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Design of Biologically Active Macromolecular Ligands and Their Luminescent Complexes with Terbium Ions

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Chinese Journal of Polymer Science 2024年第5期42卷 604-611,I0007页

作者： Tatiana N.Nekrasova Andrei I.Fischer Natalia A.Nesterova Anatoliy v.Dobrodumov Anzhelika v.Garshinina Olga D.Shuvaeva natalya.v.zakharova Evgenii F.Panarin Institute of Macromolecular Compounds Russian Academy of Sciences31 Bolshoy pr.St Petersburg199004Russia Smorodintsev Research Institute of Influenza Russian Ministry of Health15/17 ul.prof.PopovaSt Petersburg197376Russia

Water-soluble copolymers of p-methacrylamidobenzoic acid(MABA)with neutral comonomers(N-vinylpyrrolidone(vP),N-methyl-N-vinylacetamide(MvAA),N-methacryloyl glucosamine(MAG))and anionic comononer sodium styrene sulfonate(NaSS)were synthesized by radical *** interactions between the prepared copolymers and Tb^(3+)ions in aqueous solutions were studied;the significant influence of chemical structure of a comonomer on luminescence intensity of Tb^(3+)complexes with the copolymers was *** luminescence intensity of Tb^(3+)complexes with the copolymers containing N-vinylamide units(vP,MvAA)is three times more intense than that observed for the complexes between Tb^(3+)and MAG-containing *** the case of NaSS-containing copolymers,the luminescence intensity is controlled by the values of binding constants between Tb^(3+)and MABA and the content of MABA units in a *** studied copolymers and their complexes with Tb^(3+)have low cytotoxicity and a pronounced antiviral activity against human respiratory syncytial virus.

关键词： Luminescence Water-soluble copolymers Lanthanide complexes Antiviral activity Cytotoxicity

Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)

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Chinese Journal of Polymer Science 2024年第3期42卷 333-343,I0007页

作者： Elizaveta v.Batishcheva Nikolay N.Smirnov natalya v.Bobrova Maria P.Sokolova Michael A.Smirnov Institute of Macromolecular Compounds Russian Academy of SciencesBolshoy pr.31Saint Petersburg 199004Russia

Green method for preparation of ion-conducting membranes(ICM) based on bacterial cellulose nanofibers(CNF) modified by a copolymer of sodium acrylate and 2-acrylamido-2-methylpropanesulfonic acid was elaborated. FTIR and NMR data confirmed grafting of polyacrylate onto cellulose surface. Formation of porous structure of the ICM was controlled by SEM and AFM. The maximal ionic conductivity of the membranes reaches 1.5 and 3.1 mS·cm^(-1)(60 ℃ and 98% relative humidity) when they are saturated with water or H_2SO_4(1 mol·L^(-1)) electrolyte,respectively. Prepared ICM was tested as a separator in a symmetrical supercapacitor with electrodes based on polyaniline hydrogel. The assembled cell demonstrate ability to operate at high current density up to 100 A·g^(-1) maintaining specific capacitance 165 F·g^(-1). Maximal specific capacitance of 289 F·g^(-1) was achieved at current density 1 A·g^(-1). Retaining of 90% of initial capacitance after 10000 of charge-discharge cycles proves high electrochemical stability of prepared ICM.

关键词： Bacterial cellulose Ion conductivity Porous membrane Supercapacitor

Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor

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Chinese Journal of Polymer Science 2024年第8期42卷 1049-1059页

作者： Maria P.Sokolova vitaly K.vorobiov Nikolay N.Smirnov Ivan S.Kuryndin natalya v.Bobrova Michael A.Smirnov Institute of Macromolecular Compounds Russian Academy of SciencesBolshoy pr.31Saint Petersburg 199004Russia

The aim of this study was to develop self-healable and robust elect roconductive film based on polyaniline copolymer for application as electrode in flexible *** this purpose,the electroconductive polymer brushes(EPB)was *** synthesis of EPB is based on graft polymerizations of acrylamide(AAm)on poly(vinyl alcohol)(PvA)with formation of PvA-PAAm polymer brush and subsequent graft copolymerization of aniline and p-phenylenediamine on PvA-PAAm resulting in formation of EPB with electroconducting copoly(aniline-co-pphenylenediamine)(PAPh DA).It was found that the ratio between PvA and PAAm at the first stage greatly influence the electrochemical performance of the *** films were prepared by casting of EPB solution with subsequent *** of electrical current distribution through the film with AFM reveal more uniform distribution of PAPhDA in EPB in comparison with reference PvA-PAPhDA and PAAm-PAPhDA *** was demonstrated that mechanical cha racteristics and electrical conductivity values of films restore at large extent after curring and self-healing under optimal relative humidity level(58%).The flexile supercapacitor cell with EPB film electrodes demon strate specific capacitance 602 mF·cm^(-2)at the current density of 1 mA·cm^(-2)and retention 94%of initial capacitance after 5000 charge/discharge cycles.

关键词： Polymer brush Polyaniline Flexible supercapacitor Self-healing Electroconducting film

Detailed seismic zoning of the East Kazakhstan region in the Republic of Kazakhstan

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Geodesy and Geodynamics 2024年第2期15卷 156-165页

作者： natalya v.Silacheva N.P.Stepanenko O.K.Kurilova A.D.Kudabayeva A.T.Danabayeva Institute of Seismology Ministry of Emergency SituationsAlmaty 050060Kazakhstan

Kazakhstan is currently drafting new construction regulations that comply with the major provisions of the *** regulations are created on the basis of seismic zoning maps of various degrees of detail,developed by our Institute of Seismology using a new methodological approach for *** article is about creating the first normative map of the Detailed Seismic Zoning on a probabilistic foundation for the Republic of Kazakhstan’s East Kazakhstan *** carried out the probabilistic assessment of seismic hazard using a methodology consistent with the main provisions of Eurocode 8and updated compared with that used in developing maps of Kazakhstan’s General Seismic Zoning and seismic microzoning of *** most thorough and current data accessible for the area under consideration were combined with contemporary analytical *** have been done to not only the databases being used but also the way seismic sources were shown,including active faults *** a scale of 1:1000000,precise seismic zoning maps of the East Kazakhstan region were created for two probabilities of exceedance:10%and 2%in 50 years in terms of peak ground accelerations and macroseismic *** obtained seismic hazard distribution is generally consistent with the General Seismic Zoning of Kazakhstan’s previous ***,because active faults were included and a thoroughly revised catalog was used,there are more pronounced zones of increased danger along the fault in the western part of the *** the west of the territory,acceleration values also increased due to a more accurate consideration of seismotectonic *** maps are the basis for developing new state building regulations of the Republic of Kazakhstan.

关键词： Probabilistic seismic hazard assessment Detailed seismic zoning Peak ground acceleration Microseismical intensity

Semen microbiota and cytokines of healthy and infertile men

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Asian Journal of Andrology 2022年第4期24卷 353-358页

作者： Oleg v Bukharin natalya B Perunova Elena v Ivanova Irina N Chaynikova Anastasia v Bekpergenova Taisiya A Bondarenko Michael D Kuzmin Institute of Cellular and Intracellular Symbiosis Ural Department of the Russian Academy of SciencesOrenburg Federal Research Center UD of RASOrenburg 460014Russia

In this study,we determined the levels of cytokine secretory inhibitors and the microbiota biofilms of semen from healthy and infertile subjects.A total of 118 clinical bacterial isolates were isolated and *** secretory inhibitors were determined based on the difference in cytokine content between the control and experimental samples of cell-free supernatants of isolated *** formation was studied by determining the adhesion of microorganisms to the surface of a 96-well sterile plate and expressed as the optical density at 630 nm(OD_(630)).Cell-free supernatants of Staphylococcus contained higher levels of secretory inhibitor of cytokines in conditionally healthy than in infertile *** contrast,in infertile men,the ability to reduce cytokine levels was more characteristic of Enterococcus and *** Staphylococcus,Corynebacterium,and Enterococcus isolated from infertile subjects showed a greater ability to form biofilms than the same bacteria isolated from healthy *** research is needed on this topic,since it is necessary to determine the relationships between decreased secretory inhibitors of cytokines,production of biofilms by bacteria in semen,and *** is likely that the ability of microorganisms to change the concentration of cytokines and increase the level of biofilm formation in semen may be associated with minimal impairments of fertilizing ability,which are not detected using other methods.

关键词： biofilms infertility microbiota secretory inhibitor of cytokines semen

Impact of mine waters on chemical composition of soil in the Partizansk Coal Basin, Russia

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International Soil and Water Conservation Research 2019年第1期7卷 57-63页

作者： Ola Arefieva Alina v.Nazarkina natalya v.Gruschakova Julia E.Skurikhina vera B.Kolycheva Far Eastern Federal University 8Sukhanova str.690950VladivostokRussian Federation Institute of Biology and Soil Science Far-Eastern BranchRussian Academy of Sciences159Stoletia prospect690022 VladivostokRussian Federation Pacific State Medical University 2Ostryakov Avenue690002VladivostokRussian Federation

Partizansk Coal Basin,located in the south of the Russian Far Eastern Region,was intensively mined from 1918 until *** it was mostly explored by underground excavation,the natural landscapes were transformed into anthropogenic *** the mines closed,ground subsidence occurred widely,especially in areas near the waste *** caused water tables to rise to the surface and pollute the *** of the hydrochemical composition of the mine waters were conducted in 2011-2013,and showed low alkalinity and average level of *** can be explained by the fact that while going up through soil mass,the mine waters lost their much of their pollutants due to soil buffering All mine water samples contain thermo-tolerant coliform bacteria *** that indicates a source of fresh fecal *** research indicates increased hydrocarbon ion concentrations in mine waters,especially in autumn,that resulted in accumulation of chromium and copper compounds,which can cause soil pollution.A strong relationship between the chemical composition of the mine waters and soil extracts was found within areas of unregulated groundwater discharge on the *** negative correlation between pH and content of metal compounds including chromium and copper was found at the 'Avangard' mine (r =-0.95);and between alkalinity and chromium content at the 'Glubokaya' mine (r =-0.94).

关键词： Mine waters Soil solution Chemical composition Abandoned coal mines Bacteriological contamination of water

Synergistic effect of chitin nanofibers and polyacrylamide on electrochemical performance of their ternary composite with polypyrrole

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Journal of Energy Chemistry 2018年第3期27卷 843-853页

作者： Michael A.Smirnov Maria P.Sokolova natalya v.Bobrova Alexander M.Toikka Pierfrancesco Morganti Erkki Lahderanta Lappeenranta University of Technology 53850 LappeenrantaFinland Institute of Macromolecular compounds Russian Academy of Sciences199004 Saint PetersburgRussia St.Petersburg State University PeterhofSaint Petersburg 198504Russia Dermatological Institute II University of Naples80138 NaplesItaly

Development of simple methods for preparation of polymeric electrode materials with nanofibrous network structure is a perspective way toward cheap supercapacitors with high specific capacitance and energy density. In this work one-pot synthesis of electroactive ternary composite based on polypyrrole, polyacrylamide and chitin nanofibers with beneficial morphology was elaborated. Ternary system demonstrates better electrochemical performance in comparison with both polypyrrole–polyacrylamide and polypyrrole–chitin binary composites. Possible mechanism of synergistic effect of simultaneous influence of polyacrylamide and chitin nanofibers on the formation of composite＇s structure is *** highest attained specific capacitance of electroactive polypyrrole in ternary composite reached 249 F/g at 0.5 A/g and 150 F/g at 32 A/g. Symmetrical supercapacitor was assembled using the elaborated electrode material. High specific capacitance 89 F/g and good cycling stability with capacitance retention of 90% after 3000 cycles at 2 A/g were measured.

关键词： Energy materials Nanocomposites Natural fibers Electrical properties

Does ADS 9346 have a low-mass companion?

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Research in Astronomy and Astrophysics 2021年第11期21卷 202-212页

作者： Olga v.Kiyaeva Maxim Yu.Khovritchev Agrippina M.Kulikova natalya v.Narizhnaya Tatyana A.vasilyeva Arina A.Apetyan Central Astronomical Observatory Russian Academy of Sciences65/1 Pulkovskoye ChausseeSt.Petersburg196140Russia

Based on the photographic and CCD observations of the relative motion of the A and B components of the binary system ADS 9346 obtained with the 26-inch refractor of Pulkovo Observatory during 1979–2019,we discover an invisible companion associated with star *** of the ephemerides with the positional and spectroscopic observations allowed us to calculate the preliminary orbit of the photocenter(P=15 yr).The minimal mass of the companion is approximately 0.13 *** existence of the invisible low-mass companion is implied by the IR-excess based on IRAS *** confirm this,additional observations of the radial velocity near the periastron need to be carried out.

关键词： (stars:)binaries:visual stars:low-mass stars:individual(ADS 9346)

Principal Features of Building Social Accounts Matrix and Improving Statistical Database for Eco-countries

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Chinese Business Review 2014年第10期13卷 611-623页

作者： vilayat valiyev, Malik Mehdiyev Arzu Suleymanov Elnur Alakbarov Rauf Musayev Elvira Nagoibaeva natalya zakharova Institute for Scientific Research on Economic Reforms (ISRER) Baku Azerbaijan Elvira Nagoibaeva Kyrgyz Economic University Bishkek Kyrgyzstan National Statistical Committee Bishkek Kyrgyzstan

With common borders of the population, total area, and GDP （PPP-based） of Economic Cooperation Organization （ECO） member states are estimated as 416 million persons, 7.9 million m2, and US$2.7 trillion respectively （2010 data）. Although heterogeneous in the extent, there is economic development, overall, with serious energy and transport-transit relations among countries that is reflected in growing trade turnover year-by-year. However, there are still rather unused resources and capacity in such areas of cooperation among countries as exchange of energy, transport services, agricultural and industrial goods, use of opportunities for tourism, promoting investment and innovation processes and other areas. Certainly, maximum and optimal use of these resources calls for availability of analytical means capable of accounting for relations both within member states and among them. The implementation of computable general equilibrium （CGE） modeling in each member state would thus be of great significance in resolution of these problems both in terms of accounting for input-output linkages within the countries as well as enabling impact of main trading partners and goods and services among countries. The analysis carried out indicates that there are a number of problems in application of CGE model in most of the member states. As such, input-output tables are not compiled in some countries, while in others despite the fact that these tables are compiled, there are no attempts to build the model, yet in other countries, even if the CGE model is implemented, there are difficulties in taking into account the real results in the face of serious problems related to improving national accounts system database. Summarizing these problems, it is possible to conclude that to ensure the application of a CGE model,there is a great need to work out procedures of compilation of a social accounts matrix （SAM） that lies on the basis of this model, for which the relevant statistics of a m

关键词： social accounts matrix (SAM) system of national accounts (SNA) input-output table CGE model ECO countries