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Production traits and fertility of reciprocal hybrids between Argopecten irradians irradians and A.i.concentricus

Journal of Oceanology and Limnology 2024年第1期42卷 304-315页

作者： Jinjing wang Junhao NING Xia LU Min CHEN Guilong LIU Xin XU quanchao wang He XU Chunde wang Research and Development Center for Efficient Utilization of Coastal Bioresources Yantai Institute of Coastal Zone ResearchChinese Academy of SciencesYantai 264003China College of Marine Science and Engineering Qingdao Agricultural UniversityQingdao 266109China University of Chinese Academy of Sciences Beijing 100049China Yantai Spring-Sea AquaSeed Co. Ltd.Yantai 264006China Jiangsu Baoyuan Biotechnology Co. Ltd.Lianyungang 222144China Jiangsu Haitai MariTech Co. Ltd.Lianyungang 222144China

The two bay scallop subspecies,Argopecten irradians irradians(NN)and A.i.concentricus(SS),are fast growing and major cultured bivalves in China.However,their relatively small sizes and decreasing production traits caused by long-term inbreeding have been major concerns to the industry in the last two decades.Hybridization between the two bay scallop subspecies may provide a new approach to breed a new variety with superior production traits for the industry.For this end,in this study,we hybridized the two bay scallop subspecies in order to obtain a new strain that incorporates the genes of both subspecies.No significant difference was found in fertilization rate,hatching rate and metamorphosis rate between the purebred and crossbred cohorts(NN♀×SS♂,denoted as NS;SS♀×NN♂,denoted as SN).Both mating strategy(intra-vs.inter-population crosses)and egg origin had significant effects on growth and survival at the larval stage.Heterosis was observed in the crossbred and was more pronounced in older stages.Genetic diversity of the reciprocal hybrids,especially that of SN,was increased compared with the purebred cohorts.Almost all hybrids were completely fertile and able to reproduce by selffertilization or by backcrossing with either parent.Apparently,male sterile individuals whose gonads were fully occupied by the ovary part at mature stage were found in the hybrids for the first time.The hybrids,especially SN,may provide precious germplasm resources for the production of ternary hybrids with the Peruvian scallop,A.purpuratus.

关键词： bay scallop hybridization growth survival heterosis fertility ternary hybrids

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Prestoring lithium into SnO_(2)coated 3D carbon fiber cloth framework as dendrite-free lithium metal anode

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Particuology 2024年第1期84卷 89-97页

作者： Tao Wei Yanyan Zhou Cheng Sun Lesheng Liu Sijia wang Mengting wang Ye Liu Qing Huang quanchao Zhuang Yongfu Tang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang212003China College of Materials Science and Engineering Nanjing Forestry UniversityNanjing210037China Li-ion Batteries Lab School of Materials Science and EngineeringChina University of Mining and TechnologyXuzhouChina Hebei Key Laboratory of Applied Chemistry School of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao066004China

For several decades,the promise of implementing of lithium(Li)metal anodes has been regarded as the"holy grail"for Li-based batteries.Herein,we have proposed a facile design of a carbon fiber cloth(CFC)framework coated with SnO_(2)nanoparticles through a hydrothermal process,which served as a reliable host for prestoring molten Li to produce a CFC@SnO_(2)@Li composite anode.XRD,TEM,HRTEM,XPS and different electrochemical characterizations were carried out.Owing to the synergetic effects of the 3D conductive CFC and the coated lithiophilic SnO_(2)nanoparticles,the designed CFC@SnO_(2)@Li electrodes can buffer the volume changes and reduce the local current density,thus suppress the Li dendrites during cycling.Consequently,the CFC@SnO_(2)electrodes showed a high and stable CE of 98.6%for 1000 cycles at a current density of 1 mA cm^(-2)(1 mAh cm^(-2)).What is more,at a high current density of 5 mA cm^(-2)and a high areal capacity of 5 mAh cm^(-2),the symmetric cell displayed relatively low overpotential and long cycling lifetime of 1600 h.The results confirm its great potential as lithium metal anodes in practical battery applications.

关键词： Lithiophilic Lithium metal anodes SnO_(2) 3D anode Dendrite-free

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Genetic diversity and population structure of the sea star Asterias amurensis in the northern coast of China

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Journal of Oceanology and Limnology 2023年第4期41卷 1593-1601页

作者： quanchao wang Ying LIU Zirui PENG Linlin CHEN Baoquan LI Key Laboratory of Coastal Biology and Bioresource Utilization Yantai Institute of Coastal Zone ResearchChinese Academy of SciencesYantai 264003China University of Chinese Academy of Sciences Beijing 100049China Center for Ocean Mega-Science Chinese Academy of SciencesQingdao 266071China Ocean School Yantai UniversityYantai 264005China

The sea star Asterias amurensis is widely viewed as a severe“marine pest”because of its broad feeding habits.Over the past few decades,A.amurensis undergoes massive and sporadic population outbreaks worldwide,causing extensive economic and ecological losses to the local aquaculture industry and marine ecosystem.Understanding the genetic diversity and population structure of A.amurensis can provide vital information for resource management.By analyzing the polymorphism of the mitochondrial cytochrome C oxidase subunit I(COI)gene and ten simple sequence repeat(SSR)microsatellites markers,the genetic diversity and population structure of A.amurensis of four populations along the northern coast of China was uncovered.A total of 36 haplotypes were identified,and a main haplotype was found in four populations.The Qingdao(QD)population displayed the highest genetic diversity among all the populations.The AMOVA and pairwise F_(st)showed that there was small but statistically significant population differentiation among the four populations,especially between QD and Weihai(WH).Moreover,the principal component analysis(PCA)and admixture analysis showed that several individuals in Yantai(YT)and Dalian(DL)had little genetic association with other individuals.Overall,this study provided useful information of the genetic diversity and population structure of A.amurensis and will contribute to the resource management of A.amurensis in China.

关键词： Asterias amurensis cytochrome C oxidase subunit I(COI) simple sequence repeat(SSR) population structure China seas

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地下车站侧墙混凝土结构抗裂技术研究与应用

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城市轨道交通研究 2024年第1期27卷 144-148页

作者：郦亮王全超程璐占文宁波市轨道交通集团有限公司宁波315101 中交武汉港湾工程设计研究院有限公司武汉430040 海工结构新材料及维护加固技术湖北省重点实验室武汉430040

[目的]城市轨道交通工程地下车站侧墙混凝土开裂,会威胁地铁车站结构安全,需分析其开裂的原因,并提出地下车站侧墙混凝土控裂的关键技术。[方法]通过降低水泥用量及掺加高效抗裂剂,制备了低水化速率、微膨胀混凝土;对比研究了组分优化... 详细信息

[目的]城市轨道交通工程地下车站侧墙混凝土开裂,会威胁地铁车站结构安全,需分析其开裂的原因,并提出地下车站侧墙混凝土控裂的关键技术。[方法]通过降低水泥用量及掺加高效抗裂剂,制备了低水化速率、微膨胀混凝土;对比研究了组分优化前后的混凝土对结构力学性能、绝热温升及体积变形的影响,从而验证地下车站侧墙混凝土组分改善后抗裂性能提高;在此基础上,对地下车站混凝土侧墙结构进行有限元模型仿真分析,计算不同侧墙厚度、分段长度对抗裂安全系数的影响,从而在满足抗裂安全系数前提下,确定不同季节地下车站混凝土侧墙分段浇筑的最佳长度;最后通过监测地下车站试验段各典型分段的温度变化规律,提出了侧墙混凝土温度控制指标。[结果及结论]地下车站侧墙混凝土收缩及侧墙混凝土受约束是引起地下车站混凝土侧墙开裂的主要原因。关键控裂措施为:引入高效抗裂剂提高混凝土抗裂性能,优化不同季节地下车站混凝土侧墙分段浇筑长度降低混凝土约束,严格控制混凝土温度指标。采用上述关键控裂措施后,地下车站侧墙混凝土裂缝数量极大减少。

关键词：地铁车站侧墙开裂抗裂技术抗裂混凝土

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Effects of key species mud snail Bullacta exarata (Gastropoda) on oxygen and nutrient fluxes at the sediment-water interface in the Huanghe River Delta, China

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Acta Oceanologica Sinica 2019年第8期38卷 48-55页

作者： Baoquan Li Tjeerd J. Bouma quanchao wang Laura M. Soissons Francesco Cozzoli Guanghai Feng Xiaojing Li Zhengquan Zhou Linlin Chen Yantai Institute of Coastal Zone Research Chinese Academy of Sciences Yantai 264003 China Department of Spatial Ecology Royal Netherlands Institute for Sea Research (NIOZ-Yerseke) Yerseke 140 4400 AC The Netherlands University of Applied Sciences Vlissingen 4382 NW The Netherlands University of Chinese Academy of Sciences Beijing 100049 China Dawenliu Management Station of Yellow River Delta National Nature Reserve Dongying 257500 China

Since the mud snail Bullacta exarata was introduced for economic aquaculture in the Huanghe River(Yellow River) Delta in 2001, its quick population growth and expanded distribution make it a key-species in the intertidal zone of this area. This significantly contributed to the economic income of the local people, but its potential ecological impact on the benthic ecosystem remains unknown. A mesocosm study was conducted to test whether its bioturbation activities affect the microphytobenthos(MPBs;i.e., sedimentary microbes and unicellular algae)productivity and the nutrient exchange between the sediment-water interface. Our results show that the mud snail significantly impacted the dissolved oxygen(DO) flux across the sediment-water interface on the condition of normal sediment and light treatment, and significantly increased the ammonium efflux during recovery period in the defaunated sediment and dark treatment. The presence of micro-and meiofauna significantly increased the NH4-N flux in dark treatment. Whereas, in light treatment, these small animals had less effects on the DO and NH4-N flux between sediment-water interface. Our results provide better insight into the effect of the mud snail B.exarata on the ecosystem functioning via benthic fluxes.

关键词： bioturbation mud snail Bullacta exarata oxygen flux nutrient flux benthic metabolism Huanghe River(Yellow River) Delta

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养护环境对偏高岭土基地聚物性能及微观结构的影响

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硅酸盐通报 2024年第4期43卷 1463-1471页

作者：黄大建王治武唐文捷张全超强小虎兰州交通大学材料科学与工程学院兰州730070

为了探究养护环境对偏高岭土基地聚物干缩开裂特性和力学性能的影响,以不同养护环境为参数,系统研究了不同养护环境对偏高岭土基地聚物性能(抗压强度、收缩)和微观结构的影响。结果表明:温度交替变化环境(冻融循环)对偏高岭土基地聚物... 详细信息

为了探究养护环境对偏高岭土基地聚物干缩开裂特性和力学性能的影响,以不同养护环境为参数,系统研究了不同养护环境对偏高岭土基地聚物性能(抗压强度、收缩)和微观结构的影响。结果表明:温度交替变化环境(冻融循环)对偏高岭土基地聚物的结构影响较大,不利于偏高岭土基地聚物材料性能的发展;低湿度环境有利于体系中水分子排出,从而使形成的凝胶相更致密,有利于抗压强度的发展,但使干缩率和孔隙率增加。在各种养护环境中,干燥养护(温度(20±0.5)℃,湿度(50±5)%)条件下的试样28 d抗压强度达到73.94 MPa,较标准养护(温度(20±0.5)℃,湿度不低于95%)条件下的试样增长了68.77%,28 d干缩率为237.5×10^(-4),孔隙率达到最高(45.73%)。

关键词：地聚物养护环境偏高岭土孔隙率干缩率

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新型聚乙烯弹性体导向的α-二亚胺镍配合物催化剂的研究进展

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石油化工 2024年第4期53卷 463-488页

作者：张秋月闫国春王建立李艺张世杰王权超马艳平孙文华中国科学院化学研究所中国科学院工程塑料重点实验室北京100190 中国神华煤制油化工有限公司北京100011

乙烯与α-烯烃共聚所制备的聚烯烃弹性体是聚烯烃材料的热点,可广泛应用于塑料相容剂、鞋底基材、光伏封装胶膜、微电子封装材料和弹性体纤维等高附加值产品领域。在我国缺少α-烯烃单体的形势下,迫切需要跨越传统共聚体系的新型催化剂... 详细信息

乙烯与α-烯烃共聚所制备的聚烯烃弹性体是聚烯烃材料的热点,可广泛应用于塑料相容剂、鞋底基材、光伏封装胶膜、微电子封装材料和弹性体纤维等高附加值产品领域。在我国缺少α-烯烃单体的形势下,迫切需要跨越传统共聚体系的新型催化剂。Brookhart型α-二亚胺镍(Ⅱ)配合物催化剂能够实现单一乙烯聚合制备聚乙烯弹性体,是特别值得重视和推进产业化的催化剂体系。该类催化剂在催化乙烯聚合过程中采用“链行走”机理,“通过调控催化剂结构,不仅可以调节催化活性,更重要地可实现对所得聚乙烯支链的有效剪裁”;这些微观结构可控的聚乙烯弹性体在具有窄分子量分布特点的基础上,涵盖了从低分子量(降凝剂)、中等分子量(膜材)到高分子量(高强度树脂)各个范围的聚合产物。综述了可制备乙烯低聚物,油性低分子量、中等分子量、高分子量甚至超高分子量全系列支化聚乙烯的α-二亚胺镍(Ⅱ)配合物的最新结构演变进展,对结构的改性包括N-芳基取代基的修饰、配体骨架结构的修饰和双核配体的利用三个部分;从空间效应和电子效应两方面探讨了配合物结构与催化性能的关系。α-二亚胺镍(Ⅱ)催化剂合成简单,具有中试放大基础和产业化推进的潜能,为单一乙烯聚合制备多品种新型聚乙烯弹性体奠定了良好基础。

关键词： α-二亚胺镍配合物链行走机理乙烯低聚乙烯聚合聚乙烯弹性体

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热电池正极材料的研究进展

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化学通报 2024年第2期87卷 164-174页

作者：李慕荣张小强李红亮蒋江民庄全超崔艳华中国矿业大学材料与物理学院徐州221000 中国工程物理研究院电子工程研究所绵阳621000

热电池是一种热激活贮备式电池,由于其优良的贮存稳定性、放电可靠性等特点,广泛应用于多种军用武器的内部电源。为了满足当前不同军用武器装备的需求,热电池的发展趋于在提高电化学性能的同时实现小型化、微型化。热电池电化学性能的... 详细信息

热电池是一种热激活贮备式电池,由于其优良的贮存稳定性、放电可靠性等特点,广泛应用于多种军用武器的内部电源。为了满足当前不同军用武器装备的需求,热电池的发展趋于在提高电化学性能的同时实现小型化、微型化。热电池电化学性能的提高主要取决于正极材料的发展,目前对现有正极材料的优化改性和新型正极材料的开发是提高热电池性能的主要方法。本文从合成和改性方法的角度综述了近年来硫化物、氯化物、氟化物热电池正极材料的研究进展,并对其材料特性和放电性能进行了综合评估。最后,基于热电池特殊的应用场景,从热稳定性、放电电压、电导率等方面对热电池正极材料未来的发展方向进行了总结与展望。

关键词：热电池正极硫化物氯化物氟化物

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Advanced inorganic/polymer hybrid electrolytes for all-solid-state lithium batteries

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Journal of Advanced Ceramics 2022年第6期11卷 835-861页

作者： Xiaoyu JI Yiruo ZHANG Mengxue CAO quanchao GU Honglei wang Jinshan YU Zi-Hao GUO Xingui ZHOU Science and Technology on Advanced Ceramic Fibers and Composites Laboratory College of Aerospace Science and EngineeringNational University of Defense TechnologyChangsha 410073China South China Advanced Institute for Soft Matter Science and Technology School of Molecular Science and EngineeringSouth China University of TechnologyGuangzhou 510640China Department of Chemical and Environmental Engineering Yale UniversityNew Haven 06511USA

Solid-state batteries have become a frontrunner in humankind’s pursuit of safe and stable energy storage systems with high energy and power density.Electrolyte materials,currently,seem to be the Achilles’heel of solid-state batteries due to the slow kinetics and poor interfacial wetting.Combining the merits of solid inorganic electrolytes(SIEs)and solid polymer electrolytes(SPEs),inorganic/polymer hybrid electrolytes(IPHEs)integrate improved ionic conductivity,great interfacial compatibility,wide electrochemical stability window,and high mechanical toughness and flexibility in one material,having become a sought-after pathway to high-performance all-solid-state lithium batteries.Herein,we present a comprehensive overview of recent progress in IPHEs,including the awareness of ion migration fundamentals,advanced architectural design for better electrochemical performance,and a perspective on unconquered challenges and potential research directions.This review is expected to provide a guidance for designing IPHEs for next-generation lithium batteries,with special emphasis on developing high-voltage-tolerance polymer electrolytes to enable higher energy density and three-dimensional(3D)continuous ion transport highways to achieve faster charging and discharging.

关键词： solid-state electrolytes(SSEs) hybrid electrolytes energy density electrical energy storage(EES) lithium batteries

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二维插装式流量调节阀的理论分析和实验研究

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高技术通讯 2024年第6期34卷 659-670页

作者：戴权超尤逸铭赵建涛李胜阮健浙江工业大学机械工程学院杭州310023 浙江工业大学特种装备制造与先进加工技术教育部/浙江省重点实验室杭州310023

针对流量阀功重比低、体积大的问题,提出一种新型二维插装式流量调节阀。阀体后端的力矩马达带动具有双自由度的二维活塞转动并进行功率放大驱动阀芯,阀体上的压差反馈杆可精准地测量进出口压差,无需安装额外的压力传感器。首先建立该... 详细信息

针对流量阀功重比低、体积大的问题,提出一种新型二维插装式流量调节阀。阀体后端的力矩马达带动具有双自由度的二维活塞转动并进行功率放大驱动阀芯,阀体上的压差反馈杆可精准地测量进出口压差,无需安装额外的压力传感器。首先建立该阀的数学模型,并使用Matlab进行了稳定性分析;其次以AMESim为平台搭建了模型,对其动静态特性进行了仿真分析;最后进行实验验证。该阀滞环为4.4%,线性度为1.6%,响应时间约为44 ms,幅频宽约为17 Hz,相频宽约为28 Hz,压差测量范围为8 MPa。理论分析和实验结果均表明,二维插装式流量调节阀不仅结构简单、功重比高,且具有良好的动静态特性,是较为合适的解决方案。

关键词：二维阀流量阀高集成度 AMESim仿真软件实验研究

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