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Journal of Rare Earths 2018年第10期36卷 1074-1083页

作者： Monica A.Rodrigues Ariadne c.catto Elson Longo Edson Nossol renata c.lima Institute of chemistry.Federal University of Uberlandia 38400-902UberlandiaMGBrazil Institute of chemistry Sao Paulo State UniversityP.O.Box 35514801-907Araraquara.SPBrazil LIEc Department of ChemistryFederal University of Sao Carlos13565-905Sao CarlosSPBrazil

Hexagonal ceO2 and Eu-doped ceO2 nanoparticles were obtained using a facile microwave-hydro thermal method under mild conditions and their application towards manganese redox flow battery component were studied. The structural properties were studied by X-ray diffraction and indicate that samples present a fluorite structure. Raman spectroscopy shows Eu3＋ ions substitute ce4＋ and generate oxygen vacancies. Electrochemical properties of pure and Eu-doped ceO2 films deposited at graphite substrates investigated by cyclic voltammetry and galvanostatic charge-discharge indicate that dopant concentration affects the electrochemical properties of ceO2. The increase in the reversibility redox of electrochemical systems observed is attributed to coexistence of ce4＋/ce3＋ redox couple confirmed by ***-discharge tests display coulombic and voltage efficiency values of above 80% and 90%, respectively. The obtained specific capacity for ce（0.99）Eu（0.01）O2（372.49 mAh/g） and pure oxide（334.84 mAh/g）indicates that both samples are promising for application in Mn-batteries.

关键词： cerium oxide Europium Nanoparticles Electrochemical properties Batteries Rare earths

Green coNi_(2)S_(4)/porphyrin decorated carbon-based nanocomposites for genetic materials detection

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Journal of Bioresources and Bioproducts 2021年第3期6卷 215-222页

作者： Mohammad Reza Saeb Navid Rabiee Farzad Seidi Bahareh Farasati Far Mojtaba Bagherzadeh Eder c.lima Mohammad Rabiee Universitéde Lorraine CentraleSupélecLMOPSF57000 MetzFrance Department of chemistry Sharif University of TechnologyTehranIran Provincial Key Lab of Pulp&Paper Sci and Tech and Joint International Research Lab of Lignocellulosic Functional MaterialsNanjing Forestry UniversityNanjing 210037China Department of chemistry Iran University of Science and TechnologyTehranIran Institute of chemistry Federal University of Rio Grande do Sul(UFRGS)Av.Bento Goncalves 9500Postal Box15003ZIP91501-970 Brazil Biomaterial Group Department of Biomedical EngineeringAmirkabir University of TechnologyTehranIran

A one-pot synthesis method was conceptualized and implemented to develop green carbon-based nanocomposites working as *** was synthesized to adorn the surface of nanocomposites making them highly sensitive for giving rise to π-π interactions between the genetic materials,proteins and porphyrin *** hydrogen bond formed between the proteins(analytes)and the nitrogen in the porphyrin structure as well as the surface hydroxyl groups was equally *** this context,different forms of porphyrins were incorporated to explore the interrelationship between the surface morphology and the ability of detection of genetic material and/or proteins by the aid of the synthesized *** phenomenon was conceptualized to optimize the interactions between the biomolecules and the substrate by reaching significant biosensor application in the presence of Anti-cas9 protein and sgRNA(concentration changed between 10 and 500 n mol/L).Almost full quenching of fluorescence emission was observed after addition of 300 n mol/L of Anti-cas9 protein and 250 n mol/L of ***,coNi_(2)S_(4)provided 12%-29%cytotoxicity in both HEK-293 and Pc12 cell lines.

关键词： Biosensor Biomedicine Anti-cas9 Green nanocomposite sgRNA

An overview of geological originated materials as a trend for adsorption in wastewater treatment

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Geoscience Frontiers 2022年第1期13卷 457-477页

作者： Yasmin Vieira Matias Schadeck Netto Éder c.lima Ioannis Anastopoulos Marcos L.S.Oliveira Guilherme L.Dotto chemistry Department Federal University of Santa Maria-UFSM1000Roraima Avenue97105-900 Santa MariaRSBrazil chemical Engineering Department Federal University of Santa Maria-UFSM1000Roraima Avenue97105-900 Santa MariaRSBrazil Institute of chemistry Federal University of Rio Grande do Sul(UFRGS)P.O.Box 1500391501-970 Porto AlegreRSBrazil Department of chemistry University of CyprusP.O.Box 20537CY-1678 NicosiaCyprus Universidad de lima Avenida Javier Prado Este 4600-Santiago de Surco 1503Peru Department of civil and Environmental Universidad de la CostaCalle 58#55-66080002 BarranquillaAtlánticoColombia

Adsorption is a unit operation widely used for the tertiary treatment of the most diverse effluents,whose mechanism is based on removing recalcitrant compounds from the organic and inorganic *** this process,choosing a suitable adsorbent is a fundamental *** review article focuses on the adsorbents with natural geological origin:minerals,clays,geopolymers,and even wastes resulted from mining ***,over 450 articles and research papers were *** materials’main sources are described,and their characteristics,composition,and intrinsic properties are related to ***,we discuss the effects of several process parameters,such as p H,temperature,pollutant,and adsorbent ***,equilibrium,kinetics,and thermodynamic aspects are also addressed,and relevant regeneration prospects and final ***,some suggestions and perspectives on applying these adsorbents in wastewater treatment are presented as future trends.

关键词： Adsorption Equilibrium Geological-based adsorbents Process parameters Wastewater treatment

Fluidized and vibrofluidized shallow beds of fresh leaves

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Particuology 2011年第2期9卷 139-147页

作者： renata de Aquino Brito lima Maria do carmo Ferreira Drying center of Pastes Suspensions and SeedsChemical Engineering DepartmentFederal University of S o Carlos

The fluid dynamics behavior of shallow fluidized and vibrofluidized beds operating with fresh leaves was investigated with the aim of exploring drying applications in a modified conveyor belt （McB） system, which may be operated in a fixed- or fluidized-bed mode. Leaves of the specimens Duranta repens, Schinus molle, coleus barbatus, Buxus sempervirens, and Bougainvillea spectabilis were tested with a range of sphericities from 0.063 to 0.213, bulk densities from 0.038 to 0.251 g/cm3, apparent densities from 0.52 to 0.97 g/cm3 and ratios of total surface area to volume from 21 to 224 cm-1. Fluidization characteristic curves were obtained by measuring pressure drops versus air velocity in a rectangular column of 0.20 m - 0.11 m cross section. It was not possible to reach real fluidized regimes with the leaves due to strongly non-homogeneous beds. Nevertheless, the characteristic curves allowed for the identification of a transition regime from fixed- to expanded-beds, and parameters such as air velocity and pressure drop obtained from the experimental data at the transition were reproducible for specimens with lower surface area or lower specific gravity （i.e., Duranta repens, Schinus molle, and Bougainvillea spectabilis）. The transition velocity and pressure drop could not be predicted by the literature developed for estimat- ing minimum fluidization conditions. The use of vibration at dimensionless vibration parameters （Γ） of 0.5 and 1.0 helped to reduce channeling and decrease the transition velocities from fixed to expanded regimes although it did not affect the pressure drops after the bed expansion. The results suggest that drying fresh leaves using the McB dryer operating in a fluidized mode would not be feasible because none of the materials investigated attained a high-quality fluidization. Operation of the McB dryer may be pos- sible by alternating between the fixed and vibrofluidized modes. For the specimens tested, the drying should be performed in a range

关键词： LeavesLow-sphericity particlesPressure dropsFluidizationVibration

Mitochondrial GPX1 silencing triggers differential photosynthesis impairment in response to salinity in rice plants

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Journal of Integrative Plant Biology 2016年第8期58卷 737-748页

作者： Yugo lima-Melo Fabricio E.L.carvalho Márcio O.Martins Gisele Passaia Rachel H.V.Sousa Milton c.lima Neto Márcia Margis-Pinheiro Joaquim A.G.Silveira Department of Biochemistry and Molecular Biology Federal University of Ceará Department of Genetics Federal University of Rio Grande do Sul

The physiological role of plant mitochondrial glutathione peroxidases is scarcely known. This study attempted to elucidate the role of a rice mitochondrial isoform（GPX1） in photosynthesis under normal growth and salinity conditions. GPX1 knockdown rice lines（GPX1s） were tested in absence and presence of 100 mM Nacl for 6 *** reduction of GPX1 s line under non-stressful conditions, compared with non-transformed（NT） plants occurred in parallel to increased H_2O_2 and decreased GSH contents. These changes occurred concurrently with photosynthesis impairment, particularly in calvin cycle＇s reactions, since photochemical efficiency did not ***, GPX1 silencing and downstream molecular/metabolic changes modulated photosynthesis differentially. In contrast, salinity induced reduction in both phases of photosynthesis, which were more impaired in silenced *** changes were associated with root morphology alterations but not shoot growth. Both studied lines displayed increased GPX activity but H_2O_2 content did not change in response to salinity. Transformed plants exhibited lower photorespiration, water use efficiency and root growth, indicating that GPX1 could be important to salt tolerance. Growth reduction of GPX1 s line might be related to photosynthesis impairment, which in turn could have involved a cross talk mechanism between mitochondria and chloroplast originated from redox changes due to GPX1 deficiency.

关键词： cO2 assimilation glutathione peroxidase Oryza sativa photochemistry redox homeostasis

Adsorption of yttrium(Y^(3+)) and concentration of rare earth elements from phosphogypsum using chitin and chitin aerogel

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Journal of Rare Earths 2024年第4期42卷 775-782页

作者： Glaydson S.dos Reis Diana Pinto Sabrina F.Lütke Eder c.lima Luis F.O.Silva Irineu A.S.De Brum Guilherme L.Dotto Department of Forest Biomaterials and Technology Biomass Technology centre Swedish University of Agricultural SciencesUmeaE13Swedn Universidad De La costa Calle 58#55-66080002BarranquillaAtlanticoColombia Research Group on Adsorptive and catalytic Process Engineering(ENGEPAc) Federal University of Santa MariaAv.Roraima100079705900Santa MariaRSBrazil Institute of chemistry Federal University of Rio Grande do Sul90040060Porto AlegreBrazil

chitin powder and chitin-aerogel were prepared from shrimp wastes and used to uptake Y^(3+)from aqueous solutions and concentrate this rare earth element from phosphogypsum(PG).chitin aerogel displays a specific surface area of 945 m^(2)/g,while chitin powder is 3.6 m^(2)/g,which largely influences its adsorption *** the adsorption in synthetic solutions,the effect of pH on Y^(3+)removal is strong for chitin powder *** contrast,no big pH influence was detected for chitin *** interactions and chelation can highlight the proposed mechanism of Y^(3+)on chitin adsorbents for the powder and ***,in addition to these interactions,pore filling/pore diffusion is the main mechanism of Y^(3+)removal in the chitin *** aerogel is efficient in concentrating 8 times the Y^(3+)from PG,a very complex *** complex chitin aerogel-Y^(3+)can be a secondary source of rare earth elements for other applications.

关键词： Rare earths Sustainable material chitin powder chitin porous aerogel Yttrium adsorption and recovery

Adsorption of rare earth elements onto diatomite M45:Experimental investigations and modeling with statistical physics theory

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Journal of Rare Earths 2023年第11期41卷 1805-1811,I0006页

作者： Fatma Dhaouadi Guilherme L.Dotto Julien Vieillard Diana Pinto Luis F.O.Silva Éder c.lima Mu Naushad Fatma Aouaini Samia Nasr Adrián Bonilla-Petriciolet Abdelmottaleb Ben Lamine Laboratory of Quantum and Statistical Physics LR18ES18Faculty of Sciences of MonastirMonastir UniversityMonastirTunisia Research Group on Adsorptive and catalytic Process Engineering(ENGEPAc) Federal University of Santa MariaAv.Roraima1000-797105–900Santa MariaRSBrazil NormandieUniversité UNIROUENINSA RouenCNRSCOBRA(UMR 6014)27000EvreuxFrance Universidad De La costa Calle 58#55-66080002BarranquillaAtlánticoColombia Advanced Materials Research chair Department of ChemistryCollege of ScienceKing Saud UniversityRiyadh11451Saudi Arabia Department of chemistry College of ScienceBuilding#5King Saud UniversityRiyadhSaudi Arabia Department of Physics College of SciencePrincess Nourah Bint Abdulrahman UniversityP.O.Box 84428Riyadh11671Saudi Arabia Research center for Advanced Materials Science(RcAMS) King Khalid UniversityAbha61413P.O.Box 9004Saudi Arabia chemistry Department Faculty of ScienceKing Khalid UniversityP.O.Box 9004Abha61413Saudi Arabia Instituto Tecnológico de Aguascalientes 20256AguascalientesMexico

The separation of rare earth elements using diatomite M45 from aqueous solutions was *** experimental isotherms for the adsorption of trivalent lanthanum,cerium,and neodymium cations on this adsorbent were quantified under strongly acidic conditions(pH 2)at 298-328 *** adsorption equilibria of these earth elements were analyzed using two statistical physics models(homogeneous and heterogeneous monolayer models).The results show that the adsorption of these ions implies a multiionic mechanism,which is ***-containing functional groups are responsible for the adsorption of these rare-earth elements on the diatomite surface.A heterogeneous statistical physics model confirms that two Si-based functional groups participate in the separation of these *** calculated adsorption capacities at saturation follow the order:neodymium>cerium>*** interaction energies range from 28600 to 40100 J/mol,indicating physical adsorption on diatomite *** study demonstrates that diatomite M45 is a promising separation medium that can be used for the recovery of REEs dissolved in aqueous solutions via adsorption.

关键词： Lanthanum cerium Neodymium Adsorption Diatomite M45 Statistical physics model

Status and prospects for symmetric organic redox flow batteries

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Journal of Energy chemistry 2025年第1期100卷 125-143页

作者： Md Al Raihan c.Adam Dyker Department of chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(ORFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric ORFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

Acquired sensorineural hearing loss,oxidative stress,and microRNAs

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Neural Regeneration Research 2025年第9期20卷 2513-2519页

作者： Desmond A.Nunez Ru c.Guo Division of Otolaryngology–Head&Neck Surgery Department of SurgeryFaculty of MedicineThe University of British ColumbiaVancouverBCCanada Division of Otolaryngology–Head&Neck Surgery Gordon&Leslie Diamond Health Care CentreVancouver General HospitalVancouverBCCanada Faculty of Medicine–The University of British columbia VancouverBCCanada

Hearing loss is the third leading cause of human ***-related hearing loss,one type of acquired sensorineural hearing loss,is largely responsible for this escalating global health ***-induced,ototoxic,and idiopathic sudden sensorineural are other less common types of acquired hearing *** etiology of these conditions is complex and multi-fa ctorial involving an interplay of genetic and environmental *** stress has recently been proposed as a likely linking cause in most types of acquired sensorineural hearing *** non-coding RNA sequences known as microRNAs(miRNAs)have increasingly been shown to play a role in cellular hypoxia and oxidative stress responses including promoting an apoptotic *** hair cell death is a central histopathological finding in sensorineural hearing *** these cells do not regenerate in humans,it underlies the irreversibility of human age-related hearing *** EMBASE,Ovid MEDLINE,Web of Science core collection,and *** databases over the period August 1,2018 to July 31,2023 were searched with"hearing loss,""hypoxamiRs,""hypoxia,""microRNAs,""ischemia,"and"oxidative stress"text words for English language primary study publications or registered clinical *** red clinical trials known to the senior author we re also assessed.A total of 222studies were thus *** excluding duplicates,editorials,retra ctions,secondary research studies,and non-English language articles,39 primary studies and clinical trials underwent full-text *** resulted in 11 animal,in vitro,and/or human subject journal articles and 8 registered clinical trial database entries which form the basis of this narrative *** miR-34a and miR-29b levels increase with age in *** miRNAs were demonstrated in human neuroblastoma and murine cochlear cell lines to target Sirtuin 1/peroxisome proliferato r-activated receptor gamma coactivator-1-alpha(SIRT1/P Gc-1α),SIRT

关键词： hearing loss hypoxia microRNAs oxidative stress sensorineural

Multiple sclerosis is at a checkpoint: advancing the program

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Neural Regeneration Research 2025年第3期20卷 811-812页

作者： Brandon c.Smith Jessica L.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a chronic inflammatory and demyelinating disease of the central nervous system(cNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage