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Influence of TiO_2 on the electrochemical performance of pasted typeβ-nickel hydroxide electrode in alkaline electrolyte

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Journal of Energy Chemistry 2016年第1期25卷 41-48页

作者： B.Shruthi B.J.Madhu v.bheema raju Department of Chemistry Dr. Ambedkar Institute of Technology Post Graduate Department of Physics Government Science College Department of Chemistry Dayananda Sagar College of Engineering

Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide（β-Ni（OH）2 ） was prepared from nickel sulphate solution using potassium hydroxide as a precipitating agent. Pure β-phase of nickel hydroxide was confirmed from XRD and FT-IR studies. The effects of TiO2 additive on the β-Ni（OH）2 electrode performance are examined. The structure and property of the TiO2 added β-Ni（OH）2 were characterized by XRD, TG-DTA and SEM analysis. A pasted–type electrode is prepared using nickel hydroxide powder as the main active material on a nickel sheet as a current collector. Cyclic voltammetry and electrochemical impedance spectroscopy studies were performed to evaluate the electrochemical performance of the β-Ni（OH）2 and TiO2 added β-Ni（OH）2 electrodes in 6 M KOH electrolyte. Anodic（Epa） and cathodic（Epc）peak potentials are found to decrease after the addition of TiO 2 into β-Ni（OH）2 electrode material. Further,addition of TiO2 is found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current. Compared with pure β-Ni（OH）2 lectrode,TiO2 added β-Ni（OH）2 electrode is found to exhibit higher proton diffusion coefficient（D） and lower charge transfer resistance. These findings suggest that the TiO2 added β-Ni（OH）2 electrode possess improved electrochemical properties and thus can be recognized as a promising candidate for the battery electrode applications.

关键词： Nickel hydroxide Electrode material Thermogravimetric analysis Electrochemical properties Impedance spectroscopy

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A review on the current status of Fe-Al based ferritic lightweight steel

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Defence Technology（防务技术） 2023年第8期26卷 1-22页

作者： Shivkumar Khaple Brahma raju Golla v.v.Satya Prasad Defence Metallurgical Research Laboratory HyderabadIndia Metallurgical and Materials Engineering Department National Institute of TechnologyWarangalIndia

There is an ever-growing demand for lightweighting of steel for structural applications,particularly for automobile and transportation *** is mainly to improve the fuel efficiency,reduce the CO_(2) emissions and cater the increased passenger ***,the main focus is to reduce the density of the steel structure without affecting other *** can be achieved by down-gauging of the conventional steel by replacing the steel with higher strength,however,it is limited by dent resistance and ***,the novel idea is to reduce the density of the steel *** is well-known that addition of Al to steel reduces the density of the *** 1wt% of Al addition to steel can reduce the density by 1.3%,decreases the elastic modulus by 2% and it improves the strength by about 40 *** is a new class of low-density/lightweight steel with addition of about 6-9 wt% Al to *** of higher than 9 wt%of Al in steel leads to embrittlement issues due to ordering and environmental *** disordered Fe-Al lightweight steels have raised considerable interest due to their low-density,high ductility,costeffectiveness and feasibility for bulk *** low-density steels are envisaged in the development of an advanced lightweight ground transportation system,huge structures and also for certain defence applications and in thermal power plants.

关键词： Low-density steels Disordered FeeAl Thermo-mechanical processing Microstructure Properties Structure-property correlation

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Elastic scattering of ^(13)C and ^(14)C isotopes on a ^(208)Pb target at energies of approximately five times the Coulomb barriers

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Chinese Physics C 2024年第3期48卷 65-71页

作者：杨过段芳芳王康杨彦云孙志宇 valdir Guimarães 庞丹阳陈文棣金磊许世伟马军兵马朋白真汪凌昊刘泉王惠仁吕冰锋郭松 Mukhi Kumar raju 王秀华李荣华张玉虎周小红胡正国徐瑚珊 CAS Key Laboratory of High Precision Nuclear Spectroscopy Institute of Modern PhysicsChinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100080China Instituto de Física Universidade de São PauloRua do Matão1371São Paulo 05508-090SPBrazil School of Physics and Beijing Key Laboratory of Advanced Nuclear Materials and Physics Beihang UniversityBeijing 100191China School of Physics Science and Engineering Tongji UniversityShanghai 200092China School of physics and Optoelectronic Engineering Anhui UniversityHefei 230601China Department of Physics GITAM School of ScienceGITAM UniversityVisakhapatnam 530045India

The elastic scattering angular distributions of ^(13)C at 340 Mev and ^(14)C at 294 Mev and 342 Mev on a ^(208)Pb target,which correspond to approximately five times the Coulomb barriers,were measured at the Radioactive Ion Beam Line in *** data were analyzed within the optical model and continuum-discretized coupled-channels(CDCC)framework,and the results of both calculations could effectively account for the experimental *** differential cross sections of elastic scattering revealed no particular suppression at the Coulomb nuclear interference peak angles,suggesting that the breakup coupling effects on the elastic scattering angular distributions were negligibly small in this incident energy *** contributions from the couplings with inelastic states to the elastic cross sections were of minor importance within the angular range covered by these experiments.

关键词： elastic scattering radioactive ion beam angular distribution optical model coupling effects

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Thermo-diffusion impact on immiscible flow characteristics of convectively heated vertical two-layered Baffle saturated porous channels in a suspension of nanoparticles:an analytical study

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Applied Mathematics and Mechanics(English Edition) 2023年第2期44卷 307-324页

作者： S.P.v.ANANTH B.N.HANUMAGOWDA S.v.K.vARMA C.S.K.raju I.KHAN P.RANA Department of Mathematics School of Applied SciencesREVA UniversityBangalore 560064India Department of Mathematics GITAM School of ScienceGITAM UniversityBangalore 562163India Department of Mathematics College of Science Al-ZulfiMajmaah UniversityAl-Majmaah 11952Saudi Arabia School of Mathematical Sciences College of Science and TechnologyWenzhou-Kean UniversityWenzhou 325060Zhejiang ProvinceChina

The heat and mass transfer of two immiscible fluids in an inclined channel with thermal diffusion,vicious,and Darcy dissipation is *** first region consists of a clear fluid,and the second one is filled with a nanofluid saturated with a porous *** behaviors of Cu-H_(2)O,In-H_(2)O,and Au-H_(2)O nanofluids are *** transport properties are assumed to be *** coupled non-linear equations of the flow model are transformed into the dimensionless form,and the solutions for the velocity,temperature,and concentration are obtained by the regular perturbation *** are carried out on the flow characteristics for various values of the material *** results show that the velocity and temperature of the fluids enhance with the thermal Grashof number,solutal Grashof number,and Brinkman number while decrease with the porosity parameter and solid volume fraction.

关键词： viscous fluid nanofluid heat and mass transfer thermal diffusion

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Experimental study on performance of passive and active solar stills in Indian coastal climatic condition

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Frontiers in Energy 2020年第1期14卷 105-113页

作者： R.LALITHA NARAYANA v.RAMACHANDRA raju Department of Mechanical Engineering Jawaharlal Nehru Technological University(JNTUK)Kakinada533003India Department of Mechanical Engineering Rajiv Gandhi University of Knowledge TechnologiesNuzivid521201India

This present work is aimed to examine the effect of mass flow rate on distillate output and performance of a solar still in active *** experiments were conducted at the coastal town,Kakinada(16°93′N/83°33′E),Andhra Pradesh,India.A solar still with a 30°of fixed cover inclination,1 m2 of effective basin area,and a flat-plate collector(FPC)with an effective area of 2 m2 were *** attempt was also made earlier in passive mode to optimize the water depth for the same solar still for maximum yield and distillation *** the passive still,it is observed that the capacity of heat storage and heat drop are significant parameters that affect the still *** the selected still design,the study reveals that 0.04 m water depth is the optimum value for specific climatic *** the active solar still,with the optimum water depth,different flow rates of 0.5,1 and 1.5 L/min are considered through *** is observed that both the mass flow rate and the variation of internal heat transfer coefficients with the mass flow rate have a significant effect on the yield and performance of the *** experimental results show that the combination of 1.5 L/min mass flow rate and an optimum water depth of 0.04 m leads to a maximum yield for the active solar *** enhanced yield of the active solar still is 57.55%,compared with that of the passive solar still,due to increase in area of radiation collection and more heat absorption rate.

关键词： distillation efficiency solar still heat transfer coefficient water depth optimum and mass flow rate

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Effect of wall temperature modulation on the heat transfer characteristics of droplet-train flow inside a rectangular microchannel

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Chinese Journal of Chemical Engineering 2020年第3期28卷 685-697页

作者： vivekanand S.v.B.,raju v.R.K. Department of Mechanical Engineering National Institute of TechnologyWarangalTelangana 506004India

The numerical studies of water–oil two-phase slug flow inside a two-dimensional vertical microchannel subjected to modulated wall temperature boundary conditions have been discussed in the present *** researchers have contributed their efforts in exploring the characteristics of Taylor flows inside microchannel under constant wall heat flux or isothermal wall ***,there is no study available in the literature which discusses the impact of modulated thermal wall boundary conditions on the heat transfer behavior of slug flows inside ***,to bridge this gap,an effort has been made to understand the heat transfer characteristics of the flow under sinusoidal wall temperature ***,a single phase flow and heat transfer study was performed in microchannels,and the results of the fully developed velocity profile and heat transfer rate were validated with benchmark analytical *** an optimal selection of the combination of sinusoidal thermal wall boundary conditions has been made for the two-phase slug flow ***,the effects of amplitude(0 bεb 0.03)and frequency(0 bωb 750πrad·s-1)of the sinusoidal wall temperature profile on the heat transfer have been studied using the optimal combination of the wall boundary *** results of the numerical study using modulated temperature conditions on channel walls showed a significant improvement in the heat transfer over liquid-only flow by approximately 50%as well as over two-phase flow without wall temperature *** non-dimensional temperature contours obtained for different cases of temperature modulation clearly explain the root cause of such improvement in the heat ***,the results based on the hydrodynamics of the flow have also been reported in terms of variation of droplet shapes and film *** influence of Capillary number on the film thickness as well as heat transfer rates has also been *** addition,the measured fil

关键词： Heat transfer Microchannel Modulation Surface tension Taylor flow

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Analytical analysis of inclined three-layered composite channel with cobalt ferrite nanoparticles and Hall current in Darcy medium

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Propulsion and Power Research 2023年第4期12卷 523-538页

作者： P.v.Ananth Subray B.N.Hanumagowda C.S.K.raju S.v.K.varma Prakash Jagdish Se-Jin Yook Nehad Ali Shah Department of Mathematics School of Applied SciencesREVA UniversityBengaluruKarnatakaIndia School of Mechanical Engineering Hanyang University222 Wangsimni-roSeongdong-guSeoul 04763Republic of Korea Department of Mechanical Engineering Science Faculty of Engineering&The Built EnvironmentUniversity of JohannesburgSouth Africa Department of Mechanical Engineering Sejong UniversitySeoul 05006Republic of Korea

The present study explores the influence of electromagnetic effects on the flow of a nanofluid in a saturated permeable medium,confined between a clear viscous fluid in an inclined *** nanofluid consists of cobalt ferrite nanoparticles dispersed in ethylene *** governing equations are derived considering Darcy's law for the permeable medium and Tiwari's model for fluids containing nano-sized ***,radiation and dissipation effects are incorporated into the energy *** equations are transformed into dimensionless form and solved analytically using the perturbation *** results are analyzed through graphs and tables for different material *** findings reveal that higher electric and magnetic strengths have a significant impact on the fluid velocity at the interface of the two fluids,resulting in reduced shear both at the clear fluid surface and the interface between *** highlights the crucial role played by electric and magnetic strengths in modifying flow ***,combining electric and magnetic strengths with nanofluids can be utilized to achieve desired qualities in multi-fluid flow and enhance heat transfer characteristics.

关键词： Three-layered flow Inclined composite channel Electromagnetic field Nanofluid Porous region

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Application of geospatial modelling technique in delineation of fluoride contamination zones within Dwarka Basin, Birbhum, India

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Geoscience Frontiers 2017年第5期8卷 1105-1114页

作者： raju Thapa Srimanta Gupta D.v.Reddy Department of Environmental Science The University of Burdwan Burdwan 713104 West Bengal India CSIR-National Geophysical Research Institute Hyderabad 500007 Telangana India

Dwarka River Basin is one of the fluoride affected river basin in Birbhum, West Bengal. In the present research work, various controlling factors for fluoride contamination in groundwater i.e., geology, aquifer type, groundwater table, soil, rainfall, geomorphology, drainage density, land use land cover, lineament and fault density, slope and elevation were considered to delineate the potential fluoride contamination zones within Dwarka River Basin in Birbhum. Assigning weights and ranks to various inputs factor class and their sub-class respectively was carried out on the basis of knowledge driven method. Weighted overlay analysis was carried out to generate the final potential fluoride contamination zones which are classified into two broad classes i.e., 'high' and 'low', and it is observed that major portion of the study area falls under low fluoride contamination category encompassing 88.61% of the total area which accounts for 759.48 km^2 and high fluoride contaminated region accounts for 11.40% of the total study area encompassing an area of about 97.67 km^2. Majority of high fluoride areas fall along the flood plain of Dwarka River Basin. Finally, for validation 197 reported points within Dwarka having fluoride in underground water are overlaid and an overall accuracy of 92.15% is observed. An accuracy of 83.21% and84.24% is obtained for success and prediction rate curve respectively.

关键词： Fluoride Groundwater Weighted overlay method Potential fluoride contamination zone Dwarka Basin India

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Characterization of mixing in an optimized designed T–T mixer with cylindrical elements

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Chinese Journal of Chemical Engineering 2019年第10期27卷 2337-2351页

作者： T.Manoj Dundi v.R.K.raju v.P.Chandramohan Mechanical Engineering Department National Institute of TechnologyWarangalTelangana StateIndia

Passive micromixers are preferred over active mixers for many microfluidic applications due to their relative ease in integration into complex systems and operational *** also incur very low cost of ***,the degree of mixing is comparatively low in passive mixers than active mixers due to the absence of disturbance in the flow by external forces and the inherent laminar nature of microchannel *** designs of complex channel structures and three-dimensional geometries have been investigated in the past to obtain an efficient mixing in passive *** the studies on mixing enhancement with simple planar geometries of passive mixers have been few and *** present work aims to investigate the possibility of mixing enhancement by employing simple planar type designs,such as T-mixer and T–T mixer with cylindrical elements placed in the mixing *** mixing performance has been evaluated in the Reynolds number range of 6 *** results have shown that T–T mixer with cylindrical elements performed significantly well and obtained very good mixing quality over basic T-mixer for the entire range of Reynolds number(6 to 700).The device has also shown better mixing as compared to basic T–T mixer and T-mixer with cylindrical elements.A larger pair of vortices formed in the stagnation area due to the presence of a cylindrical element in the *** elements downstream caused significant enhancement in mixing due to splitting and recombining *** size of the cylindrical element in the T–T mixer has been optimized to obtain better mixing performance of the *** improvement in mixing quality by T–T mixer with cylindrical elements has been obtained at the expense of small rise in pressure drop as compared to other passive designs considered in this ***,the current design of T–T mixer with cylindrical elements can act as an effective and simple passive mixing device for various mi

关键词： CFD-simulation Cylindrical elements Micromixers Mixing quality Obstructions T–T-mixer

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Neuroprotective role of protein tyrosine phosphatase-1B in rod photoreceptor neurons

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Protein & Cell 2013年第12期4卷 890-892页

作者： raju v.S.Rajala Ammaji Rajala Department of Ophthalmology University of Oklahoma Health Sciences CenterOklahoma CityOklahoma 73104USA Department of Physiology University of Oklahoma Health Sciences CenterOklahoma CityOklahoma 73104USA Department of Cell Biology University of Oklahoma Health Sciences CenterOklahoma CityOklahoma 73104USA Dean A.McGee Eye Institute Oklahoma CityOklahoma 73104USA

Dear Editor,Protein tyrosine phosphatase-1B(PT-P1B)is an abundant,widely expressed non-receptor tyrosine phosphatase,which is thought to be a key negative regulator of insulin signaling(Tonks,2003).Increased and prolo... 详细信息

关键词： PTP1B insulin of

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