Synthesis and crystal structure of an ionic cluster {[Mo_3(μ_3-O)(μ-S)_3(dtp)_3(py)_3][CdI(dtp)_2]}

作     者：LU,Shao-Fang HUANG,Jian-Quan HUANG,Xiao-Ying WU,Qiang-JinState Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China 

作者机构：State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China [?]Invited professor at Fuzhou University. 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1997年第15卷第4期

页      面：296-303页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Project supported by the National Natural Science Foundation of China 

主　　题：Molybdenum cadmium cluster synthesis crystal structure 

摘      要：A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-was obtained from the reaction of (Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI *** molecular structure is composed of a cluster cation [Mo3OS3(dtp)3(py)3]+ and the complex anion [CdI(dtp)2]-Crystal data:Triclinic,space group P1 with cell parameters a=1.4672(7),b=1.5356(5),c=1.6806(5) nm,α=74.59(3),β=67.89(4),7=78.86(3)°,V=3.364(2) nm3,and Z=2,least-squares refinement of 8941 reflections gives a final agreement factor of R=0.052,Rw=0.065.