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Chinese Physics B 2017年第5期26卷 304-312页

作者： rafique muhammad 帅永 He-Ping Tan Hassan muhammad School of Energy Science and Engineering Harbin Institute of Technology Harbin 150001 China Mehran University of Engineering and Technology S.Z.A.B Campus Khairpur Mir' s Sindh Pakistan

Structural, electronic, and magnetic behaviors of 5d transition metal（TM） atom substituted divacancy（DV） graphene are investigated using first-principles calculations. Different 5d TM atoms（Hf, Ta, W, Re, Os, Ir, and Pt） are embedded in graphene, these impurity atoms replace 2 carbon atoms in the graphene sheet. It is revealed that the charge transfer occurs from 5d TM atoms to the graphene layer. Hf, Ta, and W substituted graphene structures exhibit a finite band gap at high symmetric K-point in their spin up and spin down channels with 0.783 μB, 1.65 μB, and 1.78 μB magnetic moments,respectively. Ir and Pt substituted graphene structures display indirect band gap semiconductor behavior. Interestingly, Os substituted graphene shows direct band gap semiconductor behavior having a band gap of approximately 0.4 e V in their spin up channel with 1.5 μB magnetic moment. Through density of states（DOS） analysis, we can predict that d orbitals of 5d TM atoms could be responsible for introducing ferromagnetism in the graphene layer. We believe that our obtained results provide a new route for potential applications of dilute magnetic semiconductors and half-metals in spintronic devices by employing 5d transition metal atom-doped graphene complexes.

关键词： substituted impurity symmetric dilute complexes monolayer Fermi replace polarized doping

Effect of Cumulative Nanosecond Laser Pulses on the Plasma Emission Intensity and Surface Morphology of Pt-and Ag-Ion Deposited Silicon

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Plasma Science and Technology 2012年第4期14卷 333-337页

作者： Khurram SIRAJ muhammad Zakria BUTT muhammad KHALEEQ-UR-RAHMAN muhammad Shahid rafique Saima rafique FAKHAR-UN-NISA Advanced Physics Laboratory Department of PhysicsUniversity of Engineering and Technology

In this work, the laser induced plasma plume characteristics and surface morphology of Pt- and Ag-ion deposited silicon were studied. The deposited silicon was exposed to cumulative laser pulses. The plasma plume images produced by each laser shot were captured through a computer controlled image capturing system and analyzed with image-J software. The integrated optical emission intensity of both samples showed an increasing trend with increasing pulses. Agion deposited silicon showed higher optical emission intensity as compared to Pt-ion deposited silicon, suggesting that more damage occurred to the silicon by Ag ions, which was confirmed by SRIM/TRIM simulations. The surface morphologies of both samples were examined by optical microscope showing thermal, exfoliational and hydrodynamical sputtering processes along with the re-deposition of the material, debris and heat affected zones＇ formation. The crater of Ption deposited silicon was deeper but had less lateral damage than Agion deposited silicon. The novel results clearly indicated that the ion deposited silicon surface produced incubation centers, which led to more absorption of incident light resulting into a higher emission intensity from the plasma plume and deeper crater formation as compared to pure silicon. The approach can be effectively utilized in the laser induced breakdown spectroscopy technique, which endures poor limits of detection.

关键词： ions deposited silicon laser irradiation plasma plume emission intensity,crater formation

Radioactive contents and background doses from northern alluvial sediment plains between rivers Ravi and Chenab,Pakistan

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Nuclear Science and Techniques 2016年第4期27卷 127-134页

作者： Abdul Jabbar Khalid Khan Tania Jabbar muhammad rafique S.U.Rehman Waheed Arshed muhammad Dilband Health Physics Division Pakistan Institute of Nuclear Science and Technology (PINSTECH) Department of Physics University of Azad Jammu and Kashmir Muzaffarbad Department of Medical Physics Nuclear Medicine Oncology and Radiotherapy Institute (NORI)

Radiometric analysis of soil samples, collected from northern alluvial sediment plains between rivers Ravi and Chenab, has been carried out. Activity concentrations of^(226) Ra,^(232)Th,^(40) K and the artificial radionuclide^(137) Cs were estimated by using high-purity germanium detector. Subsequent values of activity concentrations were used to find terrestrial absorbed dose rate and annual effective doses received by resident of area. The mean radioactivity levels of^(226) Ra,^(232)Th,^(40) K and^(137)Cs were found to be 45.0 ± 1.3,59.6 ± 2.8, 613.8 ± 20.0 and 4.0 ± 0.2 Bq kg^(-1), respectively. Terrestrial absorbed dose rate and annual effective dose received by public were found to be 85.1 n Gy h^(-1)and0.5 m Sv, respectively. The activity concentrations of^(226) Ra,^(232)Th,^(40) K and^(137)Cs and resulting doses obtained for the current study were compared with data available in the literature and with international standards.

关键词：年有效剂量冲积平原平原河流放射性含量巴基斯坦泥沙 137Cs 226Ra

Radionuclide concentrations in sand samples from riverbanks of Muzaffarabad,Azad Kashmir

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Nuclear Science and Techniques 2018年第7期29卷 103-115页

作者： Abdul Razzaq Khan muhammad rafique Abdul Jabbar Saeed Ur Rahman muhammad Ikram Shahzad muhammad Ejaiz Khan Mulaika Yasin Department of Physics University of Azad Jammu andKashmir MuzaffarbadAzad Kashmir 13100Pakistan Health Physics Division Pakistan Institute of NuclearScience and Engineering(PINSTECH)NiloreIslamabad 45650Pakistan Department of Medical Physics Nuclear MedicineOncologyand Radiotherapy InstituteIslamabadPakistan Physics Division Directorate of SciencePINSTECHP.O.NiloreIslamabad 45650Pakistan

This paper presents the results of a radiological risk assessment arising from the presence of naturally occurring radionuclides in sand samples from three riverbanks in *** mean values obtained for 232 Th,226 Ra,and 40 K were found to be 44.58 ± 3.34,48.25 ± 1.77,and 239.92 ± 22.73 Bq kg^(-1),*** assess the uniformity of exposure,the radium equivalent activity(Raeq) was calculated and was found to be130.47 ± 8.29 Bqkg^(-1).The current reported value for Raeqis lower than the maximum permissible value,that is,370 Bq kg^(-1),and equivalent to a gamma dose of1.5 m Svy^(-1).To investigate the possible contribution to health risks of alpha particle exposure,the radon exhalation rate(RER) from the sand samples was *** mean RER for all the samples was found to be335 m Bq m-^(2) h^(-1).About 43% of the samples were found to have an indoor excess lifetime cancer risk value slightly higher than recommended safety limit of 1,as proposed by the ICRP.A normalized parameter,the equivalent multiplicative factor,was defined and used to compare the current results with the findings of studies performed in other *** findings are relevant to both human health and future environmental radiation monitoring.

关键词：放射性核种样品克什米尔河岸风险评价调查结果 226Ra gamma

Extracellular matrix and nitric oxide based functional coatings for vascular stents

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Engineered Regeneration 2022年第2期3卷 149-153页

作者： Quhan Cheng muhammad Shafiq muhammad rafique Li Shen Xiumei Mo Kai Wang Key Laboratory of Bioactive Materials Ministry of EducationCollege of Life SciencesNankai UniversityTianjin 300071China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineCollege of ChemistryChemical Engineering and BiotechnologyDonghua UniversityShanghai 201620China Department of Cardiology Shanghai Institute of Cardiovascular DiseasesZhongshan HospitalFudan UniversityShanghai 200032China National Clinical Research Center for Interventional Medicine Shanghai 200032China.

Cardiovascular diseases cause huge morbidity and mortality ***,vascular stents have been most frequently used to treat cardiovascular diseases thanks to their effectiveness at dilating blood vessels and main-taining the circulation of ***,stent expansion leads to endothelium injury posing thrombogenic and in-stent restenosis(ISR).In addition,the bioinertness and an acute lack of endothelium-like function on the surface of implanted vascular stents compromise their *** coatings of vascular stents to mimic endothelium-and extracellular matrix(ECM)-like functions could prevent thrombosis,inhibit the over-growth of smooth muscle cells(SMCs),and promote the rapid restoration of native endothelium,hence effec-tively suppressing stent-related ***,ECM-based coatings including a multitude of bioactive molecular,such as growth factors,heparin,hyaluronic acid(HA)and so on,have been proven to play important effects on regulating ECs/SMCs behavior and improving blood compatibility of ***,nitric oxide(NO),which is fundamental to the endothelium-mediated anti-thrombogenesity,anti-intimal hyperplasia and anti-inflammation,has been leveraged to improve vascular stent ***,this review will highlight different strategies and biological role of ECM and NO based functional coatings on vascular ***,some potential important factors for stents development are suggested as well.

关键词： Vascular stent Nitric oxide Extracellular matrix Functional coating

Inducing opto-electronic and spintronic trends in bilayer h-BN through TMO3 clusters incorporation: Ab-initio study

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Chinese Physics B 2019年第11期28卷 284-294页

作者： Irfan Ahmed muhammad rafique Mukhtiar Ahmed Mahar Abdul Sattar Larik Mohsin Ali Tunio Yong Shuai Mehran University of Engineering and Technology SZABCampusKhairpur Mirs’Pakistan School of Energy Science and Engineering Harbin Institute of TechnologyHarbin 150001China Mehran University of Engineering and Technology JamshoroSindhPakistan

The band structure, magnetism, charge distribution, and optics parameters of TMO3–h-BN hybrid systems are investigated by adopting first-principles study(FPS) calculations. It is observed that the TMO3 clusters add finite magnetic moments to bilayer h-BN(BL/h-BN), thereby making it a magnetic two-dimensional(2D) material. Spin-polarized band structures for various TMO3–BL/h-BN hybrid models are calculated. After the incorporation of TMO3, BL/h-BN is converted into semimetal or conducting material in spin up/down bands, depending on the type of impurity cluster present in BL/h-BN lattice. Optics parameters are also investigated for the TMO3–BL/h-BN complex systems. The incorporation of TMO3 clusters modifies the absorption and extinction coefficient in visible range, while static reflectivity and refraction parameter increase. It can be surmised that the TMO3 substitution in BL/h-BN is a suitable technique to modify its physical parameters thus making it functional for nano/opto-electronic applications, and an experimental approach can be adapted to reinforce the outcomes of this study.

关键词： bilayer h-BN band structure density of states magnetic moments optics

Nanosuspension enhances dissolution rate and oral bioavailability of Terminalia arjuna bark extract in vivo and in vitro

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Asian Pacific Journal of Tropical Biomedicine 2020年第4期10卷 164-171页

作者： Fatiqa Zafar Nazish Jahan Khalil-Ur-Rahman muhammad rafique Asi Waseeq-Ul-Islam Zafar Department of Chemistry University of OkaraOkaraPakistan Department of Chemistry University of AgricultureFaisalabadPakistan Department of Biochemistry University of AgricultureFaisalabadPakistan Food Toxicology Lab Plant Protection DivisionNuclear Institute for Agriculture and BiologyFaisalabadPakistan Department of Computer Science COMSATS University of Information and TechnologyIslamabadPakistan

Objective:To enhance the dissolution rate and oral bioavailability of Terminalia arjuna bark extract by formulating its ***:Nanoprecipitation approach was used for the formulation of nanosuspension using polysorbate-80 as a *** formulated nanosuspension was assessed for particle size,polydispersity index,zeta potential value and for in vitro dissolution *** bioavailability studies were carried out in Wistar male albino rats by administering a single dose(50 mg/***)of the formulated nanosuspension and coarse *** storage stability of the formulated nanosuspension was determined after three months of storage at room temperature and under the refrigerated *** assay was carried out to evaluate the toxicity of the formulated nanosuspension using two mutant strains(Salmonella typhimurium TA100 and Salmonella typhimurium TA98).Results:The mean particle size of the formulated nanosuspension was 90.53 nm with polydispersity index and zeta potential values of 0.175 and-15.7 m V,*** arjuna nanosuspension showed improved dissolution rate and 1.33-fold higher oral bioavailability than its coarse *** formulated nanosuspension also showed better stability under the refrigerated condition and was non-mutagenic against both ***:Our study demonstrates that nanosuspension technology can effectively enhance the dissolution rate and oral bioavailability of Terminalia arjuna bark extract.

关键词： Terminalia arjuna Nanosuspension Bioavailability Stability Toxicity Polysorbate-80

Specific Capacitance and Cyclic Stability of Graphene Based Metal/Metal Oxide Nanocomposites:A Review

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Journal of Materials Science & Technology 2015年第7期31卷 699-707页

作者： Abdul Waheed Anwar Abdul Majeed Nadeem Iqbal Wasi Ullah Ahmad Shuaib Usman Ilyas Fozia Bibi Hafiz muhammad rafique Nanotechnologies Research Centre Department of PhysicsUniversity of Engineering and Technology Under Graduate Block/School of Physical Sciences University of the Punjab Department of Physics University of the Punjab

Graphene has become a worldwide admired material among researchers and scientists equally due to its unique richness in mechanical strength, electrical conductivity, optical and thermal properties. Re- searchers have explored that the composite materials based on graphene and metal/metal oxide nanostructures possess excellent potential for energy storage technologies. In particular, supercapacitors based on such composite materials have engrossed the extreme interest of researchers for its rapid charging/discharging time, safe operation and longer cyclic constancy. Till now, several fabrication techniques for composite materials and their energy storage applications have been explored. Here, specially, we have concentrated on the hottest research progress for the fabrication of graphene oxide and metal/metal oxide nanocomposites. We also emphasized on the characteristics and properties of supercapacitors fabricated using these composite materials. Moreover, our study is focused on the specific capacitance and cyclic stability of various composites to haul out the most efficient material for supercapacitor applications.

关键词： GrapheneMetal/metal oxide nanostructureSupercapacitor

Antibacterial Action of Chemically Synthesized and Laser Generated Silver Nanoparticles against Human Pathogenic Bacteria

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Journal of Materials Science & Technology 2016年第8期32卷 721-728页

作者： Nosheen Zafar Shahzadi Shamaila Jawad Nazir Rehana Sharif muhammad Shahid rafique Jalees Ul-Hasan Syeda Ammara Hina Khalid Department of Physics University of Engineering and Technology Lahore 54890 Pakistan Department of Microbiology University of Veterinary and Animal Sciences Lahore Pakistan Department of Physics Forman Christian College A Charted University Lahore Pakistan

Silver nanoparticles in the range of 10-40 nm were synthesized chemically and by laser ablation, em- ployed for in vitro antibacterial action against human pathogenic bacterium. Their formation was evidenced by UV-visible spectrophotometer; particle size confirmed by atomic force microscopy, crystal structure determined by X-ray diffraction and chemical composition investigated by Fourier transform infrared spec- troscopy. The calculated MIC （minimum inhibitory concentration） of chemically synthesized nanoparticles with 30-40 nm in size are 2.8 μg/mL 4.37 μg/mL 13.5μg/mL and 2.81 p.g/mL for E. coil, S. aureus, B. subtillis and Salmonella, respectively. Whereas laser ablated nanoparticles exhibit MIC of 2.10 μg/mL 2.36 μg/ mL and 2.68 μg/mL for E. coli, S. aureus and Salmonella, respectively.

关键词： Chemically synthesized and laser ablated nanoparticles UV-visible spectrophotometer Gram negative and gram positive bacteria

Antagonistic Potential of Bacterial Species against Fungal Plant Pathogens(FPP)and Their Role in Plant Growth Promotion(PGP):A Review

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Phyton-International Journal of Experimental Botany 2022年第9期91卷 1859-1877页

作者： Amjad Ali Yasir Iftikhar Mustansar Mubeen Haider Ali muhammad Ahmad Zeshan Zohaib Asad muhammad Zafar-ul-Hye Malik Abdul Rehman Mazhar Abbas muhammad rafique muhammad Usman Ghani Department of Plant Protection Sivas University of Science and TechnologySivas58140Turkey Department of Plant Pathology College of AgricultureUniversity of SargodhaSargodha40100Pakistan College of Bioscience University of BirminghamBirminghamB152TTUK Department of Plant Pathology PMAS University of Arid AgricultureRawalpindi43490Pakistan Department of Soil Science Faculty of Agricultural Sciences and TechnologyBahauddin Zakariya UniversityMultan60800Pakistan Citrus Research Institute Sargodha40100Pakistan Department of Agriculture and Agribusiness Management University of Karachi75270KarachiPakistan Pest warning&Quality Control of Pesticides SahiwalPunjab40210Pakistan Institute of Soil and Environmental Sciences University of AgricultureFaisalabad38000Pakistan

Since the 19th century to date,the fungal pathogens have been involved in causing devastating diseases in *** types of fungal pathogens have been observed in important agricultural crops that lead to significant pre and postharvest *** application of synthetic fungicide against the fungal plant pathogens(FPP)is a traditional management practice but at the same time these fungicides kill other beneficial microbes,insects,animal,and humans and are harmful to *** antagonistic microorganism such as bacteria are being used as an alternate strategy to control the *** antagonistic species are cost-effective and eco-friendly in *** biocontrol bacteria have a broad mechanism against fungal pathogens present in the phyllosphere and rhizosphere of the *** antagonistic bacteria have different strategies against the FPP,by producing siderophore,biofilm,volatile organic compounds(VOCs),through parasitism,antibiosis,competition for limited resources and induce systemic resistance(ISR)in the host plant by activating the immune *** commercial bio-products synthesized by the major bacterial species Pseudomonas syringae,Burkholderia cepacia,Streptomyces griseoviridis,Pseudomonas fluorescens and Bacillus subtilis are used to control Fusarium,Pythium,Rhizoctonia,Penicillium,Alternaria,and *** commercial bio-formulations of bacteria act as both antifungal and plant growth *** Plant growth-promoting rhizobacteria(PGPR)played a significant role in improving plant health by nitrogen-fixing,phosphorus solubilization,phytohormones production,minimizing soil metal contamination,and by ACC deaminase antifungal *** articles are available on the specific antifungal activity of bacteria in plant ***,this review article has summarized the information on biocontrol activity of bacteria against the FPP and the role of PGPR in plant growth *** review also provided a complete picture

关键词： Fungi plant pathogens synthetic fungicide antagonism bio-products PGPR