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Promoting effect of FeOx addition on the mechanochemically prepared vanadium-based catalyst for real PCDD/Fs removal and mechanism insight

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Journal of Environmental Sciences 2024年第3期137卷 478-487页

作者： Minghui Tang Ling Wang Hongxian Li Xinlei Huang Cuicui Du shengyong Lu State Key Laboratory for Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China

Industrial-use VOx-based catalysts usually have a higher active temperature window (>250-300℃),which becomes a“bottleneck”for the practical application of PCDD/Fs catalytic degradation *** this work,VO_(x)-FeO_(x)/TiO_(2) catalyst prepared via mechanochemically method was investigated for the catalytic removal of PCDD/*** removal efficiency of 1.2-DCBz,pure PCDD/Fs gas generated in the lab,PCDD/Fs from actual fue gas,long-term were studied,and the degradation mechanism was explored using FTIR and *** degradation efficiency of 1.2-DCBz and PCDD/Fs on VO_(x)-FeO_(x)/TiO_(2) were higher than that of VO_(x)/TiO_(2)catalyst,and the optimal FeOx addition ratio was 3 wt.%.The characterization results show that the addition of FeOx can effectively improve the pore structure,surface acidity,and VOx dispersion of the catalyst,thus contributing to increasing the V^(5+)content and surface-active oxygen,which is conducive to the improvement of adsorption and redox performance of the *** the actual MSWI (municipal solid waste incineration)fue gas,the PCDD/Fs removal efficiency over VTi-3Fe-MC maintained long-term stability,higher than 85%for 240 *** result was not significantly reduced compared with the data obtained in the *** to the analysis results of intermediate products by FTIR and GC-TOFMS,it can be inferred that the epoxidation fracture of benzene ring is the rate-limiting step of dioxin catalytic degradation *** work gives an in-depth view into the PCDD/Fs removal over VO_(x)-FeO_(x)/TiO_(2) catalysts and could provide guidelines for the rational design of reliable catalysts for industrial applications.

关键词： PCDD/F removal MSWI fue gas VO_(x)-FeO_(x)/TiO_(2) Mechanochemical GC-TOFMS

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Simultaneous removal of 1.2-dichlorobenzene and furan over Mn-Ce-Fe oxide catalyst:Catalytic activity and product analysis

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Journal of Rare Earths 2024年第5期42卷 972-979,I0006页

作者： Juan Qiu Minghui Tang Yaqi Peng Xuanhao Guo shengyong Lu Jianhua Yan Taizhou Institute of Zhejiang University Taizhou 318000China State Key Laboratory for Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China

The Mn-Ce-Fe mixed oxide(MCFe)was prepared by co-precipitation and the catalytic performance was tested by using 1.2-dichlorobenzene(1.2-DCB)and furan as model molecules of PCDD/*** effect of O_(2)concentration,SO_(2) and NO on the catalytic activity was *** 270℃,the MCFe oxide catalyst presents significant simultaneous removal efficiency of 75.25%and 1.0%for 1.2-DCB and furan,***-Emmett-Teller(BET)method(BET),X-ray diffraction(XRD),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FTIR),H_2-temperature programmed reduction(H_(2)-TPR),NH_(3)-temperature programmed desorption(NH_3-TPD)and O_(2)-TPD were used to characterize the catalysts before and after the *** tests suggest that the oxidation behavior of furan occurred prior to that of 1.*** to the intermediate products detected by gas chromatography-mass spectrometry(GC-MS),the by-products include chlorinated hydrocarbons,long-chain hydrocarbons,ketone,*** catalytic oxidation reaction paths are proposed.

关键词： 1 2-dichlorobenzene Furan Catalytic oxidation Product analysis Rare earths

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Chemical looping reforming of the micromolecular component from biomass pyrolysis via Fe_(2)O_(3)@SBA-1.

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International Journal of Coal Science & Technology 2024年第3期11卷 120-134页

作者： Yunchang Li Bo Zhang Xiantan Yang Bolun Yang shengyong Zhang Zhiqiang Wu Shaanxi Key Laboratory of Energy Chemical Process Intensification School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an710049ShaanxiPeople’s Republic of China

To solve the problems of low gasification efficiency and high tar content caused by solid–solid contact between biomass and oxygen carrier in traditional biomass chemical looping gasification *** decoupling strategy was adopted to decouple the biomass gasification process,and the composite oxygen carrier was prepared by embedding Fe_(2)O_(3) in molecular sieve SBA-1. for the chemical looping reforming process of pyrolysis micromolecular model compound methane,which was expected to realize the directional reforming of pyrolysis volatiles to prepare hydrogen-rich *** analysis of the reaction system was carried out based on the Gibbs free energy minimization method,and the reforming performance was evaluated by a fixed bed reactor,and the kinetic parameters were solved based on the gas–solid reaction *** analysis verified the feasibility of the reaction and provided theoretical guidance for experimental *** experimental results showed that the reaction performance of Fe_(2)O_(3)@SBA-1. was compared with that of pure Fe_(2)O_(3) and Fe_(2)O_(3)@SBA-1.,and the syngas yield was increased by 55.3%and 20.7%respectively,and it had good cycle *** analysis showed that the kinetic model changed from three-dimensional diffusion to first-order reaction with the increase of *** activation energy was 1.2.79 kJ/mol by *** paper provides basic data for the directional preparation of hydrogen-rich syngas from biomass and the design of oxygen carriers for pyrolysis of all-component chemical looping reforming.

关键词： Biomass pyrolysis Methane Chemical looping reforming Oxygen carrier Kinetic analysis

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Electrocatalytic Multicomponent Cascade Cross-Coupling for the Synthesis of Chalcogenosulfonates

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Chinese Journal of Chemistry 2024年第17期42卷 2049-2055页

作者： Zhiheng Zhao Hongyan Yan Yaqin Zhou Wei Xue Lijun Gu shengyong Zhang State Key Laboratoryof Green Pesticide Key Laboratoryof Green Pesticide and Agricultural BioengineeringMinistry of EducationCenter for R&D of Fine Chemicals of Guizhou UniversityGuiyangGuizhou 550025China Schoolof Pharmacy Air Force Medical UniversityShaanxiXi'anShaanxi 710032China

An electrocatalytic multicomponent cascade cross-coupling for the synthesis of chalcogenosulfonates has been *** approach does not require the use of transition metals,acids,and external *** gentle conditions and tole... 详细信息

关键词： Electrochemical catalysis Synthetic methods Radical Multi-component reaction Chalcogenosulfonates Tellurium

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Enhancing mechanisms of N-doped biomass carbon on the vanadium-based catalyst for furan degradation at low temperature

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Waste Disposal and Sustainable Energy 2024年第1期6卷 1-9页

作者： Ling Wang Minghui Tang Hongxian Li Jiamin Ding Juan Qiu shengyong Lu State Key Laboratory of Clean Energy Utilization Zhejiang University38#Zheda RoadHangzhou310027China Taizhou Institute of Zhejiang University Taizhou318012China Qingshanhu Energy Research Center Zhejiang University1699 Dayuan RoadQingshanhu Science and Technology CityHangzhou311300China

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans(PCDD/Fs)have attracted widespread concern due to their high toxicity,and their difficult manipulation in laboratories has made the research process ***,in our work,furan is selected as the model compound owing to the same structure of a central oxygenate *** catalytic oxidation is regarded as an effective and applicable method for the abatement of PCDD/Fs,the synthesis of low-temperature catalysts is still a challenging problem in practical *** this situation,we prepared a novel V_(2)O_(5)/TiO_(2)catalyst modified with N-doped hierarchical porous carbon(NHPC)via a wet impregnation *** V/T-1.NHPC catalyst could achieve expectant low-temperature performances with 50%furan conversion at 1.0℃and a complete conversion at 200℃,which decreased 23℃and 40℃compared to the V/T catalyst ***,the addition of NHPC presented lifting chemical stability during long-time *** addition of NHPC in V/T catalysts decreased the formation of crystalline V_(2)O_(5) and increased the percentages of V^(5+)and O_(lat),which improved the utilization of vanadium ions and the catalytic ***,the higher binding energy shift of O_(lat) implied more reaction possibility with other oxidise ***,this work proved the lifting catalytic activity by the interaction between catalysts and NHPC,and proposed the promoting effects of the N *** results showed that the content of the pyridinic N and graphitic N in NHPC changed after combining with V/T catalyst,which played crucial roles in the excellent catalytic ***,this work provides comprehensive research of the V/T-1.NHPC catalyst toward furan oxidation at low temperature and explain the effects of N-doped biomass carbon in catalytic activity clearly,which gave a new thought to design low-temperature catalysts in PCDD/Fs ***,the internal functional mech

关键词： Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans Furan Low-temperature catalyst V_(2)O_(5)/TiO_(2)catalyst N-doped

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Image format pipeline and instrument diagram recognition method based on deep learning

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Biomimetic Intelligence & Robotics 2024年第1期4卷 36-44页

作者： Guanqun Su Shuai Zhao Tao Li shengyong Liu Yaqi Li Guanglong Zhao Zhongtao Li Shandong Qingniao IIoT Co. ltd.Jinan 250014China Jinan Housing and Urban-Rural Development Bureau Jinan 250012China State Grid Shandong Electric Extrahigh Voltage Company Jinan 250018China School of Information Science and Engineering University of JinanJinan 250022China

In this study,we proposed a recognition method based on deep artificial neural networks to identify various elements in pipelines and instrumentation diagrams(P&ID)in image formats,such as symbols,texts,and ***,the P&ID image format is recognized manually,and there is a problem with a high recognition error rate;therefore,automation of the above process is an important issue in the processing plant *** China National Offshore Petrochemical Engineering *** the image set used in this study,which contains 51.P&ID drawings in the *** converted the PDF P&ID drawings to PNG P&IDs with an image size of 841.×*** addition,we used labeling software to annotate the images,divided the dataset into training and test sets in a 3:1.ratio,and deployed a deep neural network for *** method proposed in this study is divided into three *** first step segments the images and recognizes symbols using YOLOv5+*** second step determines text regions using character region awareness for text detection,and performs character recognition within the text region using the optical character recognition *** third step is pipeline recognition using YOLOv5+*** symbol recognition accuracy was 94.52%,and the recall rate was 93.27%.The recognition accuracy in the text positioning stage was 97.26%and the recall rate was 90.27%.The recognition accuracy in the character recognition stage was 90.03%and the recall rate was 91.87%.The pipeline identification accuracy was 92.9%,and the recall rate was 90.36%.

关键词： Deep learning Image processing Piping and instrumentation Object recognition Pipeline recognition

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An electrochemiluminescent magneto-immunosensor for ultrasensitive detection of hs-cTnI on a microfluidic chip

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Nanotechnology and Precision Engineering 2024年第3期7卷 13-23页

作者： Yun Hui Zhen Zhao Weiliang Shu Fengshan Shen Weijun Kong shengyong Geng Zhen Xu Tianzhun Wu Wenhua Zhou Xuefeng Yu Shenzhen Key Laboratory of Micro/Nano Biosensing Shenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China Shenzhen Institutes of Advanced Technology Chinese Academy of SciencesShenzhen 518055China Biomedical Imaging Science and System Key Laboratory Chinese Academy of SciencesShenzhen 518055China

Sensitive detection and precise quantitation of trace-level crucial biomarkers in a complex sample matrix has become an important area of *** example,the detection of high-sensitivity cardiac troponin I (hs-cTnI) is strongly recommended in clinical guidelines for early diagnosis of acute myocardial *** on the use of an electrode modified by single-walled carbon nanotubes (SWCNTs) and a Ru(bpy)32+-doped silica nanoparticle (Ru@SiO2)/tripropylamine (TPA) system,a novel type of electrochemiluminescent (ECL) magnetoimmunosensor is developed for ultrasensitive detection of *** this approach,a large amount of[Ru(bpy)3]2+is loaded in SiO2(silica nanoparticles) as luminophores with high luminescent efficiency and SWCNTs as electrode surface modification material with excellent electrooxidation ability for ***,a hierarchical micropillar array of microstructures is fabricated with a magnet placed at each end to efficiently confine a single layer of immunomagnetic microbeads on the surface of the electrode and enable 7.5-fold signal enhancement In particular,the use of transparent SWCNTs to modify a transparent ITO electrode provides a two-order-of-magnitude ECL signal amplification.A good linear calibration curve is developed for hs-cTnI concentrations over a wide range from 1. fg/ml to 1. ng/ml,with the limit of detection calculated as 8.720 fg/ml (S/N=3).This ultrasensitive immunosensor exhibits superior detection performance with remarkable stability,reproducibility,and *** recoveries are obtained in the detection of hs-cTnI in human serum,providing a potentia analysis protocol for clinical applications.

关键词： Electrochemiluminescent magneto-immunosensor Microﬂuidic chip High-sensitivity cardiac troponin I Single-walled carbon nanotube [Ru(bpy)3]2+-doped silica nanoparticle

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Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion

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Chinese Chemical Letters 2024年第10期35卷 180-186页

作者： Jieqiong Xu Wenbin Chen Shengkai Li Qian Chen Tao Wang Yadong Shi shengyong Deng Mingde Li Peifa Wei Zhuo Chen Institutes of Physical Science and Information Technology Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationAnhui Graphene Engineering LaboratoryAnhui UniversityHefei 230601China Molecular Science and Biomedicine Laboratory(MBL).State Key Laboratory of Chemo/Biosensing and Chemometrics College of Chemistry and Chemical EngineeringCollege of BiologyAptamer Engineering Center of Hunan ProvinceHunan UniversityChangsha 410082China Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province Shantou UniversityShantou515063China

Charge-transfer(CT)stoichiometric cocrystals are promising choice of organic materials for unveiling the structure-property ***,due to the contradiction between large CT degree required for strong NIR absorption and flexible molecular stacking,construction of stoichiomorphism-based cocystals with near-infrared(NIR)photothermal property remains ***,the first example of stoichiomorphism-based photothermal cocrystals were accomplished through the adaptive assembly of 3,3,5,5-tetramethylbenzidine(TMB)donor and 1.2,4,5-tetracyanobenzene(TCNB)*** selective cocrystallization could be controlled by varying the donor-acceptor stoichiometries via a surfactantassisted method,resulting in two cocrystals with 1.1.T1.1.and 1.2(T2C1.*** absorbance intensity of T1.1.at 808 nm was nearly twice that of T2C1.while the photothermal conversion efficiency(PCE)of the former was 60.3%±0.6%,approximately 80%of that for the latter(75.5%±2.6%),which might be caused by the different intermolecular interactions in distinct molecular stacking ***,both excellent PCEs of stoichiometric cocrystals were attributed to the nonradiative transition process,including internal conversion and charge dissociation processes,as elucidated by femtosecond transient absorption spectroscopy ***,T1.1.was used as an NIR heater for preparing agarose-based photothermal hydrogel,showing great potential for light-controlled in-situ *** strategy of balancing the CT degree and molecular packing orientation not only uncovered the relationship between stoichiometric stacking and photothermal property,but also provided an opportunity to develop advanced organic optoelectronic materials.

关键词： Charge-transfer cocrystal Stoichiometric stacking Crystal growth Photothermal conversion In-situ gelation

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FEA-Based Fatigue Life Assessment of Cycloidal Displacement Cam and Flat-Faced Follower Mechanism

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Modern Mechanical Engineering 2024年第2期14卷 51-56页

作者： shengyong Zhang Krishnajith Theril Department of Mechanical and Civil Engineering College of Engineering and Sciences Purdue University Northwest Hammond USA

Cam-followers provide reliable and controlled motions in various mechanical systems. Due to the highly fluctuating load between the cam and follower in operation, the cam-follower may be subjected to a high risk of contact fatigue failure. This paper assesses the fatigue life of a cycloidal displacement cam and a flat-faced follower under the defined loads and constraints. Computer-aided design (CAD) model of the cam-follower is developed in CATIA software and imported to ANSYS software for finite element analysis (FEA) of fatigue life. MATLAB programming is developed for determining the appropriate spring constant and pre-load force to always keep the cam and follower in contact. The fatigue life of the cam-follower has been estimated under the specified operating conditions. The analysis method can be applied to investigate the fatigue life of cams with other profiles, including the modified trapezoidal functions, polynomial functions, etc.

关键词： Cam-Follower CAD FEA Fatigue Life

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A novel predictor of unsustained return of spontaneous circulation in cardiac arrest patients through a combination of capnography and pulse oximetry: a multicenter observational study

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World Journal of Emergency Medicine 2024年第1期15卷 16-22页

作者： Jing Yang Hanqi Tang Shihuan Shao Feng Xu Yangyang Fu shengyong Xu Chen Li Yan Li Yang Liu Joseph Harold Walline Huadong Zhu Yuguo Chen Xuezhong Yu Jun Xu Emergency Department State Key Laboratory of Complex Severe and Rare DiseasesPeking Union Medical College HospitalChinese Academy of Medical Science and Peking Union Medical CollegeBeijing 100730China Emergency Department Peking University People’s HospitalBeijing 100044China Department of Emergency and Chest Pain Center Shandong Provincial Clinical Research Center for Emergency and Critical Care MedicineKey Laboratory of Emergency and Critical Care Medicine of Shandong ProvinceQilu Hospital of Shandong UniversityJinan 250012China Emergency Department Beijing Jishuitan HospitalBeijing 100035China Emergency Department Tianjin Medical University General HospitalTianjin 300052China Department of Emergency Medicine Penn State Health Milton S.Hershey Medical Center and Penn State College of MedicineHershey 17033USA

BACKGROUND:Unsustained return of spontaneous circulation(ROSC)is a critical barrier to survival in cardiac arrest *** study examined whether end-tidal carbon dioxide(ETCO_(2))and pulse oximetry photoplethysmogram(POP)parameters can be used to identify unsustained ***:We conducted a multicenter observational prospective cohort study of consecutive patients with cardiac arrest from 201. to ***’general information,ETCO_(2),and POP parameters were collected and statistically ***:The included 1.5 ROSC episodes(from 80 cardiac arrest patients)comprised 51.sustained ROSC episodes and 54 unsustained ROSC *** 24-hour survival rate was significantly higher in the sustained ROSC group than in the unsustained ROSC group(29.2%vs.9.4%,P1.95%confi dence interval[95%CI]0.881.0.984,P=0.01. and OR=0.998,95%CI 0.997-0.999,P1..The area under the receiver operating characteristic curve ofΔETCO_(2),ΔAUCp,and the combination of both to predict unsustained ROSC were 0.752(95%CI 0.660-0.844),0.883(95%CI 0.81.-0.948),and 0.902(95%CI 0.842-0.962),***:Patients with unsustained ROSC have a poor *** combination ofΔETCO_(2) andΔAUCp showed signifi cant predictive value for unsustained ROSC.

关键词： Return of spontaneous circulation Pulse oximetry photoplethysmogram End-tidal carbon dioxide Cardiac arrest Cardiopulmonary resuscitation

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