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chinese Journal of chemistry 1996年第3期14卷 228-234页

作者： song, ming liang, shu-quan institute of chemistry, chinese academy of sciences, beijing 100080, china institute of chemistry Chinese Academy of Sciences Beijing 100080 China

An extraction-free spectrophotometric method for the determination of cationic surfactants, such as cetylpyridinium chloride, cetyltrimethylammonium bromide and zephiramine is proposed, which is based on the formation of ternary complexes with Fe(Ⅲ) and chrome azurol S. The molar ratio of the complex is 2:1:1 (Fe(Ⅲ):chrome azurol S:cationic surfactant). The method is simple, rapid and sensitive, giving an apparent molar absorptivity of 4.5×104 ***-1 and a linear range of 0.1-6.0 umol/L cationic surfactants. The total cationic surfactant content can be determined directly in aqueous solutions by measuring the absorbance at 680 nm (pH 5.8). The method has been successfully applied to water samples.

关键词： Cationic surfactant determination spectrophotometry ternary complex Fe(Ⅲ) chrome azurol S

SYNTHESIS AND CHARACTERIZATION OF NEW STABILIZERS WITH OPTIMAL MOLECULAR WEIGHT

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chinese Journal of Polymer Science 2001年第4期19卷 341-350页

作者： Jiang-qing Pan institute of chemistry chinese academy of sciences, beijing 100080 china 中科院化学所北京

Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.

关键词： preparation of stabilizer antioxidant hindered amine light stabilizer isocyanation hydrosilylation

Adsorptive Stripping Voltammetric Study of the Enhancement of Copper(Ⅱ) in Phosphate and Carbonate media and in the Presence of Silicate

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chinese Chemical Letters 1997年第6期8卷 61-64页

作者： ming song Hui Min MA Yue Xian HUANG and shu quan liang(institute of chemistry chinese academy of sciences beijing 100080) institute of chemistry Academia Sinica Beijing 100080 Taiwan china institute of Atomic Energy P.O. Box 275-26 Beijing 102413 China

Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 26, and 8.9 times, respectively.

关键词： in Phosphate and Carbonate media and in the Presence of Silicate II Adsorptive Stripping Voltammetric Study of the Enhancement of Copper

Effect of multiple coulomb scattering on the beam tests of silicon pixel detectors

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Nuclear Science and Techniques 2024年第4期35卷 200-207页

作者： Lan-Kun Li ming-Yi Dong Ze Gao liang-Cheng-Long Jin shu-Jun Zhao School of Physics and Microelectronics Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Particle Detection and Electronics(institute of High Energy Physics CAS)Beijing 100049China University of chinese academy of Science Beijing 100049China University of South china Hengyang 421001China

In the research and development of new silicon pixel detectors,a collimated monoenergetic charged-particle test beam equipped with a high-resolution pixel-beam telescope is crucial for prototype verification and performance *** the beam energy is low,the effect of multiple Coulomb scattering on the measured resolution of the Device Under Test(DUT)must be considered to accurately evaluate the performance of the pixel chips and *** study aimed to investigate the effect of multiple Coulomb scattering on the measured resolution,particularly at low beam *** were conducted using Allpix^(2) to study the effects of multiple Coulomb scattering under different beam energies,material budgets,and telescope *** simulations also provided the minimum energy at which the effect of multiple Coulomb scattering could be *** with the results of a five-layer detector system tested with an electron beam at DESY,the simulation results were consistent with the beam test results,confirming the reliability of the simulations.

关键词： Silicon Pixel Detectors Beam Telescope Multiple Coulomb Scattering Spatial Resolution

PREPARATION AND PROPERTIES OF ETHYL-CYANOETHYL CELLULOSE/POLYACRYLIC ACID COMPOSITE FILMS WITH REFLECTION COLORS

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chinese Journal of Polymer Science 2001年第3期19卷 277-282页

作者： Yong Huang institute of chemistry, chinese academy of sciences, beijing 100080 china Laboratory of Cellulose and Lignocellulosics chemistry Guangzhou institute of chemistry chinese academy of sciences, Guangzhou 510650, china 中科院化学所北京

Ethyl-cyanoethyl cellulose [(E-CE)C]/acrylic acid (AA) becomes a cholesteric liquid crystalline solution withvivid colors when the (E-CE)C concentration is 42 wt%～52 wt%. (E-CE)C/polyacrylic acid (PAA) composites withcholesteric structure were prepared by polymerzing AA in (E-CE)C/AA liquid crystalline solutions. The layers of orderedpolymer chains in the cholesteric phase were inclined during polymerization and the degree of the inclination depended onthe polymerization temperature and the concentration of the solution before polymerization. The cholesteric structure in thecomposites could not be changed when temperature was lower than 100℃. Cross-linking of the PAA in compositesimproved their water-resistance. The cholesteric order of the composites without cross-linking was destroyed when theywhere immersed in water. The color derived from the selective reflection of the cholesteric phase of the cross-linkedcomposites turned from blue to red after the composites absorbed water. The color of the composites could be returned to theoriginal one when the absorbed water was removed from the swollen composites.

关键词： Cholesteric structure Composites Selective reflection Liquid crystalline solutions

STUDY ON THE SYNTHESIS AND PROPERTIES OF POLY(ESTER-IMIDEETHER)MULTIBLOCK COPOLYMERS

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chinese Journal of Polymer Science 2000年第1期18卷 9-13页

作者： Zu-yao Shan Zhen-yi Li institute of chemistry, chinese academy of sciences, beijing 100080, china 中科院化学所北京

A new class of poly(ester-imide-ether) multiblock copolymers was synthesized by transes-terification and melt copolymerization of dimethyl terephthalate (DMT) and N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide with ethylene glycol (EG) and polytetramethylene glycol (PTMG). The structure of the above copolymers was characterized by H-1-NMR and IR spectroscopy. Some properties of the coplymers were also examined. It was found that their mechanical properties and heat stability, compared with poly(ether-ester) copolymers, were obviously improved.

关键词： N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide polyester-polyether copolymer poly-(ester-imidether) multiblock copolymer imide modification

Regulating Melting Process in the Energy Storage of Solid-Liquid PCM based on Double MRT-LBM Simulation

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Journal of Thermal Science 2024年第5期33卷 1688-1700页

作者： CHEN Weiqi song Zhichao quan Dongliang HE Yurong School of Energy Science&Engineering Harbin Institute of TechnologyHarbin 150001China Heilongjiang Key Laboratory of New Energy Storage Materials and Processes Harbin 150001China Zhengzhou Research institute of Harbin institute of Technology Zhengzhou 450000China Innovation&Research institute of Hiwing Technology academy Beijing 100074China

The melting process of solid-liquid phase change materials(PCM)has a significant impact on their energy storage *** more effectively apply solid-liquid PCM for energy storage,it is crucial to study the regulation of melting process of solid-liquid PCM,which is numerically investigated based on double multiple relaxation time lattice Boltzmann method(MRT-LBM)in this *** this work we pay more attention to the effects of different Stefan numbers(Ste)and Rayleigh numbers(Ra)on the melting *** results indicate that the PCM melting is greatly influenced by the Ste number and Ra number,which can be divided into the heat conduction dominant stage and the convection dominant stage,according to the onset time of convection Fo_(C).In order to describe the contribution of the heat conduction dominant stage to the whole melting process quantitatively,we firstly propose the ratio of the heat conduction dominant stage R_(pc),which can be defined as the ratio of Fo_(C)to the complete melting time Fo_(M).R_(pc)gradually decreases as the Ra number increases,and when the Ste number rises:R_(pc)=90.0%when Ste=1.0 and Ra=1×10^(5),R_(pc)=39.6%when Ste=0.1 and Ra=1×10^(5),and R_(pc)=14.0%when Ste=1.0 and Ra=1×10~7.A regime map about the effects of different Ste numbers and Ra numbers on R_(pc)has been further *** discovered findings would be helpful in regulating melting process in the energy storage of solid-liquid PCM.

关键词： latent thermal energy storage solid-liquid phase change double MRT-LBM dominant melting mechanism

MgCl_2·6H_2O-BASED ZIRCONOCENE CATALYST FOR ETHYLENE POLYERIZATION

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chinese Journal of Polymer Science 1999年第2期17卷 185-188页

作者： Shi-jing Xiao Hui Yao Ke-quan Peng institute of chemistry, chinese academy of sciences, beijing 100080, china institute of chemistry Chinese Academy of Sciences Beijing 100080 China

Several supported zirconocene catalysts were prepared by using MgCl_2·6H_2O as a precursor forproducing an active support. Such catalysts combined with methylaluminoxane (MAO) obtained by reactingMgCl_2·6H_2O with AlMe_3 show good activity for ethylene polymerization similar to that of anhydrousMgCl_2 supported zirconocene catalyst.

关键词： MgCl_2.6H_2O, Supported zirconocene catalyst Ethylene polymerization

SYNTHESIS OF POLY(ETHYLENE TEREPHTHALATE)-POLYCAPROLACTONE BLOCK COPOLYMER BY DIRECT COPOLYMERIZATION

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chinese Journal of Polymer Science 1999年第3期17卷 231-235页

作者： Shen-guo Wang Kai Tang institute of chemistry, chinese academy of sciences, beijing 100080, china 中科院化学所北京 100080 中科院化学所北京

Po ly(ethylene terephthalate)-polycaprolactone block copolymer (PCL-b-PET) is a polyester with improved biodegradability. In the present paper, a new direct copolymerization method of epsilon-caprolactone (epsilon-CL) and bishydroxyethylene terephthalate (BHET) in the presence of Ti(OBu)(4) was proposed for the synthesis of PCL-b-PET. The PCL-b-PET copolymer was characterized by IR, GPC and H-1-NMR techniques, and the effects of synthesis conditions, such as temperature, reaction time and concentration of catalyst on the copolymerization were discussed.

关键词： poly(ethylene terephthalate)-polycaprolactone block copolymer direct copolymerization biodegradable polymer

PHASE STRUCTURE AND PROPERTIES OF EPOXY RESIN MODIFIED BY POLYSILOXANE BEARING PENDANT AMINO GROUPS

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chinese Journal of Polymer Science 2000年第2期18卷 133-138页

作者： Bing Zhang Xiang-luan Liu Ying Huang Center of Molecular sciences, institute of chemistry, chinese academy of sciences, beijing 100080, china 中科院化学所北京

Polysiloxane-modified epoxy resins were prepared through the reaction of epoxy resin with polydimethylsiloxanes bearing pendant N-(beta-aminoethyl)-gamma-aminopropyl groups. The morphology and properties of the cured epoxy resins modified by the polysiloxanes were investigated. It was found that the phase structure and properties of the cured epoxy resins depend mainly on the amino group content in the polydimethylsiloxane and the level of the modifier. The change of phase structure in the cured epoxy resin systems was responsible for the dramatic change in their mechanical and surface properties.

关键词： phase structure polysiloxane epoxy resin mechanical property