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The protocadherin alpha cluster is required for axon extension and myelination in the developing central nervous system

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Neural Regeneration Research 2018年第3期13卷 427-433页

作者： wen-cheng lu Yu-xiao Zhou Ping Qiao Jin Zheng Qiang Wu Qiang Shen Department of Orthopedics Shanghai General Hospital Shanghai Jiao Tong University School of Medicine Center for Comparative Biomedicine Key Laboratory of Systems Biomedicine (Ministry of Education) Institute of Systems Biomedicine Shanghai Center for Systems Biomedicine Shanghai Jiao Tong University Department of Orthopedics People’s Hospital of Zhangqiu

In adult mammals, axon regeneration after central nervous system injury is very poor, resulting in persistent functional loss. Enhancing the ability of axonal outgrowth may be a potential treatment strategy because mature neurons of the adult central nervous system may retain the intrinsic ability to regrow axons after injury. The protocadherin （Pcdh） clusters are thought to function in neuronal morphogenesis and in the assembly of neural circuitry in the brain. We cultured primary hippocampal neurons from E17.5 Pcdhα deletion （del-α） mouse embryos. After culture for 1 day, axon length was obviously shorter in del-α neurons compared with wild-type neurons. RNA sequencing of hippocampal E17.5 RNA showed that expression levels of BDNF, Fmod, Nrp2, OGN, and Sema3d, which are associated with axon extension, were significantly down-regulated in the absence of the Pcdhα gene cluster. Using transmission electron microscopy, the ratio of myelinated nerve fibers in the axons of del-α hippocampal neurons was significantly decreased; myelin sheaths of P21 Pcdhα-del mice showed lamellar disorder, discrete appearance, and vacuoles. These results indicate that the Pcdhα cluster can promote the growth and myelination of axons in the neurodevelopmental stage.

关键词： nerve regeneration spinal cord injury axons protocadherin α cluster hippocampal neurons RNA sequencing real-time quantitative polymerase chain reaction transmission electron microscopy neural regeneration

Dynamical complexity of Anosov systems driven by a quasi-periodic force

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Science China Mathematics 2025年第1期 89-136页

作者： wen Huang Zeng Lian Kening lu Department of Mathematics University of Science and Technology of China School of Mathematics Sichuan University

Consider C2Anosov systems on a compact manifold driven by a quasi-periodic *** study their dynamical complexity on various levels from the perspectives of both path-wise dynamics and stochastic *** that these systems are non-wandering（i.e.,every point in the phase space is nonwandering）,we prove a set of results:（1） the existence of abundance of random periodic points;（2） a random Liv?ic theorem;（3） a random Ma?é-Bousch-Conze-Guivarc'h lemma;（4） the existence of strong random ***,a concrete example constructed on a 2-dimensional torus is also given to uncover some interesting phenomena of the systems.

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专家控制技术在设施园艺中的应用

农机化研究 2006年第3期28卷 177-179页

作者：温程璐李季中国农业大学工学院北京100083

设施园艺环境有多因素、线性大、时间滞后和不确定性的特点。随着现代化控制技术的发展,专家控制技术可以取得较好的控制效果。为此,介绍了专家控制技术的基本概念和其在温室环境控制中的应用,并叙述了知识库、数据库和推理机的设计过程。

关键词：自动控制技术专家控制应用设施园艺知识库数据库推理机

Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang Wu Linke Cai Youluan lu Fanpeng cheng Lijuan Shi Qun Yi Yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering & Pharmacy Wuhan Institute of Technology Key Laboratory of Pesticide & Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of Education College of Chemistry Central China Normal University College of Materials Science and Engineering Fuzhou University

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction（OER）. Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER process. However, most of them undergo incomplete reconstruction with limited thickness of reconstruction layer, leading to low component utilization and arduous exploration of real catalytic mechanism. Herein, we identify the dynamic behaviors in complete reconstruction of Co-based complexes during OER. The hollow phytic acid（PA） cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability, in favor of the fast and complete reconstruction. A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co（Fe）(OH)xand subsequent potential-driven oxidation to Co（Fe）OOH. The obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm-2and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER activity. The work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Oxygen evolution reaction

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基于分数阶PI的逆变器双环控制研究

计算机仿真 2013年第8期30卷 127-130页

作者：郭伟徐金成温路成程远南京信息工程大学信息与控制学院江苏南京210044

研究逆变器波形控制技术的问题,传统PI控制存在明显的缺点,导致输出电压质量不佳。为了提高逆变器输出电压的稳态和动态性能,提出了一种新的分数阶PI控制策略。分数阶PI控制器比PI控制器多了一个可调参数λ,使设计更加灵活,性能更加优... 详细信息

研究逆变器波形控制技术的问题,传统PI控制存在明显的缺点,导致输出电压质量不佳。为了提高逆变器输出电压的稳态和动态性能,提出了一种新的分数阶PI控制策略。分数阶PI控制器比PI控制器多了一个可调参数λ,使设计更加灵活,性能更加优越。仿真结果显示,分数阶PI控制策略提高了逆变器输出电压的稳态精度,增强了负载抗干扰能力,系统获得较快的动态响应,改进控制策略对于中小型风力发电系统并网逆变器的实际应用具有重要圣者价值。

关键词：单相全桥逆变器分数阶PI控制器双环控制

Thermoresponsive helical dendronized poly(arylacetylene)s:modulating the dynamic chirality

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Science China Chemistry 2025年

作者： Xueting lu Lei Wang Liangxuan Ren wen Li Afang Zhang International Joint Laboratory of Biomimetic&Smart Polymers School of Materials Science and EngineeringShanghai University

Helical poly(arylacetylene)s have formed an intriguing class of polymers,whose chiralities are dynamic and liable to external *** combining dendronized polymer topology with dendritic oligoethylene glycols (OEGs),we here report on synthesis of a homologous series of thermoresponsive dendronized poly(arylacetylene)s with either poly(phenyl acetylene) or poly(naphthalene acetylene) as the backbones,and investigate tunability of their helical *** polymers carry dendritic OEG pendants with either methoxyl-or ethoxyl-terminals to tune their unprecedent thermoresponsive behaviors,and at the same time,dendritic shielding plays an important role in mediating their thermal phase transition *** of these polymers is originated from the chiral alanine or phenylalanine moieties within the dendritic pendants,which can be tailored through manipulating solvation in different organic solvents or via thermal dehydration and collapse in ***,achiral additives such as linear or dendritic OEGs and benzene derivatives can act similarly as thermal dehydration to induce chirality transitions of these polymers in aqueous phase through interplay competitions between the additives and the polymers against their hydration.

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七种常见养殖鱼血清胰酶抑制活性的比较

水产学报 2003年第5期27卷 415-419页

作者：黄素文陆承平南京农业大学农业部动物疫病诊断与免疫重点实验室南京农业大学农业部动物疫病诊断与免疫重点实验室江苏南京　210095

α2巨球蛋白能结合并抑制蛋白酶的活性,但不抑制该蛋白酶对人工合成的小分子底物的酶活。利用这一特性,选择胰酶的一种有色小分子底物BAPNA,建立BAPNA比色检测法,对7种常见养殖鱼:草鱼、鲫、鲢、胡子鲇、鳙、加州鲈和黄鳝的血清胰酶抑... 详细信息

α2巨球蛋白能结合并抑制蛋白酶的活性,但不抑制该蛋白酶对人工合成的小分子底物的酶活。利用这一特性,选择胰酶的一种有色小分子底物BAPNA,建立BAPNA比色检测法,对7种常见养殖鱼:草鱼、鲫、鲢、胡子鲇、鳙、加州鲈和黄鳝的血清胰酶抑制活性进行了比较,胰酶抑制活性由高到低依次为:草鱼>鲫>黄鳝>鳙>鲢>胡子鲇>加州鲈;α2巨球蛋白活性由高到低依次为:黄鳝>草鱼>胡子鲇>加州鲈>鲢>鳙>鲫;黄鳝和草鱼的α2巨球蛋白活性明显高于其他几种鱼的α2巨球蛋白活性。

关键词： α2巨球蛋白胰酶抑制活性

Efficient large-area flexible organic photovoltaic modules on transparent thin silver electrodes

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Science China Chemistry 2025年

作者： Cong Xie Zedong Xiong Xinlu Liu wen Wang Yang Liu Xueshi Jiang Xin lu lulu Sun Yinhua Zhou Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Kunming Institute of Physics

Large-area flexible organic photovoltaic（OPV） modules are challenging to achieve high power conversion efficiency（PCE）.Electrical shunts or shortages generally occur in large-area OPV modules due to the ultrathin（100–200 nm） and soft active layers. Improving the surface smoothness of bottom transparent electrode will be able to suppress the shunts and shortages. In this work, we report a method to fabricate smooth and flexible transparent electrodes based on thin silver film, and further to fabricate efficient large-area flexible OPV modules. The fabricated thin silver transparent electrodes simultaneously have high conductivity, high optical transmittance, good mechanical flexibility and low surface roughness. Humidity exposure（h.e.）treatment on MoO3effectively facilitates the continuous growth of the thin transparent silver electrode. 6 nm silver film on MoO3（h.e.） on plastic substrate shows a transmittance up to 89%, a sheet resistance of 15 Ω/sq, and a low surface roughness with a rootmean-square value of 0.276 nm. Furthermore, 52-cm2flexible organic solar modules（15 subcells） showed a certified PCE of12.66%. Furthermore, a 1350 cm2flexible component assembled by 25 pieces of 52–55 cm2modules showed certified PCE of12.10% with an open-circuit voltage of 62.85 V.

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Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第01期 201-208页

作者： Hui-Feng Wang wen-Jie Shi Yu-Xin Yang Bao-Xia Dong Tong-Bu lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

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