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Comparative investigation of coal-and oil-fired boilers based on emission factors,ozone and secondary organic aerosol formation potentials of VOCs

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Journal of Environmental Sciences 2020年第6期32卷 245-255页

作者： Hsi-Hsien Yang Sunil kumar Gupta Narayan Babu Dhital Lin-Chi Wang suresh Pandian Elumalai Department of Environmental Engineering and Management Chaoyang University of TechnologyTaichungChinese Taipei Department of Applied Chemistry Chaoyang University of TechnologyTaichungChinese Taipei Department of Environmental Science Patan Multiple CampusTribhuvan UniversityLalitpurNepal Department of Environmental Engineering Chung Yuan Christian UniversityTaoyuanChinese Taipei Department of Environmental Science and Engineering Indian Institute of Technology(Indian School of Mines)DhanbadIndia

Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate *** this study,VOC emission factors,O3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3)and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired *** factors ofΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg)than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired ***,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired *** OFP ranged from 3.99 to 11.39 mg-O3/kg for coal-fired *** oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O3/***,total secondary organic aerosol potential(SOAP)ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively.

关键词： Coal-and oil-fired boilers Volatile organic compounds Emission factor Ozone formation potential Secondary organic aerosol potential

Prospects for discriminating Zingiberaceae species in India using DNA barcodes

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Journal of Integrative Plant Biology 2014年第8期56卷 760-773页

作者： Meenakshi Ramaswamy Vinitha Unnikrishnan suresh kumar Kizhakkethil Aishwarya Mamiyil Sabu George Thomas Plant Molecular Biology Rajiv Gandhi Centre for BiotechnologyThiruvananthapuram Kerala 695014 India Regional Facility for DNA Fingerprinting Rajiv Gandhi Centre for BiotechnologyThiruvananthapuram Kerala 695014 India Department of Botany University of Calicut

We evaluated nine plastid （matK, rbcL, rpoCl, rpoB, rp136-rpsS, ndhJ, trnL-F, tmrnH-psbA, accD） and two nuclear （ITS and ITS2） barcode loci in family Zingiberaceae by analyzing 60 accessions of 20 species belonging to seven genera from India. Bidirectional sequences were recovered for every plastid locus by direct sequencing of polymerase chain reaction （PCR） amplicons in all the accessions tested. However, only 35 （58%） and 4o accessions （66~） yielded ITS and ITS2 sequences, respectively, by direct sequencing. In different bioinformatics analyses, matK and rbcL consistently resolved 15 species （75%） into monophyletic groups and five species into two para- phyletic groups. The 173 ITS sequences, including 138 cloned sequences from 23 accessions, discriminated only 12 species （6o%）, and the remaining species were entered into three paraphyletic groups. Phylogenetic and genealogic analyses of plastid and ITS sequences imply the possible occurrence ofnatural hybridizations in the evolutionary past in giving rise to species paraphyly and intragenomic ITS heterogeneity in the species tested. The results support using matK and rbcL loci for barcoding Zingiberaceae members and highlight the poor utility of iTS and the highly regarded ITS2 in barcoding this family, and also caution against proposing ITS loci for barcoding taxa based on limited sampling.

关键词： Concerted evolution DNA barcoding ITS heterogeneity natural hybridizations Zingiberaceae

Estimation of boswellic acids in herbal formulations containing Boswellia serrata extract and comprehensive characterization of secondary metabolites using UPLC-Q-Tof-MS^e

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Journal of Pharmaceutical Analysis 2019年第6期9卷 414-422页

作者： kumar Katragunta Bandi Siva Niharika Kondepudi PRRao Vadaparthi Nadendla Rama Rao Ashok kumar Tiwari Katragadda suresh Babu Centre for Natural Products and Traditional Knowledge CSIR-Indian Institute of Chemical TechnologyHyderabad500007India Chalapathi Institute of Pharmaceutical Sciences LamGuntur522034India College of Pharmaceutical Sciences Acharya Nagarjuna UniversityNagarjuna NagarGuntur522510India

Boswellia serrata is a widely used herb in Indian systems of medicine and is well known for its potential medicinal properties.A chromatographic method was developed for the analysis and quanti cation of six boswellic acid marker compounds,i.e.,keto boswellic acid(1),3-O-Acetyl 11-keto-boswellic acid(2),-b Boswellic acid(3),-Boswellic acid(4),3-O-Acetyl--boswellic acid(5)and 3-O-Acetyl--boswellic acid b(6)in commercial herbal products containing *** as an *** UPLCbwith Q-Tof-MS/MS makes the better identi cation of secondary metabolites and adulterants in the herbal formulations containing *** in rapid time using fragmentation approach than the traditional *** this study quanti cation of boswellic acids with UPLC-PDA method was performed as per the pharmacopeia ***,minor phytochemical constituenBoswellia serrata is a widely used herb in Indian systems of medicine and is well known for its potential medicinal properties.A chromatographic method was developed for the analysis and quantification of six boswellic acid marker compounds,i.e.,keto boswellic acid(1),3-O-Acetyl 11-keto b-boswellic acid(2),ɑ-Boswellic acid(3),b-Boswellic acid(4),3-O-Acetyl-ɑ-boswellic acid(5)and 3-O-Acetyl-b-boswellic acid(6)in commercial herbal products containing *** as an *** UPLC with Q-Tof-MS/MS makes the better identification of secondary metabolites and adulterants in the herbal formulations containing *** in rapid time using fragmentation approach than the traditional *** this study quantification of boswellic acids with UPLC-PDA method was performed as per the pharmacopeia ***,minor phytochemical constituents were identified and characterized with the help of LC-Q-Tof-MS/MS fragmentation data and various isoforms of boswellic acids and tirucallic acids in *** oleo-gum-resin extract were *** were identi ed and characterized with the help of LC-Q-Tof-MS/MS

关键词： Boswellia serrata Herbal formulations Quantification UPLC-Q-tof-MSe Boswellic acids Tirucallic acids

Phosphorus Starvation Tolerance in Rice Through Combined Physiological,Biochemical,and Proteome Analyses

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Rice science 2023年第6期30卷 613-631页

作者： Prathap V suresh kumar Nand Lal MEENA Chirag MAHESHWARI Monika DALAL Aruna TYAGI Division of Biochemistry Indian Council of Agricultural Research-Indian Agricultural Research InstituteNew Delhi 110012India Division of Germplasm Evaluation National Bureau of Plant Genetic ResourcesNew Delhi 110012India National Institute for Plant Biotechnology New Delhi 110012India

Phosphorus(P) deficiency limits the growth,development,and productivity of *** better understand the underlying mechanisms in P-deficiency tolerance and the role of Pup1 QTL in enhancing P use efficiency(PUE) for the development of P-efficient rice cultivars,a pair of contrasting rice genotypes(Pusa-44 and NIL-23) was applied to investigate the morpho-physio-biochemical and proteomic variation under P-starvation *** rice genotypes were grown hydroponically in a PusaRich medium with adequate P(16 mg/kg,+P) or without P(0 mg/kg,-P) for 30 d.P-starvation manifested a significant reductions in root and shoot biomass,shoot length,leaf area,total chlorophyll,and P,nitrogen and starch contents,as well as protein kinase *** stress increased root-to-shoot biomass ratio,root length,sucrose content,and acid phosphatase activity,particularly in the P-tolerant genotype(NIL-23).Comparative proteome analysis revealed several P metabolism-associated proteins(including OsCDPKs,OsMAPKs,OsCPKs,OsLecRK2,and OsSAPks) to be expressed in the shoot of NIL-23,indicating that multiple protein kinases were involved in P-starvation/deficiency ***,the up-regulated expression of OsrbcL,OsABCG32,OsSUS5,OsPoll-like B,and ClpC2 proteins in the shoot,and OsACA9,OsACA8,OsSPS2F,OsPP2C15,and OsBiP3 in the root of NIL-23,indicated their role in P-starvation stress control through the Pup1 QTL. Thus,our findings indicated that-P stress-responsive proteins,in conjunction with morpho-physio-biochemical modulations,improved PUE and made NIL-23 a P-deficiency tolerant genotype due to the introgression of the Pup1 QTL in the Pusa-44 background.

关键词： phosphorus deficiency Pup1 QTL protein kinase acid phosphatase proteome analysis rice

Investigating the surface integrity of aluminium based composites machined by EDM

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Defence Technology（防务技术） 2019年第3期15卷 338-343页

作者： S.suresh kumar M.Uthayakumar S.Thirumalai kumaran Temel Varol Aykut Canakci Faculty of Mechanical Engineering Kalasalingam University Krishnankoil 626126 India Materials and Metallurgy Department Karadeniz Technical University Turkey

In the present work, the surface characteristics of Electrical Discharge Machined (EDM) Al (6351)eSiC and Al (6351)eSiCeB4C composites are investigated. The composites are prepared by employing the conventional stir casting technique, as it can produce better particle dispersion in the matrix. The detailed experimental study is performed on the composites by varying current (I), duty factor (t), pulse on time (Ton), and the gap voltage (V) in order to analyze the Heat Affected Zone (HAZ) formed in the sub surface and the average crater diameter formed on the machined surface of the composites as an output function. The formation of recast layers, presence of bubbles and the surface texture of the composites at various machining conditions are observed. The results show that the increased Metal Removal Rate (MRR) increases the depth of HAZ and the average crater diameter on the machined area. Further, the addition of B4C particles to the composite produces more surface defect than the AleSiC composite.

关键词： Composites EDM Surface Crater HAZ

Intracapsular fracture of the proximal femur in a bilateral above-knee amputee: A case report with technical tips for intraoperative positioning and literature review

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Chinese Journal of Traumatology 2022年第5期25卷 306-310页

作者： Aditya Jain Hemant bansal Samarth Mittal Arvind kumar Vivek Trikha Primus Super Specialy Hospital New DelhiIndia Department of orthopaedics Jay Prakash Narayan Apex Trauma Center All India Institute of Medical SciencesNew DelhiIndia Department of Orthopaedis Hamdard Institute of Medical Sciences&ResearchNew DelhiIndia

Intracapsular fractures of the proximal femur are one of the most common fractures of the lower limbs. Most cases require osteosynthesis with suitable implants, and intraoperative positioning of the patient on the fracture table is a prerequisite to facilitate fracture manipulation, traction, reduction and fluoroscopy assessment. However, positioning the limbs of bilateral above-knee amputees for internal fixation of related proximal femoral fractures is a difficult task, which requires customized inventory for effective limb positioning and fracture manipulation. This study reported a rare case following a crush injury of bilateral lower limb in a road traffic accident, and described some technical tips of acute femoral neck fractures in bilateral above-knee amputation. The patient was managed with immediate guillotine amputation and later secondary wound closure followed by internal fixation of the right-sided femoral neck fracture with multiple cancellous cannulated screws.

关键词： Femoral neck fractures Bilateral amputee Above-knee amputation Intraoperative positioning Surgical management

Super-resolution morphological dissemination of intercalating dye in single DNA molecules via binding activated localization microscopy

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Chinese Chemical Letters 2018年第3期29卷 505-508页

作者： Guenyoung Park suresh kumar Chakkarapani Soyeong Ju Sujin Ahn Seong Ho Kang Department of Chemistry Graduate School Kyung Hee University Department of Applied Chemistry and Institute of Natural Sciences Kyung Hee University

Fluorescent dye （YOYO-I） intercalated with single DNA molecules were investigated via bindingactivated localization microscopy （BALM） at sub-diffraction limit resolutions. Various dye-to-DNA base pair （bp） ratios were imaged using the blinking property of YOYO-1 dye under optimum BALM switching buffer conditions. Individual DNA molecules exhibited regular/irregular intercalating phenomena with respect to dye-to-DNA bp ratio. The acquired images were reconstructed into super-resolution images by applying a Gaussian fit to the centroid of the point spread function. The YOYO-1 intercalated with λ-DNA possessed a non-homogeneous region due to the different binding modes of YOYO-1 with λ-DNA. Each binding mode was imaged at the sub-diffraction limit super-resolution. The distance between homogenously localized intercalating dyes within the DNA molecules was measured to be 34nm （n= 10; dye：DNAbp= 1：100） without photocleavage in 50mmol/L β-mercaptoethylamine buffer. The results were similar to those of the theoretical values without photocleavage in the base pairs of single DNA molecules below the diffraction limit. The results paved the way for an in-depth microscopic analysis of molecular variation with single λ-DNA molecules. With this method, it should be possible to analyze the exact base pair breakdown during various stages of cell apoptosis.

关键词： λ-DNA Intercalating dye Morphological dissemination Sub-diffraction limit resolution Binding-activated localization microscopy

Effect of fracture-skin on virus transport in fractured porous media

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Geoscience Frontiers 2012年第6期3卷 893-900页

作者： N.Natarajan G.suresh kumar EWRE Division Department of Civil EngineeringIndian Institute of TechnologyMadrasChennai 36India Department of Ocean Engineering Indian Institute of TechnologyMadrasChennai 36India

A numerical model is developed for describing the transport of virus in a fracture-matrix coupled system with fracture-skin. An advective dispersive virus transport equation, including first- order sorption and inactivation constant is used for simulating the movement of viruses. Implicit finite-difference numerical technique is used to solve the coupled non-linear governing equations for the triple continuum model consisting of fracture, fracture-skin and the rock-matrix. A varying grid is adopted at the fracture and fracture-skin interface to capture the mass transfer. Sensitivity analysis was performed to investigate the effect of various properties of the fracture-skin as well as viruses on the virus concentration in the fractured formation with fracture-skin. Simulation results suggest that the virus concentration in the fracture decreases with increment in the fracture-skin porosity, fracture-skin diffu- sion coefficient, mass transfer coefficient, inactivation constant and sorption distribution coefficient, and with reduction in the fracture aperture.

关键词： Fracture-skin Virus transport Rock-matrix Fracture

Isolation of Pleurotus fl orida derived acetylcholinesterase inhibitor for the treatment of cognitive dysfunction in mice

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Food Science and Human Wellness 2021年第4期10卷 490-496页

作者： Kudrat Randhawa Varinder Singh Sanimardeep Kaur Ravinder Kaur suresh kumar Richa Shri Department of Pharmaceutical Sciences and Drug Research Punjabi UniversityPatiala 147002India Chitkara College of Pharmacy Chitkara UniversityPunjabIndia

Our earlier work showed that hydromethanol extract(HME)of Pleurotus fl orida had antioxidant and anticholinesterase *** study aimed at isolating the constituent responsible for the *** was subjected to bioactivity guided fractionation using in vitro anti-acetylcholinesterase(Ellman method)and antioxidant(DPPH scavenging assay).The most active constituent was evaluated in vivo employing ***(STZ)induced dementia in *** water maze test was used for evaluating memory,followed by biochemical estimations and histopathological *** guided fractionation resulted in isolation of resveratrol(identifi ed by IR,NMR and MS)and its content in *** orida fruiting bodies was 0.0098%(m/m,by a validated TLC densitometric method).It improved STZ induced dementia and neurodegeneration in mice by reducing brain acetylcholinesterase action and oxidative *** observed effects might be the presence of *** results further endorse that *** orida derived resveratrol can be a promising therapy for Alzheimer’s disease.

关键词： Acetylcholinesterase inhibitor Alzheimer’s disease Mushrooms Pleurotus fl orida Resveratrol