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Moderately concentrated electrolyte enabling high-performance lithium metal batteries with a wide working temperature range

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Journal of Energy Chemistry 2023年第4期79卷 201-210页

作者： Sisi Wang Zhichen Xue Fulu Chu Zengqiang Guan Jie Lei Feixiang Wu School of Metallurgy and Environment Engineering Research Center of the Ministry of Education for Advanced Battery MaterialsHunan Provincial Key Laboratory of Nonferrous Value-added MetallurgyState Key Laboratory of Powder MetallurgyCentral South UniversityChangsha 410083HunanChina

The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.

关键词： Moderately concentrated electrolyte Wide temperature range LiFePO_(4)cathode Lithium metal battery Solid electrolyte interphase

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A Ruddlesden-Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

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Chinese Journal of Chemical Engineering 2023年第4期56卷 25-32页

作者： Shujun Peng Song Lei sisi Wen Jian Xue Haihui wang School of Chemistry&Chemical Engineering Jinggangshan UniversityJi'an 343009China School of Chemistry&Chemical Engineering Guangdong Provincial Key Lab of Green Chemical Product TechnologySouth China University of TechnologyGuangzhou 510640China Beijing Key Laboratory of Membrane Materials and Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

Solid oxide fuel cells(SOFCs) that operate at intermediate temperatures of 600 to 800℃ have recently received increased attention due to their improved durability, more rapid startup and shutdown, better sealing and lower cost than their counterparts operate at high temperatures. Nevertheless, intermediatetemperature SOFCs(IT-SOFCs) with popular perovskite cathodes contain alkaline-earth elements, which are prone to reaction with carbon dioxide(CO_(2)), even when the CO_(2) content is comparatively low. In this work, an alkaline-earth metal-free Ruddlesden-Popper oxide, Nd_(1.8)La_(0.2)Ni_(0.74)Cu_(0.21)Ga_(0.05)O_(4+δ)(NLNCG), is developed for IT-SOFC cathodes. The cell is based on an electrolyte with 8%(mol) Y_(2)O_(3)-stabilized Zr O_(2)(8YSZ). The NLNCG cathode exhibits an excellent CO_(2) tolerance, as proven by thermogravimetry analysis,in situ X-ray diffraction, I-V-P test, and electrochemical impedance spectroscopy(EIS), and stability measurements. The anode-supported single-cell Ni O-YSZ|YSZ|NLNCG outputs a peak power density of 0.522 W·cm^(-2) at 800℃. These findings suggest that NLNCG could be a highly suitable cathode material with CO_(2) tolerance for IT-SOFCs.

关键词： Fuel cell Hydrogen Kinetics Catalyst CO_(2)tolerance

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Elucidating the electronic metal-support interaction enhanced hydrogen evolution activity on Ti_(3)C_(2)T_(x)MXene basal plane by scanning electrochemical microscopy

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Nano Research 2023年第7期16卷 8902-8909页

作者： sisi Jiang Tong Sun Chaoqun Gu Yingfei Ma Zhenyu wang Dengchao wang Zonghua wang College of Chemistry and Chemical Engineering Shandong Sino-Japanese Center for Collaborative Research of Carbon NanomaterialsInstrumental Analysis Center of Qingdao UniversityQingdao UniversityQingdao 266071China School of Chemical Sciences University of Chinese Academy of ScienceBeijing 100190China

MXene,a family of two-dimensional(2D)transition metal carbides and nitrides,has intriguing electrochemical energy storage and electrocatalysis applications.Introducing the electronic metal-support interaction(EMSI)effect is one effective strategy to optimize the catalytic efficiency for MXene-based composites.However,most of the studies concentrate on optimizing the performance of metals rather than supported substrates by using this strategy.In this work,we mainly investigate the influence of an EMSI effect on the performance of the supported substrate(Ti_(3)C_(2)T_(x)MXene).Detailed scanning electrochemical microscopy and numerical simulations results reveal that the charge distribution on the Ti_(3)C_(2)T_(x)basal plane(approximate 100 nm-radius)surrounding Au nanoparticles(20 nm-radius)was significantly enhanced as a result of-O being the majority surface functional group on Ti_(3)C_(2)T_(x)that was attached to Au nanoparticle,and the related hydrogen evolution reaction(HER)activity was much better than that of the unaffected Ti_(3)C_(2)T_(x)basal plane,which even can be comparable to that of Au.This finding will be helpful for designing new strategies to enhance the overall catalytic performance of various MXene-based composites.

关键词： electrocatalysis nanoelectrochemistry MXenes scanning electrochemical microscopy electronic metal-support interaction

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Overcoming the Limitation of Cs_(2)AgBiBr_(6) Double Perovskite Solar Cells Through Using Mesoporous TiO_(2) Electron Extraction Layer

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Energy & Environmental Materials 2022年第4期5卷 1317-1322页

作者： Dandan Zhao Chao Liang Bingzhe wang Tanghao Liu Qi Wei Kaiyang wang Hao Gu Sisi Wang Shiliang Mei Guichuan Xing Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials EngineeringUniversity of MacaoAvenida da UniversidadeTaipa Macao 999078China

Lead-free double perovskite Cs_(2)AgBiBr_(6) has gained increasing attention recently.However,the power conversion efficiency(PCE)of Cs_(2)AgBiBr_(6) perovskite solar cells(PSCs)is still low compared with their lead-based counterparts.Here,by using photoluminescence(PL),time-resolved photoluminescence(TRPL),and ultrafast transient absorption(TA)measurements,the unbalance between the electron and hole in diffusion and transfer,which limits the performance of the Cs_(2)AgBiBr_(6) PSCs,was further revealed.Considering this issue,a strategy of using the mesoporous TiO_(2) electron transport layer(ETL)to construct a bulk heterojunction in Cs_(2)AgBiBr_(6) PSCs was proposed.Consequently,the PCE had improved by over 24%comparing with that only used compact TiO_(2) ETL.Moreover,based on mesoporous TiO_(2),the unencapsulated Cs_(2)AgBiBr_(6) PSCs maintained 90%of their initial performance after approximately 1200 h of storage in a desiccator(humidity~30%).This work gives further understanding of Cs_(2)AgBiBr_(6) perovskite and demonstrates that a proper design of balancing the electron and hole diffusion can improve device performance.

关键词： bulk heterostructure charge carrier dynamics Cs_(2)AgBiBr_(6) lead-free double perovskite solar cells

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Preclinical characterization and comparison between CD3/CD19 bispecific and novel CD3/CD19/CD20 trispecific antibodies against B-cell acute lymphoblastic leukemia:targeted immunotherapy for acute lymphoblastic leukemia

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Frontiers of Medicine 2022年第1期16卷 139-149页

作者： Sisi Wang Lijun Peng Wenqian Xu Yuebo Zhou Ziyan Zhu Yushan Kong Stewart Leung Jin wang Xiaoqiang Yan Jian-Qing Mi Shanghai Institute of Hematology State Key Laboratory of Medical GenomicsNational Research Center for Translational Medicine at ShanghaiRuijin Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai 200025China Pôle Franco-Chinois de Recherche en Sciences du Vivant et Genomique Shanghai 200025China Shanghai Blood Center Shanghai 200051China Generon Biomed Shanghai 201210China

The CD19-targeting bispecific T-cell engager blinatumomab has shown remarkable efficacy in patients with relapsed/refractory B-cell precursor acute lymphoblastic leukemia.However,several studies showed that blinatumomab has a short plasma half-life due to its low molecular weight,and thus its clinical use is limited.Furthermore,multiple trials have shown that approximately 30%of blinatumomab-relapsed cases are characterized by CD19 negative leukemic cells.Here,we design and characterize two novel antibodies,A-319 and A-2019.Blinatumomab and A-319 are CD3/CD19 bispecific antibodies with different molecular sizes and structures,and A-2019 is a novel CD3/CD19/CD20 trispecific antibody with an additional anti-CD20 function.Our in vitro,ex vivo,and in vivo experiments demonstrated that A-319 and A-2019 are potent antitumor agents and capable of recruiting CD3 positive T cells,enhancing T-cell function,mediating B-cell depletion,and eventually inhibiting tumor growth in Raji xenograft models.The two molecules are complementary in terms of efficacy and specificity profile.The activity of A-319 demonstrated superior to that of A-2019,whereas A-2019 has an additional capability to target CD20 in cells missing CD19,suggesting its potential function against CD19 weak or negative CD20 positive leukemic cells.

关键词： B-cell acute lymphoblastic leukemia bispecific antibody trispecific antibody CD19 CD20

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Comprehensive experimental database and analysis of circular concrete-filled double-skin tube stub columns:A review

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Frontiers of Structural and Civil Engineering 2023年第12期17卷 1830-1848页

作者： Hongyuan TANG Hongfei TAN sisi GE Jieyu QIN Yuzhuo wang Institute of Structural Engineering Xihua UniversityChengdu 610039China School of Civil Engineering Shandong Jianzhu UniversityJinan 250101China

A concrete-filled double-skin tube(CFDST)is a new type of composite material.Experimental studies have been conducted to investigate the axial compression behavior of CFDST members for approximately 30 years.This paper provides a review of the status of axial compression bearing capacity tests conducted on circular CFDST stub columns as well as a summary of test data for 165 circular CFDST stub columns reported in 22 papers.A relatively complete high-quality test database is established.Based on this database,the main factors affecting the axial compression bearing capacity of the CFDST stub columns are analyzed.The prediction accuracy and robustness of an existing theoretical prediction model,which is a data-driven model,are evaluated,and a numerical simulation of the axial compression bearing capacity of the CFDST stub columns is conducted.In addition,the differences between the basic theory and experimental results of various models are compared,and the possible sources of prediction errors are analyzed.The current model for predicting the axial compression capacity of CFDST stub columns cannot simultaneously satisfy the requirements of high accuracy and confidence,and the stress independency assumption introduced in the test is not valid.The main error source in the theoretical prediction model is the non-simultaneous consideration of the effects of the void ratio and inner steel tube.

关键词： CFDST bearing capacity model confined concrete model test database

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Fast Scan mode of scanning electrochemical microscopy:In-situ characterization of phase transition and mapping the hydrogen evolution activity for MoS_(2)

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Nano Research 2023年第7期16卷 10011-10017页

作者： Zhenyu wang Tong Sun Changan HuangFu sisi Jiang Chaoqun Gu Liying Jiao Zonghua wang College of Chemistry and Chemical Engineering College of Materials Science and EngineeringShandong Sino-Japanese Center for Collaborative Research of Carbon NanomaterialsInstrumental Analysis Center of Qingdao UniversityQingdao UniversityQingdao 266071China Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education Department of ChemistryTsinghua UniversityBeijing 100084China

Scanning electrochemical microscopy(SECM)is an attractive technology to in-situ characterize the structural evolution and catalytic performance for various electrocatalysts.However,spatial and temporal resolution coupling are still the obstacles that limit its wide applications.Herein,a new operation mode,Fast Scan mode,was developed by improving the dual-pass scan mode,designing novel hardware structure,and employing thermal drift calibration software to achieve a high spatial and temporal resolution simultaneously.The temporal speed can achieve 4 Hz for a high spatial resolution(less than 30 nm)image.This operation mode was employed to dynamically track the phase transition process of molybdenum disulfide(MoS_(2))over time and characterize the hydrogen evolution reaction(HER)catalytic activity on the edge of semiconducting MoS_(2)quantitatively while minimizing the diffusional broadening effect and total amount of catalytic products generated above the surface.This new approach should be useful for in-situ tracking dynamic electrochemical processes,establishing the structure-activity relationship for structural complex electrocatalysts,and offering a strategy for high-speed scanning with other electrochemical imaging techniques.

关键词： high-speed scanning scanning electrochemical microscopy molybdenum disulfide phase transition hydrogen evolution reaction

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Deciphering engineering principle of three-phase interface for advanced gas-involved electrochemical reactions

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Journal of Energy Chemistry 2023年第5期80卷 302-323,I0008页

作者： Yanzheng He sisi Liu Mengfan wang Qiyang Cheng Tao Qian Chenglin Yan Collaborative Innovation Center of Suzhou Nano Science and Technology College of EnergySoochow UniversitySuzhou 215006JiangsuChina School of Chemistry and Chemical Engineering Nantong UniversityNantong 226019JiangsuChina Light Industry Institute of Electrochemical Power Sources Suzhou 215600JiangsuChina

As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions.

关键词： Three-phase reaction Surface reactions Mass diffusion Electron transfer Gas-involved electrochemical reactions

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Nest predation pressure on Chinese Bulbuls decreases along the urbanization gradient in Hangzhou,China

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Avian Research 2022年第3期13卷 294-300页

作者： Xingmin Chen Qin Zhang sisi Lan Shuihua Chen Yanping wang Laboratory of Island Biogeography and Conservation Biology College of Life SciencesNanjing Normal UniversityNanjing210023China College of Chemistry and Life Sciences Zhejiang Normal UniversityJinhu1321004China Zhejiang Museum of Natural History Hangzhou310012China

Nest predation is an essential factor affecting bird population density,reproductive ecology and life cycle.However,there are still contradictory results about how nest predation pressure changes with urbanization.One of the reasons for the controversy is that previous studies often use artificial nests to investigate nest predation,but the result of artificial nests is often biased and contrary to that of natural nests.Therefore,it is important to perform nest predation experiments simultaneously with both natural and artificial nests.In this study,we examined the change of nest predation pressure on the Chinese Bulbul(Pycnonotus sinensis)along the urbanization gradient in Hangzhou,China.We detected 148 natural nests of Chinese Bulbuls and continuously monitored them in two continuous breeding seasons from 2012 to 2013.After the breeding season,we placed artificial eggs in natural nests of Chinese Bulbuls to investigate the changes in nest predation pressure and used infrared cameras to record the predators.We then calculated the urbanization synthetic index(USI)as the measure of the degree of urbanization and examined its relationship with nest predation pressure.We found that no matter whether natural nests or artificial eggs were used,the nest predation pressure always decreased significantly with the degree of urbanization.The average height of shrubs within 10 m of the nest differed significantly between the predated and unpredated nests,which also affected the risk of nest predation.Our study highlights the importance of using natural and artificial nests simultaneously to conduct nest predation experiments,which can reduce the bias or errors caused by only using artificial nests.We also recommend the use of infrared cameras in future nest predation studies,which has obvious advantages in monitoring and identifying potential predators.

关键词： Artificial nest Natural nest Nest predation Shrub height Urbanization

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Betaine affects muscle lipid metabolism via regulating the fatty acid uptake and oxidation in finishing pig

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Journal of Animal Science and Biotechnology 2018年第1期9卷 187-195页

作者： sisi Li Haichao wang Xinxia wang Yizhen wang Jie Feng Key Laboratory of Animal Nutrition & Feed Zhejiang Province College of Animal Science Zhejiang University

Background： Betaine affects fat metabolism in animals, but the specific mechanism is still not clear. The purpose of this study was to investigate possible mechanisms of betaine in altering lipid metabolism in muscle tissue in finishing pigs.Methods： A total of 120 crossbred gilts（Landrace × Yorkshire × Duroc） with an average initial body weight of 70.1 kg were randomly allotted to three dietary treatments. The treatments included a corn–soybean meal basal diet supplemented with 0, 1250 or 2500 mg/kg betaine. The feeding experiment lasted 42 d.Results： Betaine addition to the diet significantly increased the concentration of free fatty acids（FFA） in muscle（P 〈 0.05）. Furthermore, the levels of serum cholesterol and high-density lipoprotein cholesterol were decreased（P 〈 0.05） and total cholesterol content was increased in muscle（P 〈 0.05） of betaine fed pigs. Experiments on genes involved in fatty acid transport showed that betaine increased expression of lipoprotein lipase（LPL）, fatty acid translocase/cluster of differentiation（FAT/CD36）, fatty acid binding protein（FABP3） and fatty acid transport protein（FATP1）（P 〈 0.05）. The abundance of fatty acid transport protein and fatty acid binding protein were also increased by betaine（P 〈 0.05）. As for the key factors involved in fatty acid oxidation, although betaine supplementation didn＇t affect the level of carnitine and malonyl-CoA, betaine increased mR NA and protein abundance of carnitine palmitransferase-1（CPT1）and phosphorylated-AMPK（P 〈 0.05）.Conclusions： The results suggested that betaine may promoted muscle fatty acid uptake via up-regulating the genes related to fatty acid transporter including FAT/CD36, FATP1 and FABP3. On the other hand, betaine activated AMPK and up-regulated genes related to fatty acid oxidation including PPARα and CPT1. The underlying mechanism regulating fatty acid metabolism in pigs supplemented with betaine is associated with the up-regulation of genes involved in fatty acid transport and fatty acid oxidation.

关键词： Betaine Fatty acid intake Fatty acid oxidation Muscle Pig

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