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Large-scale error-tolerant programmable interferometer fabricated by femtosecond laser writing

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Photonics Research 2024年第3期12卷 I0028-I0040页

作者： ILYA KONDRATYEv vERONIKA IvANOvA SUREN FLDZHYAN ARTEM ARGENCHIEv nikita KOSTYUCHENKO SERGEY ZHURAvITSKII NIKOLAY SKRYABIN IvAN DYAKONOv MIKHAIL SAYGIN STANISLAv STRAUPE ALEXANDER KORNEEv SERGEI KULIK Quantum Technology Centre and Faculty of Physics M.V.Lomonosov Moscow State UniversityMoscow 119991Russia Russian Quantum Center Moscow 121205Russia Laboratory of Quantum Engineering of Light South Ural State UniversityChelyabinsk 454080Russia

We introduce a programmable eight-port interferometer with the recently proposed error-tolerant architecture capable of performing a broad class of *** interferometer has been fabricated with femtosecond laser writing,and it is the largest programmable interferometer of this kind to *** have demonstrated its advantageous error tolerance by showing an operation in a broad wavelength range from 920 to 980 nm,which is particularly relevant for quantum photonics due to efficient photon sources existing in this wavelength *** work highlights the importance of developing novel architectures of programmable photonics for information processing.

关键词： interferometer laser femtosecond

Highly selective/enantioselective Pt-ReOx/C catalyst for hydrogenation of L-malic acid at mild conditions

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Journal of Energy Chemistry 2018年第3期27卷 903-912页

作者： Bair S.Bal'zhinimaev Eugene A.Paukshtis Alexey P.Suknev nikita v.Makolkin Boreskov Institute of Catalysis SB RA5 Prospect Akademika Lavrentieva5Novosibirsk 630090Russia

The catalyst preparation strategy was based on a strict introduction sequence of rhenium and platinum precursors and their strong interaction with carbon support resulted in the formation of 0.5 nm Pt-Re Ox species of atomic dispersion, where platinum is metallic, while monolayer rhenium is partially oxidized（Re2＋）. The reaction kinetics was studied taking into account the process of L-malic acid association leading to the formation of inactive cyclic oligomeric species. High TOFs（ca. 50 h-1）, selectivities（ca. 99%）and stability of Pt-Re Ox/C catalysts in aqueous-phase hydrogenation of L-malic acid, which are close to those of the homogeneous pincer type complexes, were revealed at mild conditions（T = 90–130 ℃）. Taking into account that（i） hydrogenation reaction occurred 2–3 orders of magnitude faster than its racemization and（ii） association of L-malic acid dominates at low temperatures and in a concentrated solution,special reaction conditions that allow obtaining chemically and optically（ee 〉 99%） pure（S）-3-hydroxy-γ-butyrolactone and（S）-1,2,4-butanetriol were found. Basing on HAADF-STEM, EDX, XPS, and kinetic studies, the structure of active species and basic reaction pathways are proposed.

关键词： L-malic acid Hydrogenation Enantioselectivity Platinum Rhenium Atomic dispersion

Mechanism of the Initial Stage of Thermal Decomposition of Nitroguanidine

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火炸药学报 2023年第1期46卷 31-40页

作者： Boris E.Krisyuk Danila A.Markin Timofey M.Sypko viktor v.Zakharov nikita v.Chukanov Boris L.Korsunskiy Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences142432prosp.Academician Semenov1ChernogolovkaMoscow RegionRussia Plekhanov Russian University of Economics Department of Chemistry and Physics36 Stremyanny laneMoscow 117997Russia Lomonosov Moscow State University Faculty of Fundamental Physical and Chemical engineeringGSP-11 Leninskie Goryp.51Moscow 119991Russia N.N.Semenov Federal Research Center for Chemical Physics Russian Academy of Science 4 Kosygina StreetBuilding 1Moscow 119991Russia

A theoretical and experimental study of the thermal decomposition of nitroguanidine(NQ) has been carried out. various thermolysis channels were studied by quantum chemistry methods at the CCSD(or DLPNO-CCSD) level using the aug-cc-pvDZ basis set. It is shown that the lowest activation enthalpies(170-180kJ/mol) are characteristic of the reactions of NO2abstraction from the initial NQ and the reaction channel with the transfer of oxygen from the nitro group to carbon in the limiting stage. Additionally, the thermolysis of NQ was studied experimentally in a nonisothermal mode with heating rates from 1 to 10K/min. In these experiments, the weight loss of the sample, thermal effects, and mass spectra of the products were recorded. An analysis of the experimental data confirmed the results of a theoretical study of the mechanism of thermal decomposition of NQ. The main thermolysis products are N2O, HNCO, NH3, and NO2, which fully corresponds to quantum chemical calculations.

关键词： primary thermolysis steps quantum-chemical calculation mass spectrometry DSC TG

Calcium Carbide:From Elemental Carbon to Isotope-Economic Synthesis of^(13)C_(2)-Labeled Heterocycles

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Chinese Journal of Chemistry 2023年第21期41卷 2810-2818页

作者： Maria S.Ledovskaya vladimir v.voronin nikita R.valov Dmitriy E.Samoylenko Saint Petersburg State University Institute of ChemistryUniversitetsky prospect 26Peterhof198504 Russia

^(13)C-Carbon is the most available source of *** is a relatively inexpensive solid material,which can be easily converted to calcium carbide-^(13)C_(2).In current work,Ca^(13)C_(2)was used for in situ generation of^(13)C_(2)-acetylene in 1,3-dipolar cycloaddition and[4+2]cycloaddition *** the first time,1H-1,2,3-triazoles-4,5-^(13)C_(2)and isoxazoles-4,5-^(13)C_(2)were synthesized using calcium carbide-^(13)C_(2).A Diels-Alder type cycloaddition of 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine and Ca^(13)C_(2)was investigated,and the best way for the synthesis of 3,6-di(pyridin-2-yl)pyridazine-4,5-^(13)C_(2)was proposed for the first *** we perform a detailled description of NMR spectra of^(13)C_(2)-labeled triazoles,isoxazoles and 3,6-di(pyridin-2-yl)pyridazine.

关键词： Isotopic labeling Cycloaddition Click chemistry Sustainable Chemistry Calcium carbide

Generation of synchronized x-rays and mid-infrared pulses by Doppler-shifting of relativistically intense radiation from near-critical-density plasmas

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Matter and Radiation at Extremes 2023年第2期8卷 6-13页

作者： nikita A.Mikheytsev Artem v.Korzhimanov Lobachevsky State University of Nizhny Novgorod 603022 Nizhny NovgorodRussia Federal Research Center Institute of Applied Physics of the Russian Academy of Sciences 603950 Nizhny NovgorodRussia

It is shown that when relativistically intense ultrashort laser pulses are reflected from the boundary of a plasma with a near-critical density,the Doppler frequency shift leads to generation of intense radiation in both the high-frequency(up to the x-ray)and low-frequency(mid-infrared)*** efficiency of energy conversion into the wavelength range above 3μm can reach several percent,which makes it possible to obtain relativistically intense pulses in the mid-infrared *** pulses are synchronized with high harmonics in the ultraviolet and x-ray ranges,which opens up opportunities for high-precision pump–probe measurements,in particular,laser-induced electron diffraction and transient absorption spectroscopy.

关键词： pump intense relativistic

Blood–brain barrier and laser technology for drug brain delivery

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Journal of Innovative Optical Health Sciences 2017年第5期10卷 27-38页

作者： Oxana v.Semyachkina-Glushkovskaya Arkady S.Abdurashitov Elena I.Saranceva Eketerina G.Borisova Alexander A.Shirokov nikita v.Navolokin Saratov State University 83 Astrakhanskaya Str.Saratov 410012 Russia Institute of Electronics Bulgarian Academy of Sciences TsarigradskoChaussee 72 Sofia 1784Bulgaria Institute of Biochemistry and Physiology of Plants and Microorganisms Russian Academy of Sciences 13 Prospekt EntuziastovSaratov 410049Russia Saratov State Medical University Saratov 410010 Russia

Here,we discuss an important problem in medicine as development of efctive strategies for brain drug *** problem is related to the blood-brain barrier(BBB),which is a“customs”controlling the entrance of different molecules from blood into the brain protecting the normal function of central nervous system(CNS).We show three interfaces of anatomical side of BBB and two functional types of BBB一physical and transporter *** this protective mechanism is essential for health of CNS,it also creates a hindrance to the entry of drugs into the *** BBB was discovered over 100 years ago but till now,there is no efective methods for brain drug *** ane more than 70 approaches for overcoming BBB incuding physical,chenical and biological techniques but all of these tools have limitation to be widely used in clinical practice due to invasi venes,challenge in performing,very costly or lim-itation of drug *** therapy(PDT)is usual clinical method of surgical navigation for the resection of brain tumor and anti-cancer ***,the application of PDT is considered as a potential promising tool for brain drug delivery via opening of ***,we show the first sucoessful experimental results in this field discussing the adventures and disadv antages of PDT-related BBB disruption as well as altematives to overcome these limitations and possi ble mechanisms with new pathways for brain clearance via gly mphatic and lymphatic systems.

关键词： Blood-brain barrier laser technologies photodynamic therapy brain drug delivery

Comparison of CoMoS4/CoMoO4,CoMoS4/CoWO4 and CoMoS4/Co3v2O8 as A New Type of Electrode Materials for Supercapacitors

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Comparison of CoMoS4/CoMoO4,CoMoS4/CoWO4 and CoMoS4/Co3V2O8 ...

作者： SAZONOv nikita 兰州理工大学

学位级别：硕士

由于对环境污染的担心和化石能源的消耗,发展可替代的、并且具备高能量密度和功率密度的能量存储/转换装置具有特殊的意义。在众多电源设备中,超级电容器,也称为电化学电容器(ECs),因为其许多可取的属性,吸引了研究者极大的兴趣。即便如... 详细信息

由于对环境污染的担心和化石能源的消耗,发展可替代的、并且具备高能量密度和功率密度的能量存储/转换装置具有特殊的意义。在众多电源设备中,超级电容器,也称为电化学电容器(ECs),因为其许多可取的属性,吸引了研究者极大的兴趣。即便如此,超级电容器想要作为实际应用的能源装置,仍然需要具备高的能量密度和功率密度.就超级电容器的发展现状及动态而言,金属氧化物电极材料具有较大的发展前景和潜力。但在目前的报道中,对CoMoO,CoWO,CovO及CoMoS/材料的超级电容性能的研究仍然很少,而且制备方法比较复杂。其次单一的双金属氧化物性能比较单一,各有优缺点。据此,本文设计了以CoMoS为基体,构筑了CoMoS/CoMoO,CoMoS4/CoWO4 and CoMoS/CovO的复合材料.一、设计制备CoMoS/CoMoO复合材料。采用一步化学法,调控MoO/MoS材料中CoMoS与CoMoO的相对含量,制备出一系列不同形貌的CoMoS/CoMoO电极材料。采用XRD、SEM、TEM-Mapping等测试手段探究MoO/MoS材料的结构形貌特征,分析探CoMoS4/CoMoO4复合电极与纯CoMoS和CoMoO三种电极材料的电化学性能差异.制备的CoMoS/CoMoO纳米复合材料的比电容约为399 F g其倍率性能为80.5%,拥有较好的循环稳定性。二、在研究CoMoS/CoMoO电极材料的基础上,进一步制备并探究CoMoS/CoWO电极材料。采用XRD、SEM、TEM等手段对CoMoS/CoWO进行结构和形貌的表征,同时测试其电化学性能,从电负性发面探讨研究CoMoS/CoWO,CoMoS及CoWO的电化学性能及规律。制备的CoMoS/CoWO纳米复合材料的比电容约为528 F g其倍率性能为78.8%,拥有较好的循环稳定性。三、在研究CoMoS/CoMoO及CoMoS/CoWO等钴钼基电极材料的基础上,进一步探究CoMoS/CovO电极材料的电化学性能,制备了CoMoS/CovO,CovO及CoMoS电极材料,采用XRD、SEM、TEM等手段对三种材料进行结构和形貌的表征,同时测试对比这三种材料的其电化学性能,探讨研复合前后CoMoS/CovO,CovO及CoMoS的的电化学性能及规律。制备的CoMoS/CovO纳米复合材料的比电容约为584 F g其倍率性能为84.1%,拥有较好的循环稳定性。

关键词：超级电容器纳米复合材料 CoMoS4/Co3v2O8 CoMoS4/CoMoO4 CoMoS4/CoWO4

Tumor cell death visualization of renal cell carcinoma under the combined effect of the Gratiola officinalis extract and cyclophosphamide using fluorescent staining methods

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Journal of Innovative Optical Health Sciences 2021年第5期4卷 46-52页

作者： Artyom Mylnikov nikita Navolokin Dmitry Mudrak Natalya Polukonova Alla Bucharskaya Galina Maslyakova Saratov State Medical University named after V.I.Razumovsky 112 Bolshaya Kazachia Street Saratov 410012Russia National Research Saratov State University 83 Astrakhanskaya Street Saratov 410012Russia National Research Tomsk State University 36 Lenin Avenue Tomsk 634050Russia

Objective of the study:We used fluorescence imaging methods of apoptosis and necrosis in human renal carcinoma A498 tumor cells in vitro to reveal the indicated forms of cell death under the combined effect of flavonoid-containing extract of Gratiola officinalis and cytostatic(cyclo-phosphamide).Materials and methods:The dyes were propidium iodide and acridine orange,which were used in the"alive and dead"*** test helped us to identify the total number of dead cells in the forms of necrosis and apoptosis and the number of cells in which apoptosis had started,it was characterized by the appearance of apoptotic bodies or nucleus ***:We found the most pronounced cytotoxic activity at the ratio of extract of Gratiola officinalis and cyclophosphamide concentrations of 1∶*** number of living cells decreased when exposed to the ratio of extract and cytostatic concentrations of 2∶*** the ratio of concentration of the extract relative to the cytostatic increased to 3∶1,the cytostatic activity of the extract began to appear,the total number of tumor cells *** number of cells with nucleus pyknosis and the number of cells with apoptosis signs significantly increased at a 3∶1 ratio of extract and cytostatic concentrations,which confirms the presence of pro-apoptotic activity of the studied *** trend indicates the dependence of a certain form of cell death(apoptosis,necrosis)on the ratio of extract and cytostatic doses,and it also demon-strates the cytostatic and cytotoxic effects of this ***:Fluorescence methods of investigation in the"alive and dead"test allowed us to visualize the forms of cell death of human kidney carcinoma A498 by combined exposure to the fiavonoid-containing extract of Gratiola officinalis and cytostatic(cyclophosphamide)24 h after *** found that the combination with a concentration ratio of the extract and cyclophosphamide of 3:1 has the greatest effectiveness due to stimulation of t

关键词： A498 cell line Gratiola officinalis extract antitumor activity cytostatic activity flavonoids fluorescent methods kidney cancer

The optical tweezer of skyrmions

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npj Computational Materials 2020年第1期6卷 484-490页

作者： Xi-Guang Wang Levan Chotorlishvili vitalii K.Dugaev Arthur Ernst Igor v.Maznichenko nikita Arnold Chenglong Jia Jamal Berakdar Ingrid Mertig Józef Barnaś School of Physics and Electronics Central South University410083 ChangshaChina Institut für Physik Martin-Luther Universität Halle-Wittenberg06099 HalleSaaleGermany Department of Physics and Medical Engineering Rzeszów University of Technology35-959 RzeszówPoland Institute for Theoretical Physics Johannes Kepler UniversityAltenberger Straße 694040 LinzAustria Max Planck Institute of Microstructure Physics Weinberg 206120 HalleSaaleGermany Soft Materials Lab Linz Institute of Technology LITJohannes Kepler University LinzAltenberger Straße 694040 LinzAustria Department of Soft Matter Physics Institute for Experimental PhysicsJohannes Kepler UniversityAltenberger Straße 694040 LinzAustria Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education Lanzhou University730000 LanzhouChina Faculty of Physics Adam Mickiewicz University61-614 PoznańPoland

In a spin-driven multiferroic system,the magnetoelectric coupling has the form of effective dynamical Dzyaloshinskii–Moriya(DM)***,it is confirmed,for instance,for Cu_(2)OSeO_(3),that the DM interaction has an essential role in the formation of skyrmions,which are topologically protected magnetic *** skyrmions are very robust and can be manipulated through an electric *** external electric field couples to the spin-driven ferroelectric polarization and the skyrmionic magnetic texture emerged due to the DM *** this work,we demonstrate the effect of optical *** a particular configuration of the external electric fields it is possible to trap or release the skyrmions in a highly controlled *** functionality of the proposed tweezer is visualized by micromagnetic simulations and model analysis.

关键词： interaction field instance