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Exploring the mechanical behavior and microstructure of compacted loess subjected to dry-wet cycles and chemical contamination

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3673-3695页

作者： Yongpeng Nie Wankui Ni Xiangfei Lü wenxin tuo College of Geological Engineering and Geomatics Chang'an UniversityXi'an710054China Department of Civil Engineering Nagoya Institute of TechnologyNagoya466-8555Japan School of Water and Environment Chang'an UniversityXi'an710054China

Due to climatic factors and rapid urbanization,the soil in the Loess Plateau,China,experiences the coupled effects of dry-wet cycles and chemical *** the mechanical behavior and corresponding microstructural evolution of contaminated loess subjected to dry-wet cycles is essential to elucidate the soil degradation ***,direct shear and consolidation tests were performed to investigate the variations in mechanical properties of compacted loess contaminated with acetic acid,sodium hydroxide,and sodium sulfate during dry-wet *** mechanical response mechanisms were investigated using zeta potential,mineral chemical composition,and scanning electron microscopy(SEM)*** results indicate that the mechanical deterioration of sodium hydroxidecontaminated loess during dry-wet cycles decreases with increasing contaminant concentration,which is mainly attributed to the thickening of the electrical double layer(EDL)by Nat and the precipitation of calcite,as well as the formation of colloidal flocs induced by OH,thus inhibiting the development of large pores during the dry-wet *** contrast,the attenuation of mechanical properties of both acetic acid-and sodium sulfate-contaminated loess becomes more severe with increasing contaminant concentration,with the latter being more particularly *** is primarily due to the reduction of the EDL thickness and the erosion of cement in the acidic environment,which facilitates the connectivity of pores during dry-wet ***,the salt expansion generated by the drying process of saline loess further intensifies the structural ***,the mechanical performance of compacted loess is sensitive to both pollutant type and concentration,exhibiting different response patterns in the dry-wet cycling condition.

关键词： Contaminated loess Dry-wet cycles Compressibility Shear strength Microstructural evolution

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干湿循环下盐渍压实黄土湿陷性劣化机理研究

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工程地质学报 2024年第2期32卷 420-429页

作者：拓文鑫倪万魁聂永鹏长安大学地质与测绘学院西安710061

近年来黄土高原地区土壤盐渍化问题愈发严重,深入了解盐渍压实黄土在干湿循环作用下的湿陷性演化规律对当地填方工程安全至关重要。本文通过对不同干湿循环次数和硫酸钠(Na_(2)SO_(4))含量的压实黄土试样进行电镜扫描试验和室内湿陷试验... 详细信息

近年来黄土高原地区土壤盐渍化问题愈发严重,深入了解盐渍压实黄土在干湿循环作用下的湿陷性演化规律对当地填方工程安全至关重要。本文通过对不同干湿循环次数和硫酸钠(Na_(2)SO_(4))含量的压实黄土试样进行电镜扫描试验和室内湿陷试验,研究了盐渍压实黄土在干湿循环过程中的湿陷性劣化规律及其微观机理。结果表明:干湿和盐蚀的耦合作用使黄土结构趋于松散,造成湿陷系数增大,然而湿陷系数的增速随干湿次数增加而逐渐减小,表现出减速劣化特性,随含盐量增大而逐渐增大,呈现出加速劣化特性,且当含盐量大于0.5%时,盐蚀对湿陷性的劣化作用比干湿劣化作用更显著。最后,构建了同时考虑干湿循环次数和含盐量的经验模型,能较好描述盐渍压实黄土在干湿循环作用下的湿陷性演化规律。

关键词：压实黄土干湿循环盐蚀湿陷性解耦分析

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强夯动荷载作用方向对黄土边坡稳定性的影响分析

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振动与冲击 2024年第1期43卷 283-289页

作者：吴丙权倪万魁拓文鑫任思远陈军廷长安大学地质工程与测绘学院西安710064 长安大学西部矿业资源与地质工程教育部重点实验室西安710064

为进一步研究强夯对周边黄土边坡稳定性的影响,采用极限平衡圆弧条分法对强夯作用下的边坡安全系数进行推导计算。结合工程实例,使用TC-4850爆破测振仪对现场监测点进行加速度测试。考虑高程差和测点距离的共同影响,采用MATLAB编程对现... 详细信息

为进一步研究强夯对周边黄土边坡稳定性的影响,采用极限平衡圆弧条分法对强夯作用下的边坡安全系数进行推导计算。结合工程实例,使用TC-4850爆破测振仪对现场监测点进行加速度测试。考虑高程差和测点距离的共同影响,采用MATLAB编程对现场数据进行多元回归分析,求出强夯作用下边坡质点振动加速度解析式。在求得最小安全系数的基础上,研究不同强夯动荷载方向对黄土边坡稳定性的影响。研究结果表明:在相同荷载作用下,强夯动荷载方向与水平轴正方向夹角为0°、45°、60°、270°、315°、330°、360°时,安全系数均小于等于1.00,且随着拟静力系数不断增大,安全系数越来越小。强夯动荷载方向与水平轴正方向夹角为90°、135°、150°、180°、225°、240°时,安全系数均大于1.05。随着拟静力系数不断增大,安全系数也随之增大。该方法简单易行,便于计算,可用于黄土边坡实际工程。

关键词：极限平衡强夯动荷载方向安全系数拟静力系数

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Synergistic effect of bonding heterogeneity and phonon localization in introducing excellent thermoelectric properties in layered heteroanionic NdZnSbO material

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Journal of Energy Chemistry 2025年第1期100卷 259-272页

作者： Da Wan Shuwei Tang Shulin Bai Xiaodong Li Peng Ai Wanrong Guo tuo Zheng College of Materials Science and Engineering Liaoning Technical University Faculty of Chemistry Northeast Normal University

Layered rare-earth metal oxides, harnessing the dual properties of oxides and two-dimensional layered materials, exhibit remarkable thermal stability and quantum confinement effects. Therefore, this work adopts the first-principles calculation combined with the Boltzmann transport theory to predict the thermoelectric properties of NdZnSbO compound. The coexistence of weak interlayer van der Waals interactions, robust intralayer ionic bonding, and partial covalent bonding leads to remarkable bonding heterogeneity, which engenders pronounced phonon scattering and imposes constraints on thermal transport along the out-of-plane direction. The weakened chemical bonds induced by the antibonding states, together with the rattling-like behavior of the Zn atom, culminate in the profound anharmonicity in the layered NdZnSbO compound. The weakening bond and heavy element contribute to the softness of phonon modes, which significantly diminishes the phonon group velocity. The redistribution-dominated four-phonon scattering process spans a large optical gap, which effectively reduces the lattice thermal conductivity. The NdZnSbO compound exhibits direct semiconductor characteristic with a bandgap of 0.73 e V by adopting the Heyd-Scuseria-Ernzerhof(HSE06) functional in combination with spin–orbit coupling(SOC) effect. The multi-valley feature of NdZnSbO compound augur favorably for band degeneracy, thus amplifying the power factor. Consequently, an optimal figure-of-merit(ZT) of 3.40 at 900 K is achieved for the n-type NdZnSbO compound. The present study delves deeply insights into the origins for the low thermal conductivity of NdZnSbO compound and proposes an optimization scheme to enhance overall thermoelectric performance.

关键词： Bond strength (chemical)

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基于分数阶理论的软泥岩一维次固结蠕变模型

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吉林大学学报（地球科学版） 2024年第1期54卷 242-252页

作者：任思远倪万魁陈军廷拓文鑫杨珍珍长安大学地质工程与测绘学院西安710054

工程中因岩石蠕变而诱发的灾害屡见不鲜,其中的软岩蠕变在实际工程中也较为常见。为探讨软岩蠕变特性,并准确预测软岩蠕变变形,本研究首先对宁夏固原市隆德县的软泥岩进行了一维次固结蠕变试验,分析了一维次固结蠕变试验下软泥岩的蠕变... 详细信息

工程中因岩石蠕变而诱发的灾害屡见不鲜,其中的软岩蠕变在实际工程中也较为常见。为探讨软岩蠕变特性,并准确预测软岩蠕变变形,本研究首先对宁夏固原市隆德县的软泥岩进行了一维次固结蠕变试验,分析了一维次固结蠕变试验下软泥岩的蠕变特性;然后引入了分数阶理论的概念,推演能够描述非线性蠕变特征的分数阶Burgers模型本构方程;最后利用Matlab中lsqcurvefit算法对软泥岩一维次固结蠕变试验数据进行数值求解,分析了分数阶阶数对软泥岩一维次固结蠕变曲线的影响。蠕变试验表明:软泥岩蠕变机制符合固结蠕变中瞬时变形、固结变形、稳定变形三阶段,并呈明显的非线性特征,且原状、重塑试样在固结过程中均产生了较大程度的次固结蠕变,最大变形量可占总变形量的59%。数值模拟结果表明:分数阶Burgers模型能够更好地描述次固结蠕变的非线性特征;模型分数阶阶数γ有较强的敏感性,能够反映拟合曲线的弹性阶段及之后的非线性黏弹性阶段,而分数阶阶数β敏感性较差,仅能对黏弹性阶段的蠕变趋势做出细微反应。

关键词：软泥岩分数阶理论岩石蠕变 Burgers模型宁夏固原市

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Anomalous quality factor evolution of induced transparency in a virtualized coupled-oscillator system

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 148-155页

作者： Yunhan Yang Han Jia tuo Liu Yuzhen Yang Jun Yang Key Laboratory of Noise and Vibration Research Institute of Acoustics Chinese Academy of Sciences University of Chinese Academy of Sciences State Key Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences

The phenomenon of induced transparency, characterized by a high quality(Q) factor, holds significant importance in the fields of high-precision sensing, energy storage and wave manipulation. Conventional transparency systems are often constrained by the limited experimentally accessible parameter space and the lack of independent control over intrinsic parameters, thereby hindering advanced research on high-Q effects. Here we propose a virtualized coupled-oscillator system that enables reconfigurable induced transparency in the reflection spectrum. By virtually incorporating a pair of coupled oscillators into an individual acoustic meta-atom, we achieve the manipulation of induced transparency in a decoupled, wide-ranging, and elaborate manner. Exploiting the diverse evolutions across the intrinsic parameter space, we show experimentally a counter-intuitive increase in the Q-factor of the transparency window, which is attributed to the enhanced dissipation of the bright ***, a constant group delay at the center frequency is observed accompanying this evolution. Our work demonstrates an intriguing platform as well as a novel strategy to engineer high-Q induced transparency phenomenon, and paves the way towards applications in programmable acoustic sensors, filters and slow-wave devices.

关键词： induced transparency acoustic meta-atom high quality-factor scattering programmable intrinsic parameter

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Estimation of inverse Compton peak frequency for 4FGL Blazars

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Science China(Physics,Mechanics & Astronomy) 2023年第4期66卷 142-157页

作者： JiangHe Yang JunHui Fan Yi Liu ManXian tuo ZhiYuan Pei wenxin Yang YuHai Yuan SiLe He ShengHui Wang XiaoHai Qu YueLian Zhang JianJun Nie XiuHui Chen College of Mathematics and Physics Science Hunan University of Arts and ScienceChangde 415000China Center for Astrophysics Guangzhou UniversityGuangzhou 510006China Astronomy Science and Technology Research Laboratory of Department of Education of Guangdong Province Guangzhou 510006China

This study uses a parabolic equation to fit the Inverse Compton (IC) spectral component of 3743 blazars (794 FSRQs,1432 BLLacs,and 1517 BCUs) from the 4FGL-DR3 *** mutual correlations are investigated,and a Bayesian classification is performed to the IC peak *** analyses draw the following conclusions:(1) The Bayesian classification shows two components with a dividing boundary of log(v_(p)^(IC)/Hz)pIC=***,the 3743 blazars are divided into low IC peak frequency(LCP) blazars and high IC peak frequency (HCP) blazars.(2) A strong linear correlation exists between IC peak frequency(logv_(p)^(IC)) and γ-ray photon spectral index (Γ).The IC peak frequency can be estimated by an empirical relation logv_(p)^(IC)=–4.5·Γ+32.8 for BL Lacs and logv_(p)^(IC)=4.0+31.4pICfor FSRQs,which is consistent with the result by Abdo et al.(3) The ICspectral curvature and IC peak frequency are not as closely related as the synchrotron curvature and the synchrotron peak frequency.(4) An anti-correlation exists between IC peak frequency and IC peak luminosity,implying that as the IC peak frequency in the γ-ray band decreases,the source becomes more *** beaming effect is stronger for the source with a lower IC peak frequency.(5) Positive correlations exist between IC and synchrotron components for both peak frequencies and peak fluxes,but no clear correlation exists between IC curvature and synchrotron curvature.

关键词： active galactic nuclei Fermi blazars spectral energy distribution inverse Compton emission

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Solidification segregation behavior of Nb-containing 310S steel

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Journal of Iron and Steel Research International 2023年第1期30卷 82-87页

作者： Yu-tuo Zhang Hao Zou School of Materials Science and Engineering Shenyang Ligong UniversityShenyang 110159LiaoningChina Institute of Metal Research Chinese Academy of SciencesShenyang 110016LiaoningChina

The solidification characteristics and segregation behavior of solute elements Nb,Ni,Mn,Si,Cr and C in 0.3 wt.%Nb-310S steel were investigated using the isothermal solidification quenching experiment and Thermo-Calc *** phase transformation for 0.3%Nb-310S steel under equilibrium condition can be summarized as follows:liquid(L)→L+γ(1406℃)→γ(1334℃)→γ+NbC(1322℃)→γ+NbC+M_(23)C_(6)(1006℃)→γ+NbC+M_(23)C_(6)→σ(755℃).The results showed that the solidification began with the formation of primary austenite *** volume fraction of the liquid phase decreased rapidly as the temperature decreased in the initial solidification stage,and then,the liquid phase fraction decreased *** austenite formed,Mn and Ni were enriched in the solid phase,while Nb and C were rejected into the *** was present the highest segregation coefficient in 0.3%Nb-310S austenitic stainless *** segregation of Nb was the most serious,followed by Mn,Ni and *** and Si exhibited slight segregation during the *** solidification was terminated by the formation of NbC phase.

关键词： 310S steel Nb Solidification Segregation Thermo-Calc calculation

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Overestimated solar water splitting performance onoxide semiconductor anodes

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Science China Materials 2017年第1期60卷 90-92页

作者： tuo Wang Jinlong Gong Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China Collaborative Innovation Center of Chemical Science and Engineering Tianjin 300072 China

Water oxidation is a 4-electron uphill energy process thatlargely limits the overall water splitting reaction thermody-namically and kinetically [1]. Photocurrent measurementis one of the most important approaches to evaluate the per-formance of a photoanode. It has been well realized thatphotocurrent may render exaggerated performance whenphotocorrosion of electrode occurs, such as the case of ZnOand CdS or when sacrificial reagents are present in the elec-trolyte. However, the choice of electrolyte could be anothervery important but easily overlooked issue for the valid in-terpretation of photocurrent.

关键词：光电电流水化氧化作用半导体阳电极材料科学

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Cranial morphology of the Silurian sarcopterygian Guiyu oneiros (Gnathostomata:Osteichthyes)

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Science China Earth Sciences 2010年第12期53卷 1836-1848页

作者： QIAO tuo ZHU Min Key Laboratory of Evolutionary Systematics of Vertebrates Institute of Vertebrate Paleontology and PaleoanthropologyChinese Academy of SciencesBeijing 100044China Graduate School of Chinese Academy of Sciences Beijing 100049China

Cranial morphological features of the stem-group sarcopterygian Guiyu oneiros Zhu et al.,2009 provided here include the dermal bone pattern and anatomical details of the *** on those features,we restored,for the first time,the skull roof bone pattern in the Guiyu clade that comprises Psarolepis and *** with Onychodus,Achoania,coelacanths,and actinopterygians show that the posterior nostril enclosed by the preorbital or the preorbital process is shared by actinopterygians and sarcopterygians,and the lachrymals in sarcopterygians and actinopterygians are not *** endocranium closely resembles that of Psarolepis,Achoania and Onychodus;however,the attachment area of the vomer possesses irregular ridges and grooves as in Youngolepis and *** orbito-nasal canal is positioned mesial to the nasal capsule as in Youngolepis and *** position of the hypophysial canal at the same level or slightly anterior to the ethmoid articulation represents a synapmorphy of the Guiyu *** large attachment area of the basicranial muscle indicates the presence of a well-developed intracranial joint in Guiyu.

关键词： Sarcopterygii Osteichthyes Cranial morphology homology Silurian China

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