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A tunable ionic covalent organic framework platform for efficient CO_(2) catalytic conversion

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Frontiers of Chemical Science and Engineering 2024年第1期18卷 25-36页

作者： Ting Li Ji Xiong Minghui Chen Quan shi Xiangyu Li Yu Jiang Yaqing Feng bao Zhang School of Chemical Engineering and Technology Tianjin UniversityTianjin 300350China Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center Jieyang 522000China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

The cycloaddition reaction between epoxides and CO_(2) is an effective method to utilize CO_(2) *** organic frameworks(COFs)provide a promising platform for the catalytic CO_(2) transformations on account of their remarkable chemical and physical ***,a family of novel vinylene-linked ionic COFs named TE-COFs(TTE-COF,TME-COF,TPE-COF,TBE-COF)has been facilely synthesized from N-ethyl2,4,6-trimethylpyridinium bromide and a series of triphenyl aromatic aldehydes involving different numbers of nitrogen atoms in the central aromatic *** resulting catalyst TTE-COF with excellent adsorption capacity(45.6 cm3·g^(-1),273 K)exhibited outstanding catalytic performance,remarkable recyclability and great substrate ***,it was also observed that the introduction of nitrogen atom in the precursor led to a great improvement in the crystallinity and CO_(2) adsorption capacity of TE-COFs,thus resulting to a progressively improved catalytic *** work not only illustrated the influence of monomer nitrogen content on the crystallinity and CO_(2) adsorption capacity of TE-COFs but also provided a green heterogeneous candidate for catalyzing the cycloaddition between CO_(2) and epoxides,which shed a light on improving the catalytic performance of the CO_(2) cycloaddition reaction by designing the covalent organic frameworks structures.

关键词： CO_(2)cycloaddition nreaction covalent organic frameworks cyclic carbonate vinylene-linked synergetic effects

Identification of novel mammalian viruses in tree shrews(Tupaia belangeri chinensis)

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Zoological Research 2024年第2期45卷 429-438页

作者： Hong Zhou Ren-Rong Tian Xiu-Rong Wang Jin-Xuan Yang Yun-Xiao Wang Ming-Liang Zhao Xu-Dong Zhang Yu-Hua Ma Long-bao Lv Edward CHolmes Yong-Tang Zheng Wei-Feng shi School of Clinical and Basic Medical Sciences Shandong First Medical University&Shandong Academy of Medical SciencesJi’nanShandong 250117China Key Laboratory of Emerging Infectious Diseases in Universities of Shandong Shandong First Medical University and Shandong Academy of Medical SciencesTaianShandong 271000China Key Laboratory of Animal Models and Human Disease Mechanisms of the Chinese Academy of Sciences/Key Laboratory of Bioactive Peptides of Yunnan Province KIZ-CUHK Joint Laboratory of Bioresources and Molecular Research in Common DiseasesCenter for Biosafety Mega-ScienceKunming Institute of ZoologyChinese Academy of SciencesKunmingYunnan 650223China School of Public Health Shandong First Medical University&Shandong Academy of Medical SciencesJi’nanShandong 250117China National Resource Center for Non-Human Primates Kunming Primate Research CenterKunming Institute of ZoologyChinese Academy of SciencesKunmingYunnan 650107China Sydney Institute for Infectious Diseases School of Medical SciencesThe University of SydneySydneyNew South Wales 2006Australia Department of Infectious Diseases Ruijin HospitalShanghai Jiao Tong University School of MedicineShanghai 200025China Shanghai Institute of Virology Shanghai Jiao Tong University School of MedicineShanghai 200025China

The Chinese tree shrew(Tupaia belangeri chinensis),a member of the mammalian order Scandentia,exhibits considerable similarities with primates,including humans,in aspects of its nervous,immune,and metabolic *** similarities have established the tree shrew as a promising experimental model for biomedical research on cancer,infectious diseases,metabolic disorders,and mental health ***,we used metatranscriptomic sequencing to analyze plasma,as well as oral and anal swab samples,from 105 healthy asymptomatic tree shrews to identify the presence of potential zoonotic *** total,eight mammalian viruses with complete genomes were identified,belonging to six viral families,including Flaviviridae,Hepeviridae,Parvovirinae,Picornaviridae,Sedoreoviridae,and ***,the presence of rotavirus was recorded in tree shrews for the first *** viruses-hepacivirus 1,parvovirus,and picornavirus-exhibited low genetic similarity(94%)to known viral *** analyses also revealed that the rotavirus and mammalian orthoreovirus identified in this study may be novel *** findings provide insights into the diverse viral spectrum present in captive Chinese tree shrews,highlighting the necessity for further research into their potential for crossspecies transmission.

关键词： Tree shrew(Tupaia belangeri chinensis) Meta-transcriptomic sequencing Mammalian viruses Genomic analysis

工业云APP远程协同运维系统在锻造生产线上的应用

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机械设计 2019年第A1期36卷 340-343页

作者：施宝酉杜丽峰李利清段君艳天津市天锻压力机有限公司

简单介绍了锻造液压机锻造线的结构和工艺,锻造液压机一旦发生故障,导致整条生产线受影响。传统的故障诊断系统多是依赖维修人员经验,这种诊断方法效率低,花费成本大。为了解决此问题,基于工业云APP的远程系统运维系统,分别对硬件和软... 详细信息

简单介绍了锻造液压机锻造线的结构和工艺,锻造液压机一旦发生故障,导致整条生产线受影响。传统的故障诊断系统多是依赖维修人员经验,这种诊断方法效率低,花费成本大。为了解决此问题,基于工业云APP的远程系统运维系统,分别对硬件和软件部分进行优化设计,硬件部分主要设计了基于设备层、传输层、应用层的运维系统。与传统诊断方式相比,该系统具备数据采集、数据分析、主动预警、员工派单等优点。

关键词：工业云APP 远程诊断锻造生产线运维系统

Humanβ-defensin-1 affects the mammalian target of rapamycin pathway and autophagy in colon cancer cells through long noncoding RNA TCONS_00014506

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World Journal of Gastrointestinal Oncology 2024年第4期16卷 1465-1478页

作者： Yu-Xin Zhao Yan Cui Xin-Hong Li Wen-Hong Yang shi-Xiang An Jia-Xian Cui Min-Yu Zhang Jing-Kun Lu Xuan Zhang Xiu-Mei Wang Li-Li bao Peng-Wei Zhao Department of Anesthesiology Inner Mongolia Chest HospitalThe Fourth HospitalHohhot 010035Inner Mongolia Autonomous RegionChina College of Humanities and Education Inner Mongolia Medical UniversityHohhot 010059Inner Mongolia Autonomous RegionChina Department of Radiotherapy The Affiliated Hospital of Inner Mongolia Medical UniversityHohhot 010059Inner Mongolia Autonomous RegionChina School of Basic Medical Science Inner Mongolia Medical UniversityHohhot 010059Inner Mongolia Autonomous RegionChina Department of Medical Oncology The Affiliated Cancer Hospital of Inner Mongolia Medical UniversityHohhot 010050Inner Mongolia Autonomous RegionChina

BACKGROUND Colorectal cancer has a low 5-year survival rate and high ***β-defensin-1(hBD-1)may play an integral function in the innate immune system,contributing to the recognition and destruction of cancer *** non-coding RNAs(lncRNAs)are involved in the process of cell differentiation and *** To investigate the effect of hBD-1 on the mammalian target of rapamycin(mTOR)pathway and autophagy in human colon cancer SW620 *** CCK8 assay was utilized for the detection of cell proliferation and determination of the optimal drug *** formation assay was employed to assess the effect of hBD-1 on SW620 cell *** was used to screen potentially biologically significant lncRNAs related to the mTOR ***,p-mTOR(Ser2448),Beclin1,and LC3II/I expression levels in SW620 cells were assessed through Western blot *** hBD-1 inhibited the proliferative ability of SW620 cells,as evidenced by the reduction in the colony formation capacity of SW620 cells upon exposure to ***-1 decreased the expression of p-mTOR(Ser2448)protein and increased the expression of Beclin1 and LC3II/I ***,bioinformatics analysis identified seven lncRNAs(2 upregulated and 5 downregulated)related to the mTOR *** lncRNA TCONS_00014506 was ultimately *** the inhibition of the lncRNA TCONS_00014506,exposure to hBD-1 inhibited p-mTOR(Ser2448)and promoted Beclin1 and LC3II/I protein *** hBD-1 inhibits the mTOR pathway and promotes autophagy by upregulating the expression of the lncRNA TCONS_00014506 in SW620 cells.

关键词： Colon cancer Humanβ-defensin-1 LncRNA Mammalian target of rapamycin Autophagy

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不同管网腐蚀与水质稳定性中试研究

中国给水排水 2018年第13期34卷 66-70页

作者：张素佳王海波赵丹胡春石宝友苏州科技大学环境科学与工程学院江苏苏州215011 中国科学院生态环境研究中心北京100085 广州大学大湾区环境研究院广东广州510006

通过中试对再生水和饮用水在带水泥内衬的新球墨铸铁管和不带水泥内衬的新球墨铸铁管管网中的腐蚀及水质稳定性进行了研究。8个月中试研究证实:带水泥内衬的球墨铸铁管腐蚀较轻,水质稳定性好,但可能会引起钙离子释放而造成水质硬度增加... 详细信息

通过中试对再生水和饮用水在带水泥内衬的新球墨铸铁管和不带水泥内衬的新球墨铸铁管管网中的腐蚀及水质稳定性进行了研究。8个月中试研究证实:带水泥内衬的球墨铸铁管腐蚀较轻,水质稳定性好,但可能会引起钙离子释放而造成水质硬度增加;不带水泥内衬的球墨铸铁管虽然一开始有一个快速腐蚀阶段,但随着致密氧化层的出现,生物膜上生长出铁氧化菌、铁还原菌和硫酸盐还原菌等细菌,铁还原菌与腐蚀产物之间的相互作用可以加速氧的消耗,有效抑制管网腐蚀,保持管网水质稳定性。

关键词：管网腐蚀再生水饮用水化学与生物稳定性水泥内衬

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颗粒活性炭吸附染料时的表面分形分析

安全与环境学报 2006年第3期6卷 92-95页

作者：王毅力刘杰石宝友王东升北京林业大学资源与环境学院中国科学院生态环境研究中心环境水质学国家重点实验室北京100085

采用N2吸附脱附实验研究了颗粒活性炭吸附染料前后表面特征的变化,运用表面分形维数表征了表面屏蔽效应和表面粗糙性等性质。结果表明,颗粒活性炭的孔结构是倾斜板交错重叠而形成四面开放的缝隙,桃红、绿色、天蓝、耐晒黑可以撑开颗粒... 详细信息

采用N2吸附脱附实验研究了颗粒活性炭吸附染料前后表面特征的变化,运用表面分形维数表征了表面屏蔽效应和表面粗糙性等性质。结果表明,颗粒活性炭的孔结构是倾斜板交错重叠而形成四面开放的缝隙,桃红、绿色、天蓝、耐晒黑可以撑开颗粒活性炭的孔隙,增大平均孔径;耐晒翠蓝具有降低孔径的能力;大红却有些微孔阻塞作用。FHH理论计算出的相应的7个颗粒活性炭样品吸附6种染料前后的孔隙表面分形维数Ds很接近,为2.97左右,证明颗粒活性炭上吸附的染料并没有发生表面屏蔽效应,也没有使颗粒活性炭表面的粗糙性降低。分形吸附等温线法与基于N2吸附脱附的FHH理论法计算出的Ds相差较大,这与两种算法的理论基础和码尺大小有关。而热力学模型计算出的D远大于3,与Sahouli等的研究不符。

关键词：环境科学颗粒活性炭吸附染料表面分析表面分形维数

A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions

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Chinese Chemical Letters 2024年第10期 227-230页

作者： Bingbing shi Yuchun Wang Yi Zhou Xing-Xing Zhao Yizhou Li Nuoqian Yan Wen-Juan Qu Qi Lin Tai-bao Wei Key Laboratory of Polymer Materials of Gansu Province College of Chemistry and Chemical Engineering Northwest Normal University

Oligo[n]rotaxanes are one of the most extensively studied categories of mechanically bonded macromolecules. In this study, a supramolecular oligo[2]rotaxane is successfully constructed driven by platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions in an orthogonal way. The supramolecular oligo[2]rotaxane is further applied in fabricating a light harvesting system.

关键词：

Micro/nano flow chemistry by Beyond Limits Manufacturing

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Chinese Chemical Letters 2024年第5期35卷 3-12页

作者： Peiwen Liu Fang Zhao Jing Zhang Yunpeng Bai Jinxing Ye Bo bao Xinggui Zhou Li Zhang Changlu Zhou Xinhai Yu Peng Zuo Jianye Xia Lian Cen Yangyang Yang Guoyue shi Lin Xu Weiping Zhu Yufang Xu Xuhong Qian State Key Laboratory of Bioreactor Engineering Shanghai Key Laboratory of Chemical BiologySchool of PharmacyEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Bioreactor Engineering Shanghai Collaborative Innovation Center for BiomanufacturingEast China University of Science and TechnologyShanghai 200237China School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China School of Mechanical and Power Engineering East China University of Science and TechnologyShanghai 200237China Shanghai Key Laboratory of Green Chemistry and Chemical Processes Department of ChemistrySchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200241China

In September 2018,we proposed the cutting-edge concept of“Beyond Limits Manufacturing”(BLM).BLM technology is based on the three-dimensional inner engraving or precise outer engraving of ultra-fast laser,to invent micro/nano scale flow chips or devices,which makes it possible for the microform,integration,economy,safety,high efficiency,green and intelligence of research,development and manufacturing process,so as to realize transformational manufacturing in the era of Industry *** this paper,we reviewed the representative results we made in the field of micro/nano flow chemistry during the implementation of the BLM major project(December 2019 to August 2023),and discussed its application prospects in micro/nano flow chemistry.

关键词： Beyond Limits Manufacturing Flow chemistry Pharmaceutical manufacturing Microreactor

基于Weierstrass-Mandelbrot函数的岩体裂隙映射重构

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岩土力学 2024年第10期45卷 3058-3070页

作者：刘宏伟陈世江许有俊张旭鲍先凯内蒙古科技大学土木工程学院内蒙古包头014010 内蒙古科技大学矿山安全与地下工程院士工作站内蒙古包头014010 内蒙古科技大学内蒙古自治区高校城市地下工程研究中心内蒙古包头014010 六盘水师范学院矿业与机械工程学院贵州六盘水553004

重构岩体裂隙对精准构建裂隙岩体模型以及准确获取其力学性质具有重要意义。鉴于此,为使重构裂隙与天然状态相吻合,提出了D-n_(max)阈值公式,修正了用于岩体裂隙模拟的Weierstrass-Mandelbrot(W-M)函数。通过二值化灰度图像对Barton10... 详细信息

重构岩体裂隙对精准构建裂隙岩体模型以及准确获取其力学性质具有重要意义。鉴于此,为使重构裂隙与天然状态相吻合,提出了D-n_(max)阈值公式,修正了用于岩体裂隙模拟的Weierstrass-Mandelbrot(W-M)函数。通过二值化灰度图像对Barton10条剖面线进行数字化,经试错法及综合分析法,以等差方式确定10个粗糙度水平的Hurst值。通过对10条剖面线进行傅里叶变换得到了幅值特征新参数Spp,结合起伏角标准差σ_i线性构建新裂隙粗糙度系数(joint roughness coefficient,简称JRC)计算公式。采用二分法获得目标JRC值对应W-M函数的最佳尺度常数G值,建立了JRC与W-M函数的映射关系。W-M函数考虑了随机项,实现了重构裂隙的差异化。对重构裂隙进行粗糙度定量化研究和室内试验,验证了新参数Spp、新JRC计算公式及映射关系的有效性。所作研究为拓展岩体裂隙获取方法提供了新的思路,为裂隙岩体力学性质研究奠定了基础。

关键词：岩体裂隙自仿射分形 Weierstrass-Mandelbrot函数裂隙粗糙度系数(JRC) 映射重构