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Pre-operative enhanced magnetic resonance imaging combined with clinical features predict early recurrence of hepatocellular carcinoma after radical resection

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World Journal of Gastrointestinal Oncology 2024年第4期16卷 1192-1203页

作者： Jian-Ping Chen ri-hui yang Tian-hui Zhang Li-An Liao Yu-Ting Guan Hai-yang Dai Department of Intervention Meizhou People’s HospitalMeizhou 514031Guangdong ProvinceChina Department of Medical Imaging Meizhou People’s HospitalMeizhou 514031Guangdong ProvinceChina Department of Medical Imaging Huizhou Municipal Central HospitalHuizhou 516001Guangdong ProvinceChina

BACKGROUND Indentifying predictive factors for postoperative recurrence of hepatocellular carcinoma(HCC)has great significance for patient *** To explore the value of gadolinium ethoxybenzyl diethylenetriamine pentaacetic acid(Gd-EOB-DTPA)enhanced magnetic resonance imaging(Mri)combined with clinical features in predicting early recurrence of HCC after *** A total of 161 patients with pathologically confirmed HCC were *** patients were divided into early recurrence and non-early recurrence group based on the follow-up *** clinical,laboratory,pathological results and Gd-EOB-DTPA enhanced Mri imaging features were *** Of 161 patients,73 had early recurrence and 88 were had non-early *** analysis showed that patient age,gender,serum alpha-fetoprotein level,the Barcelona Clinic Liver Cancer stage,China liver cancer(CNLC)stage,microvascular invasion(MVI),pathological satellite focus,tumor size,tumor number,tumor boundary,tumor capsule,intratumoral necrosis,portal vein tumor thrombus,large vessel invasion,nonperipheral washout,peritumoral enhancement,hepatobiliary phase(HBP)/tumor signal intensity(SI)/peritumoral SI,HBP peritumoral low signal and peritumoral delay enhancement were significantly associated with early recurrence of HCC after *** logistic regression analysis showed that patient age,MVI,CNLC stage,tumor boundary and large vessel invasion were independent predictive *** data validation indicated that the area under the curve of the combined predictors was 0.861,suggesting that multivariate logistic regression was a reasonable predictive model for early recurrence of *** Gd-EOB-DTPA enhanced Mri combined with clinical features would help predicting the early recurrence of HCC after operation.

关键词： Hepatocellular carcinoma Enhanced magnetic resonance imaging Microvascular invasion Hepatobiliary phase Recurrence

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Stabilization/solidification mechanisms of tin tailings and fuming slag-based geopolymers for different heavy metals

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Frontiers of Environmental Science & Engineering 2024年第5期18卷 43-55页

作者： Xian Zhou Zhengfu Zhang hui yang School of Materials Science and Engineering Kunming University of Science and TechnologyKunming650093China Kunming Metallurgical Research Institute Co. Ltd.Kunming650031China

Tin mine tailings(TMT)and fuming slag(FS)contain many heavy metals(As,Cr,Cu,Zn and Mn)that cause severe pollution to the ***,geopolymers were prepared using TMT,FS and flue gas desulfurization gypsum(FGDG)to immobilize heavy metals,and their compressive strength and heavy metal leaching toxicity were *** was first determined that T4F5(TMT:FS=4:5)sample exhibited the highest compressive strength(7.83 MPa).T4F5 achieved 95%immobilization efficiency for As and Cr,and nearly 100%for Cu,Zn and Mn,showing good immobilization performance.A series of characterization analyses showed that heavy metal cations can balance the charge in the geopolymer and replace Al in the geopolymer structure to form covalent *** addition,about 2%–20%of heavy metal Fe was immobilized in hydration products,heavy metal hydroxides and non-bridging Si–O and Al–O coordination with silica-aluminate ***_(3)^(3−) was oxidized into AsO_(4)^(3−),which may form Ca–As or Fe–As ***_(2)O_(7)^(2−)was converted to CrO_(4)^(2−)under alkaline environment and then combined with OH−to form Cr(OH)3 ***^(2+)may react directly with dissolved silicate to form Mn_(2)SiO_(4) and also form Mn(OH)_(2) *** unstable Mn(OH)_(2) can be further oxidized to MnO_(2).The heavy metal cations were immobilized in the silicoaluminate lattice,while the anions tended to form insoluble *** results may benefit the industry and government for better handling of TMT,FS and solid wastes containing the abovementioned five heavy metals.

关键词： Heavy metals Cementitious materials Tin tailings Stabilization/solidification Redox

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Synthesis of granulated Li_(1.33)Mn_(1.67)O_(4) via two antisolvent methods for lithium adsorption from gas-produced water

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Chinese Journal of Chemical Engineering 2024年第5期69卷 34-46页

作者： Jun Qiu Lu-ri Bao Wei Guo Ying yang Shu-Ying Sun National Engineering Research Center for Integrated Utilization of Salt Lake Resource East China University of Science and TechnologyShanghai 200237China

Gas-produced water is an accompanying wastewater in the natural gas extraction process,and it is a potential liquid lithium resource that contains a considerable amount of *** study investigated the feasibility of using manganese-based ion sieves to adsorb and extract lithium from gas-produced *** we focused on the applicability of two different granulation methods,extrusion and droplet,in gas-produced water *** types of H_(1.33)Mn_(1.67)O_(4) particles were prepared by the extrusion method(EHMO)and the droplet method(DHMO).The porosity of DHMO was much higher than that of EHMO,and the adsorption performance of DHMO increased with the decrease of binder *** prepared with a binder concentration of 0.14 g·ml^(-1)exhibited the best adsorption performance in gas-produced water,and the Li^(+)adsorption capacity could reach 25.14 mg·g^(-1).In gas-produced water,the adsorption equilibrium of DHMO only took 9 h,and the adsorption process conformed to the Langmuir model and pseudo-second-order kinetic *** pore diffusion model(PDM)could well describe its adsorption ***,DHMO showed a great selectivity to Li^(+),and the selectivity order of DHMO in gas-produced water was Li^(+)>Ba^(2+)>>Mg^(2+),Ca^(2+),Sr^(2+)>>Na^(+)>>K^(+).After 20 cycles,the Li^(+)adsorption capacity was still higher than 17.30 mg·g^(-1),and the rate of manganese dissolution was less than 1%.

关键词： Gas-produced water Granulation Li_(1.33)Mn_(1.67)O_(4)

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Crystalline-amorphous M@MN_x(M=Co,Fe,Ni)encapsulated in nitrogen-doped carbon for enhanced efficient and durable hydrogen evolution reaction

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Rare Metals 2024年第4期43卷 1547-1556页

作者： yang yang Xiao-Chuan Duan Shao-hui Guo Xian-Ming Zhang College of Materials Science and Engineering College of ChemistryKey Laboratory of Interface Science and Engineering in Advanced MaterialsTaiyuan University of TechnologyYuci030600China

Developing earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is important for the sustainable energy ***,efficient and stable heterocatalysts consisting of crystalline-amorphous M@MN_(x)(M=Co,Fe,Ni)encapsulated in N-doped carbon layers supported with N-doped graphene sheets(denoted as M@MN_(x)@NC-NG)are synthesized by facile hydrothermal reaction and nitridation *** the nitriding process,metal ions in M(tzbc)_2(H_(2)O)_4(tzbc=4-(1H-1,2,4-triazol-1-yl)benzoic acid)complexes are reduced to crystalline M cores,accompanied by the formation of amorphous MN_(x)shells;the tzbc ligands are insitu carbonized to form outermost N-doped carbon(NC)layers that connect with inner MN_(x)via M-N-C motifs inherited from the complex precursors and inhibit the transition of MN_(x)from amorphous to crystalline *** Co@CoN_(x)@NC-NG catalyst exhibits excellent HER activity with small overpotentials of 45 and 64 mV at a cathode current density of 10 mA·cm^(-2)and low Tafel slopes of 40 and 85 mV·dec^(-1)in 0.5 mol·L^(-1)H_(2)SO_4 and1.0 mol·L^(-1)KOH electrolytes,*** Co@CoN_(x)@NC-NG retains 97%of the initial overpotential after 100,000 s in both acidic and alkaline *** outstanding HER performance originates from the crystalline-amorphous Co@CoN_(x)that redistributes electrons around the heterointerfaces,facilitating the conversion process of H^(+)/H_(2)O to hydrogen and thereby promoting HER *** outermost NC layers serve as the armor of Co@CoN_(x),and graphene nanosheets act as carriers of egg-like Co@CoN_(x)@NC and conduction paths for electron shuttles,ensuring stable and continuous electrocatalytic hydrogen production.

关键词： Hydrogen evolution reaction Electrocatalysts Iron group metals Heterojunction Crystalline-amorphous structure

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A simple route for preparation of TriP-assisted Si-Mn steel with excellent performance using direct strip casting

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International Journal of Minerals,Metallurgy and Materials 2024年第10期31卷 2173-2181页

作者： hui Xu Lejun Zhou Wanlin Wang yang Yi School of Metallurgy and Environment Central South UniversityChangsha 410083China National Center for International Research of Clean Metallurgy Central South UniversityChangsha 410083China

The complex producing procedures and high energy-consuming limit the large-scale production and application of advanced high-strength steels(AHSSs).In this study,the direct strip casting(DSC)technology with unique sub-rapid solidification characteristics and cost advantages was applied to the production of low-alloy Si-Mn steel with the help of quenching&partitioning(Q&P)concept to address these *** this method with the conventional compact strip production(CSP)process,the initial microstructure formed under different solidification conditions and the influence of heat treatment processes on the final mechanical properties were *** results show that the initial structure of the DSC sample is a dual-phase structure composed of fine lath martensite and bainite,while the initial structure of the CSP sample consists of pearlite and *** volume fraction and carbon content of retained austenite(RA)in DSC samples are usually higher than those in CSP samples after the same Q&P *** samples typically demonstrate better comprehensive mechanical properties than the CSP *** DSC sample partitioned at 300℃ for 300 s(DSC-Pt300)achieves the best comprehensive mechanical properties,with yield strength(YS)of 1282 MPa,ultimate tensile strength(UTS)of 1501 MPa,total elongation(TE)of 21.5%,and product of strength and elongation(PSE)as high as 32.3 GPa·%.These results indicate that the excellent mechanical properties in low-alloy Si-Mn steel can be obtained through a simple process(DSC-Q&P),which also demonstrates the superiority of DSC technology in manufacturing AHSSs.

关键词： direct strip casting sub-rapid solidification quenching and partitioning TriP-assisted AHSSs microstructure

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Recent progresses in thermal treatment of β-Ga_(2)O_(3) single crystals and devices

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1659-1677页

作者： Yuchao Yan Zhu Jin hui Zhang Deren yang State Key Laboratory of Silicon and Advanced Semiconductor Materials and School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China Zhejiang Provincial Key Laboratory of Power Semiconductor Materials and Devices ZJU-Hangzhou Global Scientific and Technological Innovation CenterHangzhou 311200China

In recent years,ultra-wide bandgap β-Ga_(2)O_(3) has emerged as a fascinating semiconductor material due to its great potential in power and photoelectric *** semiconductor industrial,thermal treatment has been widely utilized as a convenient and effective approach for substrate property modulation and device ***,a thorough summary of β-Ga_(2)O_(3) substrates and devices behaviors after high-temperature treatment should be *** this review,we present the recent advances in modulating properties of β-Ga_(2)O_(3) substrates by thermal treatment,which include three major applications:(ⅰ)tuning surface electrical properties,(ⅱ)modifying surface morphology,and(ⅲ)oxidating ***,regulating electrical contacts and handling with radiation damage and ion implantation have also been discussed in device *** each category,universal annealing conditions were speculated to figure out the corresponding problems,and some unsolved questions were proposed *** review could construct a systematic thermal treatment strategy for various purposes and applications of β-Ga_(2)O_(3).

关键词： β-gallium oxide thermal treatment substrates devices

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Adaptive composite anti-disturbance control for heavy haul trains

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Transportation Safety and Environment 2024年第1期6卷 75-82页

作者： Longsheng Chen hui yang School of Electrical and Automation Engineering East China Jiaotong UniversityNanchang 33013JiangxiChina School of Aircraft Engineering Nanchang Hangkong UniversityNanchang 330063JiangxiChina

In this paper,an adaptive composite anti-disturbance control of heavy haul trains(HHTs)is ***,the mechanical principle and characteristics of couplers are analysed and the longitudinal multi-particles nonlinear dynamic model of HHTs is established,which can satisfy that the forces of vehicles in different positions are ***,a radial basis function network(RBFNN)is employed to approximate the uncertainties of HHTs,and a nonlinear disturbance observer(NDO)is constructed to estimate the approximation error and external *** indicate and improve the approximation accuracy,a serial-parallel identification model of HHTs is constructed to generate a prediction error,and an adaptive composite anti-disturbance control scheme is developed,where the prediction error and tracking error are employed to update RBFNN weights and an auxiliary variable of ***,the feasibility and effectiveness of the proposed control scheme are demonstrated through the Lyapunov theory and simulation experiments.

关键词： heavy haul train(HHT) radial basis function neural network nonlinear disturbance observer(NDO) serial-parallel identification model composite anti-disturbance control

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Metagenomics reveals the microbial community and functional metabolism variation in the partial nitritation-anammox process:From collapse to recovery

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Journal of Environmental Sciences 2024年第1期135卷 210-221页

作者： Hong Wang hui Gong Xiaohu Dai Min yang State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China BIOMATH Department of Data Analysis and Mathematical ModellingGhent UniversityGhent 9000Belgium

Mainstream partial nitritation-anammox(PNA)process easily suffers from performance instability and even reactor collapse in ***,it is of great significance to unveil the characteristic of performance recovery,understand the intrinsic mechanism and then propose operational *** this study,we combined long-term reactor operation,batch tests,and metagenomics to reveal the succession of microbial community and functional metabolism variation from system collapse to *** aeration control(0.10-0.25mg O_(2)/L)was critical for performance *** was also found that Candidatus Brocadia became the dominant flora and its abundance increased from 3.5%to 11.0%.Significant enhancements in carbon metabolism and phospholipid biosynthesis were observed during system recovery,and the genes abundance related to signal transduction was dramatically *** up-regulation of sdh and suc genes showed the processes of succinate dehydrogenation and succinyl-CoA synthesis might stimulate the production of amino acids and the synthesis of proteins,thereby possibly improving the activity and abundance of AnAOB,which was conducive to the performance ***,the increase in abundance of hzs and hdh genes suggested the enhancement of the anammox *** in the abundance of key genes involved in nitrogen metabolism indicated that nitrogen removal pathway was more diverse after system *** achievement of performance recovery was driven by anammox,nitrification and denitrification coupled with dissimilatory nitrate reduction to *** results provide deeper insights into the recovery mechanism of PNA system and also provide a potential regulation strategy for the stable operation of the mainstream PNA process.

关键词： Partial nitritation-anammox Metagenomics Microbial community Functional metabolism Recovery

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Americium/lanthanide separation enabled by a distinct polyoxometalate cluster

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Science China Chemistry 2024年第1期67卷 312-313页

作者： hui yang Xiangke Wang Shengqian Ma College of Environmental Science and Engineering North China Electric Power UniversityBeijing 102206P.R.China Department of Chemistry University of North TexasDentonTexas 76201United States

Nuclear energy is viewed as a low carbon-emission electricity-generating technology with high-energy density,which has attracted extensive attention and shown broad development prospects[1].However,to ensure sustainability and cleanability in the development of nuclear energy,one crucial challenge is to exploit efficient and economical technologies to simultaneously recover fissionable nuclides from nuclear waste and separate long-lived toxic fission products[2].

关键词： lanthanide separation cluster

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Subjective transformation in poeticized language and the formation of poeticness

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Language and Semiotic Studies 2024年第1期10卷 132-152页

作者： hui yang School of Overseas Education Soochow UniversitySuzhouChina

As one locus of extraordinary collocations,poeticized language features expressions that depart from the physical reality,involving the subjective transformation of objects in the mental *** subjectivity renders extraordinary collocations resistant to rational readings,resulting in two types of constructions:“innovative”collocations and“self-created”*** meaning construction in the former is easier to achieve than in the latter;the former entails the“rational evaluation”and the latter the“speculative evaluation”processes in *** its rule-breaking defiance caused by meaning obscurity compensated for by rich implied meaning and positive aesthetic feedback,the“self-created”collocations are regarded as poetic and re-accepted by the ***,the so-termed“poeticness”is derived from the positive feedback during the speculative evaluation process and constitutes the main substance of aesthetic interpretation.

关键词： poeticized language poeticness subjectivity subjectivization metalanguage

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