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Fe-Ni-F electrocatalyst for enhancing reaction kinetics of water oxidation

Chinese Journal of Structural Chemistry 2024年第2期43卷 60-65页

作者： Yi Zhang Biao Wang Chao Hu muhammad Humayun Yaping Huang Yulin Cao Mosaad Negem Yigang Ding Chundong Wang School of Chemical Engineering and Pharmacy Key Laboratory of Green Chemical Process of Ministry of EducationKey Laboratory of Novel Reactor and Green Chemical Technology of Hubei ProvinceWuhan Institute of TechnologyWuhan430073PR China Energy Waterand Environment LabCollege of Humanities and SciencesPrince Sultan UniversityRiyadh11586Saudi Arabia School of Integrated Circuits Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan430074PR China Physics Laboratory Industrial Training CenterShenzhen Polytechnic UniversityShenzhen518055PR China Chemistry Department Faculty of ScienceFayoum UniversityFayoum63514Egypt

Highly active and low-cost oxygen evolution reaction(OER)catalytic electrodes are extremely essential for exploration of green hydrogen via water ***,an advanced Fe-Ni-F electrocatalyst is fabricated by a facile annealing strategy using ammonium fluoride,of which the structure feature is unveiled by XRD,FESEM,TEM,EDS,BET,and XPS *** as-prepared Fe-Ni-F addresses a low overpotential of 277 mV and a small Tafel slope of 49 mV dec^(-1)at a current density of 10 mA cm^(-2),significantly outperforming other control samples as well as the state-of-the-art RuO_(2).The advanced nature of our Fe-Ni-F catalyst could also be further evidenced from the robust stability in KOH alkaline solution,showing as 5.41%degradation after 24 h continuous *** analysis,it suggests that the decent catalytic activity should be attributed to the formed bimetallic(oxy)hydroxides because of the introduction of fluoride and the synergistic effect of iron and nickel towards oxygen *** work represents the potential of Fe-and/or Ni-based fluoride as efficient catalyst for low-energy consumption oxygen generation.

关键词： Fluoride Oxygen evolution reaction Fe-Ni-F Reaction kinetics

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A novel medical image data protection scheme for smart healthcare system

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CAAI Transactions on Intelligence Technology 2024年第4期9卷 821-836页

作者： Mujeeb Ur Rehman Arslan Shafique muhammad Shahbaz Khan Maha Driss Wadii Boulila Yazeed Yasin Ghadi Suresh Babu Changalasetty Majed Alhaisoni Jawad Ahmad School of Computer Science and Informatics Cyber Technology InstituteDe Montfort UniversityLeicesterUK Department of Biomedical Engineering University of GlasgowGlasgowUK School of Computing Engineering and the Built EnvironmentEdinburgh Napier UniversityEdinburghUK Robotics and Internet‐of‐Things Laboratory Prince Sultan UniversityRiyadhSaudi Arabia Department of Computer Science Al Ain UniversityAl AinUnited Arab Emirates Department of Computer Engineering College of Computer Science King Khalid UniversityAbhaSaudi Arabia Computer Sciences Department College of Computer and Information SciencesPrincess Nourah bint Abdulrahman UniversityRiyadhSaudi Arabia

The Internet of Multimedia Things(IoMT)refers to a network of interconnected multimedia devices that communicate with each other over the ***,smart healthcare has emerged as a significant application of the IoMT,particularly in the context of knowledge‐based learning *** healthcare systems leverage knowledge‐based learning to become more context‐aware,adaptable,and auditable while maintain-ing the ability to learn from historical *** smart healthcare systems,devices capture images,such as X‐rays,Magnetic Resonance *** security and integrity of these images are crucial for the databases used in knowledge‐based learning systems to foster structured decision‐making and enhance the learning abilities of ***,in knowledge‐driven systems,the storage and transmission of HD medical images exert a burden on the limited bandwidth of the communication channel,leading to data trans-mission *** address the security and latency concerns,this paper presents a lightweight medical image encryption scheme utilising bit‐plane decomposition and chaos *** results of the experiment yield entropy,energy,and correlation values of 7.999,0.0156,and 0.0001,*** validates the effectiveness of the encryption system proposed in this paper,which offers high‐quality encryption,a large key space,key sensitivity,and resistance to statistical attacks.

关键词： data analysis medical image processing security

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Parallel Inference for Real-Time Machine Learning Applications

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Journal of Computer and Communications 2024年第1期12卷 139-146页

作者： sultan Al Bayyat Ammar Alomran Mohsen Alshatti Ahmed Almousa Rayyan Almousa Yasir Alguwaifli College of Computer Science and Information Technology Imam Abdulrahman Bin Faisal University Dammam Saudi Arabia

Hyperparameter tuning is a key step in developing high-performing machine learning models, but searching large hyperparameter spaces requires extensive computation using standard sequential methods. This work analyzes the performance gains from parallel versus sequential hyperparameter optimization. Using scikit-learn’s Randomized SearchCV, this project tuned a Random Forest classifier for fake news detection via randomized grid search. Setting n_jobs to -1 enabled full parallelization across CPU cores. Results show the parallel implementation achieved over 5× faster CPU times and 3× faster total run times compared to sequential tuning. However, test accuracy slightly dropped from 99.26% sequentially to 99.15% with parallelism, indicating a trade-off between evaluation efficiency and model performance. Still, the significant computational gains allow more extensive hyperparameter exploration within reasonable timeframes, outweighing the small accuracy decrease. Further analysis could better quantify this trade-off across different models, tuning techniques, tasks, and hardware.

关键词： Machine Learning Models Computational Efficiency Parallel Computing Systems Random Forest Inference Hyperparameter Tuning Python Frameworks (TensorFlow PyTorch Scikit-Learn) High-Performance Computing

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Research on the Collaborative Governance of Social Responsibility in Online Audiovisual Enterprises

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Social Networking 2024年第1期13卷 1-13页

作者： Chuying Kang muhammad Zaffwan Idris Juan Liu Faculty of Art Sustainability & Creative Industry University Pendidikan Sultan Idris Tanjung Malim Malaysia Faculty of Journalism and Communication Henan University of Technology Zhengzhou China

This paper aims to analyze the present conditions of the social responsibility ecosystem in online audiovisual enterprises in the digital age. It focuses on the governance of social responsibility in these enterprises and conducts an in-depth analysis of the problems and influencing factors related to the social responsibility aberrations of online audiovisual enterprises. Drawing upon social responsibility theory and collaborative governance theory, this research constructs a social responsibility guidance and governance system guided by the public, supported by the voluntary fulfillment of responsibilities by online audiovisual enterprises, and based on the collaborative participation of diverse stakeholders. It explores and optimizes the implementation pathways of this system, providing theoretical support and practical guidance for promoting the sustainable development of online audiovisual enterprises. Furthermore, it aims to contribute to the creation of a harmonious Internet ecosystem.

关键词： Online Audiovisual Enterprises Social Responsibility Collaborative Governance

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A rare presentation of unicentric Castleman's disease in the thigh:A case report and review of literature

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World Journal of Clinical Cases 2024年第19期12卷 4003-4009页

作者： sultan AlSheikh Abdulmajeed Altoijry Husain Al-Mubarak Ofays Dakkam Alsallum Fadi Alakeel Tariq Alanezi Division of Vascular Surgery Department of SurgeryCollege of MedicineKing Saud UniversityRiyadh 11322Saudi Arabia Division of Vascular Surgery Department of SurgeryKing Khalid Hospital NajranNajran 11321Saudi Arabia Department of Pathology College of MedicineKing Saud UniversityRiyadh 11322Saudi Arabia

BACKGROUND Castleman's disease(CD)is a rare lymphoproliferative,emulating both benign and malignant *** diagnosis of CD is formulated upon the combination of clinical and laboratory criteria and ultimately confirmed by histopathological *** to its rarity,CD presents a challenge in treatment selection,with available options encompassing surgery,chemotherapy,and autologous stem cell ***,studies suggest that surgical resection of the lesion is the most effective treatment modality,especially for unicentric CD(UCD).CASE SUMMARY Here,we describe the case of a 25-year-old woman who presented with painless left thigh swelling for 10 *** had been following a low-fat diet to lose weight and had normal laboratory *** resonance imaging revealed a wellcircumscribed,demarcated cystic lesion located in the left inguinal region with eccentrically positioned signal void vascular structures,measuring 4.3 cm×3 cm×3.2 cm,likely of lymphoid *** patient underwent surgical resection,and the final histopathology showed a vascular proliferation and hyalinization of the vessel walls,along with atretic germinal centers traversed by penetrating vessels,consistent with *** patient was discharged home one day after the procedure in good condition,with a follow-up appointment scheduled in our outpatient *** Although surgical resection is the mainstay for UCD,a multidisciplinary approach is needed due the lack of specific diagnostic features and treatments.

关键词： Castleman’s disease Lymph nodes Surgical resection Lymphoproliferative disorder Case report

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The Impact of Simulation Education on Self-Efficacy in Pre-Registration Nursing Students

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Open Journal of Nursing 2024年第1期14卷 51-76页

作者： Ahmed A. Hakami Aisha Hussin Rabie sultan Ghormallah M. Alzahrani Faisal Mohammed Alnakhilan Khalid Awaidhalharbi College of Nursing Umm Al-Qura University Makkah Saudi Arabia Al-Noor Specialist Hospital Makkah Saudi Arabia (MOH) Ministry of Health King Fahad Hospital Al Baha Saudi Arabia (MOH) Ministry of Health Eradah Complex Riyadh Saudi Arabia King Salman Medical City Al Madinah Saudi Arabia

This literature review primarily aims to explore and synthesise the previous studies in simulation education research conducted over the past five years related to the effects of simulation training on the self-efficacy of undergraduate pre-registration nursing students. The second aim of this study is to explore additional outcome variables that were examined in the previous studies. Five electronic databases were searched systematically. These databases were MEDLINE, CINAHL Plus, Scopus, Embase and PsycINFO. The PICO model was employed to identify the search terms, with a thesaurus being used to provide synonyms. Reference lists of relevant articles were examined and hand searches of journals were also undertaken. The quality of each study was assessed using the Simulation Research Rubric (SRR). A total of 11 studies were included. All studies explored the impact of simulation education on undergraduate pre-registration nursing. Six studies explored nursing students’ competence and performance and two papers examined their critical thinking. Problem solving, learning motivation, communication skills and knowledge acquisition were examined once. The majority of studies indicated that simulation training has a positive impact on pre-registration nursing students’ self-efficacy and other outcome variables. Furthermore, the study results indicate that simulation training is more dependable than traditional training, and students were extremely satisfied with the simulation training. However, most of the studies included in this review had several gaps, including study design, sample size and dissimilarities between the scales used. Further research with large samples, reliable and valid instruments, and outcomes measures (such as critical thinking and transferability of skills) is required to provide better insight into the effectiveness of simulation in undergraduate nursing education. .

关键词： Simulation Education Self-Efficacy Pre-Registration Nursing Students Clinical Skills Undergraduate Nursing Education Teaching Techniques Decision-Making

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电化学介导胺再生CO捕集技术研究进展

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化工进展 2024年

作者：毛元豪范会峰 Sayd sultan 方芙蓉钟琦余云松吴小梅张早校西安交通大学化学工程与技术学院动力工程多相流国家重点实验室

随着全球气候变化问题的日益严重，降低大气中的二氧化碳(CO2)浓度已成为急需解决的全球性问题。然而，现今最具应用潜力的有机胺化学吸收工艺的大范围推广仍受到高能耗问题的阻碍。以电化学介导胺再生CO2捕集技术为代表的电化学碳捕集... 详细信息

随着全球气候变化问题的日益严重，降低大气中的二氧化碳(CO2)浓度已成为急需解决的全球性问题。然而，现今最具应用潜力的有机胺化学吸收工艺的大范围推广仍受到高能耗问题的阻碍。以电化学介导胺再生CO2捕集技术为代表的电化学碳捕集技术避免了高温蒸汽的适用，具有灵活、高效的特点，为低能耗碳捕集技术的发展开辟了新路径。本文介绍了了电化学介导胺CO2捕集技术在反应体系选择、系统模拟计算和高效反应器设计方面的最新进展，分析其研究现状并指出其发展方向。随后进一步分析电化学体系与碳捕集、利用与封存（CCUS）技术领域更广泛交叉应用的潜力，提出电化学CO2压缩机、电化学碳捕集还原一体化工艺流程。本次综述将为推动电力驱动的低能耗碳捕集技术的研究和发展提供新的发展方向与策略。

关键词：电化学介导胺再生碳捕集铜-胺配合物反应器电化学压缩机 CO 电还原

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Nasal Dermoid Cyst with Sinus Tract Intranasal Bone: A Case Report

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International Journal of Otolaryngology and Head & Neck Surgery 2024年第2期13卷 149-156页

作者： sultan Kadasah Abdullah Alhelali Saud Aldhabaan Abdulaziz Al Qahtani Abdullah Musleh Ali Alshahrani Shahd Dlboh Sahar Al-Otaibi Department of Surgery College of Medicine University of Bisha Bisha Saudi Arabia Department of Otolaryngology Head and Neck Surgery Abha Children’s Hospital Abha Saudi Arabia Department of Otolaryngology Head and Neck Surgery Armed Forces Southern Region Hospital Khamis Mushait Saudi Arabia Department of Surgery College of Medicine King Khalid University Abha Saudi Arabia College of Medicine King Khalid University Abha Saudi Arabia

Dermoid cysts are benign tumors originating from germ cells, which can form in various locations, including the nasal area in rare cases. They are of unknown exact etiology, but it is suggested that it is due to abnormal tissue migration during early embryonic development. Nasal dermoid cysts albeit rare, can present in various forms such as sinuses, fistulas, or intracranially extending tracts. They can be asymptomatic and incidentally discovered or present with a visible external mass or sinus that is either painful, infected or cosmetically concerning. If nasal dermoid cysts with an intra-nasal bone sinus tract are left untreated, they can lead to life-threatening complications. This report describes the case of a 6-year-old girl with a nasal dermoid cyst connected to a superficial punctum by an intra-nasal tract. She had undergone surgical excision of a nasal swelling previously diagnosed as a dermoid cyst. One year later, she returned to our clinic with a recurrence of the nasal swelling. Imaging tests revealed a nasal dermoid cyst with a tract extending to the nasal tip, without intracranial expansion. The cyst, along with the entire tract, was successfully removed surgically, and the postoperative follow-up indicated no complications. Histopathology confirmed the diagnosis of a dermoid cyst. This case underscores the significance of considering the dermoid tract in nasal cyst cases and the necessity of its complete removal to prevent recurrence.

关键词： Dermoid Cyst Nasal Sinus Sinus Tract Intranasal Bone Benign Tumor Congenital Anomaly

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Calibration of CO and CO₂ Monitors Used in Periodic Inspection of Vehicles at Fixed Stations for Environmental Control

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Green and Sustainable Chemistry 2024年第2期14卷 29-41页

作者： Adel Bassuoni Shehata Abdulrahman Rashed Al Askar Najjy Hamad Al Yami Abdullah Suleiman Al Owaysi sultan K. Alharbi Chemistry Department National Measurement and Calibration Center (NMCC) Saudi Standards Metrology and Quality Organization (SASO) Riyadh Kingdom of Saudi Arabia

Global efforts for environmental cleanliness through the control of gaseous emissions from vehicles are gaining momentum and attracting increasing attention. Calibration plays a crucial role in these efforts by ensuring the quantitative assessment of emissions for informed decisions on environmental treatments. This paper describes a method for the calibration of CO/CO2 monitors used for periodic inspections of vehicles in cites. The calibration was performed in the selected ranges: 900 - 12,000 µmol/mol for CO and 2000 - 20,000 µmol/mol for CO2. The traceability of the measurement results to the SI units was ensured by using certified reference materials from CO/N2 and CO2/N2 primary gas mixtures. The method performance was evaluated by assessing its linearity, accuracy, precision, bias, and uncertainty of the calibration results. The calibration data exhibited a strong linear trend with R² values close to 1, indicating an excellent fit between the measured values and the calibration lines. Precision, expressed as relative standard deviation (%RSD), ranged from 0.48 to 4.56% for CO and from 0.97 to 3.53% for CO2, staying well below the 5% threshold for reporting results at a 95% confidence level. Accuracy measured as percent recovery, was consistently high (≥ 99.1%) for CO and ranged from 84.90% to 101.54% across the calibration range for CO2. In addition, the method exhibited minimal bias for both CO and CO2 calibrations and thus provided a reliable and accurate approach for calibrating CO/CO2 monitors used in vehicle inspections. Thus, it ensures the effectiveness of exhaust emission control for better environment.

关键词： Monitors Periodic Inspection CO/CO2 Calibration Linearity Precision Accuracy

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Transmission dynamics of Hand-Foot-Mouth Disease with partial immunity through non-integer derivative

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生物数学学报:英文版 2023年第6期16卷 149-173页

作者： Rashid Jan Salah Boulaaras sultan Alyobit muhammad Jawad Department of Mathematics University of Swabi Swabi 23561Khyber PakhtunkhwaPakistan Department of Mathematics College of Sciences and Arts Qassim UniversityAr RassSaudi Arabia Department of Mathematics College of Science 8 Arts King Abdulaziz UniversityRabighSaudi Arabia

In this paper,we formulate the transmission phenomena of Hand-Foot-Mouth Disease(HFMD)through non-integer *** interrogate the biological meaningful results of the recommended system of *** basic reproduction number is determined through next generation method and the impact of different parameters on the reproduction number is examined with the help of partial rank correlation coeficient(PRCC)*** addition,we concentrated on qualitative analysis and dynamical behavior of HFMD ***'s and Schaefer's fixed-point theorems are used to analyze the uniqueness and existence of the solution of the proposed HFMD *** HFMD system's Ulam-Hyers stability has been confirmed to be *** highlight the impact of the parameters on the dynamics of HFMD,we performed several simulations through numerical scheme to conceptualize the transmission route of the *** be more specific,numerical simulations are used to visualize the effect of input parameters on the systems *** have shown the key input parameters of the system for the control of infection in the society.

关键词： Hand-Foot-Mouth Disease fractional derivatives mathematical model threshold parameter numerical scheme dynamical behavior

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