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Friction and wear properties of ultra-high molecular mass polyethylene reinforced with Al2O3 nano-particle

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中国有色金属学会会刊：英文版 2004年第Z1期14卷 354-358页

作者： FAN Dong-li XIONG dang-sheng Department of Materials Science & Engineering Nanjing University of Science and Technology Nanjing 210094 China Department of Materials Science & Engineering Nanjing University of Science and Technology Nanjing 210094 China

The ultra-high molecular mass polyethylene (UHMMPE) as an artificial joint acetabular material was filled with nano-powder of Al2O3 of various mass fractions. The effect of Al2O3 mass fraction on the hardness, wetting property and tribological properties of the Al2O3-UHMMPE composites under dry friction sliding against both stainless steel and Ti-6Al-4V alloy was investigated. The morphologies of the worn surfaces of composites were observed with optical microscope. The results show that, wetting property and wear resistance of the composites are improved by filling Al2O3, while the friction coefficient is decreased largely under dry friction as compared with that of the unfilled UHMMPE. This is attributed to the reinforcing function of the nano-powder of Al2O3 in the composites. The wear of UHMMPE is dominated by plowing, plastic deformation and fatigue wear; while the Al2O3-UHMMPE composites are characterized by the mild fatigue wear.

关键词： ultra-high molecular mass polyethylene Al2O3 nano-powder filling modification friction and wear properties artificial joint

An effective and green H2O2/H2O/O3 oxidation method for carbon nanotube to reinforce epoxy resin

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Journal of Materials Science & Technology 2020年第5期40卷 24-30页

作者： Qi Wang Wen Shi Bo Zhu dang sheng Su School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China Institute of Metal Research Chinese Academy of SciencesShenyang 110016China Shenyang National Laboratory for Materials Science Shenyang 110016China Jiangsu Gunuo New Materials Technology Go. Ltd.Yancheng 224051China

Facile green oxidation methods are always desired to functionalize carbon nanotubes(CNTs)in the production of advanced CNT/epoxy *** the present work,an optimized H2O2/H2O/O3 oxidation method was developed,and performances of the H2O2/H2O/O3 oxidized CNT in epoxy matrix were tested and compared with that of the H2O/O3 oxidized CNT and the most commonly used concentrated HNO3 oxidized *** physical and chemical characteristics of the obtained oxidized CNTs were systematically characterized via transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS)and *** performances of the obtained composites were explored by tensile tests,impact tests,dynamic mechanical analysis(DMA)and fracture toughness *** was found that the H2O2/H2O/O3 oxidized CNT exhibited all-around overwhelming advantages over the concentrated HNO3 oxidized CNT on reinforcing the epoxy matrix,while the H2O/O3 oxidized CNT only improved the material *** mechanisms for the different methods oxidized CNTs were studied and *** optimized H2O2/H2O/O3 oxidation method makes scaled production possible,avoids environment pollutions,and holds great potentials to replace the most commonly used concentrated HNO3 oxidation method to oxidize CNT during the preparation of the advanced CNT/epoxy composite.

关键词： Green oxidation method Carbon nanotube Epoxy composite Mechanical properties Interfacial interaction

Reinforcing epoxy resin with nitrogen doped carbon nanotube:A potential lightweight structure material

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Journal of Materials Science & Technology 2018年第11期34卷 2205-2211页

作者： Qi Wang Guodong Wen Junnan Chen dang sheng Su School of Materials Science and Engineering University of Science and Technology of China Institute of Metal Research Chinese Academy of Sciences

The outstanding mechanical properties of nanocarbon materials, especially carbon nanotube（CNT）, make them one of the most promising reinforcing nanofillers for the high-performance lightweight structural material. However, the complicated but not eco-friendly surface functionalization processes（e.g. HNO3 oxidation） are generally necessary to help disperse nanocarbon materials into epoxy or build chemical bonds between them. Herein, nitrogen doped carbon nanotube（NCNT） was used to replace CNT to reinforce the epoxy resin, and the mechanical properties of the NCNT/epoxy nanocomposite showed significant superiorities over the CNT/epoxy nanocomposites. The fabrication process was simple and environmentally friendly, and avoided complicated, polluting and energy intensive surface functionalization processes. Moreover, the NCNT/epoxy suspension exhibited a relative low viscosity, which was favorable for the subsequent application. The reinforcing mechanism of NCNT was also proposed. The present work gives out an easy solution to the preparation of a high-performance nanocomposite as a potential lightweight structure material.

关键词： Epoxy-matric nanocomposite Nitrogen doped carbon nanotube NCNT/epoxy Mechanical properties Toughness

Leiomyosarcoma with coronary fistulae and ventricular septal perforation： A case study

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Journal of Geriatric Cardiology 2014年第4期11卷 354-356页

作者： dang-sheng HUANG Yu-Mei WANG Yu CHEN Department of Cardiology the First Affiliated Hospital of Chinese PLA General Hospital Beijing100048 China Department of Cardiac Surgery Peking University People's Hospital Beijing 100044 China

Coronary fistulae and ventricular septal perforation are very rare clinically, and even less caused by cardiac leiomyosarcoma. A case is reported that a 67-year-old female had cardiac leiomyosarcoma with progressive heart failure and coronary fistulae and ventricular septal perforation. This case was special since all ante-mortem examinations and cardiac surgery failed to detect the presence of any abnormal car-diac mass. Therefore, the malignant cardiac tumors could appear in an invasive form without mass and be one of the causes of the coronary fistulae and ventricular septal perforation.

关键词： Cardiac leiomyosarcoma Coronary fistulae Ventricular septal perforation Heart failure

Synthesis and properties of physically crosslinked poly (vinyl alcohol) hydrogels

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Journal of China University of Mining and Technology 2008年第2期18卷 271-274页

作者： MA Ru-yin XIONG dang-sheng Department of Materials Science ＆ Engineering Nanjing University of Science and Technology Nanjing Jiangsu 210094 China

The present study is an investigation of the properties of poly(vinyl alcohol),which would be a better contact lens mate- rial than conventional HEMA in some ways.A transparent PVA hydrogel was prepared from a PVA solution in a mixed solvent consisting of water and a water-miscible organic solvent,DMSO,by the freezing-thawing *** water content,visible light transmittance,mechanical and swelling properties of the hydrogels were evaluated as a function of PVA concentration and number of freeze-thaw *** results show that the properties of PVA hydrogels depend on the polymer concentration,the number of freeze-thaw cycles and the addition of the organic solvent.

关键词： poly (vinyl alcohol) hydrogel freezing-thawing method swelling property

Effect of Counterface Material on Friction and Wear Behavior of Ni-Cr-W-Al-Ti-MoS_2 Composites

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Chinese Journal of Aeronautics 2006年第B12期19卷 74-77页

作者： LI Jian-liang XIONG dang-sheng WAN Yi Department of Materials Science and Engineering Nanfing University of Science and Technology Nanjing 210094 China

Ni-Cr-W-Al-Ti-MoS2 self-lubricating composites were prepared through the powder metallurgy （P/M） method. Their friction properties were investigated by a pin-on-disk tribometer in the range from the room temperature to 600 ℃. Alumina, silicon nitride and nickel-iron-sulfide alloys were selected as the counterface materials. Results indicate that the lowest friction coefficients under 0.22 can be obtained at 600℃ when rubbed against alumina. When rubbed against nickel-iron-sulfide alloys, are presented the lowest wear rates in the magnitude of 10^-6 mm^3/N-m, one order of magnitude lower than those when rubbed against ceramics. In the case of three rubbing pairs, the wear rates of the composite containing MoS2 present themselves inversely proportional to friction coefficients. With alumina ceramics used as a counterface, transfer films and glaze layers will form on the contact surface playing a main role in lubrication at high temperatures. However, when silicon nitride and nickel-iron-sulfide alloy are used, the lubricating transfer films appear not to be prominent.

关键词： powder metallurgy (P/M) high temperature solid lubrication Ni-based composite

Land cooperatives as an approach of suburban space construction： Under the reform of Chinese land transfer market

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Frontiers of Architectural Research 2016年第4期5卷 425-432页

作者： sheng dang Dachang Yuan Weiyuan Kong School of Architecture Tianjin University Tianjin 300072 China

In China, the urban-rural dual structure of land market has resulted in urban sprawl caused by industrial diffusion. Urban sprawl disintegrated agricultural communities in suburbs, thereby increasing the unemployment rate among farmers who lost their lands. To address this problem, the Chinese government proposed a reform program to analyze the monopoly of the government in the land market and guarantee the property rights of farmers. This study analyzed the connection between land market mechanism and suburban space formation. Results concluded that the current land transfer system caused industrial urban sprawl, and the reform program may promote the urban sprawl of population. Two typical models of rural land development were studied. A model called land cooperatives based on land pooling joint stock system was proposed to build a compact and sustainable suburban space.

关键词： Land institution Suburban space Urban sprawl Land cooperatives

Targeting methyltransferase-like 5-mediated sphingomyelin metabolism:A novel therapeutic approach in gastric cancer

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World Journal of Gastrointestinal Oncology 2024年第10期16卷 4060-4063页

作者： Jin-Juan Zhang Chang Yuan sheng-Chun dang Department of General Surgery The Affiliated Hospital of Jiangsu UniversityZhenjiang 212001Jiangsu ProvinceChina

Gastric cancer(GC)is a global health problem and a leading cause of cancerrelated deaths,with its mortality rate ranking third among all *** etiology and progression of GC are characterized by a complex interplay of genetic and epigenetic changes,which present challenges for its early diagnosis and effective *** the mechanisms underlying the occurrence and development of GC and identifying novel biomarkers for early detection and prognosis are crucial to improving patient *** editorial examines the role of methyltransferase-like 5(METTL5)in the progression of GC through sphingomyelin metabolism by considering an article published by Zhang et al in the World Journal of Gastrointestinal Oncology in 2024,which is entitled“METTL5 promotes GC progression via sphingomyelin metabolism”.These authors investigated the biological behavior of METTL5 in GC by examining its expression patterns,clinical relevance,functional effect,and potential mechanisms,as well as its response to *** editorial provides valuable insights into the role of METTL5 in the progression of GC and its potential as a therapeutic target.

关键词： Gastric cancer Methyltransferase-like 5 Sphingomyelin metabolism Biomarkers Chemotherapy response

Palladium and carbon synergistically catalyzed room-temperature hydrodeoxygenation(HDO) of vanillyl alcohol–A typical lignin model molecule

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Journal of Energy Chemistry 2017年第1期26卷 8-16页

作者： Qi Wang Neeraj Gupta Guodong Wen Sharifah Bee Abd Hamid dang sheng Su School of Materials Science and Engineering University of Science and Technology of China Institute of Metal Research Chinese Academy of Sciences Nanotechnology & Catalysis Research Centre (NANOCAT) University of Malaya IPS Building

Vanillyl alcohol, which is made up of an aromatic ring, an alcoholic hydroxyl group, a phenolic hydroxyl group and a methoxy group, was selected as the model molecule of lignin. Various carbon materials supported Pd catalysts were chosen to catalyze the HDO of vanillyl alcohol. The catalysts were characterized via TEM, TPD, XRD, XPS and CO-chemisorption. It was found that different carbon materials could obviously influence the particle sizes, dispersion and distribution of Pd or PdO particles. Palladium and carbon can synergistically catalyze the room-temperature HDO of vanillyl alcohol even at room temperature, and the carboxyl group was found to be the effective active acid site during the reaction. Possible reaction mechanism was also proposed. The existence of the effective active acid sites on the carbon supports could obviously lower the reaction temperature without decreasing the selectivity, as a result, making the production of renewable fuels by HDO much more economically feasible, which is of much importance. © 2016 Science Press

关键词： Bioconversion Carbon Catalysts Dispersions Molecules Palladium