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MXenes and heterostructures-based electrocatalysts for hydrogen evolution reaction:Recent developments and future outlook

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Journal of Energy Chemistry 2024年第5期92卷 176-206页

作者： Abdul Hanan Hafiz Taimoor Ahmed awan Faiza Bibi Raja Rafidah Raja Sulaiman Wai Yin Wong Rashmi Walvekar Seema Singh mohammad Khalid Sunway Centre for Electrochemical Energy and Sustainable Technology(SCEEST) School of Engineering and TechnologySunway UniversityNo.5 Jalan UniversitiBandar Sunway47500 Petaling JayaSelangorMalaysia Fuel Cell Institute Universiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia Faculty of Innovation and Technology School of EngineeringChemical Engineering ProgrammeNo.1 Jalan Taylor’sTaylor’s University Malaysia47500 Subang JayaSelangorMalaysia Chitkara Centre for Research and Development Chitkara UniversityHimachal Pradesh 174103India School of Applied and Life Sciences Uttaranchal UniversityDehradunUttarakhand 248007India Manipal Institute of Technology Manipal Academy of Higher EducationManipal 576104KarnatakaIndia Centre of Research Impact and Outcome Chitkara UniversityPunjab 140401India

The increasing focus on electrocatalysis for sustainable hydrogen(H_(2))production has prompted significant interest in MXenes,a class of two-dimensional(2D)materials comprising metal carbides,carbonitrides,and *** materials exhibit intriguing chemical and physical properties,including excellent electrical conductivity and a large surface area,making them attractive candidates for the hydrogen evolution reaction(HER).This scientific review explores recent advancements in MXene-based electrocatalysts for HER *** discusses various compositions,functionalities,and explicit design principles while providing a comprehensive overview of synthesis methods,exceptional properties,and electro-catalytic approaches for H_(2) production via electrochemical ***,challenges and future prospects in designing MXenes-based electrocatalysts with enhanced kinetics are highlighted,emphasizing the potential of incorporating different metals to expand the scope of electrochemical *** review suggests possible efforts for developing advanced MXenes-based electrocatalysts,particularly for efficient H_(2) generation through electrochemical water-splitting reactions..

关键词： MXenes Electrocatalyst Water Splitting Hydrogen Generation Clean Energy

A review:Health benefits and physicochemical characteristics of blended vegetable oils

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Grain & Oil Science and Technology 2024年第2期7卷 113-123页

作者： Hina daud Memon Sarfaraz Ahmed Mahesar Sirajuddin Huseyin Kara Syed Tufail Hussain Sherazi mohammad Younis Talpur National Centre of Excellence in Analytical Chemistry University of SindhJamshoro 76080Pakistan International Center for Chemical and Biological Sciences HEJ Research Institute of ChemistryUniversity of KarachiKarachi 75270Pakistan Department of Chemistry Faculty of ScienceSelcuk UniversityKonya 42075Turkey Dr.M.A.Kazi Institute of Chemistry University of SindhJamshoro 76080Pakistan

Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional *** is no such edible oil/fat that meets all the recommendations from the health point of *** fatty acid composition of vegetable oils decides the fate of the *** single oil is unable to provide a balanced amount of fatty acids(FAs)required/recommended on a daily intake *** oils/fats is an appropriate procedure of physically mixing multiple oils in suitable proportions which may provide functional lipids with improved antioxidant potential and desirable physical and chemical *** review piled up the accessible data on the blending of diverse oils/fats in the combination of binary,ternary,quaternary,or other types of oils into a single blended *** can be found very convincing towards appropriate FA profile,enhancement in physicochemical characteristics,and augmented stability for the period of storage or when used as cooking/frying processes which could ultimately serve as an effectual dietary intervention towards the health protectiveness.

关键词： Vegetable oil Oil blending Physicochemical properties Nutritional benefits

Auto-tuning PVT data using multi-objective optimization:Application of NSGA-II algorithm

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Petroleum 2024年第1期10卷 135-149页

作者： Abdolhadi Zarifi mohammad Madani mohammad Jafarzadegan Reservoir Engineering Systems Petroleum Engineering DepartmentMain Office Building of National Iranian South Oil Company(NISOC)AhvazIran Reservoir Engineering Division Petroleum Engineering DepartmentPetroleum Engineering and Development Company(PEDEC)TehranIran Combined Planning Management National Iranian Oil Company(NIOC)TehranIran

Reservoir simulation is known as perhaps the most widely used,accurate,and reliable method for field development in the petroleum *** integral part of a reliable reservoir simulation process is to consider robust and rigorous tuned EOS ***,EOS models are tuned iteratively through arduous workflows against experimental PVT ***,this comes with a number of drawbacks such as forcingly using weight factors,which upon alteration adversely affects the optimization *** objective of the current work is thus to introduce an auto-tune PVT matching tool using NSGA-II multi-objective *** order to illustrate the robustness of the presented technique,three different PVT samples are used,including two black-oil and one gas condensate *** utilize PengRobinson EOS during all the manual and auto-tuning *** of auto-tuned EOS-generated results with those of experimental and computed statistical error values for these samples clearly show that the proposed method is *** addition,the proposed method,contrary to the manual matching process,provides the engineer with several matched solutions,which allows them to select a match based on the engineering background to be best amenable to the problem at *** addition,the proposed technique is fast,and can output several solutions within less time compared to the traditional manual matching method.

关键词： Auto-tuning PVT Equation of state NSGA-II Multi-objective optimization

Investigation of material composition,design,and performance of open-graded asphalt mixtures for semi-flexible pavement:A comprehensive experimental study

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Journal of Traffic and Transportation Engineering(English Edition) 2024年第1期11卷 92-116页

作者： mohammad Taghipoor Abolfazl Hassani mohammad M.Karimi Department of Civil and Environmental Engineering Tarbiat Modares UniversityTehranIran

The primary goal of this study is the design and construction of semi-flexible pavement(SFP)mixture in accordance with the engineering and mechanical *** study involves the use of a range of gradation curves,air void contents,cellulose and synthesized fibers,and neat and modified asphalt binders to prepare the open-graded asphalt(OGA)*** analyze the characteristics of these mixtures,a variety of test,namely binder drainage,semi-circular bending(SCB),Cantabro,wheel tracking,indirect tensile strength(ITS),and permeability tests were ***,to analyze the prepared grouting material,flexural strength,compressive strength,and fluidity tests were *** the final stage,SFP was compared to HMA in terms of engineering characteristics and *** to the results,SFP was more resistant to skid,rutting,fire,and moisture damage,while HMA had a better performance in fracture tests,including SCB *** to the results of the mechanical performance tests conducted on OGA mixtures,the highest and lowest values for air void content to achieve the highest mechanical performance level were 30%-35%and 25%,***,based on the laboratory results,it was determined that the required void ratio for constructing OGA mixtures was 24%-26%based on the bitumen type and fibers amount in the ***,SFP mixture can be regarded as a viable alternative to common pavements thanks to its high resistance to rutting and moisture damage,long freezing-thawing fatigue life,and adequate fire and skid resistance.

关键词： Semi-flexible pavement mixture Open-graded asphalt mixture Engineering properties Cantabro test Hot mix asphalt

Change in mean postoperative pain in patients undergoing tonsillectomy with cold water versus usual practice:A pragmatic trial

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World Journal of Otorhinolaryngology-Head and Neck Surgery 2024年第1期10卷 24-28页

作者： Haissan Iftikhar Nida Zahid Adan Zubair mohammad Wasif Nabeel N.Baig Khadijah Abid Muhammad Ozair awan Muhammad Sohail awan Department of Otolaryngology Queen Elizabeth HospitalBirminghamUK Department of Surgery Aga Khan University HospitalKarachiPakistan College of Physicians and Surgeons Higher Education CommissionKarachiPakistan Department of UGME Aga Khan UniversityKarachiPakistan

Introduction:Tonsillectomy is one of the most common procedures performed in *** are various methods to perform tonsillectomies(cold and hot).Thermal damage and inflammation of the surrounding tissue using monopolar cautery is said to point to increased pain whereas immediate cooling of the burnt area is thought to reduce pain owing to heat *** objective was to determine the difference in mean post‐tonsillectomy pain scores among patients irrigated with cold water(4℃)and in patients not irrigated with cold *** and Methods:A quasi‐experimental trial was conducted from January 2016 to December 2017 at a tertiary care *** tonsillectomies were carried out with monopolar cautery at a power of 20 *** either received cold water irrigation post tonsillectomy of the tonsillar bed(intervention arm)or no irrigation(control arm).The pain score was measured on Days 0,1,3,5,and *** scores were charted on a visual analog scale on the respective ***:Seventy‐eight patients were included in the *** mean age of our patients was 10.26(4.24)years old in the intervention arm,and 11.95(4.19)years old in the control *** was observed that the pain was significantly lower in patients with cold water irrigation of the tonsillar fossa on Days 1,3,5,and 7(p=0.001).There were no readmissions postprocedure and none of our patients developed any complications ***:In this trial,we report a reduced pain score at all days of observation in the intervention *** of the tonsillar fossa is a safe,cost-effective,and less technically demanding technique that could be employed to reduce postoperative *** studies with randomization,blinding and a larger sample size could further improve on our results.

关键词： cold water tonsillectomy monopoalr tonsillectomy postoperative pain tonsillectomy

Recent Progress in Bionic Hydrogels for Articular Cartilage:Tribological and Mechanical Characteristics

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Journal of Bionic Engineering 2024年第2期21卷 653-673页

作者： mohammad Javan Almasi Dangsheng Xiong School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjing210094China

Cartilage regeneration and repair are considered clinical challenges since cartilage has limited capability for *** tissue-engineered materials have the ability to repair cartilage,they have weak mechanical characteristics and cannot resist long-term *** the other hand,surgery to replace the joint is frequently done to treat significant cartilage deterioration these ***,the materials that are being used for replacement have high friction coefficients,lack shock absorption functions,and lack *** research on natural articular cartilage structure and function may lead to bionic hydrogels,which have suitable physicochemical and biological characteristics(e.g.,tribological and mechanical properties and the ability to support loadbearing capability),but need *** on their tribological and mechanical characteristics,the current review highlights the most recent advancements of bionic hydrogels used for articular cartilage,highlighting both the field's recent progress and its potential for future *** this reason,firstly,some important property improvement methods of bionic hydrogels are discussed and then,the recent findings of various research on the making of those bionic materials are provided and *** seems that by using some modifications such as product design,surface treatments,animal tests,controlling the isoelectric point of hydrogels,and computer simulation,the intended mechanical and tribological characteristics of natural articular cartilage may be attained by the bionic hydrogels.

关键词： Bionic hydrogel Articular cartilage Mechanical property Tribological property Lubrication

Ultrasensitive plasmonic sensor based on MDM waveguide containing Persian Orsi window cavities for refractive index and blood plasma sensing

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Optoelectronics Letters 2024年第7期20卷 406-411页

作者： mohammad Ghanavati mohammad Azim Karami School of Electrical Engineering Iran University of Science and TechnologyTehran 16846-13114Iran12

We developed a plasmonic refractive index(RI)with a metal-dielectric-metal(MDM)structure that utilizes two Persian Orsi windows-like separated cavities with a high figure of merit(FoM)and *** simulated and optimized Ag-air-Ag MDM sensor for surface plasmon resonance(SPR)offers high RI sensitivity(SRI)and the ability to detect blood plasma concentration(BPC).The results verified that structural parameters have an effect on SRI,full width at half maximum(FWHM),FoM,sensitivity of blood plasma(S_(p))for right and left peaks,whose values are 1345.45 nm·RIU^(−1),32 nm,42.04 RIU^(−1),0.26 and 0.19 nm·L·g^(-1),*** proposed design opens a new horizon in sensor development.

关键词： index utilize MDM

Enhanced adaptive nonlinear extended state observer for pure feedback systems with matched and mismatched disturbances

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Control Theory and Technology 2024年第2期22卷 254-268页

作者： Mahtab Delpasand mohammad Farrokhi School of Electrical Engineering Iran University of Science and TechnologyTehran16846-13114Iran Center of Excellence for Modelling and Control of Complex Systems Iran University of Science and TechnologyTehran16846-13114Iran

In this paper, an enhanced adaptive nonlinear extended state observer (EANESO) for single-input single-output pure feedback systems in the presence of external time-varying disturbances is proposed. In this paper, a nonlinear system with matched and mismatched disturbances is considered. The conventional extended state observer (ESO) can only be applied to systems that are in the form of integral chains. Moreover, this method has limitations in the face of mismatched disturbances. In the presence of time-varying disturbances, the traditional ESOs cannot estimate the disturbances accurately. To overcome this limitation, an EANESO is proposed in this paper. The main idea is to design the nonlinear ESO (NESO) to estimate the states of the system and multiple disturbances simultaneously. The observer gains are considered time-varying and adjusted with adaptation laws to improve the estimation accuracy and overcome the peaking phenomenon. Next, the proposed controller is designed based on output feedback to eliminate the effects of multiple disturbances and stabilize the closed-loop system. Subsequently, the stability analysis of the closed-loop system and convergence of the observer error are discussed. Finally, the proposed method is applied to the inverted pendulum system. The simulated results show good performance of the proposed method as compared with a recently published scheme in the related literature.

关键词： Nonlinear extended state observer Enhanced adaptive extended state observer Adaptation law Multiple-channel disturbances Inverted pendulum system Time-varying gain

The modeling non-sequential double ionization of helium atom under highintensity femtosecond laser pulses with shielding charge approximation

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Communications in Theoretical Physics 2024年第2期76卷 151-156页

作者： Marjan Zakavi mohammad Sabaeian Department of Physics Faculty of ScienceShahid Chamran University of AhvazIran Center for Research on Laser and Plasma Shahid Chamran University of AhvazIran

In this study,we successfully extracted the‘knee structure’for non-sequential double ionization(NSDI)in the helium *** achieve this,for the first time,we solved the time-dependent Schrödinger equation in three dimensions for the helium atom,utilizing the shielding charge *** findings corroborate prior observations by Wang et al[Wang and Eberly,***.105,083001(2010)],demonstrating that NSDI occurs within a narrower time window in circular polarization compared to linear *** a result,the yield of linear polarization was higher than that of circular polarization,aligning with the previously reported ***,in the case of circular polarization,the time window further narrows with increasing intensity,attributed to a decrease in the time-of-flight.

关键词： NSDI knee structure TDSE shielding charge helium 3D-TDSE