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Boosting aqueous nickel-zinc battery stability with bimetallic ion-integrated 1D metal-organic nanowires

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Science China Chemistry 2025年

作者： Yihao Chen Jin Liang Yichun Su Guoyin Zhu Hengyue Xu Hongye Ding Guangxun Zhang Dianheng yu Zizhou Shen Yizhou Zhang Wei huang Huan Pang School of Chemistry and Chemical Engineering Yangzhou University Key Laboratory of Flexible Electronics (KLoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Institute of Advanced Materials and Flexible Electronics (IAMFE) School of Chemistry and Materials Science Nanjing University of Information Science & Technology Department of Chemistry Tsinghua University State Key Laboratory of Coordination Chemistry Nanjing University

Limited by low conductivity,designing cathode materials with excellent electron transfer efficiency for high-performance nickel-zinc batteries （NZBs） remains *** this study,a series of bimetallic metal-organic nanowires were fabricated by doping M ions in NiNTA,resulting in NiMNTA (M=Mg2+,Mn2+,Co2+,Zn2+,Ag+),and NixCo6-xNTA （x=1,2,3,4,5）.The proportions and types of metal ions can be modified without altering the initial coordination structure.X-ray absorption fine structure spectroscopy （XAFS） revealed that only M–O bonds,not metal bonds,were present in the *** performance of Ni2Co4NTA as the cathode for aqueous NZBs was significantly improved,achieving the maximum energy density of 279.17Wh kg-1with the high cycle stability （retention rate of 72.0%after 1,000 cycles）.The flexible Ni2Co4NTA//Zn@carbon cloth battery employing gel electrolyte also exhibits the excellent Coulombic efficiency of 96%after 350 *** approach shows considerable potential for designing one-dimensional materials with bimetallic modifications,providing new strategies for developing cathode materials for NZBs with high specific capacity and cycle stability.

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Relationship between tumor necrosis factor-α and liver fibrosis

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World Journal of Gastroenterology 1998年第1期4卷 23-23页

作者： WANG Xin, CHEN yue Xiang, XU Cai Fu, ZHAO Guo ning, huang yu Xin and WANG Qin Li Department of Gastroenterology, Tangdu Hospital, The Fourth Military Medical University, Xi′an 710038, Shaanxi Province, China

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关键词： tumor necrosis factor/metabolism laminin/blood hyaluronic acid/blood liver cirrhosis/blood

普罗布考联合瑞舒伐他汀对冠心病患者胆固醇代谢及炎症因子的影响研究

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标记免疫分析与临床 2017年第2期24卷 175-178,203页

作者：刘宁黄宇玲白华王志军华北理工大学附属医院河北唐山063000

目的研究普罗布考联合瑞舒伐他汀用药对冠心病患者胆固醇代谢及炎症因子的影响。方法选取60例冠心病患者为研究对象,随机分为观察组和对照组各30例。对照组给予瑞舒伐他汀治疗;观察组采用瑞舒伐他汀联合普罗布考治疗,比较两组患者的治... 详细信息

目的研究普罗布考联合瑞舒伐他汀用药对冠心病患者胆固醇代谢及炎症因子的影响。方法选取60例冠心病患者为研究对象,随机分为观察组和对照组各30例。对照组给予瑞舒伐他汀治疗;观察组采用瑞舒伐他汀联合普罗布考治疗,比较两组患者的治疗效果。结果观察组患者颈动脉IMT及斑块面积均低于对照组水平,差别有统计学意义(P<0.05)。观察组与对照组的治疗有效率分别为97%与80%,观察组的临床疗效优于对照组(P<0.05)。两组患者经过治疗后TC、TG、LDL-C水平及炎性因子hs-CRP、IL-6和TNF-α水平较均治疗前下降,而HDL-C水平则升高。且经过联合用药治疗后,观察组血脂水平改善程度、炎症因子下降程度均显著优于对照组,差异有统计学意义(P<0.05)。结论冠心病患者给予瑞舒伐他汀及普罗布考联合用药治疗能够显著改善血脂水平,提高胆固醇代谢和抑制炎症反应。

关键词：普罗布考瑞舒伐他汀冠心病胆固醇代谢炎症因子

Wind-tunnel experimental studies of the spatial snow distribution over grass and bush surfaces

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Journal of Hydrodynamics 2022年第1期34卷 85-93页

作者： Guang Li Jun-ming Qin Hong-xiang yu ning huang Key Laboratory of Mechanics on Disaster and Environment in Western China The Ministry of Education of ChinaLanzhou UniversityLanzhou730000China School of Civil Engineering and Mechanics Lanzhou UniversityLanzhou730000China College of Atmospheric Science Lanzhou UniversityLanzhou730000China School of Architecture Civil and Environmental EngineeringSwiss Federal Institute of Technology LausanneLausanneSwitzerland

The snow is one of the most important water resources in grassland in northern and western China, while the wind blowing snow due to the strong wind there is a common phenomenon, which can lead to heavy disasters to harm the local animal husbandry and transportation. A reasonable arrangement of the snow protection forests is one of the most economical and effective methods to prevent the wind blowing snow, and a great number of investigations were carried out for its wind block effects. However, the deposition patterns of the snowfall and the blowing snow in the forests are still largely unknown. In this study, the wind tunnel experiments are performed to investigate the influences of the vegetation (grass and bush) on the wind speed profiles and the spatial distribution of the accumulated snow, by using the bran as the snow substitute. The snow blocking abilities of two bush models are analyzed to show the effects of different coverages. The results show that the grass and the bush have different effects on the wind speed profiles, and the snow-blocking abilities of the vegetation and the resulting spatial distribution are determined by the amount of the snowfall, the wind speed, and the height and the coverage of the vegetation. For the engineering design, if the snow is required on the windward side of the vegetation or in the vegetation, the densely arranged forest belts are needed, if the snow is required to accumulate on the leeward side of the vegetation, the sparse forest belts can be used. This work would be helpful as a reference to the reasonable arrangement of the snow-protection forests in pastoral areas.

关键词： Wind tunnel experiment wind speed profile vegetation snow-protection forest snow blocking ability

Small modifications of endo-functionalized cavities lead to large changes in molecular interaction in water

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Science China Chemistry 2025年第1期 369-376页

作者： Song-Meng Wang Hao Nian Yan-Fang Wang Li-Shuo Zheng yu-Tao Zheng Yi-Wei Dong Liping huang Xiaoping Wang Wei Jiang Liu-Pan Yang Department of Chemistry Southern University of Science and Technology School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesGuangxi Normal University School of Pharmaceutical Science Hengyang Medical School University of South China

Studying molecular recognition in aqueous environments is crucial for understanding biological processes. Herein, we present a series of N-doped endo-functionalized anthracene-based cavities by introducing inward-directed pyridine units. The subtle modifications can significantly affect the binding properties of these receptors, which is similar to the mutations in biological systems. Combining theoretical calculations and molecular recognition experiments demonstrated that these “mutations” have an impact on the hydrophobicity and charge distribution of the hosts, consequently significantly influencing molecular *** is crucial for understanding the intricate mechanisms of molecular-level interactions in biological receptors.

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TLR9 mRNA在实验变态反应性神经炎中表达的研究

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现代免疫学 2009年第2期29卷 148-152页

作者：邓永宁徐宁安王玉忠黄国祥吴敏唐海源周文斌中南大学附属湘雅医院神经内科长沙410008

观察TLR9在实验性变态反应性神经炎（EAN）大鼠的坐骨神经、脾脏、外周血、淋巴结的动态表达,探讨TLR9与EAN的发病关系,为临床寻找新的治疗自身免疫性疾病的策略奠定理论基础。将36只Lewis大鼠随机分为抗原注射组（EAN组：n=4,4,4,4）,... 详细信息

观察TLR9在实验性变态反应性神经炎（EAN）大鼠的坐骨神经、脾脏、外周血、淋巴结的动态表达,探讨TLR9与EAN的发病关系,为临床寻找新的治疗自身免疫性疾病的策略奠定理论基础。将36只Lewis大鼠随机分为抗原注射组（EAN组：n=4,4,4,4）,完全弗氏佐剂组（CFA组：n=4,4,4,4）,生理盐水对照组（NS组：n=4）,EAN组用抗原乳剂（100μg P0 180~199,100μl完全弗氏佐剂,100μl生理盐水）进行免疫,观察免疫后大鼠的发病情况和组织病理学改变。分别在第7天、第16天、第24天,第33天处死动物,取坐骨神经根、脾脏、外周血和淋巴结,制作病理切片行HE染色和Weil染色观察其病理改变,利用RT-PCR检测TLR9的mRNA表达水平。结果：EAN大鼠在发病16 d时症状达高峰,第33天时好转,TLR9 mRNA整个实验过程中一直呈上升趋势,前后各时间点相比具有统计学意义（P〈0.05）,与对照组相比有显著差异。结论：TLR9在EAN的起始及效应阶段有着重要作用。

关键词：实验变态反应性神经炎 TLR 抗原提呈细胞

Role of nutrition in diabetes mellitus and infections

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World Journal of Clinical Cases 2025年第3期13卷 1-8页

作者： Xue-Lu yu Li-yun Zhou Xiao huang Xin-yue Li Ming-Ke Wang Ji-Shun Yang Naval Medical Center of PLA Naval Medical UniversityShanghai 200052China

In this editorial,we have commented on the article that has been published in the recent issue of World Journal of Clinical *** authors have described a case of unilateral thyroid cyst and have opined that the acute onset of infection may be linked to diabetes mellitus(DM).We have focused on the role of nutrition in the association between DM and *** with DM are at a high risk of infection,which could also be attributed to nutrition-related *** interventions for patients with diabetes are mainly based on a low-calorie diet,which can be achieved by adhering to a low-carbohydrate ***,dietary fiber supplementation is recommended to maintain the diversity of the gut ***,high-quality protein can prevent the increased risk of infection due to *** of vitamins C,vitamins A,vitamins D,and folic acid improves blood sugar control and facilitates immune *** deficiencies augment the risk of infection,but the relationship with diabetes is mostly U-shaped and a good intake should be maintained.

关键词： Diabetes mellitus Infection Macronutrients Vitamins Minerals

Cerebral fat embolism following autologous fat injection in facial reconstruction:A case report

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World Journal of Clinical Cases 2025年第2期13卷 50-58页

作者： Xiu-Ying Chen Fa Shen Chang Cheng yu-Han Wang Wen-Chao Cheng De-Zhi yuan Wen huang Department of Neurology Chongqing Emergency Medical CenterChongqing University Central HospitalChongqing 400000China Department of Neurology Xinqiao HospitalThe Army Medical University(Third Military Medical University)Chongqing 400000China

BACKGROUND Autologous fat injection in facial reconstruction is a common cosmetic *** cerebral fat embolism(CFE)as a complication is rare,it carries serious health *** SUMMARY We present a case of a 29-year-old female patient who developed acute CFE following facial fat filling *** the surgery,the patient experienced symptoms including headache,nausea,vomiting,and difficulty breathing,which was followed by neurological symptoms such as slurred speech and left-sided *** physical examination and auxiliary investigations,including blood tests,head and neck computed tomography angiography,and cranial magnetic resonance diffusion-weighted imaging,were performed upon *** clinical diagnosis was acute cerebral embolism following facial fat filling *** included measures to improve cerebral circulation,dehydration for intracranial pressure reduction,nutritional support,and rehabilitation therapy for left limb *** patient showed a significant improvement in symptoms after 2 weeks of *** recovered left limb muscle strength to grade 5,had clear speech,and experienced complete relief of *** Our case highlights the potential occurrence of severe complications in patients undergoing fat injection in facial *** prevent these complications,plastic surgeons should enhance their professional knowledge and skills.

关键词： Cerebral fat embolism Mechanical thrombectomy Thrombolysis Steroid therapy Symptomatic treatment Case report

ENTRESTO对心力衰竭大鼠血清cAMP、BNP、Gal-3及生存时间的影响

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标记免疫分析与临床 2018年第3期25卷 421-423,444页

作者：刘宁黄宇玲刘杰白华王志军华北理工大学附属医院河北唐山063000

目的研究ENTRESTO对心力衰竭大鼠血清c AMP、BNP、Gal-3及生存时间的影响。方法将SD雄性大鼠采用结扎冠状动脉左前降支近端的方法建立心肌梗死后心力衰竭大鼠模型,将其随机分为4组:正常组、建模组及低、高剂量实验组(sacubitril/缬沙坦,... 详细信息

目的研究ENTRESTO对心力衰竭大鼠血清c AMP、BNP、Gal-3及生存时间的影响。方法将SD雄性大鼠采用结扎冠状动脉左前降支近端的方法建立心肌梗死后心力衰竭大鼠模型,将其随机分为4组:正常组、建模组及低、高剂量实验组(sacubitril/缬沙坦,49/51 mg,97/103 mg),每组8只,灌胃给药。正常组及建模组给予同等剂量蒸馏水。分别于给药后3、9、18 h取大鼠静脉血,采用化学发光法测定BNP;采用ELISA检测法测定c AMP、Gal-3;观察小鼠生存时间。结果建模组大鼠个时段血清Gal-3、BNP含量较其他组最高,差异具有统计学意义(P<0.05),经ENTRESTO治疗后,低、高剂量组大鼠血清Gal-3、BNP水平均有不同程度下降,且高剂量组大鼠Gal-3、BNP水平低于低剂量组,高于正常组(P<0.05)。建模组大鼠个时段血清c AMP含量较其他组最低,差异差异具有统计学意义(P<0.05),经ENTREST治疗后,低、高剂量组大鼠血清c AMP水平均有不同程度升高,且高剂量组大鼠c AMP水平高于低剂量组,低于正常组,差异具有统计学意义(P<0.05)。建模组大鼠最早出现死亡个体,且最早全部死亡;经生存分析得知,与低、高剂量组对比,差异显著,具有统计学差异(P<0.05)。结论ENTRESTO能够降低心力衰竭大鼠血清中的Gal-3、BNP水平,升高c AMP水平,延长心力衰竭大鼠生存时间。

关键词： ENTRESTO 环磷酸腺苷(cAMP) B型脑钠钛(BNP) 半乳糖凝集素-3(Gal-3) 生存时间