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Development of nickel based cermet anode materials in solid oxide fuel cells–Now and future

Materials Reports(Energy) 2021年第1期1卷 101-126页

作者： Yu Liu Zongping Shao Toshiyuki mori San Ping Jiang WA School of Mines:Minerals Energy and Chemical EngineeringCurtin UniversityPerthWA6102Australia Centre for Green Research in Energy and Environmental Materials National Institute of Materials ScienceTsukubaIbaraki305-0044Japan Department of Physics and Astronomy Fuels and Energy Technology InstituteCurtin UniversityGPO Box U1987PerthWA6845Australia

High temperature solid oxide fuel cell(SOFC)is the most efficient and clean energy conversion technology to electrochemically convert the chemical energy of fuels such as hydrogen,natural gas and hydrocarbons to electricity,and also the most viable alternative to the traditional thermal power ***,the power output of a SOFC critically depends on the characteristics and performance of its key components:anode,electrolyte and *** to the highly reducing environment and strict requirements in electrical conductivity and catalytic activity,there are limited choices in the anode materials of SOFCs,particularly for operation in the intermediate temperature range of 500–800*** them,Ni-based cermets are the most common and popular anode materials of *** objective of this paper is to review the development of Ni-based anode materials in SOFC from the viewpoints of materials microstructure,performance and industrial scalability associated with the fabrication and optimization *** latest advancement in nano-structure architecture,contaminant tolerance and interface optimization of Ni-based cermet anodes is *** at the end of this paper,we propose and appeal for the collaborative work of scientists from different disciplines that enable the inter-fusion research of fabrication,microanalysis and modelling,aiming at the challenges in the development of Ni-based cermet anodes for commercially viable intermediate temperature SOFC or IT-SOFC technologies.

关键词： Ni-based cermet anode Intermediate temperature solid oxide fuel cell Activity Interface optimization Carbon deposition Sulfur poisoning Multidisciplinary collaborative work

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High-throughput Three-dimensional Gel Electrophoresis for Versatile Utilities: A Stacked Slice-gel System for Separation and Reactions (4SR)

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Genomics, Proteomics & Bioinformatics 2006年第1期4卷 26-33页

作者： Md. Salimullah Masaki mori Koichi Nishigaki Department of Functional Materials Science Saitama University Saitama 338-8570 Japan Rational Evo-lutionary Design of Advanced Biomolecules (REDS) Group Saitama Small Enterprise Promotion CorporationSKIP City Kawaguchi 333-0844 Japan.

A novel high-throughput system, called the stacked slice-gel system for separation and reactions （4SR）, was developed for the analysis of DNA/RNA and protein/peptide. The system provides a novel three-dimensional gel electrophoresis approach that exploits the property of stacked slice gels. It allows multiple samples simultaneously to react as well as to be separated, offering a two-dimensional （m×n） sample loading system. For this purpose, high-throughput multi-micro vessels （MMVs） containing variable numbers of wells （100 wells in this paper） have been used, which are made of 25 mm square-size polyacrylamide gels. Furthermore, after electrophoretic separation, a slice gel containing a desired sample can be easily removed and proceeded to the next step. Different biological reactions as well as successive separation of products were effectively carried out dealing with DNA/RNA and protein/peptide. It shows that this system has a diversity of potentials to be developed.

关键词： three-dimensional polyacrylamide gel electrophoresis (3D-PAGE) high-throughput screening three-dlmensional separation microarray technology

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It is time to abandon the Milan criteria

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Hepatobiliary Surgery and Nutrition 2019年第1期8卷 56-58页

作者： Tomoharu Yoshizumi Ken Shirabe Masaki mori Department of Surgery and Science Graduate School of Medical SciencesKyushu UniversityFukuokaJapan Department of General Surgical Science Gunma University Graduate School of MedicineGunmaJapan

Hepatocellular carcinoma(HCC)is the fifth most common neoplasm worldwide and the third most common cause of cancer-related *** transplantation(LT),which offers the theoretical advantage of removing both the tumor and the organ that are at risk of developing future malignancy,is an established therapy for HCC in patients with liver cirrhosis.A shortage of cadaveric organs for transplantation continues to impair our ability to provide LT despite progress in surgical techniques and ***,it is important to allocate the deceased donor livers with excellent results,and to ensure reasonable outcome for living donors who need to undergo invasive surgery.

关键词： organs Liver surgery

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Thermoelectric performance enhancement of(BiS)1.2(TiS2)2 misfit layer sulfide by chromium doping

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Journal of Advanced Ceramics 2013年第1期2卷 42-48页

作者： Yulia Eka PUTRI Chunlei WAN Ruizhi ZHANG Takao mori Kunihito KOUMOTO Graduate School of Engineering Nagoya UniversityNagoya 464-8603Japan CREST Japan Science and Technology AgencyTokyo 102-0075Japan Department of Physics State Key Laboratory of Photoelectric Technology and Functional Materials(Culture Base)Northwest UniversityXi’an 710069China National Institute for Materials Science(NIMS) Tsukuba 305-0044Japan

A misfit layer sulfide(BiS)_(1.2)(TiS_(2))_(2) with a natural superlattice structure has been shown to be a promising thermoelectric material,but its high carrier concentration should be reduced so as to further optimize the thermoelectric ***,ordinary acceptor doping has not succeeded because of the non-parabolic band *** this paper,we have successfully doped chromium ions into the Ti sites,which can maintain or even enhance the high effective mass of electrons so as to effectively improve ZT value.X-ray diffraction analysis,coupled with X-ray photoelectron spectroscopy,shows that chromium has been substituted into titanium sites in TiS2 layers and confirms its ionic *** chromium doping has successfully reduced the carrier concentration with the subsequent reduction of electrical *** other acceptor dopants(alkaline earth metals),chromium also enhances Seebeck coefficient and the effective mass,which can possibly be attributed to the formation of additional resonant states near Fermi *** the power factor does not improve,the significant reduction in the electronic part of the thermal conductivity leads to a measurable improvement in ZT.

关键词： thermoelectric misfit layer sulfide spark plasma sintering electrical conductivity thermal conductivity

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Present status and future prospect of design of Pt-cerium oxide electrodes for fuel cell applications

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Progress in Natural Science:Materials International 2012年第6期22卷 561-571页

作者： Toshiyuki mori Ding Rong Ou Jin Zou John Drennan Graduate School of Chemical Sciences and Engineering.Hokkaido University Kita13Nishi8Kita-ku.Sapporo.Hokkaido 060-8628.Japan Hetero interface design group.Global Research Center for Environment and Energy based on Nanomaterials Science(GREEN).National Institute for Materials Science.1-1 Namiki Tsukuba.Ibaraki 305-0044.Japan Centre for Microscopy and Microanalysis The University of QueenslandSt.LuciaBrisbaneQld 4072Australia Laboratory of Fuel Cells Dalian Institute of Chemical Physics Chinese Academy of Sciences457 Zhongshan RoadDalian

In the research field of proton exchange membrane fuel cells,the design of electrocatalytic activities on Pt-oxide promoter in the anode side has attracted attention for improvement of CO tolerance of Pt in anode side and a lowering of large over-potential loss of the oxygen reduction reaction on the cathode in the fuel *** the Pt-oxide promoter series,Pt-CeOx/C is one of the unique *** is because the unique behavior of CeOxsuch as electrochemical redox reaction between Ce3+and Ce4+in the anodic and cathodic reactions of fuel cell is *** present short review gives an overview of the recent works for improvement of the CO tolerance of Pt in the Pt-CeOx/C anodes and enhancement of the oxygen reduction reaction activity on Pt in the Pt-CeOx/C cathodes for fuel cell *** show the design paradigm for fabrication of high quality Pt-CeOx/C electrodes,the authors re-introduced parts of our research results to highlight the important role of interface structure of Pt-CeOxbased on the ultimate analysis results. The usefulness of the combined approach of microanalysis and the processing route design is presented.

关键词： Pt-CeO_x electrode CO tolerance of Pt Oxygen reduction reaction Interface of Pt and cerium oxide Microanalysis

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Applicability of the Arrhenius model for Ammonia Oxidizing Bacteria subjected to temperature time gradients

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Frontiers of Environmental Science & Engineering 2015年第6期9卷 988-994页

作者： Alberto MANNUCCI Giulio MUNZ Gualtiero mori Claudio LUBELLO Jan A. OLESZKIEWICZ Department of Civil and Environmental Engineering University of Florence Florence 50139 Italy Consorzio Cuoiodepur Pisa 56020 Italy Department of Civil Engineering University of Manitoba Winnipeg R3T 5V6 Canada

The aim of this work is to identify the range of applicability of Arrhenius type temperature dependence for Ammonia Oxidizing Bacteria （AOB） subjected to tem- perature time gradients through continuous titrimetric tests. An innovative online differential titrimetric technique was used to continuously monitor the maximum biologic ammonia oxidation rate of the biomass selected in a pilot scale membrane bioreactor, as a function of temperature time gradients. The monitoring technique is based on the measurement of alkalinity and hydrogen peroxide con- sumption rates in two parallel reactors operated in non- limiting substrate conditions for AOB; both reactors were continuously fed with mixed liquor and in one of them AOB were inhibited with allylthiourea. The effects of temperature decrease rates in the range 1 to 4℃h^-1 were evaluated by controlling the titrimetric reactor in the temperature range 10℃-20℃. The dependence of growth kinetics on temperature time gradients and the range of applicability of Arrhenius model for temperature depen- dency of AOB growth kinetics were assessed. The Arrhenius model was found to be accurate only with temperature gradients lower than 2℃·h^-1. The estimated Arrhenius coefficients （θ） were shown to increase from 1.07 to 1.6 when the temperature decrease rate reached 4℃.h^-1.

关键词： nitrification rate temperature effect contin-uous tilrimetric tests time-gradient temperature variations,Ammonia Oxidizing Bacteria (AOB)

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Novel concept of endoscopic device delivery station system for rapid and tight attachment of polyglycolic acid sheet

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World Journal of Gastroenterology 2018年第2期24卷 211-215页

作者： Hirohito mori Hideki Kobara Noriko Nishiyama Tsutomu Masaki Departments of Gastroenterology and Neurology Kagawa University

AIM To evaluate appropriate and rapid polyglycolic acid sheet(PGAs) covering time using device delivery station system(DDSS).METHODS This pilot basic study was conducted to evaluate the potential of accurate and rapid PGAs delivery using DDSS. Three 11-month-old female Beagle dogs were used in this study. Two endoscopic submucosal dissections(ESDs) 4 cm in diameter were performed in lesser curvature of middle gastric body and greater curvature of antrum(total 6 ESDs performed). DDSS(3 cm length, 12 mm in outer diameter) has 2 chambers which 16 cm^2 large 2 PGAs were stored, and DDSS was attached post ESD ulcers, respectively. Beriplast P?(CSL Behring K.K., Tokyo, Japan)(combination of fibringlue and thrombin) was applied equally to the artificial ulcer, and tight attachment of 2 PGAs with DDSS were completed. The evaluation items were covering times, post ESD bleeding and perforation during *** The covering time of PGAs(defined as the duration from the beginning of endoscope insertion into the mouth to the end of the fibrin glue coating process) was 6.07(4.86-8.29) min. There was no postESD bleeding(1-7 d after ESD), and there was no perforation during *** DDSS was very useful for rapid delivering and tight attachment of PGAs, and has potentials of multipurpose delivery station system.

关键词： Post-endoscopic submucosal dissection ulcers Bleeding Polyglycolic acid sheet Rapidly delivery Tightly attachment

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How Specialists Become Primary Care Physicians in Japan

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Health 2019年第3期11卷 322-331页

作者： takuma Kato Naoki Ikegami Keio University Tokyo Japan

Background: Most countries have a shortage of Primary Care (PC) physicians. Japan has mitigated this problem by specialists making a mid-career change to PC when they go into private practice. This study examines the circumstances under which specialists shift to PC. Methods: Since the division between specialists and PC physicians is blurred in Japan, we focus on Physicians Providing Home Visits (PPHV). The list of PPHV was obtained from the local medical associations in two neighboring medical planning areas in Japan. The methods used were a questionnaire and in-depth interviews. Results: Of the 46 listed as PPHV, 38 responded to the questionnaires. Physicians mainly acquired their knowledge and skills in primary care from post-graduate clinical training and on the job training after becoming PPHV. The specialists who had moved to PC were equally knowledgeable regarding PC as those had taken the PC accreditation exam. The in-depth interviews revealed that the higher income earned in clinics and being able to retain their identity as a specialist were also important factors. Conclusions: The factors that contributed to physicians making a mid-career change from specialists to PC were their experiences after being certified, the higher income in clinics and the ability to retain their professional identity as specialists. These enabling factors might also be applicable for increasing the ratio of PC physicians at the global level although further studies are required.

关键词： Mid-Career Changes Primary Care Specialists Professional Identity

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Adenomyoepithelioma of the breast with malignant transformation and repeated local recurrence:A case report

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World Journal of Clinical Cases 2021年第29期9卷 8864-8870页

作者： Goshi Oda Tsuyoshi Nakagawa Mio mori Tomoyuki Fujioka Iichiro Onishi Department of Breast Surgery Tokyo Medical and Dental UniversityTokyo 113-8519Japan Department of Radiology Tokyo Medical and Dental UniversityTokyo 113-8519Japan Department of Pathology Tokyo Medical and Dental UniversityTokyo 113-8519Japan

BACKGROUND Adenomyoepithelioma(AME)of the breast is a rare type of benign breast *** AMEs show benign behavior,but reports of the malignant type are *** present the case of a patient with AME with repeated local recurrences and further malignant *** SUMMARY A 53-year-old woman visited our hospital with a 16-mm palpable mass in the right breast.A core needle biopsy was *** pathological diagnosis was *** with a safety margin was performed without axillary lymph node dissection(ALND).Two years later,local recurrence developed,and the patient again underwent lumpectomy with a safety *** pathology showed malignant AME,and the margin was *** months later,local recurrence developed again in the same location,and a total mastectomy was performed without *** pathological diagnosis was malignant *** patient was disease-free for three years *** The treatment of AME requires caution,as it may exhibit repeated recurrences after local excision as well as malignant transformation.

关键词： Breast tumor Adenomyoepithelioma Malignant adenomyoepithelioma Local recurrence Malignant transformation Case report

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Role of nuclear receptor CAR in carbon tetrachloride-induced hepatotoxicity

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World Journal of Gastroenterology 2005年第38期11卷 5966-5972页

作者： Yuichi Yamazaki Satoru Kakizaki Norio Horiguchi Hitoshi Takagi Masatomo mori Masahiko Negishi Department of Medicine and Molecular Science Pharmacogenetics Section

AIM： To investigate the precise roles of CAR in CCI4- induced acute hepatotoxicity. METHODS： To prepare an acute liver injury model, CCI4 was intraperitoneally injected in CAR＋/＋ and CAR-/- mice. RESULTS： Elevation of serum alanine aminotransferase and extension of centrilobular necrosis were slightly inhibited in CAR-/- mice compared to CAR＋/＋ mice without PB. Administration of a CAR inducer, PB, revealed that CCl4-induced liver toxicity was partially inhibited in CAR-/- mice compared with CAR＋/＋ mice. On the other hand, androstanol, an inverse agonist ligand, inhibited hepatotoxicity in CAR＋/＋ but not in CAR./. mice. Thus, CAR activation caused CCl4 hepatotoxicity while CAR inhibition resulted in partial protection against CCl4-induced *** were no differences in the expression of CYP2E1, the main metabolizing enzyme for CCl4, between CAR＋/＋ and CAR./. mice. However, the expression of other CCI4-metabolizing enzymes, such as CYP2B10 and 3All, was induced by PB in CAR＋/＋ but not in CAR-/- mice. Although the main pathway of CCl4-induced acute liver injury is mediated by CYP2E1, CAR modulates its pathway via induction of CYP2B10 and 3All in the presence of activator or inhibitor. CONCLUSION： The nuclear receptor CAR modulates CCl4- induced liver injury via induction of CCl4-metabolizing enzymes in the presence of an activator. Our results suggest that drugs interacting with nuclear receptors such as PB might play critical roles in drug-induced liver injury or drug- drug interaction even though such drugs themselves are not hepatotoxic.

关键词： CAR Phenobarbital Cytochrome P450 CCl4 Drug-induced liver injury

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