检索结果-南通市图书馆

Adsorption of 2-mercaptobenzothiazole from aqueous solution by organo-bentonite

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2013年第6期25卷 1139-1144页

作者： ping jing Meifang Hou ping Zhao Xiaoyan Tang Hongfu Wan South China Botanical Garden Chinese Academy of Sciences Graduate School of Chinese Academy of Sciences School of Ecological Technology and Engineering Shanghai Institute of Technology Guangdong Key Laboratory of Agricultural Environment Pollution Integrated Control Guangdong Institute of Eco-environmental and Soil Sciences

The adsorption behavior of 2-mercaptobenzothiazole onto organo-bentonite was investigated. Natural bentonite from Gaozhou in Guangdong Province, China was collected. Organo-bentonite was prepared by intercalation of cetyltrimethyl ammonium bromide into the natural bentonite. The physicochemical properties of the prepared organo-bentonite were characterized by X-ray diffraction, N2 adsorption-desorption isotherm and Fourier transform infrared spectroscopy. The results showed that montmorillonite is the main component of the natural bentonite. The basal spacing of the natural bentonite is 1.47 nm, which increased to 1.98 nm on intercalation with cetyltrimethyl ammonium bromide. Moreover, both the surface area and pore volume increased with intercalation. Clear CH2 stretching （3000-2800 cm-1） and scissoring （1480-1450 cm-1） modes of the intercalated surfactants were observed for organo- bentonite. Compared with the pseudo first-order kinetic model, the pseudo second-order kinetic model is more suitable to describe the adsorption kinetics of 2-mercaptobenzothiazole onto organo-bentonite. The adsorption capacity of 2-mercaptobenzothiazole onto organo-bentonite increased with increasing initial concentration of 2-mercaptobenzothiazole, but decreased with increasing adsorbent dosage. The adsorption isotherm of 2-mercaptobenzothiazole onto organo-bentonite fits well with the Langmuir model. The maximum adsorption capacity of organo-bentonite for 2-mercaptobenzothiazole was 33.61 mg/g, indicating that organo-bentonite is a promising adsorbent for 2-mercaptobenzothiazole.

关键词： 2-mercaptobenzothiazole bentonite intercalation adsorption

Crystal Structure of the 1:2 Stoichiometric Nd: [α-SiW_(11)O_(39)]^(8-): K_5Na_5H_3[Nd(α-SiW_(11)O_(39))_2]·6H_2O

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2007年第2期26卷 234-238页

作者： HAN Qiu-Xia WANG jing-ping NIU jing-Yang Basic Experiment Teaching Center Henan University Kaifeng 475001 China Institute of Molecular and Crystal Engineering School of Chemistry and Chemical Engineering Henan University Kaifeng 475001 China

Single-crystal X-ray structural analysis of K5Na5H3[Nd（α-SiW11O39）2]·6H2O （triclinic, space group P1^-, a = 13.7738（10）, b = 19.722（2）, c = 20.6647（15） A, α = 111.0090（10）, β = 105.1740（10）, y = 98.6870（10）°, Z = 2, V = 4867.2（8）, Mr = 5914.40, Dc = 4.026,μ = 26.754 mm^-1, F（000） = 5076, R = 0.0750 and wR = 0.2077） reveals that two [α-SiW11O39]^8- moieties are connected through one Nd atom which is in a square antiprismatic coordination environment by eight oxygen atoms from two [α-SiW11O391]^8- moieties. The Nd（Ⅲ） ion is substituted for a [WO]^4＋ unit in the ＂cap＂ region of the tungsten-oxygen framework of the parent Keggin ion. Disordered Na^＋ cations and water molecules reside outside these channels, leaving empty pores with an intersecting slot （13 A × 10 A）.

关键词： crystal structure characterization polyoxometalates

Hydrothermal Synthesis and Crystal Structure of a New 2D Layer Compound [{Ni(en)_2}_2Sb_8V_(14)O_(42)]·5.5H_2O

在线全文

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2009年第4期25卷 426-429页

作者： YU Li LIU Jiang-ping WANG jing-ping NIU jing-yang Institute of Molecular and Crystal Engineering School of Chemistry and Chemical Engineering Ifenan University Kaifeng 475001 P. R. China

A new compound based on polyoxovanadate [{Ni（en）2}2Sb8V14O42]·5.5H2O（en=ethylenediamine）（1） was synthesised hydrothermally as black rhombus *** 1 crystallized in the monoclinic system with space group P21/n,Z=4,a=1.46953（9） nm,b=1.28623（8） nm,c=1.76008（11） nm,β=105.7230（10）°.In the asymmetric unit,cluster {Sb8V14O42} can be considered as an Sb derivative of the {V18O42} *** {Sb8V14O42} cluster as a building block interconnected to four other neighboring units by {Ni（en）2} bridging groups which are linked through the terminal oxygen atoms of the polyoxoanions,forming a two dimensional network.

关键词： Hydrothermal synthesis Antimony-substituted Polyoxovanadate

Calculation of Hugoniot properties for shocked nitromethane based on the improved Tsien's EOS

在线全文

学校读者我要写书评

暂无评论

Acta Mechanica Sinica 2010年第3期26卷 365-370页

作者： Bo Zhao Ji-ping Cui jing Fan Key Laboratory of High Temperature Gas Dynamics Institute of Mechanics Chinese Academy of SciencesBeijing 100190 China

We have calculated the Hugoniot properties of shocked nitromethane based on the improved Tsien＇s equa- tion of state （EOS） that optimized by ＂exact＂ numerical molecular dynamic data at high temperatures and pressures. Comparison of the calculated results of the improved Tsien＇s EOS with the existed experimental data and the direct simu- lations show that the behavior of the improved Tsien＇s EOS is very good in many aspects. Because of its simple analytical form, the improved Tsien＇s EOS can be prospectively used to study the condensed explosive detonation coupling with chemical reaction.

关键词： Equation of state High pressures andtemperatures Shocked nitromethane Hugoniot properties

A Novel 3D Extended Network Cobalt Paradodecatungstate:Synthesis,Characterization and Crystal Structure of [Co(H_2O)_5]_2[Co(H_2O)_4]_3[H_2W_(12)O_(42)]·11H_2O

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2006年第10期25卷 1167-1174页

作者： WANG jing-ping REN Qing ZHAO Jun-Wei NIU jing-Yang Institute of Molecular and Crystal Engineering College of Chemistry and Chemical Engineering Henan University Kaifeng Henan 475001 China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhcu Fujian 350002 China

A cobalt paradodecatungstate [Co（H2O）5]2[Co（H2O）4]3[H2W12O42]·11H2O has been successfully synthesized and structurally characterized by X-ray crystallography. Structure analysis indicates that the title compound is of monoclinic, space group P21/n, with a = 13.449（3）, b = 19.585（4）, c = 13.990（3） °A, = 113.79（3）°, V = 3371.8（12） °A^3, Z = 2, R = 0.0519 and wR = 0.1242. The title compound exhibits a novel 3D extended network structure constructed by interconnecting the paradodecatungstate polyanion [H2W12O42]^10- clusters and cobalt^11 coordination ions.

关键词： paradodecatungstate polyoxometalate cobalt Keggin structure

A new sesquiterpene trilactone from the roots of Ginkgo biloba

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2009年第10期20卷 1224-1226页

作者： ping Yu jing Yu Liang Department of Natural Medicinal Chemistry China Pharmaceutical University Nanjing 210009 China

A new sesquiterpene trilactone, named bilobanol （1）, along with four known terpene trilactones （ginkgolide A, B, C and bilobalide） were isolated from the roots of Ginkgo biloba collected in Jiangsu Province, China... 详细信息

关键词： Ginkgo biloba Sesquiterpene trilactone Bilobanol

Hydrothermal Synthesis and Crystal Structure of a Hybrid Compound Based on β-Octamolybdate [Mn(2,2’-bipy)_3]_2[β-Mo_8O_(26)]·4H_2O

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2005年第10期24卷 1164-1168页

作者： SHEN Yue YU Li NIU jing-Yang WANG jing-ping School of Chemistry and Chemical Engineering Henan University Kaifeng 475001 China

A hybrid compound [Mn（2,2＇-bipy）3]2[β-Mo8O26]·4H2O prepared by the hydrothermal method consists of a [β-Mo8O26]^4- isopolyanion, two isolated manganese-bipyridyl units [Mn（2,2＇-bipy）3]^2＋ and four crystal water molecules. Each [Mn（2,2＇-bipy）3]^2＋ is defined by six nitrogen atoms from three 2,2＇-bipyridine molecules forming a distorted MnN6 octahedron. Crystallographic data for the title compound： monoclinic, space group P21/c, a = 12.156（2）, b = 13.738（3）, c = 21.949（4） A,β = 90.44（3）°, V = 3665.3（13） A^3, Mr = 2302.57, Z = 2, Dc = 2.086 g/cm^3, F（000） = 2252, T= 293（2） K,μ（Mo-Kα） = 1.745 mm^-1, R = 0.0436, wR = 0.1056, and GOF = 1.074 for 550 parameters and 5515 observed reflections with I 〉 2σ（I）.

关键词： hydrothermal synthesis isopolyanion crystal structure octamolybdate

A Novel Organic-Inorganic Complex: Synthesis and Crystal Structure of [Ca(DMSO)_5(H_2O)]_2SiMo_(12)O_(40)

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2002年第9期13卷 915-918页

作者： jing ping WANG Qiang WU jing Yang NIU School of Chemistry and Chemical Engineering Henan UniversityKaifeng 475001

A novel organic-inorganic complex [Ca(DMSO)5(H2O)]2SiMo12O40 was synthesized from CaCl2, DMSO and H4SiMo12O40nH2O in mixed solvent of acetonitrile and water. Its structure was characterized with elemental analysis, I... 详细信息

关键词： Synthesis crystal structure organic-inorganic complex.

Existence of Solutions to Generalized Vector Quasi-Equilibrium Problems with Discontinuous Mappings

在线全文

学校读者我要写书评

暂无评论

Acta Mathematica Sinica,English Series 2006年第4期22卷 1127-1132页

作者： Ya ping FANG Nan jing HUANG Department of Mathematics Sichuan University Chengdu 610064 P. R. China

Let X, Y be two finite-dimensional topological vector spaces, Z a Hausdorff topological vector space, K C X and D C Z be two nonempty sets, C be a pointed, closed, and convex cone in Y with int C ≠θ Let S ： K → 2^K and T ： K → 2^D be two multivalued mappings, and φ ： K × D × K → Y be a trifunction. In this paper, we consider the generalized vector quasi-equilibrium problem, which is formulated by finding X∈ K and y∈ T（x） such that x∈ E S（x） and φ（x,y, u）（∈/） -int C for all u ∈ S（x）. We establish an existence result in which T is not supposed to have any continuity property. Our results extend and improve the corresponding results of Cubiotti, Yao and Guo.

关键词： Generalized vector quasi-equilibrium problem Upper semi-continuity Lower semi-continuity Fixed point Existence