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ASSIGNMENTS FOR THE GROUND stateS OF METAL MONOCARBONYLS

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Chinese Chemical Letters 1995年第10期6卷 887-890页

作者： Xin XU Nan Qin WANG Xin LU Qian Er ZHANG(state key laboratory for Physical chemistry of the Solid Surface,Department of chemistry,Xiamen University,fujian 361005) Xiamen Univ Dept Chem State Key Lab Phys Chem Solid Surface Xiamen 361005 Peoples R China

The bonding mechanisms between the first-row transition metal and carbon monoxide were discussed. Three basic rules have been drawn up to determine the ground states of the metal monocarbonyls. The theoretical assignm...

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A NEW TYPE OF CHAIN COMPOUND,STRUCTURE OF TA_4(TE_2)_4TE_4I

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Chinese Chemical Letters 1993年第3期4卷 273-274页

作者： Shui Quan DENG Hong Hui ZHUANG Ding Ming WU Jin Ling BUANG fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences and state key laboratory of Structure chemistry,fuzhou,fujian 350002

Ta_4(Te_2)_4Te_4I,Mr=2381.90,Monoclinic,C2/c,a=21.987(2),b=6.153(2),c= 19.936(3),β=122.42(14),V=2276.7 ~3,z=4,Dm=6.8(5)g/cm^3,Dc=6.95g/cm^3,λ(Mok)= 0.71073,μ=354.0cm^(-1),F(000)=3876,T=296(1)k,R=5.3%,Rw=6.8%,for 1118 unique observed reflections(1>3σ(Ⅰ)).The structure is composed of [Ta_4(Te_2)_4Te_4I]_∞~ chains,which are formed by the four-nuclear butterfly cluster units "Ta_4(Te_2)_4Te_4" with the Ⅰ atoms as the bridging atoms between different cluster units.

关键词： Ta Te A NEW TYPE OF CHAIN COMPOUND,STRUCTURE OF TA4 TE2

Exploring Novel Metal Chalcogenides:The Synthesis,structural Construction and Property

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Exploring Novel Metal Chalcogenides:The Synthesis,Structural...

中国化学会第六届全国结构化学学术会议

作者： Xiao-Ying Huang~* 1 state key laboratory of structural chemistry,fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,fuzhou 350002

＜正＞Metal chalcogenides are a class of compounds having rich structural chemistry and many potential *** the past few years,we have devoted much effort in the synthesis,structural design and property study of novel metal *** have successfully employed the ionic liquids of imidazolium halides as solvent and structure directing agent to synthesize novel metal chalcogenides that

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THE　STUDY　ON　ELECTROXIDATION　OF　Fe（CN）_6^（4－）　WITH　TIME－RESOLVED　IN　FRARED　SPECTRA

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Chinese Chemical Letters 1994年第3期5卷 233-236页

作者： Yong YANG(state key laboratory for Physical chemistry of the Solid Surface,Departmetn of chemistry ,Xiamen University,fujian

We have in vestigated the dynamic process of electroxidation of Fe(CN)at different electrode surface by usign in-situ time-resoved infrared *** possible intermediates produced in the electroxidation process on platiinum electrode have been monitored and *** effect of surface state on the time-resolved spectra of the electrode reaction has also been observed and discussed.

关键词： CN OF Fe ELECTROXIDATION

Structure　of　Molybdenum　Complex　of　Benzothiazole－2－thiolate（η5－C5H5）Mo（CO）2（C7H4NS2）

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Chinese Journal of structural chemistry 1995年第1期 47-50页

作者： Cheng Guo-Bao Wu Qiang-Jin Huang Xiao-Ying￣b(state key laboratory of structural chemistry,fuzhou,China)(Dalian Institute of Chemical Physics,Dalian,116023)(fujian Institute of Research on the Structure of Matter,fuzhou,350002)

ＳｔｒｕｃｔｕｒｅｏｆＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘｏｆＢｅｎｚｏｔｈｉａｚｏｌｅ－２－ｔｈｉｏｌａｔｅ（η５－Ｃ５Ｈ５）Ｍｏ（ＣＯ）２（Ｃ７Ｈ４ＮＳ２）ＣｈｅｎｇＧｕｏ－Ｂａｏａ；ＷｕＱｉａｎｇ－Ｊｉｎｂ；Ｈｕ... 详细信息

ＳｔｒｕｃｔｕｒｅｏｆＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘｏｆＢｅｎｚｏｔｈｉａｚｏｌｅ－２－ｔｈｉｏｌａｔｅ（η５－Ｃ５Ｈ５）Ｍｏ（ＣＯ）２（Ｃ７Ｈ４ＮＳ２）ＣｈｅｎｇＧｕｏ－Ｂａｏａ；ＷｕＱｉａｎｇ－Ｊｉｎｂ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ...

关键词： crystal structure molybdenum complex benzothiazole-2-thiolate

Ordered mesoporous carbon supported hydrous ruthenium oxide for supercapacitor

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Ordered mesoporous carbon supported hydrous ruthenium oxide ...

中国化学会第五届全国结构化学学术会议

作者： Hongfang Li Rong Cao state key laboratory of structural chemistry,fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,fujian,fuzhou,350002,china

Ruthenium oxide/ordered mesoporous carbon composites materials were prepared by impregnating an ordered mesoporous carbon CMK-3 with RuCla’xH20 solution followed by annealing in nitrogen atmosphere from 80 to 400℃.The content of ruthenium oxide in the composites ranged from 10.0 to 30.7 wt.%.X-ray diffraction(XRD),thermogravimetric analysis (TGA),nitrogen adsorption measurement and transmission electron microscopy(TEM)were used to characterize the *** results showed that the ruthenium oxide deposited on CMK-3 mesoporous carbon was hydrous and amorphous when annealed up to 400℃.The specific capacitance of the composites was determined by cyclic *** composites had high specific capacitance,which was derived from the high specific surface area of CMK-3 mesoporous carbon and the pseudo-capacitance of amorphous *** addition,the specific capacitance depended on the annealing temperature and the RuO *** the temperature increased,the specific capacitance *** contrast,the specific capacitance increased with higher RuO content and reached 639 F/g with heavy ***,as the RuO content increased,its contribution to the pseudo-capacitance became *** rate capability of the composite electrodes also decreased as a function of RuO content,due to an increase in the equivalent series resistance(ESR)and the overall capacitance.

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A new family of high valent Mn-containing heterometallic complexes derived from Ce4+oxidation

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A new family of high valent Mn-containing heterometallic com...

中国化学会第五届全国结构化学学术会议

作者： Chengbing Ma Changneng Chen Qiutian Liu state key laboratory of structural chemistry,fujian Institute of Research on the Structure of Matter,CAS,fuzhou,fujian 350002,PRC

＜正＞Polynuclear coordination compounds of Mn（Ⅲ）and Mn（Ⅳ）have long been of interest. Apart from their relevance to a wide variety of biological redox processes,and their inherent potential as redox catalysts or...

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Synthesis and Crystal Structure of a 2-D Zn（Ⅱ） Complex with Azobenzene-containing Ligand

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Synthesis and Crystal Structure of a 2-D Zn（Ⅱ） Complex wi...

中国化学会第五届全国结构化学学术会议

作者： Bing Hu Jie Zhang state key laboratory of structural chemistry,fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,fuzhou 350002

＜正＞As the isomerization of azobenzene would lead to a change of the intrinsic properties of its correlated complexes,complexes based on azobenzene-containing ligands have attracted much attention. A two-dimensional （2D）Zn（Ⅱ）complex with Alizarin Yellow GG （AYG）has been prepared by the one-pot reaction

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MOLECULAR AND CRYSTAL STRUCTURE OF Co_3 (μ-PSCH_2CH_2O)_3 (CO)_6 CONTAINING NEW BRIDGING HETEROCYCLIC PHOSPHIDO LIGANDS

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Chinese Chemical Letters 1994年第5期5卷 405-408页

作者： Qi Wang LIU Xiang HU Shu Tang LIU Jian Qiu SHI Li Ping ZHANG and Bao Shan WU.(Department of chemistry, Inner Mongolia University, Huhhot 010021 state key laboratory of structural chemistry, fuzhou 350002)

Reaction of ClP with Co2(CO)8 in the presence of pulverous Zn gives the heterocyclic phosphido ligand containing Co3 cluster Co3 (μ-PACH2CH2O)3 (CO)6(1), in 1 three cobalt atoms form an isosceles triangle, two of the three phosphido bridges are generally coplanar with Co3 triangle but the third phosphido bridge is almost orthogonal from the Co3 plane.

关键词： CONTAINING NEW BRIDGING PSCH2CH2O HETEROCYCLIC Co3 AND CH