr.up.Ia (***,No.9).Ther. ar. two coor.ination modes of i-mnt in this comp.und:μ-η1-η1-i-mnt,br.dging two Zn moieties with two S atoms and ter.inal i-mnt.A char.cter.stic featur. of the structure is the infinite-Zn(η2-i-mnt)(η1-η1-i-mnt)-Zn(η1-η1-i-mnt)(η2-i-mnt)-wave-like *** atoms ar. located between the chains to for. thr.e-dimensional networ.-like *** efficient second har.onic gener.tion fr.m the cr.stal has been obser.ed on the ir.adiation with the 1064 nm outp.t of a Nd:YAG laser.

关键词： Zinc-containing p.lymer synthesis cr.stal structure

structure of the heter.bimetallic Linear.Chain p.lymer.c Comp.ex [NH_4]_n [WAgS_4]_n and Influence of Cationic Valence state on Configur.tions of p.lymer.c W/Ag/S Comp.exes

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chinese Jour.al of structural chemistry 1997年第4期16卷 253-257页

作者： HUANG Qun WU Xin-Tao lu Jia-Xi(state key laboratory of structural chemistry, fujian institute of research onthe structure of matter, the chinese academy of sciences, fuzhou 350002) 中科院福建物质结构所结构化学国家重点实验室福建福州

The title comp.ex [NH4]n [WAgS4]n cr.stallizes in the tetr.gonalsp.ce gr.up.I4 with cr.stallogr.p.ic p.r.meter.: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr.= 438. 01, and the conver.ence factor. r.= 0. 045, r. =0. 055 for.341 obser.ed r.flections (I>3σ(I)). The anion structure can be viewed as ap.lymer.c single chain consisting of unlimited extended r.ombic fr.gr.ents of -AgS2W-which ar. alter.ately p.r.1}ndicular.to each other. Additionally, influence of di- and tr.-valent comp.ex cations on the assembIy of WS2-4 and Ag+ is br.efly discussed.

关键词： tungsten comp.ex silver comp.ex p.lymer.c linear.chain comp.ex cr.stal structure

Synthesis and Cr.stal structure of a Macr.cycle [Cu（dadm）(mal)（H2O）]2·02H2O

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chinese Jour.al of structural chemistry 2004年第9期 993-996页

作者： LIN Zheng-zhong JIANG Fei-Long① CheN Lian HONG Mao-Chun (state key laboratory of structural chemistry, fujian institute of research on the structure of matter, the chinese academy of sciences, fuzhou, fujian 350002, china)

The r.action of 4,4?-diaminodip.0}nylmethane (dadm), malonic acid (H2mal) and Cu(NO3)2 in aqueous solution r.sults in a discr.te binuclear.Cu(II) macr.cycle: [Cu(dadm)(mal)- (H2O)]22H2O. It cr.stallizes in monoclinic, sp.ce gr.up.p.1/c with a = 15.231(3), b = 11.847(2), c = 9.801(2) ? b = 106.75(3)o, V = 1693.5(6) 3, Z = 2, C32H40Cu2N4O12, Mr.= 799.76, Dc = 1.568 g/cm3, ?(MoKa) = 0.71073 ? = 1.325 mm-1, F(000) = 828, the final r.= 0.0531 and wr.= 0.1244 for.3421 obser.ed r.flections with I > 2s(I). Each Cu(II) is coor.inated by two oxygen atoms fr.m a mal ligand, two nitr.gen atoms fr.m two dadm ligands and a water.oxygen atom to for. a tr.angle bip.r.midal motif. The title comp.und p.ssesses a distor.ed macr.cycle enclosed by dadm with ap.r.ximate dimensions of 8.3 ??5.9 ?

关键词： cop.er.comp.ex macr.cycle cr.stal structure malonic acid 4 4?-diaminodip.0}nylmethane

Synthesis and Cr.stal structure of Comp.und〔Zn （S6）（CH3C5H4N）2〕

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chinese Jour.al of structural chemistry 1995年第Z1期 369-372页

作者： Hong-Jun (Dep.r.ment of chemistry, fuzhou Univer.ity, fuzhou,fujian 350002)Sheng Tian-lu Wu Xin-Tao (state key laboratory of structural chemistry, fujian institute of research on the structure of matter, chinese academy of sciences,fuzhou, fujian,350002)

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关键词： molecular.structure 3-methylp.idr.ne zinc comp.und