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Polycaprolactone-carboxymethyl cellulose composites for manufacturing porous scaffolds by material extrusion

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Bio-Design and Manufacturing 2018年第4期1卷 245-253页

作者： M.E.Aleman-Domfnguez z.Ortega A.N.Benitez Mario Monzon L.v.Garzon Sara Ajami Chaozong Liu Departamento de Ingenier/a de Procesos Universidad de Las Palmas de Gran CanadaEdificio de Fabricacion integrada Parque Cientifico-Tecnologico de la ULPGC35017Las PalmasSpain Departamento de Ingenierfa Mecainica Universidad de Las Palmas de Gran CanadaEdificio de Fabricacion integrada Parque Cientifico-Tecnologico de la ULPGC35017 Las PalmasSpain Institute of Orthopaedic and Musculoskeletal Science Royal National Orthopaedic HospitalUniversity College London StanmoreLondon HA74LPUK

Polycaprolactone-carboxymethyl cellulose composites have been obtained and used to print porous structures by material *** materials used contained 0,2 and 5% w/w of the carboxymethyl cellulose *** structures have been analyzed in terms of their morphology (including the evaluation of their porosity),mechanical properties under compression load and cell *** affinity has been evaluated by culturing sheep mesenchymal stem cells and analyzing their viability by the Alamar Blue(R)assay at days 1,3,6 and *** results show that composites samples have similar values of porosity and apparent density than pure polycaprolactone ***,samples containing 5%w/w of carboxymethyl cellulose have micropores on the filaments due to a hindered deposition *** characteristic affects the mechanical properties of the structures,so these ones have a mean compression modulus significantly lower than pure polycaprolactone ***, the samples containing 2%w/w of carboxymethyl cellulose show no significant difference with the pure polycaprolactone ones in terms of their mechanical ***,the presence of 2%w/w of additive improves cell proliferation on the surface of the porous *** complementary information,the flow properties of the composite materials were studied and the power law equations at 210℃ obtained,as this temperature was the 3D printing *** equations can be useful for simulation and designing purposes of other manufacturing processes.

关键词： Additive manufacturing Tissue engineering viscosity model Biomaterials 3D printing Bone regeneration

The Holocene environmental changes revealed from the sediments of the Yarkov sub-basin of Lake Chany,south-western Siberia

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Geoscience Frontiers 2023年第2期14卷 133-153页

作者： S.K.Krivonogov A.N.zhdanova P.A.Solotchin A.Y.Kazansky v.v.Chegis z.Liu M.Song S.v.zhilich N.A.Rudaya X.Cao O.v.Palagushkina L.B.Nazarova L.S.Syrykh Institute of Geology and Mineralogy Russian Academy of SciencesSiberian BranchNovosibirskRussia Novosibirsk State University NovosibirskRussia Korkyt Ata Kyzylorda University KyzylordaKazakhstan Moscow State University MoscowRussia Geological Institute Russian Academy of SciencesMoscowRussia Pushkov Institute of Terrestrial Magnetism Ionosphere and Radio Wave PropagationRussian Academy of SciencesTroitskRussia Department of Earth Sciences The University of Hong KongHong KongChina State Key Laboratory of Loess and Quaternary Geology Institute of Earth EnvironmentChinese Academy of SciencesXi’anChina Institute of Archaeology and Ethnography Russian Academy of SciencesSiberian BranchNovosibirskRussia Tomsk State University TomskRussia Alpine Paleoecology and Human Adaptation Group(ALPHA) State Key Laboratory of Tibetan Plateau Earth SystemEnvironment and Resources(TPESER)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijingChina volga Region Federal University KazanRussia Krasnoyarsk Science Center Russian Academy of SciencesSiberian BranchKrasnoyarskRussia Herzen State Pedagogical University St.PetersburgRussia

Lake Chany is the largest endorheic lake in Siberia whose catchment is entirely on the territory of *** geographical location on the climate-sensitive boundary of wet and dry landscapes provides an opportunity to gain more knowledge about environmental changes in the West Siberian interior during the Holocene and about the evolution of the lake *** cores obtained from the Yarkov subbasin of the lake in 2008 have been comprehensively studied by a number of approaches including sedimentology and AMS dating,pollen,diatom and chironomid analyses(with statistical interpretation of the results),mineralogy of authigenic minerals and geochemistry of plant lipids(biomarker analysis.).Synthesis of new results presented here and published data provides a good justification for our hypothesis that Lake Chany is very young,no older than 3.6 ka *** that,between 9 and 3.6 ka BP,the Chany basin was a swampy landscape with a very low sedimentation rate;it could not be identified as a water *** the early lake phase,between 3.6 and 1.5 ka BP,the lake was shallow,1.2–3.5 m in depth,and it rose to its modern size,up to 6.5 m in depth,during the last *** data reveal important changes in the understanding of the history of this large endorheic lake,as before it was envisioned as a large lake with significant changes in water level since ca.14 ka *** addition to hydrology,our proxies provide updates and details of the regional vegetation and climate change since ca.4 ka BP in the WestSiberian forest-steppe and *** evolution of the Chany basin is dependent on hydroclimatic changes in a large region of southern West Siberia,we compare lake-level change and climate-change proxies from the other recently and most comprehensively studied lakes of the region.

关键词： Saline lake Multiproxy study Holocene Climate Environment West Siberia

Crystal Structure of 5 ( l Menthyloxy) 3 Chloro 4 Pyrrolidinyl 2(5H) Furanone

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Chinese Journal of Structural Chemistry 1999年第2期18卷 35-38页

作者： Geng, z Chen, QH Capital Normal Univ Dept Chem Beijing 100037 Peoples R China Beijing Normal Univ Dept Chem Beijing 100875 Peoples R China

The molecular structure of the title compound 5 ( l menthyloxy) 3 chloro 4 pyrrolidinyl 2(5H) furanone, C 18 H 28 ClNO 3(Ⅰ), has been determined by X ray diffraction at 296(1)K. The crystal is monoclinic with space group P2 1, a=9 457(3), b=10.413(3), c=9.525(2) , β=95.19(2)°, v=934(1)  3, z=2, M r=341.88, D x =1.22 g/cm 3, μ =2.15 cm -1 , F(000)=368. The final R factor is 0 059, and R w is 0.065 for 1020 observed reflections with I≥3σ(I) . The absolute configuration at C(14) of the acetal carbon was proved to be S , taking into account the known configuration of 1R, 2S, 5R menthyl moiety. There are three rings in the molecule of this compound: the furanone ring, the pyrrolidine ring and the mentholoxy group ring. The franone ring is connected with the pyrrolidine ring and the mentholoxy ring by N atom and μ 2 O bridge atom respectively.

关键词： crystal structure absolute configuration Michael addition elimination reaction

Effects of Plant Residue Decomposition on Soil N Availability,Microbial Biomass and β-Glucosidase Activity During Soil Fertility Improvement in Ghana

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Pedosphere 2019年第5期29卷 608-618页

作者： Samuel T. PARTEY Robert B. z0UGM0RE Naresh v. THEvATHASAN Richard F. PREzIOSI CGI AR CCAFS West Africa ProgramInternational Crops Research Institute for the Semi-Arid Tropics (ICRISAT)Bamako B.P. Box 320 (Mali) School of Environmental Sciences University of GuelphGuelph NIG 2W1 (Canada) Faculty of Life Sciences The University of ManchesterManchester M13 9PL (UK)

With limited use of inorganic fertilizers on smallholder farms,plant residues could be viable alternatives for soil fertility *** study was conducted to determine how residue quality and decomposition of nine plant species influence soil N availability,microbial biomass,andβ-glucosidase activity during soil fertility *** differences in N concentration were found among the species,ranging from 12.2 g kg-1 in zea mays to 39.2 g kg-1 in Baphia *** C/N ratio was the highest in ***(34.4),whereas lignin and polyphenol concentrations were the greatest in Acacia *** highest decomposition rate(0.251%per day)occurred in Tithonia diversifolia,and the lowest in ***,Albizia zygia,***,and ***,with the half-lives of 28-56 *** 80%and 89%of N,P,K,Ca,and Mg were released from *** in 7 d,compared with over 70%retention in ***,***,and *** decomposition and nutrient release half-lives of Gliricidia sepium,Leucaena leucocephala,Azadirachta indica,and Senna spectabilis were less than 14 *** mineral N,microbial biomass,andβ-glucosidase activity increased under all treatments,with *** having the greatest *** N mineralization occurred in all of the species throughout the experiment,an initial N immobilization was recorded in the ***,***,***,and *** treatments for up to 14 *** and nutrient release rates,mineral N,soil microbial biomass,andβ-glucosidase activity were dependent on residue quality,and P and lignin levels,the lignin/N ratio,and the(lignin+polyphenol)/N ratio had the most significant effects(P≤0.05).

关键词： leguminous species litter quality microbial activity N mineralization nutrient release organic matter

Charge self-trapping in two strand biomolecules:Adiabatic polaron approach

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Chinese Physics B 2023年第1期32卷 253-263页

作者： D Chev.zovich S zdravković A v Chizhov.z Ivić University of Belgrade Vinča Institute of Nuclear SciencesP.O.Box 522Belgrade 11001Serbia Joint Institute for Nuclear Research Laboratory for Radiation BiologyDubna 141980Russia Dubna State University Dubna 141980Russia Department of Physics University of CreteP.O.Box 2208Heraklion 71003Greece National University of Science and Technology MISiS Leninsky prosp.4Moscow 119049Russia

We investigate the properties of the excess charge(electron, hole) introduced into a two-strand biomolecule. We consider the possibility that the stable soliton excitation can be formed due to interaction of excess charge with the phonon subsystem. The influence of overlap of the molecular orbitals between adjacent structure elements of the macromolecular chain on the soliton properties is discussed. Special attention is paid to the influence of the overlapping of the molecular orbitals between structure elements placed on the different chains. Using the literature values of the basic energy parameters of the two-chain biomolecular structures, possible types of soliton solutions are discussed.

关键词： charge self-trapping adiabatic polaron soliton two-stranded biomolecules

Pitting Corrosion Behaviour of Monel-400 Alloy in Chloride Solutions

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Journal of Materials Science & Technology 1999年第3期15卷 208-212页

作者： v.K.Gouda I.z.Selim A.A.Khedr and A.M.Fathi(Physical Chemistry Dept., National Research Centre, Dokki, Cairo, Egypt) Physical Chemistry Dept. National Research Centre Dokki Cairo Egypt

Pitting corrosion behaviour of Monel-400 alloy in 3.5 wt pct NaCl sodium chloride solution has been investigated using the cyclic potentiodynamic anodic polarization technique. The effect of chloride ion concentration, pH values and difFerent temperatures on the pitting parameters were determined. The morphology of the pits produced after anodic polarization treatments was inspected by scanning electron microscope (SEM). The results indicated that, the increase in chloride ion concentration shifts Epit and Eprot of the alloy toward negative values and the pitting potential is much more dependent on pH value in the basic region. The breakdown of passivity with increasing temperature may be due to kinetic changes of passivating films and dissolution rate of the alloy in its passive state

关键词： Figure Pitting Corrosion Behaviour of Monel-400 Alloy in Chloride Solutions

Plasma electrolytic oxidation of Az31 and Az91 magnesium alloys:Comparison of coatings formation mechanism

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Journal of Magnesium and Alloys 2020年第3期8卷 587-600页

作者： A.G.Rakoch E.P.Monakhova z.v.Khabibullina M.Serdechnova C.Blawert M.L.zheludkevich A.A.Gladkova aDepartment of Metal Protection and Surface Treatment National University of Science and Technology‘MISiS’Leninskiy prospekt 4119049 MoscowRussia Helmholtz-zentrum Geesthacht Centre for Materials and Coastal Research GmbHMax-Plank Str.l21502 GeesthachtGermany Faculty of Engineering Kiel UniversityKaiserstrasse 224143 KielGermany

The growth kinetics of PEO coatings on Az31 and Az91 magnesium alloys were studied and correlated with their structure,compositions(phase and elemental)and corrosion *** was established that the coatings have a two-(outer and anodic)or three-layer structure(outer,inner and anodic)depending on the treatment ***,at short treatment time only an anodic layer and outer layer *** of the outer PEO layer takes place due to the micro discharges,which occur in vertical pores and voids with spherical *** the time is increasing,and electrolyte inside of the pores is heating-up,etching of the Mg substrate and oxide film becomes more dominant and horizontal pores in the interface between coating and metal are *** the pores new anodic layer will form and at this time the formation of the third inner layer *** growth of the inner layer happens via the anodic film as a result of micro discharge ignition in the horizontal pores,accompanied by formation of plasma in numerous micro-voids of this *** coatings formed on Az91 alloy are denser,than those on Az31,which is related to the difference in the rates of inner layer growth and dissolving of oxides which are located at the bottom of the horizontal *** of the lower Al content,the Az31 substrate itself and the also the oxide films are less stable and tend to dissolve at a higher rate compared to ***,it was demonstrated that a good corrosion resistance of the coatings was only obtained on Az91 and if the average thickness of the coating is around 50μm,correlating with the formation of a sufficiently dense inner laye-Knowing this mechanism,a new two-step treatment was suggested,combining the standard PEO treatment with a subsequent PEO process in an electrolyte supporting the inner film *** concept was successfully applied and a further improved corrosion resistance was obtained compared to the single stage PEO *** improvement of corrosion re

关键词： Plasma electrolytic oxidation Magnesium alloys Coating formation Coating growth Corrosion resistance.

Evidence for particle acceleration approaching Pev energies in the W51 complex

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Science Bulletin 2024年第18期69卷 2833-2841页

作者： LHAASO Collaboration zhen Cao F.Aharonian Axikegu Y.X.Bai Y.W.Bao D.Bastieri X.J.Bi Y.J.Bi W.Bian A.v.Bukevich Q.Cao W.Y.Cao zhe Cao J.Chang J.F.Chang A.M.Chen E.S.Chen H.X.Chen Liang Chen Lin Chen Long Chen M.J.Chen M.L.Chen Q.H.Chen S.Chen S.H.Chen S.z.Chen T.L.Chen Y.Chen N.Cheng Y.D.Cheng M.Y.Cui S.W.Cui X.H.Cui Y.D.Cui B.z.Dai H.L.Dai z.G.Dai Danzengluobu X.Q.Dong K.K.Duan J.H.Fan Y.z.Fan J.Fang J.H.Fang K.Fang C.F.Feng H.Feng L.Feng S.H.Feng X.T.Feng Y.Feng Y.L.Feng S.Gabici B.Gao C.D.Gao Q.Gao W.Gao W.K.Gao M.M.Ge L.S.Geng G.Giacinti G.H.Gong Q.B.Gou M.H.Gu F.L.Guo X.L.Guo Y.Q.Guo Y.Y.Guo Y.A.Han M.Hasan H.H.He H.N.He J.Y.He Y.He Y.K.Hor B.W.Hou C.Hou X.Hou H.B.Hu Q.Hu S.C.Hu D.H.Huang T.Q.Huang W.J.Huang X.T.Huang X.Y.Huang Y.Huang X.L.Ji H.Y.Jia K.Jia K.Jiang X.W.Jiang z.J.Jiang M.Jin M.M.Kang I.Karpikov D.Kuleshov K.Kurinov B.B.Li C.M.Li Cheng Li Cong Li D.Li F.Li H.B.Li H.C.Li Jian Li Jie Li K.Li S.D.Li W.L.Li W.L.Li X.R.Li Xin Li Y.z.Li zhe Li zhuo Li E.W.Liang Y.F.Liang S.J.Lin B.Liu C.Liu D.Liu D.B.Liu H.Liu H.D.Liu J.Liu J.L.Liu M.Y.Liu R.Y.Liu S.M.Liu W.Liu Y.Liu Y.N.Liu Q.Luo Y.Luo H.K.Lv B.Q.Ma L.L.Ma X.H.Ma J.R.Mao z.Min W.Mitthumsiri H.J.Mu Y.C.Nan A.Neronov L.J.Ou P.Pattarakijwanich z.Y.Pei J.C.Qi M.Y.Qi B.Q.Qiao J.J.Qin A.Raza D.Ruffolo A.Sáiz M.Saeed D.Semikoz L.Shao O.Shchegolev X.D.Sheng F.W.Shu H.C.Song Yu.v.Stenkin v.Stepanov Y.Su D.X.Sun Q.N.Sun X.N.Sun z.B.Sun J.Takata P.H.T.Tam Q.W.Tang R.Tang z.B.Tang W.W.Tian C.Wang C.B.Wang G.W.Wang H.G.Wang H.H.Wang J.C.Wang Kai Wang Kai Wang L.P.Wang L.Y.Wang P.H.Wang R.Wang W.Wang X.G.Wang X.Y.Wang Y.Wang Y.D.Wang Y.J.Wang z.H.Wang z.X.Wang zhen Wang zheng Wang D.M.Wei J.J.Wei Y.J.Wei T.Wen C.Y.Wu H.R.Wu Q.W.Wu S.Wu X.F.Wu Y.S.Wu S.Q.Xi J.Xia G.M.Xiang D.X.Xiao G.Xiao Y.L.Xin Y.Xing D.R.Xiong z.Xiong D.L.Xu R.F.Xu R.X.Xu W.L.Xu L.Xue D.H.Yan J.z.Yan T.Yan C.W.Yang C.Y.Yang F.Yang F.F.Yang L.L.Yang M.J.Yang R.z.Yang W.X.Yang Y.H.Yao z.G.Yao L.Q.Yin N.Yin X.H.You z.Y.You Y.H.Yu Q.Yuan H.Yue H.D.zeng T.X.zeng W.zeng M.zha B.B.zhang F.zhang H.zhang 不详 Key Laboratory of Particle Astrophysics&Experimental Physics Division&Computing Center Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences Beijing 100049China TIANFU Cosmic Ray Research Center ChengduChina Dublin Institute for Advanced Studies 31 Fitzwilliam Place2 DublinIreland Max-Planck-Institut for Nuclear Physics P.O.Box 103980Heidelberg 69029Germany School of Physical Science and Technology&School of Information Science and Technology Southwest Jiaotong UniversityChengdu 610031China School of Astronomy and Space Science Nanjing UniversityNanjing 210023China Center for Astrophysics Guangzhou UniversityGuangzhou 510006China Tsung-Dao Lee Institute&School of Physics and Astronomy Shanghai Jiao Tong UniversityShanghai 200240China Institute for Nuclear Research of Russian Academy of Sciences Moscow 117312Russia Hebei Normal University Shijiazhuang 050024China University of Science and Technology of China Hefei 230026China State Key Laboratory of Particle Detection and Electronics China Key Laboratory of Dark Matter and Space Astronomy&Key Laboratory of Radio Astronomy Purple Mountain ObservatoryChinese Academy of SciencesNanjing 210023China Research Center for Astronomical Computing Zhejiang LaboratoryHangzhou 311121China Key Laboratory for Research in Galaxies and Cosmology Shanghai Astronomical ObservatoryChinese Academy of SciencesShanghai 200030China School of Physics and Astronomy Yunnan UniversityKunming 650091China Key Laboratory of Cosmic Rays(Tibet University) Ministry of EducationLhasa 850000China National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China School of Physics and Astronomy(zhuhai)&School of Physics(Guangzhou)&Sino-French Institute of Nuclear Engineering and Technology(zhuhai) Sun Yat-sen UniversityZhuhai 519000&Guangzhou 510275GuangdongChina Institute of Frontier and Interdisciplinary Science Shandong UniversityQingdao 266237China APC UniversitéParis Cité

Theγ-ray emission from the W51 complex is widely acknowledged to be attributed to the interaction between the cosmic rays(CRs)accelerated by the shock of supernova remnant(SNR)W51C and the dense molecular clouds in the adjacent star-forming region,***,the maximum acceleration capability of W51C for CRs remains *** on observations conducted with the Large High Altitude Air Shower Observatory(LHAASO),we report a significant detection ofγrays emanating from the W51 complex,with energies from 2 to 200 *** LHAASO measurements,for the first time,extend theγ-ray emission from the W51 complex beyond 100 Tev and reveal a significant spectrum bending at tens of *** combining the"π^(0)-decay bump"featured data from Fermi-LAT,the broadbandγ-ray spectrum of the W51 region can be well-characterized by a simple pp-collision *** observed spectral bending feature suggests an exponential cutoff at~400 Tev or a power-law break at~200 Tev in the CR proton spectrum,most likely providing the first evidence of SNRs serving as CR accelerators approaching the Pev ***,two young star clusters within W51B could also be theoretically viable to produce the most energeticγrays observed by *** findings strongly support the presence of extreme CR accelerators within the W51 complex and provide new insights into the origin of Galactic CRs.

关键词： UHE c-ray Cosmic rays SNR W51C Star clusters

Synthesis of self-assembled nanorod vanadium oxide bundles by sonochemical treatment

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Journal of Natural Gas Chemistry 2009年第3期18卷 312-318页

作者： Y.H.Taufiq-Yap Y.C.Wong z.zainal M.z.Hussein Centre of Excellence for Catalysis Science and Technology Faculty of ScienceUniversiti Putra Malaysia Department of Chemistry Faculty of ScienceUniversiti Putra Malaysia

Self-assembled nanorod of vanadium oxide bundles were synthesized by treating bulk v2O5 with high intensity sonochemical technique. The synthesized materials were characterized by X-ray diffraction （XRD）, scanning electron microscope （SEM）, transmission electron microscope （TEM） and temperature-programmed reduction （TPR） in H2. Catalytic behaviour of the materials over anaerobic n-butane oxidation was studied through temperature-programmed reaction （TPRn）. Catalytic evaluation of the sonochemical treated v2O5 products was also studied on microreactor. XRD patterns of all the vanadium samples were perfectly indexed to v2O5. The morphologies of the nanorod vanadium oxides as shown in SEM and TEM depended on the duration of the ultrasound irradiation. Prolonging the ultrasound irradiation duration resulted in materials with uniform, well defined shapes and surface structures and smaller size of nanorod vanadium oxide bundles. H2-TPR profiles showed that larger amount of oxygen species were removed from the nanorod v2O5 compared to the bulk. Furthermore, the nanorod vanadium oxide bundles, which were produced after 90, 120 and 180 min of sonochemical treatment, showed an additional reduction peak at lower temperature （-850 K）, suggesting the presence of some highly active oxygen species. TPRn in n-butane/He over these materials showed that the nanorod v2O5 with highly active oxygen species showed markedly higher activity than the bulk material, which was further proven by catalytic oxidation of n-butane.

关键词： nanorod vanadium oxide sonochemical treatment butane oxidation