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Flotation separation of feldspar from quartz using sodium fluosilicate as a selective depressant

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Rare Metals 2024年第3期43卷 1288-1300页

作者： Xin Hu Xian-Ping Luo Zi-Shuai Liu Yong-Bing Zhang He-Peng Zhou Zhi-Zhao Yang Xue-kun tang Faculty of Resource and Environmental Engineering Jiangxi University of Science and TechnologyGanzhou341000China Yichun Lithium New Energy Industry Research Institute Jiangxi University of Science and TechnologyYichun336000China

The physical and chemical properties of feldspar and quartz are highly similar,thus they cannot be easily separated *** this work,the flotation separation of feldspar from quartz using sodium fluosilicate(Na_(2)SiF_(6);SF)as a selective depressant was ***,the influence mechanism of SF on the selective flotation separation of feldspar and quartz was investigated via flotation tests,chemical analysis of flotation solution,Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS)and contact angle *** results of the flotation tests show that feld spar and quartz without SF treatment have good *** SF treatment,feldspar still has good floatability,whereas quartz has significantly reduced *** solution chemical analysis shows that the functional group plays an important role in depressing the quartz is[SiF_(6)]^(2-).FTIR,XPS and contact angle analysis results show that[SiF_(6)]^(2-)is adsorbed only on the surface of ***,a thin hydrophilic SiOF layer is generated on the surface,which interferes with the adsorption of the collector on the surface of the *** phenomenon leads to a significant reduction in quartz's ***,SF has a good ability to separate feldspar from quartz by flotation.

关键词： Flotation separation Depressants Sodium fluorosilicate Quartz Feldspar

Enones from aldehydes and alkenes by carbene-catalyzed dehydrogenative couplings

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Chinese Chemical Letters 2024年第9期35卷 150-154页

作者： kun tang Fen Su Shijie Pan Fengfei Lu Zhongfu Luo Fengrui Che Xingxing Wu Yonggui Robin Chi National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityHuaxi DistrictGuiyang 550025China School of chemistry Chemical Engineeringand BiotechnologyNanyang Technological UniversitySingapore 637371Singapore

Enones are widely explored in synthetic chemistry as fundamental building blocks for a wide range of reactions and exhibit intriguing biological activities that are pivotal for drug *** development of synthetic strategies for highly efficient preparation of enones thereby receives intense attention,in particular through the transition metal-catalyzed coupling ***,we describe a carbene-catalyzed cross dehydrogenative coupling(CDC)reaction that enables effective assembly of simple aldehydes and alkenes to afford a diverse set of enone ***,the in situ generated aryl radical is pivotal to“activate”the alkene by forming an allyl radical through intermolecular hydrogen atom transfer(HAT)pathway and thus forging the carbon-carbon bond formation with aldehyde as the acyl ***,our method represents the first example on the enone synthesis through coupling of“non-functionalized”aldehydes and alkenes as coupling partners,and offers a distinct organocatalytic pathway to the transition metal-catalyzed coupling transformations.

关键词： Enones Cross dehydrogenative coupling N-Heterocyclic carbene Aryl radical Hydrogen atom transfer

Kuicolong-yu enema decoction retains traditional Chinese medicine enema attenuates inflammatory response ulcerative colitis through TLR4/NF-κB signaling pathway

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World Journal of Gastrointestinal Surgery 2024年第4期16卷 1149-1154页

作者： Li Han kun tang Xiao-Li Fang Jing-Xi Xu Xi-Yun Mao Ming Li Department of Anorectal Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese Medicine Anhui HospitalHefei 230001Anhui ProvinceChina Anorectal Center The First Affiliated Hospital of Anhui University of Traditional Chinese MedicineHefei 230001Anhui ProvinceChina Department of Spleen and Stomach Diseases Department of GastroenterologyAffiliated Wuhu Hospital of Traditional Chinese Medicine of Anhui College of Traditional Chinese MedicineWuhu 241000Anhui ProvinceChina

BACKGROUND Ulcer colitis(UC)is a chronic,nonspecific,and noninfectious inflammatory bowel ***,Toll-like receptors(TLRs)have been found to be closely associated with clinical inflammatory *** complete remission in patients with intermittent periods of activity followed by dormancy is ***,no study has explored the mechanism by which Kuicolong-yu enema decoction retains traditional Chinese medicine enemas to attenuate the inflammatory response in *** To explore the mechanism by which Kuicolong-yu enema decoction retains traditional Chinese medicine enemas to attenuate the inflammatory response in *** This prospective clinical study included patients who met the exclusion criteria in 2020 and *** patients with UC were divided into two groups(control and experimental).The peripheral blood of the experimental and control groups were collected under aseptic *** expression of TLR4 protein,NF-κB,IL-6,and IL-17 was detected in the peripheral blood of patients in the experimental group and control group before and 1 month after taking the *** co rrelation analysis was used to analyze the relationship between the expression level of TLR4 protein and the expression levels of downstream signal NF-κB and inflammatory factors IL-6 and IL-17,and P<0.05 was considered statistically *** There were no significant differences in the patient characteristics between the control and experimental *** results showed that the expression levels of TLR4 and NF-κB in the experimental group were significantly lower than those in the control group(P<0.05).The levels of IL-6 and IL-17 in the experimental group were significantly lower than those in the control group(P<0.05).The TLR4 protein expression in the experimental group was positively correlated with the expression level of downstream signal NF-κB and was positively correlated with the levels of downstream inflammatory cytokines IL-6 and IL-

关键词： Ulcerative colitis TLR4 NF-κB signaling pathway Kuicolong-yu enema

Mesenchymal stem cell therapy for liver fibrosis need“partner”:Results based on a meta-analysis of preclinical studies

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World Journal of Gastroenterology 2024年第32期30卷 3766-3782页

作者： Yan Xu Xue-Song Wang Xiao-Lei Zhou Wen-Ming Lu Xing-kun tang Yu Jin Jun-Song Ye Subcenter for Stem Cell Clinical Translation First Affiliated Hospital of Gannan Medical UniversityGanzhou 341000Jiangxi ProvinceChina School of Rehabilitation Medicine Gannan Medical UniversityGanzhou 341000Jiangxi ProvinceChina Ganzhou Key Laboratory of Stem Cell and Regenerative Medicine Gannan Medical UniversityGanzhou 341000Jiangxi ProvinceChina Department of Medical Genetics School of MedicineTongji UniversityShanghai 200092China Key Laboratory of Prevention and Treatment of Cardiovascular and Cerebrovascular Diseases Ministry of EducationGannan Medical UniversityGanzhou 341000Jiangxi ProvinceChina

BACKGROUND The efficacy of mesenchymal stem cells(MSCs)in treating liver fibrosis has been demonstrated in several clinical ***,their low survival and liver implantation rates remain *** recent years,a large number of studies in animal models of liver fibrosis have shown that MSCs combined with drugs can improve the efficacy of MSCs in the treatment of liver fibrosis alone and inhibit its progression to end-stage liver *** has inspired new ways of thinking about treating liver *** To investigate the effectiveness and mechanisms of MSCs combined with drugs in treating liver *** Data sources included four electronic databases and were constructed until January *** subjects,interventions,comparators,outcomes,and study design principle were used to screen the literature,and the quality of the literature was evaluated to assess the risk of *** randomised controlled trials were selected,and the final 13 studies were included in the final *** A total of 13 studies were included after *** analysis showed that MSCs combined with drug therapy significantly improved liver function,promoted the repair of damaged liver tissues,reduced the level of liver fibrosis-related indexes,and effectively ameliorated hepatic fibrosis by modulating the hepatic inflammatory microenvironment,promoting the homing of MSCs,and regulating the relevant signaling pathways,and the treatment efficacy was superior to MSCs ***,the combined treatment statistics showed no amelioration in serum albumin levels(standardized mean difference=0.77,95%confidence interval:-0.13 to 1.68,P=0.09).CONCLUSION In conclusion,MSCs combined with drugs for treating liver fibrosis effectively make up for the shortcomings of MSCs in their therapeutic ***,due to the different drugs,the treatment mechanism and effect also ***,more randomized controlled trials are needed to compare the therapeutic effic

关键词： drugs alone partner

Programmable repulsive potential for tight-binding from ChenM?bius inversion theorem

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Science China(Physics,Mechanics & Astronomy) 2024年第1期 75-87页

作者： Jian-Gao Li Jin-kun tang Hong-Quan Song Gotthard Seifert Dong-Bo Zhang College of Nuclear Science and Technology Beijing Normal University Department of Physics Beijing Normal University College of Physics and Telecommunication Engineering Zhoukou Normal University Theoretische Chemie Technische Universit?t Dresden

An accurate total energy calculation is essential in materials computation. To date, many tight-binding(TB) approaches based on parameterized hopping can produce electronic structures comparable to those obtained using first-principles ***, TB approaches still have limited applicability for determining material properties derived from the total energy. That is, the predictive power of the TB total energy is impaired by an inaccurate evaluation of the repulsive energy. The complexity associated with the parametrization of TB repulsive potentials is the weak link in this evaluation. In this study, we propose a new method for obtaining the pairwise TB repulsive potential for crystalline materials by employing the Chen-M?bius inversion theorem. We show that the TB-based phonon dispersions, calculated using the resulting repulsive potential, compare well with those obtained by first-principles calculations for various systems, including covalent and ionic bulk materials and twodimensional materials. The present approach only requires the first-principles total energy and TB electronic band energy as input and does not involve any parameters. This striking feature enables us to generate repulsive potentials programmatically.

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Reform of Teaching Practice of Modern Instrumental Analysis in Biotechnology Programs

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Agricultural Biotechnology 2024年第3期13卷 93-95页

作者： kun tang Tong LIN Zhenxia SHI Jie QIAO Chunyan XIE Lixin DU College of Life Science Langfang Normal UniversityLangfang 065000China

Through the online and offline practical reform of the Modern Instrumental Analysis course of biotechnology majors from teaching content,teaching method,teaching demonstration to teaching effect,the traditional single offline lecture is transformed into diversified and interactive modern *** practical reform enriches and optimizes the course content,perfects and improves the course assessment system,and improves the teaching *** achieves the student-centered and application-oriented teaching goal,and also provides reference for further cultivating high-quality applied talents.

关键词： Modern instrumental analysis Biotechnology Online and offline Reform of teaching

预制轻钢轻混凝土剪力墙-楼板连接部抗剪性能试验研究

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建筑钢结构进展 2024年第5期26卷 42-49页

作者：唐坤高静贤唐钷建研院检测中心有限公司北京100013 国家建筑工程技术研究中心北京100013 中国建筑技术集团有限公司北京100013

提出一种装配式轻钢轻混凝土剪力墙与混凝土楼板的装配连接方式,为研究该连接节点的抗剪性能,开展了4个墙体-楼板连接试件的低周往复加载试验,分析了连接节点的滞回性能、刚度退化、延性、耗能能力及承载力性能。结果表明:不同连接构造... 详细信息

提出一种装配式轻钢轻混凝土剪力墙与混凝土楼板的装配连接方式,为研究该连接节点的抗剪性能,开展了4个墙体-楼板连接试件的低周往复加载试验,分析了连接节点的滞回性能、刚度退化、延性、耗能能力及承载力性能。结果表明:不同连接构造形式对墙体-楼板连接节点的承载力影响显著,抗剪螺栓能有效提高节点的刚度与水平抗剪承载力;承载力分析结果显示,设有抗剪螺栓的连接节点承载力比预制墙体抗剪承载力高了34.3%,满足节点承载力要求,最后给出了装配式轻钢轻混凝土墙-楼板连接节点设计建议。

关键词：轻钢轻混凝土预制剪力墙-楼板连接部抗剪性能低周往复加载试验

Diamond-based electron emission:Structure,properties and mechanisms

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Chinese Physics B 2024年第9期33卷 165-177页

作者： Liang-Xue Gu Kai Yang Yan Teng Wei-Kang Zhao Geng-You Zhao Kang-Kang Fan Bo Feng Rong Zhang You-Dou Zheng Jian-Dong Ye Shun-Ming Zhu kun tang Shu-Lin Gu School of Electronic Science and Engineering Nanjing UniversityNanjing 210046China

Diamond has an ultrawide bandgap with excellent physical properties,such as high critical electric field,excellent thermal conductivity,high carrier mobility,*** with a hydrogen-terminated(H-terminated)surface has a negative electron affinity(NEA)and can easily produce surface electrons from valence or trapped electrons via optical absorption,thermal heating energy or carrier transport in a PN *** NEA of the H-terminated surface enables surface electrons to emit with high efficiency into the vacuum without encountering additional barriers and promotes further development and application of diamond-based emitting *** article reviews the electron emission properties of H-terminated diamond surfaces exhibiting NEA *** electron emission is induced by different physical *** advancements in electron-emitting devices based on diamond are also ***,the current challenges and future development opportunities are discussed to further develop the relevant applications of diamond-based electronemitting devices.

关键词： diamond negative electron affinity (NEA) PN junction electron emission

AIGC背景下全民数字素养教育的内涵变革与应对策略

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图书与情报 2024年第3期 32-39页

作者：李白杨唐昆南京大学数据管理创新研究中心江苏苏州215163

随着AIGC技术的应用和推广,全民数字素养教育进入智能时代。文章首先分析了AIGC背景下全民数字素养教育的国内外进展,包括中国和联合国、美国、欧盟等国际组织在数字素养教育方面的政策和框架。然后从概念内涵、受众群体和教育模式等维... 详细信息

随着AIGC技术的应用和推广,全民数字素养教育进入智能时代。文章首先分析了AIGC背景下全民数字素养教育的国内外进展,包括中国和联合国、美国、欧盟等国际组织在数字素养教育方面的政策和框架。然后从概念内涵、受众群体和教育模式等维度分析了全民数字素养教育的变革趋势,指出其概念从信息素养、媒介素养等逐渐演变为融合人工智能素养的综合性概念,其受众群体从特定技术群体扩展到全年龄、全职业和全社会,教育模式则朝着终身化、个性化方向发展,并深度融合人工智能技术。最后提出了针对AIGC背景下提升全民数字素养的六点应对策略,包括学科主体建设、课程体系建设、用户需求导向、混合教学手段、开放教育资源和教学效果评估。

关键词：生成式人工智能数字素养教育全民性教智融合变革