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Progress in electrocatalytic nitrate reduction for green energy:Catalyst engineering,mechanisms,and techno-economic feasibility

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Journal of Energy Chemistry 2024年第8期95卷 380-406,I0009页

作者： Hafiz muhammad Adeel Sharif Hafiz muhammad Farooq Khan Sadeeq Ullah Yuwei Wang muhammad ahmad Bo Yang Changping Li muhammad Bilal Asif Research Center for Eco-Environmental Engineering Dongguan University of TechnologyDongguan 523808GuangdongChina College of Chemistry and Engineering Shenzhen UniversityShenzhen 518060GuangdongChina FMH College of Medicine and Dentistry LahorePakistan School of Environment and Civil Engineering Research Center for Eco-Environment EngineeringDongguan University of TechnologyDongguan 523106GuangdongChina Advanced Membranes and Porous Materials Center(AMPMC) Physical Sciences and Engineering(PSE)King Abdullah University of Science and Technology(KAUST)Thuwal 23955Saudi Arabia

Ammonia(NH_(3))is an irreplaceable chemical that has been widely demanded to keep the sustainable development of modern ***,its industrial production consumes a huge amount of energy and releases extraordinary greenhouse gases(GHGs),leading to various environmental *** the green production of ammonia is a great challenge,which has been extensively pursued in the last *** this review,the most promising strategy,electrochemical nitrate reduction reaction(e-NO_(3)RR),is comprehensively investigated to give a complete understanding of its development and mechanism and provide guidance for future ***,owing to the complex reactions and limited selectivity,a comprehensive understanding of the mechanisms is crucial to further development and ***,NO_(3)^(-)RR is a promising strategy for simultaneous water treatment and NH_(3)production.A detailed overview of the recent progress in NO_(3)^(-)RR for NH_(3)production with nontransition and transition metal based electrocatalysts is *** addition,critical advanced techniques,future challenges,and prospects are discussed to guide future research on transition metal-based catalysts for commercial NH_(3)synthesis by NO_(3)^(-)reduction.

关键词： Nitrate reduction Electrolysis Pollution to solution Transition metal catalysts Ammonia synthesis Green energy

Enhancing Security and Privacy in Distributed Face Recognition Systems through Blockchain and GAN Technologies

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Computers, Materials & Continua 2024年第5期79卷 2609-2623页

作者： muhammad ahmad Nawaz Ul Ghani Kun She muhammad Arslan Rauf Shumaila Khan Javed Ali Khan Eman Abdullah Aldakheel Doaa Sami Khafaga School of Information and Software Engineering University of Electronic Science and Technology of ChinaChengdu611731China Department of Computer Science University of Science&TechnologyBannu28100Pakistan Department of Computer Science University of HertfordshireHatfieldAL109ABUK Department of Computer Sciences College of Computer and Information SciencesPrincess Nourah bint Abdulrahman UniversityRiyadh11671Saudi Arabia

The use of privacy-enhanced facial recognition has increased in response to growing concerns about data securityand privacy in the digital age. This trend is spurred by rising demand for face recognition technology in a varietyof industries, including access control, law enforcement, surveillance, and internet communication. However,the growing usage of face recognition technology has created serious concerns about data monitoring and userprivacy preferences, especially in context-aware systems. In response to these problems, this study provides a novelframework that integrates sophisticated approaches such as Generative Adversarial Networks (GANs), Blockchain,and distributed computing to solve privacy concerns while maintaining exact face recognition. The framework’spainstaking design and execution strive to strike a compromise between precise face recognition and protectingpersonal data integrity in an increasingly interconnected environment. Using cutting-edge tools like Dlib for faceanalysis,Ray Cluster for distributed computing, and Blockchain for decentralized identity verification, the proposedsystem provides scalable and secure facial analysis while protecting user privacy. The study’s contributions includethe creation of a sustainable and scalable solution for privacy-aware face recognition, the implementation of flexibleprivacy computing approaches based on Blockchain networks, and the demonstration of higher performanceover previous methods. Specifically, the proposed StyleGAN model has an outstanding accuracy rate of 93.84%while processing high-resolution images from the CelebA-HQ dataset, beating other evaluated models such asProgressive GAN 90.27%, CycleGAN 89.80%, and MGAN 80.80%. With improvements in accuracy, speed, andprivacy protection, the framework has great promise for practical use in a variety of fields that need face recognitiontechnology. This study paves the way for future research in privacy-enhanced face recognition systems, emphasizingt

关键词： Facial recognition privacy protection blockchain GAN distributed systems

Automatic Finding of Brain-Tumour Group Using CNN Segmentation and Moth-Flame-Algorithm,Selected Deep and Handcrafted Features

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Computers, Materials & Continua 2024年第5期79卷 2585-2608页

作者： Imad Saud Al Naimi Syed Alwee Aljunid Syed Junid muhammad lmran ahmad K.Suresh Manic Faculty of Electronic Engineering Technology University Malaysia Perils(UniMAP)Pauh Putra CampusArauPerlis02600Malaysia Department of Electrical and Communication Engineering National University of Science and TechnologyAL HailAL Seeb130Sultanate of Oman Department of Research and Innovation Saveetha School of EngineeringSaveetha Institute of Medical and Technical Sciences(SIMATS)ChennaiTamiNadu602105India

Augmentation of abnormal cells in the brain causes brain tumor(BT),and early screening and treatmentwill reduce its harshness in ***’s clinical level screening is usually performed with Magnetic Resonance Imaging(MRI)due to its multi-modality *** overall aims of the study is to introduce,test and verify an advanced image processing technique with algorithms to automatically extract tumour sections from brain MRI scans,facilitating improved *** research intends to devise a reliable framework for detecting the BT region in the twodimensional(2D)MRI slice,and identifying its class with improved *** methodology for the devised framework comprises the phases of:(i)Collection and resizing of images,(ii)Implementation and Segmentation of Convolutional Neural Network(CNN),(iii)Deep feature extraction,(iv)Handcrafted feature extraction,(v)Moth-Flame-Algorithm(MFA)supported feature reduction,and(vi)Performance *** study utilized clinical-grade brain MRI of BRATS and TCIA datasets for the *** framework segments detected the glioma(low/high grade)and glioblastoma class *** work helped to get a segmentation accuracy of over 98%with VGG-UNet and a classification accuracy of over 98%with the VGG16 *** study has confirmed that the implemented framework is very efficient in detecting the BT in MRI slices with/without the skull section.

关键词： Brain tumour VGG-UNet VGG16 moth-flame-algorithm classification

A review on marine collagen:sources,extraction methods,colloids properties,and food applications

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M_(4)X_(3) MXenes:Application in Energy Storage Devices

胶原与皮革（英文） 2024年第1期6卷 1-27页

作者： Shahzad Farooq muhammad Ijaz ahmad Shijie Zheng Usman Ali Yang Li Cui Shixiu Hui Zhang Jiaxing Institute of Future Food Jiaxing 314050China College of Biosys-tems Engineering and Food Science Zhejiang Key Laboratory for Agro-Food ProcessingZhejiang UniversityHangzhou 310058China Jiaxing Institute of Future Food Jiaxing 314050China College of Biosys-tems Engineering and Food Science Zhejiang Key Laboratory for Agro-Food ProcessingZhejiang UniversityHangzhou 310058China

The growing interest in valorizing industrial by-products has led researchers to focus on exploring different sources and optimizing collagen extraction conditions over the past *** bovine hide,cattle bones,pork,and pig skins remain the most abundant collagen sources,there is a growing trend in the industrial utilization of collagen from non-mammalian *** review explores alternative marine collagen sourcesand summarizes emerging trends in collagen recovery from marine sources,with a particular focus on environmentally friendly ***-tionally,this review covers the colloidal structure-forming properties of marine collagens,including foam,film,gel,and emulsion *** also highlights the potential and important applications of marine collagen in various food *** on the currently reported marine sources,collagens extracted from fish,jellyfish,and sea cucumbers were found to have the highest yield and mostly comprised type-l collagen,while crustaceans and mollusks yielded lower percentages of *** extraction techniques isolate collagen based on acetic acid and pepsin treatment,but they come with drawbacks such as being time-consuming,causing sample destruction,and using ***,marine collagen extracted using conventional methods assisted with ultrasonication resulted in higher yields and strengthened the triple-stranded helical ***,an increasing number of new applications have been found in the food industry for marine collagens,such as biodegradable film-forming materi-als,colloid stabilizers,foaming agents,and micro-encapsulating ***,collagen is a modern foodstuff and is extensively used in the beverage,dairy,and meat industries to increase the stability,consistency,and elasticity of products.

关键词： Marine collagen Jellyfish Sea cucumber Colloid stabilizer Edible film Dairy product

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Nano-Micro Letters 2024年第10期16卷 522-542页

作者： Iftikhar Hussain Waqas Ul Arifeen Shahid Ali Khan Sikandar Aftab muhammad Sufyan Javed Sajjad Hussain muhammad ahmad Xi Chen Jiyun Zhao PRosaiah Khaled Fahmi Fawy Adnan Younis Sumanta Sahoo Kaili Zhang Department of Mechanical Engineering City University of Hong Kong83 Tat Chee AvenueKowloon TongHong KongPeople's Republic of China School of Mechanical Engineering Yeungnam UniversityDaehak-roGyeongsan-siGyeongbuk-do 38541South Korea Department of Semiconductor Systems Engineering and Clean Energy Sejong UniversitySeoul 05006Republic of Korea School of Physical Science and Technology Lanzhou UniversityLanzhou 730000People's Republic of China Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Department of Physics Saveetha School of EngineeringSaveetha Institute of Medical and Technical Sciences(SIMATS)ThandalamChennai 602105India Department of Chemistry Faculty of ScienceKing Khalid UniversityP.O.Box 900461413 AbhaSaudi Arabia Department of Physics College of ScienceUnited Arab Emirates UniversityP.O.Box 15551Al-AinUnited Arab Emirates School of Chemical Engineering Yeungnam UniversityGyeongsanGyeongbuk 38541South Korea

MXene has garnered widespread recognition in the scientific com-munity due to its remarkable properties,including excellent thermal stability,high conductivity,good hydrophilicity and dispersibility,easy processability,tunable surface properties,and admirable *** have been categorized into different families based on the number of M and X layers in M_(n+1)X_(n),such as M_(2)X,M_(3)X_(2),M_(4)X_(3),and,recently,M_(5)X_(4).Among these families,M_(2)X and M_(3)X_(2),par-ticularly Ti_(3)C_(2),have been greatly explored while limited studies have been given to M_(5)X_(4)MXene ***,studies on the M_(4)X_(3)MXene family have developed recently,hence,demanding a compilation of evaluated ***,this review provides a systematic overview of the latest advancements in M_(4)X_(3)MXenes,focusing on their properties and applications in energy storage *** objective of this review is to provide guidance to researchers on fostering M_(4)X_(3)MXene-based nanomaterials,not only for energy storage devices but also for broader applications.

关键词： MXene M_(4)X_(3)MXenes 2D materials Energy storage Properties

Beta-cyclodextrin adsorbents to remove water pollutants-a commentary

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Frontiers of Chemical Science and Engineering 2022年第9期16卷 1407-1423页

作者： Fadina Amran muhammad Abbas ahmad Zaini Centre of Lipids Engineering&Applied Research(CLEAR) Ibnu-Sina Institute for Scientific&Industrial Research(ISI-SIR)Universiti Teknologi MalaysiaJohorMalaysia School of Chemical&Energy Engineering Faculty of EngineeringUniversiti Teknologi MalaysiaJohorMalaysia

Beta-cyclodextrin-based adsorbent is a promising adsorbent because it has unique characteristics and able to form host-guest complexes with various organic *** using beta-cyclodextrin-based adsorbent has continuously improved by various preparation strategies and crosslinking *** commentary aims to highlight the preparation strategies,properties,and adsorption mechanisms of beta-cyclodextrin-based *** adsorbents can be generally classified according to the preparation methods and display high adsorption capacity especially for ***,composite/nanocomposite beta-cyclodextrin-based adsorbents exhibit outstanding adsorption capacity even though the surface area is lower than that of porous and magnetic betacyclodextrin-based *** beta-cyclodextrin/chitosan functionalized graphene oxide hydrogel with specific surface of 17.6 m^(2)·g^(–1)yields an extraordinarily maximum adsorption capacity of 1499 mg·g^(–1)methylene blue,while beta-cyclodextrin/chitosan modified with iron(Ⅱ,Ⅲ)oxide nanoparticles displays a much greater maximum adsorption capacity at 2780 mg·g^(–1).The hydrophobic interaction,functional groups,hydrogen bonding,and electrostatic interaction govern the adsorption to a greater *** this commentary is not exhaustive,the preparation strategies and illustrated mechanisms provide useful insights into the adsorbent–adsorbate interactions,costeffective analysis,challenges,and future directions of betacyclodextrin-based adsorbents in wastewater treatment.

关键词： beta-cyclodextrin adsorbent adsorption inclusion complex mechanism water pollutant wastewater treatment

Chaos-Based Cryptographic Mechanism for Smart Healthcare IoT Systems

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Computers, Materials & Continua 2022年第4期71卷 753-769页

作者： muhammad Samiullah Waqar Aslam Arif Mehmood muhammad Saeed ahmad Shafiq ahmad Adel M.Al-Shayea muhammad Shafiq Department of Computer Science&IT The Islamia University of BahawalpurBahawalpur63100Pakistan Department of Computer Science&IT Government Sadiq College Women UniversityBahawalpurPakistan Industrial Engineering Department College of EngineeringKing Saud UniversityP.O.Box 800Riyadh11421Saudi Arabia Department of Information and Communication Engineering Yeungnam UniversityGyeongsan38541Korea

Smart and interconnected devices can generate meaningful patient data and exchange it automatically without any human intervention in order to realize the Internet of Things(IoT)in healthcare(HIoT).Due to more and more online security and data hijacking attacks,the confidentiality,integrity and availability of data are considered serious issues in HIoT *** this regard,lightweight block ciphers(LBCs)are promising in resourceconstrained environment where security is the primary *** prevalent challenge while designing an LBC for the HIoT environment is how to ascertain platform performance,cost,and *** of the existing LBCs primarily focus on text data or grayscale *** main focus of this paper is about securing color images in a cost-effective *** emphasis high confidentiality of color images captured by cameras in resource-constrained smartphones,and high confidentiality of sensitive images transmitted by low-power sensors in IoT *** order to reduce computational complexity and simulation time,the proposed Lightweight Symmetric Block Cipher(LSBC)exploits chaos-based confusion-diffusion operations at the inter-block level using a single *** strength of LSBC is assessed by cryptanalysis,while it is ranked by comparing it to other privacy-preserving *** results show that the proposed cipher produces promising results in terms of key sensitivity and differential attacks,which proves that our LSBC is a good candidate for image security in HIoT.

关键词： IoT healthcare lightweight block cipher symmetric block cipher

A hybrid circuit breaker with fault current limiter circuit in a VSC-HVDC application

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Protection and Control of Modern Power Systems 2022年第1期7卷 657-669页

作者： muhammad ahmad Chunyang Gong muhammad Haroon Nadeem Hui Chen Zhixin Wang School of Electronics Information and Electrical Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Shanghai University of Electric Power Shanghai 200090People’s Republic of China EnergyVille/Electa Research Group Electrical Engineering Department ESATKU Leuven3001 HeverleeBelgium.

A conventional hybrid circuit breaker(HCB)is used to protect a voltage source converter-based high voltage direct current transmission system(VSC-HVDC)from a short circuit *** the increased converter capacity,the DC protection equipment also requires a regular *** paper adopts a novel type of HCB with a fault current limiter circuit(FCLC),and focuses on the responses of voltage and current during DC faults,which are associated with parameter ***/EMTDC based simulation of a three-terminal VSC-HVDC system confirms the effectiveness and value of HCB with FCLC,by using an equivalent circuit modelling *** experimental tests validate the simulation *** peak fault current is reduced according to the current limiting inductor(CLI)increase,and can be isolated more *** adopting parallel metal oxide arrester(MOA)with the main branch of HCB,voltage stresses across the breaker components decrease during transient and continuous operation,and less energy needs to be dissipated by the *** remnant current for all cases is transmitted to power dissipating resis-tor(PDR)in the final stage,and the fault current is reduced to the lowest possible *** the current from the main branch is transferred to the FCLC branch,transient voltage spikes occur,while smaller PDR is required to absorb current in the final stage.

关键词： VSC-HVDC HCB FCLC Short circuit fault MOA

Minimal Doubly Resolving Sets of Certain Families of Toeplitz Graph

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Computer Modeling in Engineering & Sciences 2023年第6期135卷 2681-2696页

作者： muhammad ahmad Fahd Jarad Zohaib Zahid Imran Siddique Department of Mathematics University of Management and TechnologyLahore54770Pakistan Department of Mathematics Cankaya UniversityEtimesgutAnkara06790Turkey Department of Medical Research China Medical University HospitalChina Medical UniversityTaichung40402Taiwan

The doubly resolving sets are a natural tool to identify where diffusion occurs in a complicated *** realworld phenomena,such as rumour spreading on social networks,the spread of infectious diseases,and the spread of the virus on the internet,may be modelled using information diffusion in *** is obviously impractical to monitor every node due to cost and overhead limits because there are too many nodes in the network,some of which may be unable or unwilling to send information about their *** a result,the source localization problem is to find the number of nodes in the network that best explains the observed *** problem can be successfully solved by using its relationship with the well-studied related minimal doubly resolving set problem,which minimizes the number of observers required for accurate *** paper aims to investigate the minimal doubly resolving set for certain families of Toeplitz graph Tn(1,t),for t≥2 and n≥t+*** come to the conclusion that for Tn(1,2),the metric and double metric dimensions are equal and for Tn(1,4),the double metric dimension is exactly one more than the metric ***,the double metric dimension for Tn(1,3)is equal to the metric dimension for n=5,6,7 and one greater than the metric dimension for n≥8.

关键词： Family of Toeplitz graph resolving sets metric dimension doubly resolving sets double metric dimension