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Chemical compounds as well as antioxidant and litholytic activities of Arbutus unedo L. leaves against calcium oxalate stones

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Journal of Integrative Medicine 2019年第6期17卷 430-437页

作者： Rabie Kachkoul Tarik Squalli Housseini Mohamed Mohim radouane el habbani Youssef Miyah Anissa Lahrichi Laboratory of Biochemistry Faculty of Medicine and PharmacyUniversity Sidi Mohammed Ben AbdellahBP 1893FezMorocco Faculty of Science and Technology University Sidi Mohammed Ben AbdellahBP 2202FezMorocco Laboratory of Molecular Bases in Human Pathology and Therapeutic Tools Faculty of Medicine and PharmacyUniversity Sidi Mohammed Ben AbdellahBP 1893FezMorocco Department of Nephrology University Hospital HassanⅡBP 1835AtlasFezMorocco

Objective: The present study aimed to quantify and identify the bioactive compounds of the Arbutus unedo L. leaves in order to evaluate both their antioxidant properties and litholytic activities against calcium oxalate ***: This survey was carried out using hydroalcoholic extract(***) and infusion(***) of A. unedo leaves. The quantification of phenolic compounds, flavonoids, flavonols and anthocyanins was done by spectrophotometric methods and identification of chemical components was performed by ultraperformance liquid chromatography with photodiode array and electrospray ionization tandem mass spectrometry. Antioxidant activity was measured using the 1,1-diphenyl-2-picrylhydrazyl(DPPH)method and by the ferric reducing/antioxidant power(FRAP) assay. Litholytic activity of *** and *** was studied using a special model that resembles circuitry of the urinary ***: *** showed greater antioxidant efficacy than ***(P < 0.05). Its higher efficiency was shown via the values of median inhibitory concentration, which was close to(76.14 ± 0.91) mg/mL for *** versus(202.64 ± 5.77) lg/mL for *** using the DPPH method, and(53.77 ± 0.81) lg/mL for *** versus(236.86 ± 31.90) lg/mL for ***, using FRAP method. *** exhibited significantly higher litholytic activity compared to ***(P < 0.05), with dissolution values of 31.03% ± 0.63% versus 14.55% ± 0.65%, ***: Overall, the results suggest that the A. unedo is rich in bioactive compounds, and possesses antioxidant and litholitic abilities that are worthy of further study.

关键词： Antioxidant activity Arbutus unedo L Litholytic activity Phenolic compounds Liquid chromatography Photodiode array electrospray ionization tandem Mass spectrometry

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Mechanics of Twisted DNA Molecule Adsorbed on a Biological Membrane

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Open Journal of Biophysics 2020年第3期10卷 129-149页

作者： radouane el Kinani Hamid Kaidi Noureddine Barka Departement of Mathematics Computer Science and Engineering University of Quebec at Rimouski Rimouski Canada Laboratory of Scientific Research and Pedagogical Development CRMEF Meknes Morocco

DNA is the carrier of all cellular genetic information and increasingly used in nanotechnology. The study of DNA molecule achieved in vitro while submitting the DNA to all chemicals agent capabilities to destabilize links hydrogen, such as pH, temperature. In fact, the DNA enveloped in the membrane cellular, so it is legitimate to study the influence of membrane undulations. In this work, we try to show that the fluctuations of the membrane can be considerate as a physics agent is also capable to destabilize links hydrogen. In this investigation, we assume that each pair base formed an angle an with the membrane’s surface. We have proposed a theoretical model, and we have established a relationship between the angle formed by the pair base θeq and an angle formed by the membrane and each pair base. We assume that DNA and biomembrane interact via a realistic potential of Morse type. To this end, use is made of a generalized model that extends that introduced by M. Peyrard and A. R. Bishop in the past modified by M. Zoli. This generalized model is based on the resolution of a Schrödinger-like equation. The exact resolution gives the expression of the ground state, and the associated eigenvalue (energy) that equals the free energy, in the thermodynamic limit. First, we compute the denaturation temperature of DNA strands critical temperature. Second, we deduce all critical properties that mainly depend on the parameters of the model, and we quantify the effects of the membrane undulations. These undulations renormalize all physical quantities, such as harmonic stacking, melting temperature, eigenfunctions, eigenvalues and regular part of specific heat.

关键词： Biomembrane DNA Molecule Denaturation Interactions Critical Properties

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Structural Features and Properties of the Vitreous Part of the System 50P2O5-25CaO-(25-x)Na2O-xCoO (with 0 ≤ x ≤ 25;mol%)

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Advances in Materials Physics and Chemistry 2021年第12期11卷 254-266页

作者： Brahim Bachachir Yassine Er-Rouissi radouane Makhlouk Achraf Harrati Abdeslam el Bouari Said Aqdim Faculty of Sciences Ain Chock Laboratory of Materials Engineering for Environment and Valorization Hassan II University Casa-blanca Morocco Faculty of Sciences Ben-M’sik Laboratory Physical-Chemistry of Applied Materials Hassan II University Casablanca Morocco Department of Chemistry Faculty of Science Mineral Chemistry Laboratory Hassan II University Ain Chock Casablanca Morocco

The glass series 50P2O5-25CaO-(25-x)Na2O-xCoO (with (0 ≤ x ≤ 25;mol%), has been prepared by direct melting at 1080°C ± 20°C. The introduction of cobalt in calcium phosphate glasses is used to compare its effect with calcium in inhibition corrosion. The dissolution rate has been investigated. It indicated an improvement of chemical durability when the cobalt oxide increases in the network glass at the expense of Na2O content. Both, IR spectroscopy and X-ray diffraction have confirmed the structure changes when the CoO content increases in the glass. This change results in the disappeara

关键词： Chemical Durability Phosphate Glasses Cobalt Oxide Density DTA DRX IR SEM Micrograph

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