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A review on the transformation of birnessite in the environment:Implication for the stabilization of heavy metals

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Journal of Environmental Sciences 2024年第5期139卷 496-515页

作者： Miao Shi Qingzhu Li qingwei Wang Xuelei Yan Bensheng Li Linhai Feng Chao Wu Rongrong Qiu Hongkai Zhang Zhihui yang Weichun yang Qi Liao Liyuan Chai School of Metallurgy and Environment Central South UniversityChangsha 410083China National Engineering Research Centre for Control and Treatment ofHeavy Metal Pollution Central South UniversityChangsha 410083China Water Pollution Control Technology Key Lab of Hunan Province Changsha 410083China

Birnessite is ubiquitous in the natural environment where heavy metals are retained and easily transformed.The surface properties and structure of birnessite change with the changes in external environmental conditions,which also affects the fate of heavy metals.Clarifying the effect and mechanism of the birnessite phase transition process on heavy metals is the key to taking effective measures to prevent and control heavy metal pollution.Therefore,the four transformation pathways of birnessite are summarized first in this review.Second,the relationship between transformation pathways and environmental conditions is proposed.These relevant environmental conditions include abiotic(e.g.,co-existing ions,pH,oxygen pressure,temperature,electric field,light,aging,pressure)and biotic factors(e.g.,microorganisms,biomolecules).The phase transformation is achieved by the key intermediate of Mn(Ⅲ)through interlayer-condensation,folding,neutralizationdisproportionation,and dissolution-recrystallization mechanisms.The AOS(average oxidation state)of Mn and interlayer spacing are closely correlated with the phase transformation of birnessite.Last but not least,the mechanisms of heavy metals immobilization in the transformation process of birnessite are summed up.They involve isomorphous substitution,redox,complexation,hydration/dehydration,etc.The transformation of birnessite and its implication on heavy metals will be helpful for understanding and predicting the behavior of heavy metals and the crucial phase of manganese oxides/hydroxides in natural and engineered environments.

关键词： Birnessite Transformation Heavy metals Pathways Mechanism

Glymphatic system:a gateway for neuroinflammation

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Neural Regeneration Research 2024年第12期19卷 2661-2672页

作者： Kailu Zou qingwei Deng Hong Zhang Changsheng Huang Department of Anesthesiology Xiangya HospitalCentral South UniversityChangshaHunan ProvinceChina Xiangya School of Medicine Central South UniversityChangshaHunan ProvinceChina National Clinical Research Center for Geriatric Disorders Xiangya HospitalCentral South UniversityChangshaHunan ProvinceChina

The glymphatic system is a relatively recently identified fluid exchange and transpo rt system in the brain.Accumulating evidence indicates thatglymphatic function is impaired not only in central nervous system disorders but also in systemic diseases.Systemic diseases can trigger the inflammatory responses in the central nervous system,occasionally leading to sustained inflammation and functional disturbance of the central nervous system.This review summarizes the current knowledge on the association between glymphatic dysfunction and central nervous system inflammation.In addition,we discuss the hypothesis that disease conditions initially associated with peripheral inflammation ove rwhelm the performance of the glymphatic system,thereby triggering central nervous system dysfun ction,chronic neuroinflammation,and neurodegeneration.Future research investigating the role of the glymphatic system in neuroinflammation may offer innovative therapeutic approaches for central nervous system disorders.

关键词： aquaporin-4 central nervous system disease cerebrospinal fluid chronic neuroinflammation glymphatic dysfunction neurodegeneration peripheral nerve injury perivascular space systemic disease vicious cycle

Progress of gaseous arsenic removal from flue gas by adsorption:Experimental and theoretical calculations

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Journal of Environmental Sciences 2024年第2期136卷 470-485页

作者： Xuelei Yan Qingzhu Li Xiaowei Huang Bensheng Li Shengtu Li qingwei Wang School of Metallurgy and Environment Central South UniversityChangsha 410083China National Engineering Research Centre for Control and Treatment of Heavy Metal Pollution Central South UniversityChangsha 410083China National Engineering Research Center for Rare Earth Materials General Research Institute for Non-Ferrous MetalsBeijing 100088China

Because of its high mobility and difficult capture,gaseous arsenic pollution control has become the focus of arsenic pollution control.It mainly exists in the form of highly toxic As_(2)O_(3)in the flue gas.Therefore,removing gaseous As_(2)O_(3)from flue gas is of great practical significance for arsenic pollution control.Stabilizing gaseous As_(2)O_(3)on the surface of adsorbents by physical or chemical adsorption is an effective way to reduce the content of arsenic in the flue gas and alleviate arsenic pollution.Over the past few decades,various adsorbents have been developed to capture gaseous As_(2)O_(3)in the flue gas,and their adsorption mechanisms have been studied in detail.Thus,it is necessary to review the strategies of arsenic removal from flue gas by adsorption,which can inspire further research.Based on summarizing the morphological distribution of gaseous As_(2)O_(3)in the flue gas,this review further summarizes the removal of gaseous As_(2)O_(3)by several adsorbents and the effect of temperature and the main components of the flue gas on arsenic adsorption.In addition,the mechanism of arsenic removal based on adsorption in the flue gas is discussed in depth through theoretical calculations,which is the particular focus of this review.Finally,prospects based on the present research state of arsenic removal by adsorption are proposed to provide ideas for developing effective and stable adsorbents for arsenic removal from flue gas.

关键词： Gaseous arsenic Flue gas Adsorption Theoretical calculation Mechanism

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhance hydrogen production activity

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Frontiers in Energy 2024年第1期18卷 89-100页

作者： Zhouzhou WANG qingwei WU Jieming WANG Ying YU Institute of Nanoscience and Nanotechnology College of Physical Science and TechnologyCentral China Normal UniversityWuhan 430079China

Hydrogen production from photoelectrochemical(PEC)water splitting has been regarded as a promising way to utilize renewable and endless solar energy.However,semiconductor film grown on photoelectrode suffers from numerous challenges,leading to the poor PEC performance.Herein,a straightforward sol-gel method with the ligand-induced growth strategy was employed to obtain dense and homogeneous copper bismuthate photocathodes for PEC hydrogen evolution reaction.By various characterizations,it was found that the nucleation and surface growth of CuBi_(2)O_(4)layer induced by 2-methoxyethanol ligand(2-CuBi_(2)O_(4))demonstrated a decent crystallinity and coverage,as well as a large grain size and a low oxygen vacancy concentration,leading to the good ability of light absorption and carrier migration.Consequently,under simulated sunlight irradiation(AM1.5G,100 mW/cm^(2)),the 2-CuBi_(2)O_(4)photocathode achieved an enhanced photocurrent density of−1.34 mA·cm^(−2)at 0.4 V versus the reversible hydrogen electrode and a promising applied bias photon-to-current efficiency of 0.586%.This surface modification by ligand growth strategy will shed light on the future design of advanced photoelectrodes for PEC water splitting.

关键词： copper bismuthate photocathode ligand growth strategy dense film PEC

Enhancing Strength-Ductility Synergy of CoCrNi-Based Medium-Entropy Alloy Through Coherent L1_(2)Nanoprecipitates and Grain Boundary Precipitates

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Acta Metallurgica Sinica(English Letters) 2024年第1期37卷 78-88页

作者： Leilei Li Kaikai Song qingwei Gao Changshan Zhou Xiaoming Liu Yaocen Wang Xiaojun Bai Chongde Cao School of Physical Science and Technology Northwestern Polytechnical UniversityXi’an710016China Weihai Research Institute of Industrial Technology Shandong UniversityWeihai264209China Research and Development Institute of Northwestern Polytechnical University in ShenzhenShenzhen518057China

The L1_(2)-strengthened Co_(34)Cr_(32)Ni_(27)Al_(4)Ti_(3)medium-entropy alloy(MEA)with precipitations of grain boundaries has been developed through selective laser melting(SLM)followed by cold rolling and annealing,exhibiting excellent strength-ductility synergy.The as-printed alloy exhibits low yield strength(YS)of~384 MPa,ultimate tensile strength(UTS)of~453 MPa,and uniform elongation(UE)of 1.5%due to the existence of the SLM-induced defects.After cold rolling and annealing,the YS,UTS,and UE are significantly increased to~739 MPa,~1230 MPa,and~47%,respectively.This enhancement primarily originates from the refined grain structure induced by cold rolling and annealing.The presence of coherent sphericalγ'precipitates(L1_(2)phases)and Al/Ti-rich precipitates at the grain boundaries,coupled with increased lattice defects such as dislocations,stacking faults,and ultrafine deformation twins,further contribute to the property’s improvement.Our study highlights the potential of SLM in producing high-strength and ductile MEA with coherent L1_(2)nanoprecipitates,which can be further optimized through subsequent rolling and annealing processes.These findings offer valuable insights for the development of high-performance alloys for future engineering applications.

关键词： Medium-entropy alloy Selective laser melting Precipitation Strength Ductility

Nanosize-effect on the distribution of heavy metals in copper smelting dust:Based on sophisticated dust sorting approach

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Nano Research 2024年第1期17卷 312-320页

作者： Ken Li Zuwu Liao Hengdi Ye Qingzhu Li Fenghua Shen Qian Li Hui Liu qingwei Wang Xu Yan Zhang Lin Liyuan Chai School of Metallurgy and Environment Central South UniversityChangsha 410083China Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution Changsha 410083China National Engineering Research Center of Sintering and Pelletizing Equipment System Zhongye Changtian International Engineering Co.LtdChangsha 410205China

Dust particles emitted from smelters can be hazardous to ecosystems and humans,as they are often enriched in metallic compounds.Here,we combined multi-method mineralogical analysis with a sophisticated size sorting approach for copper smelting dust to study the nanosize-effect on heavy metal distribution,which has hitherto been underestimated.Three types of dust were collected from a copper flash smelter and then size-sorted using a Dekati low-pressure impactor.Results showed that all three samples could easily sort out nanoscale dust particles(<1μm,grades 10–2)and even those smaller than 100 nm(grades 5–2).Especially for electrostatic precipitators dust,the mass fraction of nanoscale dust(<1μm)could reach 10.71%.The presence of heavy metals(Pb,Zn,Cu,and As)and their mineral species in dust was examined at various particle sizes.It was discovered that different heavy metals are enriched on nanoparticles in specific sizes.In micron-sized particles,heavy metals are generally found in discrete phases(e.g.,CuSO_(4),PbSO_(4),and As_(2)O_(3)).In nanoscale particles,the dominant phase is Fe_(3)O_(4),while heavy metals are mostly found in lattice substitution(e.g.,CuFe_(2)O_(4)and ZnFe_(2)O_(4)).Two distinct nano-dust morphologies were found:One with irregular mesh or chain structures consisting of particles of a few nanometers,and the other with polygonal crystals in larger sizes of hundreds of nanometers.The enrichment of heavy metals in the latter morphology is more pronounced,possibly because lattice substitution of heavy metals is more likely to occur when polycrystalline particles are formed.

关键词： copper flue dust size-sorted heavy metal distribution morphology nano-sized effects

Stormwater Quality Characteristics and Reuse Analysis of Different Underlying Surfaces at Wanzhou North Station

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Journal of Environmental & Earth Sciences 2022年第2期4卷 45-53页

作者： Shaochun Yuan Ting Li qingwei yang Shun You Tao He Bo Lv Key Laboratory of Hydraulic and Waterway Engineering of the Ministry of Education Chongqing Jiaotong UniversityChongqing400074China Chongqing Engineering Technology Research Center for Sponge City Construction Chongqing400020China Chongqing Academy of Science and Technology Chongqing401123China

In response to the water shortage in Wanzhou North Station(WNS),the authors investigated the stormwater quality characteristics with different underlying surfaces of WNS and carried out stormwater reuse analysis in conjunction with the InfoWorks ICM model.The results show that during heavy,torrential,and moderate rainfall,the road stormwater runoff has the highest concentrations of pollutants,with an average EMC(event mean concentration)value of 206 mg/L for COD.For the square runoff,the average EMC values of COD,SS,TN,and TP are 108 mg/L,395 mg/L,2.113 mg/L,and 0.128 mg/L,in comparison,the average EMC values of the corresponding indexes for the roof runoff are 65 mg/L,212 mg/L,1.449 mg/L,and 0.086 mg/L,respectively,demonstrating their potential for reuse.The R2(coefficient of determination)of SS and COD in both roof and square runoff are greater than 0.85,with a good correlation,indicating that SS removal is the key to stormwater purification.InfoWorks ICM analysis shows that the recyclable volume of rainwater from WNS in 2018 is 29,410 m3,accounting for 61.8%of the total annual rainfall.This study is expected to provide an ideal reference for the stormwater management of public buildings in mountainous areas.

关键词： Stormwater quality Underlying surface Recyclable rainfall Stormwater utilization

重庆市悦来新城土地利用/覆被变化对地表温度的影响

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生态学杂志 2024年第1期43卷 206-215页

作者：张沁张守平杨清伟重庆交通大学国家内河航道整治工程技术研究中心重庆400074 重庆交通大学水利水运工程教育部重点实验室重庆400074

为探求山地新开发区城市化进程中的土地利用/覆被变化对地表温度的影响,利用遥感手段对重庆市悦来新城的历史影像进行解译,获取了研究区城市化前、中、后3期的土地利用类型、归一化植被指数(NDVI)及陆地表面温度(LST)的空间分布,并分析... 详细信息

为探求山地新开发区城市化进程中的土地利用/覆被变化对地表温度的影响,利用遥感手段对重庆市悦来新城的历史影像进行解译,获取了研究区城市化前、中、后3期的土地利用类型、归一化植被指数(NDVI)及陆地表面温度(LST)的空间分布,并分析了土地利用类型变化和各土地利用类型的NDVI变化对LST的影响。结果表明:城市化进程中的居民组合用地大量扩张,占用的主要是农田,其次是林地;总体上,城市化后比城市化前的植被长势好,其中农田、林地的植被覆盖呈增加趋势,居民组合用地的植被覆盖呈大幅降低趋势;LST在各土地利用类型和区域空间上具有明显的异质性,同时对城市化过程具有一定的敏感性,在夏冬两季表现更明显;LST与各土地利用面积呈显著线性相关;LST与NDVI呈不显著线性关系,二者的空间关系形状在3个时期均呈“三角形”,植被覆盖具有缓解热岛效应的作用。该研究结果可为山地新开发区城市化进程中的生态规划及热岛效应缓解提供理论依据。

关键词：地表温度土地利用/覆被植被指数城市化悦来新城

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UHPC直拉试验方法与本构关系研究

材料导报 2024年第6期38卷 153-161页

作者：杨简李洋陈宝春徐港黄卿维防灾减灾湖北省重点实验室湖北宜昌443002 三峡大学土木与建筑学院湖北宜昌443002 福建工程学院土木工程学院福州350116 福州大学土木工程学院福州350108

超高性能混凝土(Ultra-high performance concrete, UHPC)单轴拉伸(直拉)试验是分析UHPC抗拉性能和直拉本构关系的基础性试验,经过对其试件形状与尺寸的优化,试验成功率已得到了较大提升。但由于试件连接方式和局部加强方式的差异,各机... 详细信息

超高性能混凝土(Ultra-high performance concrete, UHPC)单轴拉伸(直拉)试验是分析UHPC抗拉性能和直拉本构关系的基础性试验,经过对其试件形状与尺寸的优化,试验成功率已得到了较大提升。但由于试件连接方式和局部加强方式的差异,各机构试验成功率参差不齐。为进一步保证直拉试验成功率,采用试验研究和数值模拟的方法系统分析了常见的四种试件连接方式和三种试件局部加强方式对试验成功率的影响,比选出最优试验方法。结果表明:面内夹持装置具有连接可靠、操作简单的优点,适合推广。但夹具的尺寸加工误差或微变形可能导致其与试件的接触面变窄、加剧夹持引发的试件应力集中,致使主裂纹位于测距范围之外;试件与夹具的接触区域进行柔性加强(粘贴碳纤维布)和刚性加强(粘贴铝片)均能有效解决上述问题,提高试验成功率。此外,采用比选的直拉试验方法,探究了钢纤维长径比和体积率对UHPC直拉损伤本构关系的影响。通过声发射(Acoustic emission, AE)监测探究了UHPC在直拉荷载作用下的损伤演化规律,利用声发射参数(累积计数比)构建损伤因子,得到了考虑钢纤维影响的UHPC直拉损伤本构关系。

关键词：超高性能混凝土直拉试验连接装置加强方式钢纤维特征参数直拉本构关系