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Experimental and theoretical investigation of high-entropy-alloy/support as a catalyst for reduction reactions

Journal of Energy Chemistry 2023年第6期81卷 132-142,I0005页

作者： Wail Al Zoubi Bassem Assfour Abdul Wahab Allaf stefano leoni Jee-Hyun Kang Young Gun Ko Materials Electrochemistry Laboratory School of Materials Science and EngineeringYeungnam UniversityGyeongsan 38541Republic of Korea Atomic Energy Commission Department of ChemistryP.O.Box 6091DamascusSyria Arab International University Department of Pharmaceutical Chemistry and Quality ControlFaculty of PharmacyGhabaghibDarraSyria Cardiff University School of ChemistryPark PlaceCF103AT CardiffUnited Kingdom School of Materials Science and Engineering Institute of Materials TechnologyYeungnam UniversityGyeongsan 38541Republic of Korea

Control of chemical composition and incorporation of multiple metallic elements into a single metal nanoparticle(NP)in an alloyed or a phase-segregated state hold potential scientific merit;however,developing libraries of such structures using effective strategies is challenging owing to the thermodynamic immiscibility of repelling constituent metallic ***,we present a one-pot interfacial plasma-discharge-driven(IP-D)synthesis strategy for fabricating stable high-entropy-alloy(HEA)NPs exhibiting ultrasmall size on a porous support ***,an electric field was applied for 120 s to enhance the incorporation of multiple metallic elements(i.e.,CuAgFe,CuAgNi,and CuAgNiFe)into ally ***,NPs were attached to a porous magnesium oxide surface via rapid *** solar light as the sole energy input,the CuAgNiFe catalyst was investigated as a reusable and sustainable material exhibiting excellent catalytic performance(100%conversion and 99% selectivity within1 min for a hydrogenation reaction)and consistent activity even after 20 cycles for a reduction reaction,considerably outperforming the majority of the conventional ***,the proposed strategy establishes a novel method for designing and synthesizing highly efficient and stable catalysts for the convertion of nitroarenes to anilines via chemical reduction.

关键词： Plasma Miscible Multicomponent Metal nanoparticle Nanocatalysts

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Confinement and synergy effects of supported-confined bimetal catalysts with superior stability and catalytic activity

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Journal of Energy Chemistry 2024年第12期99卷 93-99页

作者： Yujun Sheng Farah Hazmatulhaq Abdullah Al Mahmud Mostafa S.Sayed Iftikhar Hussain stefano leoni Wail Al Zoubi Young Gun Ko Integrated Materials Chemistry Laboratory School of Materials Science and EngineeringYeungnam UniversityGyeongsan 38541Republic of Korea School of Chemical Engineering Yeungnam UniversityGyeongsanGyeongbuk 38541Republic of Korea Analysis and Evaluation Department Egyptian Petroleum Research InstituteNasr CityCairo 11727Egypt Department of Mechanical Engineering City University of Hong KongHong Kong 999077China Cardiff University School of ChemistryCardiff CF103ATUnited Kingdom

Bimetallic nanocrystals have attracted considerable attention because of their complicated systems,which are far superior to those of their individual constituents.A TiO_(2)-confined PtMnP bimetallic catalyst(PtMnP@TiO_(2)) was prepared using an ultrasonic-assisted coincident strategy,which demonstrated exceptional catalytic activity in the universal hydrogen evolution reaction (HER).Owing to the bimetallic synergistic effect and TiO_(2) confinement,PtMnP@TiO_(x)showed ultrasmall metal nanoparticles (NPs),a higher active Pt^(0) content,adequate activation at the porous surface,and abundant acid *** were performed to visualize the strain properties of Mn and Pt during the bending process and demonstrate the high activity of *** Pt-Mn bimetallic catalysts were enriched with Pt NPs,convoyed by electron transfer from Mn to ***,PtMnP@TiO_(2) showed robust evolution reaction activities (an overpotential of 220 mV at a current density of 10 mA cm^(-2) and a Tafel slope of 186 mV dec^(-1))and the ability to contrast stated catalysts without *** protocol revealed that the geometrical and electronic effects of Pt and P surrounding the Mn species in PtMnP@TiO_(2) were crucial for increasing the catalytic activity (99%) and durability (over 20 cycles),which were far superior to those of other reported catalysts.

关键词： Synergy Bimetal Catalyst Stability Activity

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Origin of the synergistic effects of bimetallic nanoparticles coupled with a metal oxide heterostructure for accelerating catalytic performance

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SusMat 2024年第3期4卷 227-239页

作者： Wail Al Zoubi Abdullah Al Mahmud Farah Hazmatulhaq Mohammad R.Thalji stefano leoni Jee-Hyun Kang Young Gun Ko Integrated Materials Chemistry Laboratory School of Materials Science and EngineeringYeungnam UniversityGyeongsanRepublic of Korea School of Chemical Engineering Yeungnam University280 Daehak-roGyeongsanGyeongbukRepublic of Korea Korea Institute of Energy Technology(KENTECH) 200 Hyeokshin-roJeollanam-doNajuRepublic of Korea Cardiff University School of ChemistryCF103AT CardiffUnited Kingdom

Precisely tuning bicomponent intimacy during reactions by traditional methods remains a formidable challenge in the fabrication of highly active and stable catalysts because of the difficulty in constructing well-defined catalytic systems and the occurrence of agglomeration during *** overcome these limitations,a PtRuPNiO@TiO_(x)catalyst on a Ti plate was prepared by ultrasound-assisted low-voltage plasma *** method involves the oxidation of pure Ti metal and co-reduction of strong metals at 3000◦C,followed by sonochemical ultrasonication under ambient conditions in an aqueous *** intimacy of the bimetals in PtRuPNiO@TiOx is tuned,and the metal nanoparticles are uniformly distributed on the porous titania coating via strong metal-support interactions by leveraging the instantaneous high-energy input from the plasma discharge and ultrasonic *** intimacy of PtRuPNiO@TiO_(x)increases the electron density on the Pt ***,the paired sites exhibit a high hydrogen evolution reaction activity(an overpotential of 220 mV at a current density of 10 mA cm^(−2)and Tafel slope of 186 mV dec^(−1)),excellent activity in the hydrogenation of 4-nitrophenol with a robust stability for up to 20 cycles,and the ability to contrast stated catalysts without ultrasonication and plasma *** study facilitates industrially important reactions through synergistic chemical interactions.

关键词： bimetals nanoparticles oxides heterostructures hydrogenation

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Long-term durable response to lenalidomide in a patient with hepatic epithelioid hemangioendothelioma

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World Journal of Gastroenterology 2014年第22期20卷 7049-7054页

作者： Maria Caterina Pallotti Margherita Nannini Claudio Agostinelli Simona leoni Valerio Di Scioscio Anna Mandrioli Cristian Lolli Maristella Saponara stefano Pileri Luigi Bolondi Guido Biasco Maria Abbondanza Pantaleo Department of Specialized Experimentaland Diagnostic MedicineS. Orsola-Malpighi HospitalUniversity of Bologna40138 BolognaItaly Hematopathology Section Department of ExperimentalDiagnosticand Specialty MedicineS. Orsola-Malpighi HospitalUniversity of Bologna40138 BolognaItaly Division of Internal Medicine Department of Digestive Disease and Internal MedicineS. Orsola-Malpighi HospitalUniversity of Bologna40138 BolognaItaly Department of Radiology S. Orsola-Malpighi HospitalUniversity of Bologna40138 BolognaItaly InterdepartmentalCentre for Cancer Research "G. Prodi" University of Bologna40138 BolognaItaly

Epithelioid hemangioendothelioma(EH)is a rare tumor arising from the vascular endothelial cells of soft tissue or visceral *** most common visceral site is the liver,where it is often involved in a multifocal man-ner known as hepatic EH(HEH).Surgical resection with curative intent represents the gold standard *** surgery is not feasible,or in cases of metastatic disease,no standard medical treatment is currently *** small series,drugs with anti-angiogenic activity(such as bevacizumab,sorafenib,thalidomide,and lenalidomide)have been proposed with promising *** describe a 73-year-old man with multifocal non-resectable HEH treated with *** status was evaluated by abdominal ultrasound and magnetic resonance every four *** patient was treated for a total of 39 mo with prolonged disease stabilization and,at the time of writing,is still under treatment with a good tolerance *** a short period of treatment discontinuation,the disease showed slight progression that immediately resolved after the reintroduction of *** may represent a valid treatment option for HEH due to its anti-angiogenic and antineoplastic *** preliminary result merits further study in a large series.

关键词： Hepatic epithelioid hemangioendothelioma Liver Lenalidomide Magnetic resonance Abdominal ultrasound

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FK-506 ointment： an effective adjuvant therapy to treat a dramatic case of pyoderma gangrenosum of unilateral hand

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Chinese Journal of Traumatology 2009年第3期12卷 181-183页

作者： stefano Lucchina Sandra leoni Parvex Paul Biegger Cesare Fusetti Hand Surgery Unit Surgical Department Locarno's Regional Hospital Via all'Ospedale 1 6600 Locarno Switzerland Cantonal Institute of Pathology Locarno Switzerland

Pyoderma gangrenosum （PG） is a cutaneous ulcer developing so rapidly that may mimic a fulminating infection. The correct treatment is nonsurgical, and surgery may get the condition worse.^1 FK-506 ointment （0.1% Protopic, Astellas Pharma AG, Fribourg） is usually indicated for inflammatory skin diseases, such as atopic dermatitis and psoriasis^2 or for acute rejection reversal of human hand transplantation^3. Afew reports of PG affecting the functions of hands can be found in the scientific literature and this report describes the first case treated by FK-506 ointment as an adjuvant therapy.

关键词：非手术治疗坏疽性脓皮病辅助疗法软膏单方案件戏剧暴发性感染

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