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阴离子双子表面活性剂分子结构对其溶液表、界面活性的影响

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西安石油大学学报（自然科学版） 2020年第5期35卷 98-107页

作者：胡睿智唐善法金礼俊邓虹 musa mpelwa 长江大学石油工程学院湖北武汉430100 长江大学非常规油气湖北省协同创新中心湖北武汉430100

在合成一系列阴离子双子表面活性剂的基础上,使用表面张力仪和旋转滴界面张力仪考察了阴离子双子表面活性剂分子结构(亲水头基、疏水碳链、间隔基团)对其溶液表、界面活性的影响。研究发现,疏水链和间隔基团碳数相同时,磺酸盐双子表面... 详细信息

在合成一系列阴离子双子表面活性剂的基础上,使用表面张力仪和旋转滴界面张力仪考察了阴离子双子表面活性剂分子结构(亲水头基、疏水碳链、间隔基团)对其溶液表、界面活性的影响。研究发现,疏水链和间隔基团碳数相同时,磺酸盐双子表面活性剂具有更高的表面活性,羧酸盐双子表面活性剂的界面活性更高。间隔基团碳数相同时,随着疏水链碳数增加,双子表面活性剂的表面活性、降低溶液表面张力的能力、吸附效率均先上升后降低,界面活性升高。疏水链碳数相同时,随着间隔基团碳数增加,双子表面活性剂表面活性、降低溶液表面张力的能力、吸附效率均先上升后降低,界面活性降低。结果表明,阴离子双子表面活性剂分子结构的变化影响到其溶液的表、界面活性,在一定的条件下,调整阴离子双子表面活性剂分子结构可以使其溶液具有较为优异的表、界面活性。

关键词：阴离子双子表面活性剂分子结构表面活性界面活性

低界面张力阴离子双子表面活性剂黏弹流体的构筑与性能评价

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油田化学 2020年第1期37卷 93-101页

作者：胡睿智唐善法金礼俊 musa mpelwa 冯树云姜昭文长江大学石油工程学院湖北武汉430100 长江大学非常规油气湖北省协同创新中心湖北武汉430100

为了有效提高我国低渗、特低渗油藏采收率,提出了构筑低界面张力阴离子双子表面活性剂黏弹流体的思路,以满足驱油剂同时提高波及效率及洗油效率、注入性好、无色谱分离的要求。本文以阴离子双子表面活性剂分子结构对其溶液黏度、黏弹性... 详细信息

为了有效提高我国低渗、特低渗油藏采收率,提出了构筑低界面张力阴离子双子表面活性剂黏弹流体的思路,以满足驱油剂同时提高波及效率及洗油效率、注入性好、无色谱分离的要求。本文以阴离子双子表面活性剂分子结构对其溶液黏度、黏弹性、界面活性影响为研究基础,构筑了GCET黏弹流体,并评价了其主要性能及油藏环境适应性。研究表明,羧酸盐双子表面活性剂溶液流变性及界面活性优于磺酸盐双子表面活性剂的;疏水链碳数较大(m=18),间隔基团碳数适中(s=3)的羧酸盐双子表面活性剂溶液流变性能较好;疏水链碳数较大(m=18),间隔基团碳数较小(s=2)的羧酸盐双子表面活性剂溶液界面活性较高。以此,优化分子结构设计并构筑的GCTE流体具有良好的黏度行为、黏弹性、界面活性及油藏温度及矿化度适应性。在模拟矿化度(12000 mg/L)条件下,0.5%的GCTE黏弹流体黏度12.68 mPa·s;溶液黏弹性较好(=0.366<1、松弛时间=11.302 s);稳态油水界面张力达到2.93×10^-3mN/m。GCTE黏弹流体在非常规油藏提高采收率方面具有良好的应用前景。

关键词：阴离子双子表面活性剂黏弹流体黏度黏弹性油水界面张力

Comparative seismic design optimization of spatial steel dome structures through three recent metaheuristic algorithms

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Frontiers of Structural and Civil Engineering 2022年第1期16卷 57-74页

作者： Serdar CARBAS musa ARTAR Department of Civil Engineering Karamanoglu Mehmetbey UniversityKaraman 70200Turkey Department of Civil Engineering Bayburt UniversityBayburt 69000Turkey

Steel dome structures,with their striking structural forms,take a place among the impressive and aesthetic load bearing systems featuring large internal spaces without internal *** this paper,the seismic design optimization of spatial steel dome structures is achieved through three recent metaheuristic algorithms that are water strider(WS),grey wolf(GW),and brain storm optimization(BSO).The structural elements of the domes are treated as design variables collected in member *** structural stress and stability limitations are enforced by ASD-AISC ***,the displacement restrictions are considered in design *** metaheuristic algorithms are encoded in MATLAB interacting with SAP2000 for gathering structural reactions through open application programming interface(OAPI).The optimum spatial steel dome designs achieved by proposed WS,GW,and BSO algorithms are compared with respect to solution accuracy,convergence rates,and reliability,utilizing three real-size design examples for considering both the previously reported optimum design results obtained by classical metaheuristic algorithms and a gradient descent-based hyperband optimization(HBO)algorithm.

关键词： steel dome optimization water strider algorithm grey wolf algorithm brain storm optimization algorithm hyperband optimization algorithm

EFFECT OF THE COMPOSITION OF m-CRESOL/H_2O SOLVENT ON HYDRODYNAMIC PROPERTIES OF NYLON 6

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Chinese Journal of Polymer Science 2006年第4期24卷 369-377页

作者： musa Kaleem Baloch Mohsan Nawaz Department of Chemistry

The intrinsic viscosity [η], Huggins constant （Ku）, [η]0, α^3 and flow activation energy values of nylon 6 have been measured in wateηm-cresol （0/100-20/80） systems at different temperatures （20-60℃）. It has been found that the intrinsic viscosity, [η]0 and α^3 increase with the increase in water contents in m-cresol up to 15% and then decrease. They increase with the increase in temperature irrespective of solvent composition. It has been noted that the percent increase of α^3 is the highest at 60℃ and the lowest at 20℃ for a particular solvent system. The intrinsic viscosity data obey Arrhenius equation over the considered conditions. The activation energy and the KH values decrease very sharply with the addition of water, giving a minimum value at 15% of water and then increase slowly. The variation of all the parameters has been explained in terms of variation in thermodynamic quality of solvent with the addition of water to m-cresol and change in temperature, resulting in the change of conformational and orientational properties of polymer molecules. This change of solvent quality also results in variation of selective sorption of solvent over the polymer, such as hydrogen bonding, etc.

关键词： Intrinsic viscosity Huggins constant Thermodynamic quality of solvent Activation energy Hydrogen bonding Conformation Selective sorption.

Monte Carlo Study of CO-NO Catalytic Surface Reaction Including CO-CO Repulsion

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Chinese Physics Letters 2006年第4期23卷 1034-1037页

作者： Waqar Ahmad musa Kaleem Baloach Physics Research Division Pakistan Institute of Nuclear Science and Technology PO Nilore Islamabad Pakista Department of Chemistry Gomal University D.I. Khan Pakistan

The CO-NO reaction on a catalytic surface is studied by using Langmuir-Hinshclwood thermal mechanism with Monte Carlo computer simulation. In this model, a novel concept of CO CO repulsion is introduced, which has experimental evidence due to the formation of dipoles when these molecules are chemisorbed on the surface. The system is investigated by applying two approaches of NO dissociation. In the first ***, NO always decomposes into N and O before adsorption on the surface, In the second case, NO adsorbs on the surface molecularly and then dissociates into N and O if a vacancy is present in its adjacent neighbourhood. The steady state reactive window （i.e. the continuous production of CO2 and N2） is obtained only with the diffusion of N-atoms on the surface, which extends with CO-CO repulsion in the first, case. Itowever, in the second case, reactive window is obtained with CO-CO repulsion alone, The reactive window width in this case is reasonably large. The first-order phase transition is eliminated in both the cases with CO-CO repulsion.

关键词： KINETIC PHASE-TRANSITIONS SQUARE LATTICE HEXAGONAL SURFACES REACTIONMODEL NITRIC-OXIDE SIMULATION MECHANISM

Miscibility between PS and PSAN Affected by Solvent and Temperature of the System

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Chinese Journal of Polymer Science 2014年第11期32卷 1442-1449页

作者： Zafarullah Khan Marwat musa Kaleem Baloch Department of Chemistry Gomal University Dera Ismail Khan Khyber PakhtoonkhwaPakistan

The influence of solvent on the miscibility of polystyrene（PS） and poly（styrene-co-acrylonitrile）（PSAN） blends has been investigated viscometrically. The miscibility of different PS/PSAN blend（30/70, 50/50 and 70/30） compositions in acetone and benzene at 20, 30, and 40 °C was investigated on the basis of the sign of Chee（ΔB and ）, and Sun’s（α） criteria. The values of these parameters were evaluated from the analyses of reduced viscosity data of binary（solvent/polymer） and ternary（solvent/polymer1/polymer2） polymer systems. These investigations indicated partial miscibility for both the blend systems. However, PS/PSAN/acetone blend system showed somewhat higher partial miscibility than the PS/PSAN/Benzene blend system highlighting the impact of solvent over the polymer-polymer interactions and hence their miscibility. The results obtained through viscometry were also corroborated by the refractive index and density results for the blends under study. The effect of temperature on miscibility in both the cases was almost negligible.

关键词： Miscibility Polystyrene Poly(styrene-co-acrylonitrile) Viscosity Density Refractive index.

Budd-Chiari syndrome:Etiology,pathogenesis and diagnosis

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World Journal of Gastroenterology 2007年第19期13卷 2693-2696页

作者： musa Aydinli Yusuf Bayraktar Gastroenterology Department Hacettepe University School of Medicine Ankara Turkey

Budd-Chiari syndrome is a congestive hepatopathy caused by blockage of hepatic veins. This syndrome occurs in 1/100 000 in the general population. Hypercoagulable state could be identified in 75% of the patients; more than one etiologic factor may play a role in 25% of the patients. Primary myeloproliferative diseases are the leading cause of the disease. Two of the hepatic veins must be blocked for clinically evident disease. Liver congestion and hypoxic damage of hepatocytes eventually result in predominantly centrilobular fibrosis. Doppler ultrasonography of the liver should be the initial diagnostic procedure. Hepatic venography is the reference procedure if required. Additionally liver biopsy may be helpful for differential diagnosis. The prognosis of the chronic form is acceptable compared to other chronic liver diseases.

关键词： Budd-Chiari syndrome Etiology Pathogenesis Diagnosis

Performance analysis of empirical models for predicting rock mass deformation modulus using regression and Bayesian methods

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Journal of Rock Mechanics and Geotechnical Engineering 2020年第6期12卷 1263-1271页

作者： Adeyemi Emman Aladejare musa Adebayo Idris Oulu Mining School University of OuluOuluFinland Division of Mining and Geotechnical Engineering Department of CivilEnvironmental and Natural Resources EngineeringLuleåUniversity of TechnologyLuleåSweden

Deformation modulus of rock mass is one of the input parameters to most rock engineering designs and *** field tests for determination of deformation modulus are cumbersome,expensive and *** has prompted the development of various regression equations to estimate deformation modulus from results of rock mass classifications,with rock mass rating(RMR)being one of the frequently used *** regression equations are of different types ranging from linear to nonlinear functions like power and *** method has recently been developed to incorporate regression equations into a Bayesian framework to provide better estimates of geotechnical *** question of whether Bayesian method improves the estimation of geotechnical properties in all circumstances remains ***,a comparative study was conducted to assess the performances of regression and Bayesian methods when they are used to characterize deformation modulus from the same set of RMR data obtained from two project *** study also investigated the performance of different types of regression equations in estimation of the deformation ***,probability distributions and prediction indicators were used to assess the performances of regression and Bayesian methods and different types of regression *** was found that power and exponential types of regression equations provide a better estimate than linear regression *** addition,it was discovered that the ability of the Bayesian method to provide better estimates of deformation modulus than regression method depends on the quality and quantity of input data as well as the type of the regression equation.

关键词： Deformation modulus Rock mass Regression equation Bayesian method Performance analysis Rock mass rating(RMR)

Antimicrobial Property of 2-Hydroxypropane-1,2,3-Tricarboxylic Acid Isolated from Citrus microcarpa Extract

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Agricultural Sciences in China 2009年第7期8卷 880-886页

作者： Seong Wei Lee musa Najiah Department of Fishery and Aquaculture Faculty of Agrotechnology and Food Science Universiti Malaysia Terengganu

This article described antimicrobial property and structure analysis of 2-hydroxypropane-1,2,3-tricarboxylic acid isolated from the crude extract of Citrus microcarpa. Presently, there was no report on compound from C. microcarpa that possessed antimicrobial property against fish pathogenic bacteria. Therefore, in this study, the bioactive principle in C. microcarpa extract was isolated using thin layer chromatography. It＇s structure was elucidated based on nuclear magnetic resonance （NMR） spectroscopic data, such as proton NMR （1HNMR）, correlation spectroscopy, carbon 13 NMR, and heteronuclear multiple bond correlation data. This study showed that the bioactive compound isolated from C. microcarpa was 2-hydroxypropane-1,2,3-tricarboxylic acid monohydrate. The minimum inhibitory concentration （MIC） values of crude C. microcarpa extract and its bioactive component, 2-hydroxypropane-1,2,3-tricarboxylic acid as well as commercially available synthetic 2-hydroxypropane-1,2,3-tricarboxylic acid, were determined against 18 isolates of Edwardsiella tarda and 7 bacterial reference strains, namely, Escherichia coli （ATCC 25922）, Citrobacter freundii （ATCC 8090）, Aeromonas hydrophila （ATCC 49140）, Pseudomonas aeruginosa （ATCC 35032）, Streptococcus agalatiae （ATCC 13813）, E. tarda （ATCC 15947）, and Yersinia enterocolitica （ATCC 23715）, using two-fold microdilution method. The MIC values for both the natural 2-hydroxypropane-1,2,3-tricarboxylic acid and the synthetic one were ranging from 15.6 to 62.5 mg mL-1, whereas that of the crude extract was ranging from 7.8 to 31.3 mg mL-1. These findings showed that both the crude extract and its bioactive component might have potential as antimicrobial agent for aquaculture use.

关键词： antimicrobial property 2-hydroxypropane-1,2,3-tricarboxylic acid Citrus microcarpa NMR MIC