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Growth behavior and electronic regulation of Pt on various Mo-based supports for hydrogen evolution electrocatalysis

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Science China Chemistry 2025年

作者： Lulu Chen Yichao huang Jiajun Wang Meihong liao Zhiyuan Liu Meiqi Liu Hanqing Cai Lin Wang Lidong Gao Dawei hu Lianming Zhao Ning Pu Zhuangjun Fan State Key Laboratory of Chemical Safety School of Materials Science and Engineering China University of Petroleum (East China) School of Mechanical and Electronic Engineering Qingdao Binhai University Qingdao Chuangqi New Energy Catalysis Technology Co.Ltd. Sinopec Research Institute of Petroleum Processing Co.Ltd. Institute of Energy Hefei Comprehensive National Science Center

Insight into the growth behavior and electronic regulation of platinum （Pt） on various transition metal supports is paramount in developing high-performing electrocatalysts for hydrogen evolution reactions （HER）.Herein,we studied the influence of molybdenum-based supports （MoX,X=C,N,P,and S） on the growth behavior and electronic regulation of *** found that the formation energy variations between Pt single atom and clusters on MoX supports play a pivotal role in the growth behavior of ***,the electronic regulation of Pt induced by metal-support interaction may reflect the valence changes of Pt in Pt-MoX/*** Pt-MoC/C catalyst with a moderate valence state of Pt exhibits the best HER activity with an overpotential of 12.0 mV at 10 mA cm-2and a mass activity of 27.1 A mgPt-1,12.3 times as high as that of commercial 20 wt% Pt/*** work provides constructive guidance for the design of high-performance HER catalysts.

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Bullous pemphigoid associated with acquired hemophilia A: A case report

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World Journal of Clinical Cases 2025年第4期13卷 28-33页

作者： Su-Ye hu Meng-Can Li Zi-Jia Hao Xu-Ya Chai Pei-sai Li Yang Liu Li-Xia Liu Ying Xu Pan-Pan Yang Ling-E Li Department of Dermatology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina Graduate School Hebei University of Traditional Chinese MedicineShijiazhuang 050051Hebei ProvinceChina Department of Pathology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina

BACKGROUND Acquired hemophilia A (AHA) is a rare and potentially severe bleeding disordercaused by circulating autoantibodies against factor Ⅷ (FⅧ). In approximately50% of the patients, the condition is associated with autoimmune diseases,cancers, medication use, pregnancy, and the post-partum period. Bullous pemphigoid(BP) is a chronic autoimmune subepidermal blistering disease associatedwith tissue-bound and circulating autoantibodies against BP antigens 180 (BP180)and 230 (BP230). AHA-associated BP has a high mortality rate;hence, the understandingof this disease must *** SUMMARY A 69-year-old man presented with erythema, blisters, blood blisters, and crustsaccompanied by severe pruritus for more than 20 days, and ecchymosis andswelling on his left upper arm for 3 days. Pathological examination revealed asubepidermal blister that contained eosinophils. Laboratory tests showed that theBP180 autoantibody levels had increased, isolated activated partial thromboplastintime was notably prolonged (115.6 s), and coagulation FⅧ activity wasextremely low (< 1.0%). Furthermore, the FⅧ inhibitor titer had greatlyincreased (59.2 Bethesda units). Therefore, the patient was diagnosed as having BP associated with AHA, prescribed 0.05% topical halometasone cream, and transferred to a higher-level hospitalfor effective treatment;however, he died after 2 *** AHA associated BP is rare, dangerous, and has a high mortality rate. Therefore, its timely diagnosis and effectivetreatment are necessary.

关键词： Bullous pemphigoid Acquired hemophilia A Acquired hemophilia A FactorⅧ Case report

单层Janus Ga_(2)SSe光催化水解性质的第一性原理研究

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原子与分子物理学报 2025年第3期42卷 45-51页

作者：胡新华廖杨芳贵州省贵阳市乌当区第四中学贵阳550018 贵州师范大学物理与电子科学学院贵阳550025

光催化水解制氢为解决能源危机和环境污染问题提供了一种可行的策略.本文通过第一性原理计算,提出了单层Janus Ga_(2)SSe是一种有效的水解光催化剂.结构稳定性分析表明,单层Janus Ga_(2)SSe具有能量和动力学稳定性.电子性质表明,单层Jan... 详细信息

光催化水解制氢为解决能源危机和环境污染问题提供了一种可行的策略.本文通过第一性原理计算,提出了单层Janus Ga_(2)SSe是一种有效的水解光催化剂.结构稳定性分析表明,单层Janus Ga_(2)SSe具有能量和动力学稳定性.电子性质表明,单层Janus Ga_(2)SSe属于间接带隙半导体,有利于降低载流子的复合几率.光催化性能分析表明,单层Janus Ga_(2)SSe的能带边缘位置适合PH=0~14宽范围的光催化水解.此外,单层Janus Ga_(2)SSe具有较高的紫外光和可见光吸收、较大的内建电场、较小的载流子有效质量保证了光生载流子有效分离并快速迁移到反应活性位点参与水的氧化还原反应.研究结果为单层Janus Ga_(2)SSe的合成及其作为水解光催化剂的潜在应用提供了有价值的理论指导.

关键词： Janus材料光催化水解第一性原理

Modeling Topic-Based human Expertise for Crowd Entity Resolution

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Journal of Computer Science & Technology 2018年第6期33卷 1204-1218页

作者： sai-sai Gong Wei hu Wei-Yi Ge Yu-Zhong Qu State Key Laboratory for Novel Software Technology Nanjing University Nanjing 210023 China Science and Technology on Information Systems Engineering Laboratory Nanjing 210007 China

Entity resolution （ER） aims to identify whether two entities in an ER task refer to the same real-world *** ER uses humans, in addition to machine algorithms, to obtain the truths of ER tasks. However, inaccurate orerroneous results are likely to be generated when humans give unreliable judgments. Previous studies have found thatcorrectly estimating human accuracy or expertise in crowd ER is crucial to truth inference. However, a large number ofthem assume that humans have consistent expertise over all the tasks, and ignore the fact that humans may have variedexpertise on different topics （e.g., music versus sport）. In this paper, we deal with crowd ER in the Semantic Web *** identify multiple topics of ER tasks and model human expertise on different topics. Furthermore, we leverage similartask clustering to enhance the topic modeling and expertise estimation. We propose a probabilistic graphical model thatcomputes ER task similarity, estimates human expertise, and infers the task truths in a unified framework. Our evaluationresults on real-world and synthetic datasets show that, compared with several state-of-the-art approaches, our proposedmodel achieves higher accuracy on the task truth inference and is more consistent with the human real expertise.

关键词： entity resolution crowdsourcing human expertise topic modeling task similarity

Asymmetric Polymerization of N-Vinylcarbazole with Optically Active Anionic Initiators

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Chinese Journal of Polymer Science 2015年第11期33卷 1618-1624页

作者： Wei hu 曹靖 Yi-ling huang sai Liang Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education College of ChemistryXiangtan University

The anionic polymerization of N-vinylcarbazole（NVC） by using optically active anionic initiators such as the lithium salts of（S）-1-（9H-fluoren-2-yl）-4-isopropyl-4,5-dihydrooxazole（（S）-1-FIDH） and（S）-2-（9H-fluoren-2-yl）-4-isopropyl-4,5-dihydrooxazole（（S）-2-FIDH） and complexes of（-）-Sparteine with n-butylithium（n-Bu Li-（-）-Sp） or fluorenyl lithium（FILi-（-）-Sp） was achieved. The yield and specific rotation of poly（N-vinylcarbazole）s（poly（NVC）s） were considerably affected by the molar ratio of（S）-FIDH to NVC. The highest yield and specific rotation were obtained with Li-（S）-1-FIDH as an initiator, with a molar ratio of monomer and initiator [M]/[I] = 10/1. The effects of the chiral initiators, type of solvent and the polymerization temperature were investigated. The obtained optical activity of polymers was attributed to asymmetric induction of the chiral initiators.

关键词： Helical polymer Anionic polymerization Chiral carbon anionic initiator N-vinylcarbazole

A perspective on recent methods on testing predictability of asset returns

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Applied Mathematics(A Journal of Chinese Universities) 2018年第2期33卷 127-144页

作者： liao Xiao-sai CAI Zong-wu CHEN Hai-qiang The Wang Yanan Institute for Studies in Economics MOE Key Laboratory of Econometrics (Xiamen University) Fujian Provincial Key Laboratory of Statistical Science Xiamen University Department of Economics University of Kansas

This paper highlights some recent developments in testing predictability of asset returns with focuses on linear mean regressions, quantile regressions and nonlinear regression models. For these models, when predictors are highly persistent and their innovations are contemporarily correlated with dependent variable, the ordinary least squares estimator has a finite-sample bias, and its limiting distribution relies on some unknown nuisance parameter, which is not consistently estimable. Without correcting these issues, conventional test statistics are subject to a serious size distortion and generate a misleading conclusion in testing pre- dictability of asset returns in real applications. In the past two decades, sequential studies have contributed to this subject and proposed various kinds of solutions, including, but not limit to, the bias-correction procedures, the linear projection approach, the IVX filtering idea, the variable addition approaches, the weighted empirical likelihood method, and the double-weight robust approach. Particularly, to catch up with the fast-growing literature in the recent decade, we offer a selective overview of these methods. Finally, some future research topics, such as the econometric theory for predictive regressions with structural changes, and nonparametric predictive models, and predictive models under a more general data setting, are also discussed.

关键词： asset returns Heteroskedasticity high persistency nonlinearity predictability quantile regressions

Delamination failure analysis of G10 insulator in electromagnetic rail launcher

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High Voltage 2023年第5期8卷 889-897页

作者： Xinkai hu Junyong Lu sai Tan Bai Li Jiawei Zhang National Key Laboratory of Science and Technology on Vessel Integrated Power System Naval University of EngineeringWuhanHubeiChina

The electromagnetic(EM)rail launcher G10 insulator is prone to delamination damage during launch,which affects the service life of the *** the secondary development of ABAQUS®commercial finite‐element software,an EM‐structure coupling launch dynamics model considering projectile‐barrel coupling is *** simulation indicates that the transverse swing of the projectile changes in a sine‐like law,and the time of the upper half wave corresponds to the pulse width of the impact force pulse *** stress concentration occurs on the inner surface of the insulator where the contact‐impact occurs,resulting in impact *** midline of the insulator inner surface bears a large compressive strain under the action of pre‐tightening force,and the insulator is compressed oscillatingly under the influence of the timevarying load of the rail during *** the condition of repeated launch,the launch package repeatedly impacts the insulator,and the alternating load of the rail is cyclically loaded on the insulator with impact damage,which will cause the compression fatigue of the insulator and the expansion of impact damage *** are the main reasons for the delamination failure of insulator,and the experimental analysis is carried *** study provides a method to study the delamination failure mechanism of the insulator,and provides guidance for improving the life of the insulator.

关键词： insulator damage analysis

Effects of adeno-associated virus (AAV) of transforming growth factors β_1 and β_3 (TGFβ_(1,3)) on promoting synthesis of glycosaminoglycan and collagen type II of dedifferentiated nucleus pulposus (NP) cells

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Science China(Life Sciences) 2007年第5期50卷 605-610页

作者： sai JiaMing hu YouGu WANG DeChun Orthopaedic Laboratory The Orthopaedics and Traumatology Hospital Qingdao 266003 China Department of Orthopedic Surgery Affiliated Hospital of Medical College Qingdao University Qingdao 266003 China Department of Orthopedic Surgery Affiliated Hospital of Medical College Qingdao University Qingdao 266003 China

The effects of AAV-TGF beta_1 and AAV-TGF beta_3 on promoting synthesis ofglycosaminoglycan and collagen type II of dedifferentiated rabbit lumbar disc NP cells were studiedin this *** rabbit lumbar disc NP cells were isolated and *** earlier and laterdedifferentiated NP cells were established by *** AAV transfection efficiency todedifferentiated NP cells was analyzed with AAV-EGFP in *** dedifferentiated NP cells weretransfected by AAV-TGFp,or AAV-TGF beta_3,their biological effects on promoting synthesis ofglycosaminoglycan or collagen type II were detected and compared by the methods of 35S incorporationor *** experimental results showed that AAV could transfect efficiently the earlierdedifferentiated NP cells,but its transfection rate was shown to be at a low level to the laterdedifferentiated NP *** AAV-TGF beta_1,and AAV-TGF beta_3 could promote the earlierdedifferentiated NP cells to synthesize glycosaminoglycan and collagen type II,and the effect ofAAV-TGFp,was better than that of AAV-TGF beta_*** the later dedifferentiated NP cells,the AAV-TGFbeta_3 could promote their synthesis,but AAV-TGFp,could slightly inhibit ***,AAV-TGFp,and AAV-TGF beta_3 could be used for the earlier dedifferentiated NPcells,and the TGF beta_3 could be used as the objective gene for the later dedifferentiated NPcells.

关键词： adeno-associated virus (AAV) transforming growth factor-beta_1 (TGF beta_1) transforming growth factor-beta_3 (TGFp3) glycosaminoglycan collagen type II gene transfection

Recognizable type of pituitary, heart, kidney and skeletal dysplasia mostly caused by SEMA3A mutation: A case report

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World Journal of Clinical Cases 2019年第20期7卷 3310-3315页

作者： Fang hu liao Sun Department of Endocrinology and Metabolism Fifth Affiliated Hospital Sun Yat-Sen University Sun Yat-Sen University

BACKGROUND The SEMA3A gene,which is located at 7q21.11,is involved in hypothalamic neuron migration,heart development,kidney development,and skeleton *** of the SEMA3A gene is associated with Kallmann syndrome 16 with or without a normal sense of *** addition,two case reports showed that mutation of the SEMA3A gene could cause short stature,low gonadotropin,hypogonadism,thoracic deformity,a high scapula,rib and lower limb deformity,facial deformity(long face,epicanthic folds,backwards ears),and arterial *** SUMMARY We reported the case of a 26-year-old Chinese man who was admitted because of short *** examination showed that he had many abnormal symptoms,including a short neck,facial moles,knee valgus,transverse palm,continuous grade 5/6 murmurs in the pulmonary auscultation area,no whiskers,or pubic hair,no Adam’s apple,short penis and *** examination showed pituitary,gonad,heart,kidney and skeletal *** laboratory tests revealed low growth hormone,luteinizing hormone,folliclestimulating hormone,testosterone and *** whole-exome detection showed that our patient,unlike previously reported patients,has a new SEMA3A gene mutation(c.950A>G).Now,his height has increased by 3 *** addition,he has a good appetite and reduced subcutaneous fat over 3 mo of recombinant human growth hormone injections ***,he refuses further treatment about *** Patients who come to a hospital because of their short stature must undergo gene detection if they have other simultaneous abnormal phenotypes.

关键词： Pituitary dysplasia Heart dysplasia Kidney dysplasia Short stature Cryptorchidism SEMA3A Case report