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Synergistic effect of bonding heterogeneity and phonon localization in introducing excellent thermoelectric properties in layered heteroanionic NdZnSbO material

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Journal of Energy Chemistry 2025年第1期100卷 259-272页

作者： Da wan Shuwei Tang Shulin Bai Xiaodong Li peng Ai wanrong Guo Tuo Zheng College of Materials Science and Engineering Liaoning Technical University Faculty of Chemistry Northeast Normal University

Layered rare-earth metal oxides, harnessing the dual properties of oxides and two-dimensional layered materials, exhibit remarkable thermal stability and quantum confinement effects. Therefore, this work adopts the first-principles calculation combined with the Boltzmann transport theory to predict the thermoelectric properties of NdZnSbO compound. The coexistence of weak interlayer van der Waals interactions, robust intralayer ionic bonding, and partial covalent bonding leads to remarkable bonding heterogeneity, which engenders pronounced phonon scattering and imposes constraints on thermal transport along the out-of-plane direction. The weakened chemical bonds induced by the antibonding states, together with the rattling-like behavior of the Zn atom, culminate in the profound anharmonicity in the layered NdZnSbO compound. The weakening bond and heavy element contribute to the softness of phonon modes, which significantly diminishes the phonon group velocity. The redistribution-dominated four-phonon scattering process spans a large optical gap, which effectively reduces the lattice thermal conductivity. The NdZnSbO compound exhibits direct semiconductor characteristic with a bandgap of 0.73 e V by adopting the Heyd-Scuseria-Ernzerhof(HSE06) functional in combination with spin–orbit coupling(SOC) effect. The multi-valley feature of NdZnSbO compound augur favorably for band degeneracy, thus amplifying the power factor. Consequently, an optimal figure-of-merit(ZT) of 3.40 at 900 K is achieved for the n-type NdZnSbO compound. The present study delves deeply insights into the origins for the low thermal conductivity of NdZnSbO compound and proposes an optimization scheme to enhance overall thermoelectric performance.

关键词： Bond strength (chemical)

Preparation of Modified Composite Nanofiltration Membrane Synergistically Using Carboxylic Multi- walled Carbon Nanotube and β-cyclodextrin

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 232-239页

作者： LIU peng MAO junpeng FANG Yanfeng YU Yunwu CHEN Changxiu TANG Ning wan Ye GU Yaxin LIU Yunxue wanG Lihua School of Materials Science and Engineering Shenyang Jianzhu UniversityShenyang 110168China

A new modified blend ultrafiltration(UF)membrane with good hydrophilicity,high porosity and excellent anti-fouling performance was developed by using carboxylic multi-walled carbon nanotube(CMWCNT)as casting solution ***,a composite nanofiltration(NF)membrane with large water flux and good retention rate was fabricated by using the PVDF/CMWCNT blend UF membrane as the substrate,and polyvinyl alcohol(PVA),β-cyclodextrin(β-CD)and polyethylenimine(PEI)as the coating *** results show that with the appropriate addition of CMWCNT in the casting solution,the surface roughness,porosity and recovery rate of the PVDF/CMWCNT blend UF membrane is obviously *** water flux of blend UF membrane is significantly improved when the CMWCNT content increases from 0 wt%to 0.2 wt%.The water flux of blend UF membrane with 0.2 wt%CMWCNT is 162.7 L/(m^(2)·h),which is 44.3%higher than that of the pure PVDF ***β-CD content is 0.8 wt%,the retention rate of Congo red by PVDF/CMWCNT/β-CD composite NF membrane reaches 98.7%,which is 28.3%higher than that of single PVA/PEI modified *** research will provide a new idea and simple method for developing novel high-performance composite NF membranes.

关键词： CMWCNT cyclodextrin nanofiltration membrane

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生物基呋喃衍生物在有机涂层中的应用

材料工程 2019年第1期47卷 42-49页

作者：彭晚军丁纪恒陈浩余海斌中国科学院宁波材料技术与工程研究所中国科学院海洋新材料与应用技术重点实验室浙江宁波315201 湖南大学材料科学与工程学院长沙410006 宁波大学材料科学与化学工程学院浙江宁波315201

随着环境保护意识的增强,减少石油基材料的使用成为社会的共识,生物基呋喃类衍生物因其独特的性质引起了研究人员的极大兴趣,其在生物基涂层、自修复涂层和光固化涂层等领域有着极大的使用潜力,但在我国尚未有成熟的研究。基于此,本文... 详细信息

随着环境保护意识的增强,减少石油基材料的使用成为社会的共识,生物基呋喃类衍生物因其独特的性质引起了研究人员的极大兴趣,其在生物基涂层、自修复涂层和光固化涂层等领域有着极大的使用潜力,但在我国尚未有成熟的研究。基于此,本文对其在生物基涂层、自修复涂层和其他涂层的应用等方面进行了总结,介绍和分析了国内外呋喃类衍生物在有机涂层方面的最近研究成果,并指出目前呋喃类衍生物的大规模应用所存在的困难:生产成本的居高不下。最后对呋喃衍生物的其他应用,如呋喃甲基缩水甘油醚作为环氧涂层的活性稀释剂取代商业化的石油基活性稀释剂以及利用呋喃环的大π键非共价改性石墨烯再制备石墨烯/有机涂层复合材料等进行了分析和展望。

关键词：呋喃类衍生物有机涂层自修复生物基

基于Bootstrap-SVR-ANN算法的TBM施工速度预测

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岩土工程学报 2021年第6期43卷 1078-1087,F0002页

作者：闫长斌汪鹤健周建军杨风威彭万军郑州大学土木工程学院河南郑州450001 盾构及掘进技术国家重点实验室河南郑州450001 黄河勘测规划设计研究院有限公司河南郑州450003

合理评价预测施工速度关乎隧道TBM施工的成败与效益。现有的TBM施工速度预测模型多利用岩体参数和掘进参数预测瞬时/平均施工速度,对掘进过程中的不确定性和施工风险考虑不足。基于此,引入区间预测方法,提出一种基于Bootstrap-SVR-ANN... 详细信息

合理评价预测施工速度关乎隧道TBM施工的成败与效益。现有的TBM施工速度预测模型多利用岩体参数和掘进参数预测瞬时/平均施工速度,对掘进过程中的不确定性和施工风险考虑不足。基于此,引入区间预测方法,提出一种基于Bootstrap-SVR-ANN算法的TBM施工速度预测模型。以兰州水源地建设工程输水隧洞双护盾TBM施工为工程依托,分析了单一性输入参数的不足,指出了选择岩体质量分级指标(RMR)、TBM工作条件等级(TWCR)两个综合性参数的合理性,并对构建的TBM施工速度区间预测模型的有效性进行了验证。研究表明,TBM施工速度区间预测模型不但具有良好的点预测效果,而且预测区间可将TBM施工速度的实测值完全包络,模型可靠性较高;模型测试集在90%,95%置信水平下的MPIW分别为9.84,11.73 m/d,随着置信水平的提高,预测区间可容纳的不确定性也不断上升;TBM掘进过程中可能的风险性与区间宽度的异常相互印证,验证了区间预测模型可以定量解释施工过程中不确定性的特点。研究成果可为TBM掘进效能预测、施工工期估算和掘进参数优化等提供科学参考。

关键词：隧道掘进机(TBM) 施工速度区间预测 Bootstrap方法支持向量回归神经网络

Maintaining moderate levels of hypochlorous acid promotes neural stem cell proliferation and differentiation in the recovery phase of stroke

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Neural Regeneration Research 2025年第3期20卷 845-857页

作者： Lin-Yan Huang Yi-De Zhang Jie Chen Hai-Di Fan wan wang Bin wang Ju-Yun Ma peng-peng Li Hai-Wei Pu Xin-Yian Guo Jian-Gang Shen Su-Hua Qi School of Medical Technology Xuzhou Key Laboratory of Laboratory DiagnosticsXuzhou Medical UniversityXuzhouJiangsu ProvinceChina School of Pharmacy Xuzhou Medical UniversityXuzhouJiangsu ProvinceChina Department of Laboratory Medicine Branch Hospital of Huai’an First People’s HospitalHuai’anJiangsu ProvinceChina Department of Laboratory Medicine the Affiliated Hospital of Xuzhou Medical UniversityXuzhouJiangsu ProvinceChina School of Chinese Medicine The University of Hong KongHong Kong Special Administrative RegionChina

It has been shown clinically that continuous removal of ischemia/reperfusion-induced reactive oxygen species is not conducive to the recovery of late ***,previous studies have shown that excessive increases in hypochlorous acid after stroke can cause severe damage to brain *** previous studies have found that a small amount of hypochlorous acid still exists in the later stage of stroke,but its specific role and mechanism are currently *** simulate stroke in vivo,a middle cerebral artery occlusion rat model was established,with an oxygen-glucose deprivation/reoxygenation model established in vitro to mimic *** found that in the early stage(within 24 hours)of ischemic stroke,neutrophils produced a large amount of hypochlorous acid,while in the recovery phase(10 days after stroke),microglia were activated and produced a small amount of hypochlorous ***,in acute stroke in rats,hypochlorous acid production was prevented using a hypochlorous acid scavenger,taurine,or myeloperoxidase inhibitor,4-aminobenzoic acid *** results showed that high levels of hypochlorous acid(200μM)induced neuronal apoptosis after oxygen/glucose deprivation/***,in the recovery phase of the middle cerebral artery occlusion model,a moderate level of hypochlorous acid promoted the proliferation and differentiation of neural stem cells into neurons and *** suggests that hypochlorous acid plays different roles at different phases of cerebral ischemia/reperfusion *** levels of hypochlorous acid(5 and 100μM)promoted nuclear translocation ofβ-*** transfection of single-site mutation plasmids,we found that hypochlorous acid induced chlorination of theβ-catenin tyrosine 30 residue,which promoted nuclear ***,our study indicates that maintaining low levels of hypochlorous acid plays a key role in the recovery of neurological function.

关键词： cell differentiation cerebral ischemia/reperfusion injury chlorination hypochlorous acid microglia neural stem cell neurogenesis nuclear translocation stroke β-catenin

Infiltration by monocytes of the central nervous system and its role in multiple sclerosis: reflections on therapeutic strategies

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Neural Regeneration Research 2025年第3期20卷 779-793页

作者： Guangyong Zhang Qing Yao Chubing Long pengcheng Yi Jiali Song Luojia Wu Wei wan Xiuqin Rao Yue Lin Gen Wei jun Ying Fuzhou Hua Department of Anesthesiology the Second Affiliated Hospital of Nanchang UniversityNanchangJiangxi ProvinceChina Key Laboratory of Anesthesiology of Jiangxi Province NanchangJiangxi ProvinceChina

Mononuclear macrophage infiltration in the central nervous system is a prominent feature of neuroinflammation. Recent studies on the pathogenesis and progression of multiple sclerosis have highlighted the multiple roles of mononuclear macrophages in the neuroinflammatory process. Monocytes play a significant role in neuroinflammation, and managing neuroinflammation by manipulating peripheral monocytes stands out as an effective strategy for the treatment of multiple sclerosis, leading to improved patient outcomes. This review outlines the steps involved in the entry of myeloid monocytes into the central nervous system that are targets for effective intervention: the activation of bone marrow hematopoiesis, migration of monocytes in the blood, and penetration of the blood–brain barrier by monocytes. Finally, we summarize the different monocyte subpopulations and their effects on the central nervous system based on phenotypic differences. As activated microglia resemble monocyte-derived macrophages, it is important to accurately identify the role of monocyte-derived macrophages in disease. Depending on the roles played by monocyte-derived macrophages at different stages of the disease, several of these processes can be interrupted to limit neuroinflammation and improve patient prognosis. Here, we discuss possible strategies to target monocytes in neurological diseases, focusing on three key aspects of monocyte infiltration into the central nervous system, to provide new ideas for the treatment of neurodegenerative diseases.

关键词： blood–brain barrier macrophages monocytes multiple sclerosis neuroinflammation review therapy

生物基呋喃甲基缩水甘油醚对环氧树脂固化物性能的影响

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塑料工业 2017年第8期45卷 23-26,43页

作者：彭晚军丁纪恒夏伟军余海斌湖南大学材料科学与工程学院湖南长沙410006 中国科学院宁波材料技术与工程研究所中国科学院海洋新材料与应用技术重点实验室浙江省海洋材料与防护技术重点实验室浙江宁波315201

利用改进的合成工艺成功合成了高纯度的呋喃甲基缩水甘油醚(FGE),并用红外对其结构进行了表征。将FGE作为活性稀释剂添加到环氧树脂中,研究了FGE含量对树脂黏度及固化物热性能、涂膜力学性能的影响。结果表明,随着FGE含量的增加,树脂黏... 详细信息

利用改进的合成工艺成功合成了高纯度的呋喃甲基缩水甘油醚(FGE),并用红外对其结构进行了表征。将FGE作为活性稀释剂添加到环氧树脂中,研究了FGE含量对树脂黏度及固化物热性能、涂膜力学性能的影响。结果表明,随着FGE含量的增加,树脂黏度急剧下降,固化物热稳定性下降,涂膜力学性能得到提升。当FGE含量为10%~15%时,环氧树脂黏度下降至2 000~4 000 mPa·s,且热稳定性良好,涂膜力学性能好。FGE的最佳含量范围是10%~15%。

关键词：活性稀释剂生物基呋喃甲基缩水甘油醚环氧树脂力学性能热性能

Engineering N3C vacancies in hierarchical porous carbon nitride nanosheets for room temperature ultradeep photocatalytic aerobic oxidative desulfurization

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Science China Chemistry 2025年

作者： Yina Nie Weijie Yang Xin wang Xiang Li Lele Wei Xiaolin Bai Lin Liu Feng Fu jun wan College of Chemistry & Chemical Engineering Research Institute of Comprehensive Energy Industrial Technology Shaanxi Key Laboratory of Chemical Reaction Engineering Yan'an University Anhui Engineering Research Center of Carbon Neutrality College of Chemistry and Materials Science Anhui Normal University

The production of ultra-low sulfur clean fuels holds global significance for improving energy efficiency and reducing environmental pollution. Photocatalytic aerobic oxidative desulfurization（PODS） offers an attractive approach to efficiently remove refractory heterocyclic aromatic sulfur compounds under mild conditions. However, the sluggish charge dynamics,insufficient molecule activation, and slow mass transfer within photocatalysts restrict the overall desulfurization efficiency,hindering the widespread application of this technology. Herein, we developed a defective g-C3N4（M1U3CN） photocatalyst with bridged N3Cvacancies and hierarchical porous structures to address these limitations. This catalyst not only demonstrates outstanding dibenzothiophene（DBT） removal efficiency of 99.6% for model oil with high conversion and selectivity but also achieves complete sulfur removal from gasoline as well as 96.7% sulfur removal for distilled diesel at room temperature,successfully achieving ultradeep aerobic oxidative desulfurization. The introduction of rich N3Cvacancies and abundant micromeso-macroporous distribution in M1U3CN enhances kinetic efficiencies by promoting charge carrier separation, mass transfer,and molecular activation simultaneously; resulting in exceptional PODS performance. This work provides a collaborative strategy to overcome kinetic challenges in aerobic oxidative desulfurization via defect and structural engineering of the catalyst.

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江西红壤缓坡地壤中流影响因素分析

西北林学院学报 2006年第5期21卷 1-6,64页

作者：尹忠东左长清高国雄彭婉君北京林业大学水土保持学院北京100083 江西省水土保持科学研究所江西南昌330046 西北农林科技大学资源环境学院陕西杨陵712100

针对地表植被覆盖、死地被物敷盖、裸地3种类型的坡面,采用径流小区试验方法,研究江西红壤表层(距地表30 cm)、底层(距地表60 cm)壤中流及地下径流(距地表105 cm)特征,运用数理统计方法分析壤中流流量、流速、历时与降雨、径流因子的相... 详细信息

针对地表植被覆盖、死地被物敷盖、裸地3种类型的坡面,采用径流小区试验方法,研究江西红壤表层(距地表30 cm)、底层(距地表60 cm)壤中流及地下径流(距地表105 cm)特征,运用数理统计方法分析壤中流流量、流速、历时与降雨、径流因子的相关关系。结果表明:1.与裸地相比,百喜草覆盖、死地被物敷盖显著增加壤中流量,2种措施都延长壤中流历时;2.壤中流量与雨量、雨强、降雨历时、初渗雨量呈正相关关系,覆盖、敷盖小区壤中流量受雨量影响较大,而裸地小区壤中流量受雨强影响较大;3.表层壤中流历时与降雨因子有较好相关性,而底层壤中流历时与降雨因子相关性很差;降雨历时对壤中流历时影响最大,降雨量影响最小;4.壤中流流速与因子的关系受措施及土层深影响,在植被覆盖、死地被物敷盖小区表层与雨量相关性最好,在裸地表层与雨强相关性最好。在各小区底层流速均与降雨历时相关性最好;5.裸地地表径流量与壤中流量相关关系不显著,在采取2种措施后,地表径流量与壤中流量呈线性正相关关系。随地表径流量的增大,覆盖措施壤中流量增大幅度大于敷盖措施。

关键词：壤中流红壤缓坡地特征影响因子