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Journal of Mountain Science 2024年第7期21卷 2173-2192页

作者： ZHANG Cheng CHEN peng ZHU Chengchang lu Jierui ZHANG Yuchen YANG Xinyue WU Mengyan College of Geomatics Xi'an University of Science and TechnologyXi'an 710054China State Key Laboratory of Geodesy and Earth’s Dynamics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430077China

Changes in water resource storage are inevitable due to climate change and human activities,thus understanding alterations in water storage within a specific region is imperative for the planning and management of water *** from the Gravity Recovery and Climate Experiment(GRACE)satellite mission are extensively employed to analyze large-scale total terrestrial water storage anomalies(TWSA).In this study,we derived a more reliable TWSA using different types of GRACE gravity models,which served as the basis for evaluating spatial and temporal variations in total terrestrial water storage and its hydrological components(soil moisture and groundwater)across the Loess ***,we analyzed the impact of natural and anthropogenic influences on water storage in the Loess Plateau,categorizing them into primary and secondary influences,utilizing data on climate and human *** findings revealed a declining trend in the overall TWSA of the Loess Plateau,with a rate of decrease at-0.65±0.05 cm/yr from 2003 to 2020(Pluenced by natural factors to a limited *** findings provided valuable insights for local governments to implement proactive water management policies.

关键词： GRACE Terrestrial water storage Human activity Loess Plateau

Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with superior Stability

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Nano-Micro Letters 2024年第4期16卷 350-363页

作者： Bin Li pengchao Ruan Xieyu Xu Zhangxing He Xinyan Zhu Liang Pan Ziyu peng Yangyang Liu peng Zhou Bingan lu Lei Dai Jiang Zhou School of Chemical Engineering North China University of Science and TechnologyTangshan 063009People’s Republic of China School of Materials Science and Engineering Central South UniversityChangsha 410083People’s Republic of China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China Hunan Provincial Key Defense Laboratory of High Temperature Wear‑Resisting Materials and Preparation Technology Hunan University of Science and TechnologyXiangtan 411201People’s Republic of China School of Physics and Electronics Hunan UniversityChangsha 410082People’s Republic of China

Achieving a highly robust zinc(Zn)metal anode is extremely important for improving the performance of aqueous Zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable growth of Zn dendrite and severe side reactions including hydrogen evolution reaction,corrosion,and passivation,***,an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups(COF-S-F)is developed on Zn metal(Zn@COF-S-F)as the artificial solid electrolyte interface(SEI).sulfonic acid group(-SO_(3)H)in COF-S-F can effectively ameliorate the desolvation process of hydrated Zn ions,and the three-dimensional channel with fluoride group(-F)can provide interconnected channels for the favorable transport of Zn ions with ion-confinement effects,endowing Zn@COF-S-F with dendrite-free morphology and suppressed side ***,Zn@COF-S-F symmetric cell can stably cycle for 1,000 h with low average hysteresis voltage(50.5 m V)at the current density of 1.5 m A cm^(-2).Zn@COF-S-F|Mn O_(2)cell delivers the discharge specific capacity of 206.8 m Ah g^(-1)at the current density of 1.2 A g^(-1)after 800 cycles with high-capacity retention(87.9%).Enlightening,building artificial SEI on metallic Zn surface with targeted design has been proved as the effective strategy to foster the practical application of high-performance AZIBs.

关键词： Aqueous Zn ion batteries Covalent organic framework Interfacial modification Zn ion flux regulation Desolvation effect

Development of a prognostic scoring system for hepatic vena cava Budd-Chiari syndrome with hepatocellular carcinoma

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Hepatobiliary & Pancreatic Diseases International 2024年第4期23卷 370-375页

作者： Sheng-Yan Liu lu-Hao Li Zhao-Chen Liu su-Xin Li Xiao-Wei Dang Department of Hepatopancreatobiliary surgery the First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052China Budd-Chiari Syndrome Diagnosis and Treatment Center of Henan Province Zhengzhou 450052China

Background:Hepatocellular carcinoma(HCC)is a serious complication of hepatic vena cava Budd-Chiari syndrome(HVC-BCS)that significantly reduces the survival time of *** study aimed to analyze the prognostic factors influencing the survival of HVC-BCS patients with HCC and to develop a prognostic scoring ***:The clinical and follow-up data of 64 HVC-BCS patients with HCC who received invasive treatment at the First Affiliated Hospital of Zhengzhou University between January 2015 and December 2019 were retrospectively ***-Meier curves and log-rank tests were used to analyze the survival curve of patients and the difference in prognoses between the *** and multivariate Cox regression analyses were performed to analyze the influence of biochemical,tumor,and etiological characteristics on the total survival time of patients,and a new prognostic scoring system was developed according to the regression coefficients of the independent predictors in the statistical *** prediction efficiency was evaluated using the time-dependent receiver operating characteristics curve and concordance ***:Multivariate analysis showed that serum albumin level7 cm(HR=8.623,95%CI:3.771-19.715,Psurvival.A prognostic scoring system was developed according to the above-mentioned independent predictors,and patients were classified into grades A,B,C and *** differences in survival were found among the four ***:This study successfully developed a prognostic scoring system for HVC-BCS patients with HCC,which is helpful for clinical evaluation of patient prognosis.

关键词： Budd-Chiari syndrome Hepatocellular carcinoma Prognostic factors Inferior vena cava stenosis Prognostic scoring system

260 fs,403 W coherently combined fiber laser with precise high‑order dispersion management

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Frontiers of Optoelectronics 2024年第1期17卷 21-27页

作者： Shuangxi peng Zhihao Wang Feilong Hu Zhengyan Li Qingbin Zhang Peixiang lu Wuhan National Laboratory for Optoelectronics and School of Physics Huazhong University of Science and TechnologyWuhan 430074China School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China Optics Valley Laboratory Wuhan 430074China

An ultrafast fiber laser system comprising two coherently combined amplifier channels is *** this system,each channel incorporates a rod-type fiber power amplifier,with individual operations reaching approximately 233 *** active-locking of these coherently combined channels,followed by compression using gratings,yields an output with a pulse energy of 504μJ and an average power of 403 *** stability is maintained,with a 0.3%root mean square(RMS)deviation and a beam quality factor M^(2)subsequent amplification *** strategic approach results in a significant reduction in the final output pulse duration for the coherently combined laser beam,reducing it from 488 to 260 fs after the gratings compressor,while concurrently enhancing the energy of the primary peak from 65%to 92%.

关键词： Fiber lasers amplifier Power scaling Coherent beam combination Dispersion compensation

Spin effect on redox acceleration and regioselectivity in Fe-catalyzed alkyne hydrosilylation

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National Science Review 2024年第2期11卷 155-167页

作者： peng He Meng-Yang Hu Jin-Hong Li Tian-Zhang Qiao Yi-Lin lu Shou-Fei Zhu Frontiers Science Center for New Organic Matter State Key Laboratory and Institute of Elemento-Organic Chemistry Nankai University

Iron catalysts are ideal transition metal catalysts because of the Earths abundant, cheap, biocompatible features of iron salts. Iron catalysts often have unique open-shell structures that easily undergo spin crossover in chemical transformations, a feature rarely found in noble metal catalysts. Unfortunately, little is known currently about how the open-shell structure and spin crossover affect the reactivity and selectivity of iron catalysts, which makes the development of iron catalysts a low efficient trial-and-error program. In this paper, a combination of experiments and theoretical calculations revealed that the iron-catalyzed hydrosilylation of alkynes is typical spin-crossover catalysis. Deep insight into the electronic structures of a set of well-defined open-shell active formal Fe(0) catalysts revealed that the spin-delocalization between the iron center and the 1,10-phenanthroline ligand effectively regulates the iron center's spin and oxidation state to meet the opposite electrostatic requirements of oxidative addition and reductive elimination, respectively,and the spin crossover is essential for this electron transfer process. The triplet transition state was essential for achieving high regioselectivity through tuning the nonbonding interactions. These findings provide an important reference for understanding the effect of catalyst spin state on reaction. It is inspiring for the development of iron catalysts and other Earth-abundant metal catalysts, especially from the point of view of ligand development.

关键词： spin effect spin-delocalization spin crossover iron-catalysis alkyne hydrosilylation

Optical properties of stacked liquid crystal superstructures with opposite chirality [Invited]

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Chinese Optics Letters 2024年第6期22卷 158-163页

作者： Lin Zhu Yiheng Zhang Shijun Ge peng Chen Yanqing lu National Laboratory of Solid State Microstructures Key Laboratory of Intelligent Optical Sensing and ManipulationCollege of Engineering and Applied Sciencesand Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China

Cholesteric liquid crystal (CLC) has been widely used in flat optical elements due to the Pancharatnam–Berry(PB) phase modulation. In order to achieve PB phase modulation for both circular polarizations, it is natural to come up with stacking CLCs with opposite chirality. Here, various optical properties of diverse CLC stacking structures are systematically investigated by numerical calculations. With the thickness of the CLC sublayers becoming smaller, the reflection bandgap splits into three main parts, and the rotatory dispersion gradually becomes negligible. Vector beams provide a more intuitive verification. These results provide theoretical guidance for future studies on stacked chiral anisotropic media.

关键词： cholesteric liquid crystals Pancharatnam–Berry phases chirality vector beams

In situ observation of the electrochemical behavior of Li–CO_(2)/O_(2)batteries in an environmental transmission electron microscope

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Carbon Energy 2024年第4期6卷 244-255页

作者： peng Jia Yunna Guo Dongliang Chen Jingming Yao Xuedong Zhang Jianguo lu Yuqing Qiao Liqiang Zhang Hebei Key Laboratory of Applied Chemistry College of Environmental and Chemical EngineeringYanshan UniversityQinhuangdaoChina State Key Laboratory of Metastable Materials Science and Technology Clean Nano Energy CenterYanshan UniversityQinhuangdaoChina State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhouChina Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education School of Materials Science and EngineeringXiangtan UniversityXiangtanChina

Li–CO_(2)/O_(2)batteries,a promising energy storage technology,not only provide ultrahigh discharge capacity but also capture CO_(2)and turn it into renewable *** electrochemical reaction pathways'ambiguity,however,creates a hurdle for their practical *** study used copper selenide(CuSe)nanosheets as the air cathode medium in an environmental transmission electron microscope to in situ study Li–CO_(2)/O_(2)(mix CO_(2)as well as O_(2)at a volume ratio of 1:1)and Li–O_(2)batteries as well as Li–CO_(2)*** discharge reactions take place successively in the Li–CO_(2)/O_(2)–CuSe nanobattery:(I)4Li^(+)+O_(2)+4e^(−)→2Li_(2)O;(II)Li_(2)O+CO_(2)→Li_(2)CO_(3).The charge reaction proceeded via(III)2Li_(2)CO_(3)→4Li^(+)+2CO_(2)+O_(2)+4e^(−).However,Li–O_(2)and Li–CO_(2)nanobatteries showed poor cycling stability,suggesting the difficulty in the direct decomposition of the discharge *** fluctuations of the Li–CO_(2)/O_(2)battery's electrochemistry were also shown to depend heavily on O_(2).The CuSe‐based Li–CO_(2)/O_(2)battery showed exceptional electrochemical *** Li^–CO_(2)/O_(2)battery offered a discharge capacity apex of 15,492 mAh g^(−1) and stable cycling 60 times at 100 mA g^(−1).Our research offers crucial insight into the electrochemical behavior of Li–CO_(2)/O_(2),Li–O_(2),and Li–CO_(2)nanobatteries,which may help the creation of high‐performance Li–CO_(2)/O_(2)batteries for energy storage applications.

关键词： CuSe nanosheets electrochemical reaction in situ environmental transmission electron microscopy Li-CO_(2)battery Li-CO_(2)/O_(2)battery Li-O_(2)battery

Synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48(ANMZ-48)directed by metal complexes in amphiphilic molecules

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Science China Chemistry 2024年第1期67卷 343-350页

作者： Yu Chen Quanzheng Deng Yiru Mao Yuxi Fang Zhihua Cao Honggen peng Shunai Che lu Han School of Chemical Science and Engineering Tongji UniversityShanghai 200092China School of Chemistry and Chemical Engineering Nanchang UniversityNanchang 330031China School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240China School of Resources and Environment Nanchang UniversityNanchang 330031China State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai 200240China

The synthesis of mesoporous zeolite-anchored atomically dispersed metal catalysts(ADCs)is a considerable challenge in chemistry and materials *** we report the synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48(ANMZ-48)by in situ hydrothermal reaction employing a designed tri-functional metal complex template,by which the triquaternary ammonium groups in the hydrophilic region direct the formation of ZSM-48 zeolite;the aromatic groups in the hydrophobic tail generate the mesopores through π-π stacking;and the complexes formed by nickel ions coordinated with terpyridyl groups generate atomically dispersed Ni2+confined in zeolite frameworks due to the strong sintering resistance generated by the strong coordination *** ANMZ-48 is consisting of stacking of sheet-like ZSM-48 domains connected by multiply crystal twinning sharing the common(011)plane,generating abundant of imbedded mesopores with the uniform thickness of~2.4 nm and with the width of 10-50 *** excellent catalytic activity and stability of ANMZ-48 were also reflected in the dry reforming of methane(DRM)reaction.

关键词： atomically dispersed catalyst mesoporous zeolite ZSM-48 in situ hydrothermal synthesis the dry reforming of methane reaction

Epigenetic regulation of SARS-Cov-2 spike protein modulates cellular viability and nascent RNA transcription in neuronal cells

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Genes & Diseases 2024年第2期11卷 535-538页

作者： Xi Kong peng lu Jinyue Zhang Zheng Bao Chenghao Kuang Bingqing Xie Jianhua peng Ning Ma Yong Jiang Shigang Yin Laboratory of Neurological Diseases and Brain Function The Affiliated Hospital of Southwest Medical UniversityLuzhouSichuan 646000China Institute of Epigenetics and Brain Science Southwest Medical UniversityLuzhouSichuan 646000China Department of Neurosurgery The Affiliated Hospital of Southwest Medical UniversityLuzhouSichuan 646000China Inflammation and Allergic Diseases Research Unit The Affiliated Hospital of Southwest Medical UniversityLuzhouSichuan 646000China

SARS-CoV-2 has been demonstrated to be highly susceptible to neuron-and glial-like cells,1 but there is no consensus regarding how the virus affects neurons following *** is therefore unknown if and how SARS-CoV-2 maintains the homeostasis of neuronal ***,we revealed that the receptor-binding domain(RBD)of the SARS-CoV-2 spike protein acted as an extracellular remodeling component to undermine epigenetic regulation,perturbnascentRNA(nsRNA)transcription,promote mitochondrial biogenesis,and increase cellular viability in SH-SY5Y cells.

关键词： invasion homeostasis maintain

A self-powered biosensor based on triboelectric nanogenerator for dual-specificity bacterial detection

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InfoMat 2024年第3期6卷 117-130页

作者： Wei lu Xiaoqiang Wang Congyu Wang Ke Gong Jiawei Li Xue Li peng Wang State Key Laboratory of Heavy Oil Processing College of Chemistry and Chemical EngineeringChina University of Petroleum(East China)Qingdaothe People's Republic of China Institute of Oceanology Chinese Academy of SciencesQingdaothe People's Republic of China School of Material Science and Engineering China University of Petroleum(East China)Qingdaothe People's Republic of China State Key Laboratory of Microbial Technology Shandong UniversityQingdaothe People's Republic of China Guangxi Academy of Sciences Nanningthe People's Republic of China

Pathogenic and corrosive bacteria pose a significant risk to human health or economic *** specific,sensitive,and on-site detection of these bacteria is thus of paramount significance but remains *** inspiration from immunoassays with primary and secondary antibodies,we describe here a rational design of microbial sensor(MS)under a dualspecificity recognition strategy using Pseudomonas aeruginosa(***)as the detection *** the MS,engineered aptamers are served as the primary recognition element,while polydopamine-N-acetyl-D-galactosamine(PDA-Gal NAc)nanoparticles are employed as the secondary recognition element,which will also generate and amplify changes in the output voltage sig*** achieve self-powering capability,the MS is constructed based on a triboelectric nanogenerator(TENG)with the specific aptamers immobilized on the TENG electrode *** as-prepared MS-TENG system exhibits good stability in output performance under external forces,and high specificity toward ***,with no cross-reactivity observed.A linear relationship(R^(2)=0.995)between the output voltage and *** concentration is established,with a limit of detection estimated at around 8.7×10^(3) CFU mL^(-1).The utilization of PDA-Gal NAc nanoparticles is found to play an important role in enhancing the specific and reliability of detection,and the underlying mechanisms are further clarified by computational *** addition,the MS-TENG integrates a wireless communication module,enabling real-time monitoring of bacterial concentration on mobile *** work introduces a pioneering approach to designing self-powered smart microbial sensors with high specificity,using a double recognition strategy applicable to various bacteria beyond ***.

关键词： bacterial detection high specificity microbial sensor triboelectric nanogenerator wireless transmission