MOLECULAR AND CRYSTAL STRUCTURE OF Co_3 (μ-PSCH_2CH_2O)_3 (CO)_6 CONTAINING NEW BRIDGING HETEROCYCLIC PHOSPHIDO LIGANDS

作     者：Qi Wang LIU Xiang HU Shu Tang LIU Jian Qiu SHI Li Ping ZHANG and Bao Shan WU.(Department of Chemistry, Inner Mongolia University, Huhhot 010021 State Key Laboratory of Structural Chemistry, Fuzhou 350002) 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1994年第5卷第5期

页      面：405-408页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

主　　题：CONTAINING NEW BRIDGING PSCH2CH2O HETEROCYCLIC Co3 AND CH 

摘      要：Reaction of ClP with Co2(CO)8 in the presence of pulverous Zn gives the heterocyclic phosphido ligand containing Co3 cluster Co3 (μ-PACH2CH2O)3 (CO)6(1), in 1 three cobalt atoms form an isosceles triangle, two of the three phosphido bridges are generally coplanar with Co3 triangle but the third phosphido bridge is almost orthogonal from the Co3 plane.