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Layered niobium carbide enabling excellent kinetics and cycling stability of li-Mg-B-H hydrogen storage material Layered niobium carbide enabling excellent kinetics

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Rare Metals 2024年第3期43卷 1153-1166页

作者： li-wen lu Hui luo Guang-Xu li Yun li Xin-Hua Wang Cun-Ke Huang Zhi-QiangLan wen-Zheng Zhou Jin Guo Mohammad Ismail Hai-Zhen liu Guangxi Novel Battery Materials Research Center of Engineering Technology Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science and TechnologyGuangxi UniversityNanning530004China State Key Laboratory of Featured Metal Materials and life-Cycle Safety for Composite Structures Nanning530004China School of Mechanical and Electrical Engineering Quzhou College of TechnologyQuzhou324000China Department of Materials Science and Engineering Zhejiang UniversityHangzhou310027China Faculty of Ocean Engineering Technology and Informatics Universiti Malaysia Terengganu21030Kuala NerusTerengganuMalaysia Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin300071China

The li-Mg-B-H composite(2liBH_(4)+MgH_(2))has a high capacity of 11.4 wt%as a hydrogen storage ***,the slow kinetics and poor cycling stability severely restrict its practical *** this work,a layered Nb_(2)C MXene was first synthesized and then introduced to tailor the kinetics and cycling stability of the li-Mg-B-H *** milled 2liH+MgB_(2)composites were initially hydrogenated to obtain the 2liBH_(4)+MgH_(2)*** 2liBH_(4)+MgH_(2)+5wt%Nb_(2)C can release 9.0 wt%H_(2)in 30 min at 400℃,while it is only 2.7 wt%for the undoped 2liBH_(4)+MgH_(2).The dehydrogenation activation energies of MgH_(2)and liBH_(4)are 123 and 154 kJ·mol^(-1)respectively for the 5 wt%Nb_(2)C-doped composite,lower than the undoped composite(164 and 165 kJ·mol^(-1)).The 2liBH_(4)+MgH_(2)+5 wt%Nb_(2)C possesses excellent cycling stability,with the reversible capacity only slightly reduced from 9.4 wt%for the 1st cycle to 9.3 wt%for the 20th ***_(2)C keeps stable in the composite and acts as an efficient catalyst for the li-Mg-B-H *** is believed that both the layered structure and the active Nb element contribu te to the enhanced hydrogen storage performances of the li-Mg-B-H *** work confirms that the Nb_(2)C MXene with layered stru cture has a significant enhancing impact on the li-Mg-B-H hydrogen storage materials,which is different from the bulk NbC.

关键词： Hydrogen storage lithium borohydride Magnesium hydride Nb_(2)C MXene

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Digital and analog hybrid control in adaptive interference cancellation system

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The Journal of China Universities of Posts and Telecommunications 2010年第6期17卷 1-10页

作者： JIANG Yun-hao ZHAO Zhi-hua TANG Jian li wen-lu XIAO Huan College of Electrical and Electronic Engineering Huazhong Utliversity of Science and Technology Wuhan 430074 China National Key Laboratory for Vessel Integrated Power System Technology Naval University of Engineering Wuhan 430033 China

The digital proportion control is introduced to improve the performance of the analog adaptive interference cancellation system （ICS）. For the high frequency parts of the signals after multiplier are not required,the sampling frequency need not satisfy the sampling theorem for high frequency. Because the sampling,calculation and output expend time in digital control,the ideal condition,delay condition and delay-wait condition are taken into account. Through analyzing the system model with three conditions,we gain the stable conditions of the system,the optimization step factors that can make the system converge fastest and the formulas of the interference cancellation ratios （ICRs）. One step convergence can be accomplished under ideal condition,whereas the system can not converge in one step under delay condition and delay-wait condition. The calculation results show the convergence speed of delay-wait condition is slower than that of delay condition. The ICR is improved with the increase of the step factor which is in stable bound,but the convergence speed is decreased if the step factor exceeds the optimization step factor. In order to avoid that confine,the method of amending the steady state weight to improve the ICR is proposed. The analyses are in agreement with the computer simulations.

关键词： digital and analog hybrid control adaptive interference cancellation weight ICR convergence speed

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Electrochemical Activation of CO_2 for the Synthesis of Ethyl Carbanilate under Mild Conditions

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Chemical Research in Chinese Universities 2007年第6期23卷 708-711页

作者： NIU Dong-fang XU Cheng-tian luO Yi-wen ZHANG li lu Jia-xing Shanghai Key Laboratory of Green Chemistry and Chemical Processes Department of Chemistry East China Normal University Shanghai 200062 P. R. China

A novel electrochemical procedure for the synthesis of ethyl carbanilate from aniline and carbon dioxide was developed via the selective cathodic reduction of carbon dioxide in CO2-saturated DMF solution containing 0. 1 mol/L TEABr at room temperature, followed by the addition of Eft as an alkylating agent. The synthesis was carried outun der mild[p（CO2） = 1.0×10^5 Pa, t =20 ℃ ] and safe conditions. Influences of the nature of the electrodes, the current densities, the passed charges during electrolysis, temperatures, and supporting electrolytes on the yield of ethyl carbanilate were studied to optimize the electrolytic conditions. The selectivity of ethyl carbanilate is 100%.

关键词： Carbon dioxide Electrochemistry Aniline Synthesis Ethyl carbanilate Mild condition

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Yang cycle enzyme DEP1: its moonlighting functions in PSI and ROS production during leaf senescence

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Molecular Horticulture 2022年第1期2卷 133-148页

作者： Chu-Kun Wang Xiu-Ming li Fang Dong Cui-Hui Sun wen-li lu Da-Gang Hu National Key Laboratory of Crop Biology MOA Key Laboratory of Horticultural Crop Biology and Germplasm InnovationCollege of Horticulture Science and EngineeringShandong Agricultural UniversityTai’an 271018ShandongChina Shandong Institute of Pomology Key Laboratory for Fruit Biotechnology Breeding of ShandongTai’an 271000ShandongChina

Ethylene-mediated leaf senescence and the compromise of photosynthesis are closely associated but the underlying molecular mechanism is a *** we reported that apple DEHYDRATASE-ENOLASE-PHOSPHATASE-COMPLEX1(MdDEP1),initially characterized to its enzymatic function in the recycling of the ethylene precursor SAM,plays a role in the regulation of photosystem I(PSI)activity,activating reactive oxygen species(ROS)homeostasis,and negatively regulating the leaf senescence.A series of Y2H,Pull-down,CO-IP and Cell-free degradation biochemical assays showed that MdDEP1 directly interacts with and dephosphorylates the nucleus-encoded thylakoid protein MdY3IP1,leading to the destabilization of MdY3IP1,reduction of the PSI activity,and the overproduction of ROS in plant *** findings elucidate a novel mechanism that the two pathways intersect at MdDEP1 due to its moonlighting role in destabilizing MdY3IP1,and synchronize ethylene-mediated leaf senescence and the compromise of photosynthesis.

关键词： DEHYDRATASE-ENOLASE-PHOSPHATASE-COMPLEX1 Yang cycle Photosystem I ROS Leaf senescence Photosynthesis

Neuroprotective effects of stearic acid against toxicity of oxygen/glucose deprivation or glutamate on rat cortical or hippocampal slices

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Acta Pharmacologica Sinica 2006年第2期27卷 145-150页

作者： Ze-jian WANG Guang-mei li wen-lu TANG Ming YIN~2 School of Pharmacy,Shanghai Jiaotong University.Shanghai 200030,China School of Pharmacy Shanghai Jiaotong University Shanghai China

Aim:To observe the effects of stearic acid,a long-chain saturated fatty acidconsisting of 18 carbon atoms,on brain(cortical or hippocampal)slices insultedby oxygen-glucose deprivation(OGD),glutamate or sodium azide(NAN3)in ***:The activities of hippocampal slices were monitored by population spikesrecorded in the CA1 region,In vitro injury models of brain slice were induced by10min of OGD,1 mmol/L glutamate or 10 mmol/L *** 30min of pre-incubation with stearic acid(3-30μmol/L),brain slices(cortical or hippocampal)were subjected to OGD,glutamate or NaN3,and the tissue activities were evalu-ated by using the 2,3,5-triphenyltetrazolium chloride ***886 [5 mmol/L;a noncompetitive inhibitor of proliferator-activated receptor(PPAR-α)] or BADGE(bisphenol A diglycidyl ether;100μmol/L;an antagonist of PPAR-γ)were testedfor their effects on the neuroprotection afforded by stearic ***:Viabilityof brain slices was not changed significantly after direct incubation with ***,glutamate and NaN3injury significantly decreased the viability ofbrain *** acid(3-30 μmol/L)dose-dependently protected brain slicesfrom OGD and glutamate injury but not from NaN3injury,and its neuroprotectiveeffect was completely abolished by ***:Stearic acid can protectbrain slices(cortical or hippocampal)against injury induced by OGD or *** neuroprotective effect may be mainly mediated by the activation of PPAR-γ.

关键词： fatty acid brain slices ischemia glutamate energy metabolism

Alström syndrome with a novel mutation of ALMS1 and Graves’hyperthyroidism:A case report and review of the literature

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World Journal of Clinical Cases 2021年第13期9卷 3200-3211页

作者： Juan-Juan Zhang Jun-Qi Wang Man-Qing Sun De Xu Yuan Xiao wen-li lu Zhi-Ya Dong Department of Pediatrics Ruijin HospitalShanghai Jiao-Tong UniversitySchool of MedicineShanghai 200025China

BACKGROUND Alström syndrome(AS,OMIM ID 203800)is a rare disease involving multiple organs in children and is mostly reported in non-Chinese *** the Chinese population,there are few reports on the clinical manifestations and pathogenesis of *** is the first report on the association between AS and Graves’*** SUMMARY An 8-year-old Chinese girl was diagnosed with *** years later,Graves’hyperthyroidism developed with progressive liver *** patient’s clinical data were collected;DNA from peripheral blood of the proband,parents and sibling was collected for gene mutation detection using the second-generation sequencing method and gene panel for *** association between the patient’s genotype and clinical phenotype was *** carried the pathogenic compound heterozygous mutation of ALMS1(c.2296_2299del4 and c.11460C>A).These stop-gain mutations likely caused truncation of the ALMS1 *** The manifestation of hyperthyroidism may suggest rapid progression of AS.

关键词： ALMS1 Alström syndrome Stop-gain mutations Protein truncation Graves’hyperthyroidism Case report

Clinical and molecular characterization of 10 Chinese children with congenital adrenal hyperplasia due to 11beta‑hydroxylase deficiency

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World Journal of Pediatrics 2024年第4期20卷 422-433页

作者： wen‑li lu Xiao‑Yu Ma Jiao Zhang Jun‑Qi Wang Ting‑Ting Zhang Lei Ye Yuan Xiao Zhi‑Ya Dong Wei Wang Shou‑Yue Sun Chuan‑Yin li Rong‑Gui Hu Guang Ning li‑Dan Zhang Department of Pediatrics Ruijin HospitalShanghai Jiao Tong University School of MedicineNo.197Ruijin 2nd RdHuangpu DistrictShanghai 200025China Department of Pediatric Genetic and Metabolic Endocrinology West China Second University HospitalSichuan UniversityNo.20Section 3Renmin South RoadSichuan 610041China Department of Endocrine and Metabolic Diseases Shanghai Clinical Center for Endocrine and Metabolic DiseasesRuijin HospitalShanghai Jiao Tong University School of MedicineShanghai 200025China Cancer Center School of MedicineShanghai Tenth People’s HospitalTongji UniversityYanchang Zhong Lu 301St RdJing’an DistrictShanghai 200031China

Background The clinical manifestations of nonclassical 11beta-hydroxylase deficiency are very similar to those of nonclassical 21-hydroxylase *** this study,we investigated the relationship between the clinical and molecular features of congenital adrenal hyperplasia caused by 11beta-hydroxylase deficiency and reviewed the related literature,which are expected to provide assistance for the clinical diagnosis and analysis of congenital adrenal *** Clinical data for 10 Chinese patients diagnosed with congenital adrenal hyperplasia in our hospital from 2018 to 2022 were retrospectively *** examined the effects of gene mutations on protease activity and constructed threedimensional structure prediction models of *** We describe 10 patients with 11beta-hydroxylase gene mutations(n=5,46,XY;n=5,46,XX),with 10 novel mutations were *** patients received treatment at an early stage,with an average age of 2.08±1.66 years,whereas male patients received treatment significantly later,at an average age of 9.77±3.62 *** most common CYP11B1 pathogenic variant in the Chinese population was found to be c.1360C>*** mutations lead to spatial conformational changes that affect protein *** Our study found that there was no significant correlation between each specific mutation and the severity of clinical *** patients with the same gene pathogenic variant may have mild or severe clinical *** correlation between genotype and phenotype needs further ***-dimensional protein simulations may provide additional support for the physiopathological mechanism of genetic mutations.

关键词： 11β-hydroxylase deficiency CYP11B1 Enzymatic activity Phenotype-genotype correlation Threedimensional protein simulations

Empirical Research On College-students' Leisure Motivation——take some universities in si-chuan province as an example

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Empirical Research On College-students' Leisure Motivation—...

Thermoresponsive helical dendronized poly(arylacetylene)s:modulating the dynamic chirality

2013年教育技术与管理科学国际会议

作者： li wen-lu Feng Ming-yi li Qi-yuan School of Management China West Normal University

Based on a sample of some universities in si-chuan province, with the method of question-and-answer survey and mathematical statistics, we have analyzed the behavioural characteristic of college-students’ leisure motivation. The main conclusions are that leisure motivation is single, and leisure life is monotonous, etc. According to the conclusions, we discuss about the solving suggestions.

关键词： college-students leisure motivation conclusion

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Science China Chemistry 2025年

作者： Xueting lu Lei Wang liangxuan Ren wen li Afang Zhang International Joint Laboratory of Biomimetic&Smart Polymers School of Materials Science and EngineeringShanghai University

Helical poly(arylacetylene)s have formed an intriguing class of polymers,whose chiralities are dynamic and liable to external *** combining dendronized polymer topology with dendritic oligoethylene glycols (OEGs),we here report on synthesis of a homologous series of thermoresponsive dendronized poly(arylacetylene)s with either poly(phenyl acetylene) or poly(naphthalene acetylene) as the backbones,and investigate tunability of their helical *** polymers carry dendritic OEG pendants with either methoxyl-or ethoxyl-terminals to tune their unprecedent thermoresponsive behaviors,and at the same time,dendritic shielding plays an important role in mediating their thermal phase transition *** of these polymers is originated from the chiral alanine or phenylalanine moieties within the dendritic pendants,which can be tailored through manipulating solvation in different organic solvents or via thermal dehydration and collapse in ***,achiral additives such as linear or dendritic OEGs and benzene derivatives can act similarly as thermal dehydration to induce chirality transitions of these polymers in aqueous phase through interplay competitions between the additives and the polymers against their hydration.

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