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Li2SnO3 branched nano- and microstructures with intense and broadband white-light emission

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Nano Research 2019年第2期12卷 441-448页

作者： miguel garcia-Tecedor Javier Bartolome David Maestre Achim Trampert Ana Cremades Dpt. Fisica de Materials Facultad de CC. Fisicas Universidad Complutense de Madrid Madrid 28040 Spain Paul-Drude-Institut fur Festkorperelektronik Hausvogteiplatz 5-7 Berlin 10117 Germany Institute of Advanced Materials (INAM) Universitat Jaume I Castello 12006 Spain Dpt. Fisica de Materiales Facultad de CC. Ftsicas Universidad Complutense de Madrid Madrid 28040 Spain

Exploiting the synergy between microstructure, morphology and dimensions by suitable nanomaterial engineeri ng, can effectively upgrade the physical properties and material performances. Li2SnO3 elongated nano- and microstructures in form of belts, wires, rods and branched structures have been fabricated by a vapor-solid method at temperatures ranging from 700 to 900℃ using metallic Sn and Li2CO3 as precursors. The achievement of these new morphologies can face challenging applications for Li2SnO3, not only in the field of energy storage, but also as building blocks in optoelectronic devices. The micro? and nanostructures grown at 700 and 800℃ correspond to monoclinic Li2SnO3, while at 900℃ complex Li2S nO/SnO2 core-shell microstructures are grow n, as con firmed by X-ray diffractio n and Rama n spectroscopy. Transmission electron microscopy reveals structural disorder related to stacking faults in some of the branched structures, which is associated with the prese nee of the low-temperature phase of L12S nO3. The luminescent resp onse of these structures is domi nated by in tense emissi ons at 2, 2.5 and 3 eV, almost completely covering the whole range of the visible light spectrum. As a result, white-light emission is obtained without the need of phosphors or complex quantum well heterostructures. Enhanced functionality in applications such as in light-emitting devices could be exploited based on the high luminescenee intensity observed in some of the analysed Li2SnO3 structures.

关键词： lithium oxides white light emitters nanostructures luminescenee

Land-use change and windstorms legacies drove the recolonization dynamics of laurel forests in Tenerife, Canary islands

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Forest Ecosystems 2023年第1期10卷 113-124页

作者： Vicente Rozas Maria A.garcia-Lopez Jose M.Olano Gabriel Sanguesa-Barreda miguel garcia-Hidalgo Susana Gomez-Gonzalez Roberto Lopez-Rubio Jose M.Fernandez-Palacios Ignacio garcia-Gonzalez Laura Lozano-Lopez Paula garcia-Gonzalez Ana I.garcia-Cervigon EiFAB-iuFOR Universidad de ValladolidCampus Duques de Soria42004SoriaSpain Departamento de Biologia-IVAGRO Universidad de CadizCampus Rio San Pedro11510Puerto RealSpain Center for Climate and Resilience Research(CR)2 Blanco Encalada 20028370449SantiagoChile Area de Biodiversidad y Conservacion Universidad Rey Juan Carlosc/Tulipan s/n28933MostolesSpain Grupo de Ecologia y Biogeografia Insular Universidad de La Laguna38206La LagunaTenerifeSpain BIOAPLIC Departamento de BotanicaEscola Politecnica Superior de EnxenariaCampus TerraUniversidade de Santiago de CompostelaLugo27002Spain

Laurel forests are quite relevant for biodiversity conservation and are among the island ecosystems most severely damaged by human *** the past,Canary laurel forests have been greatly altered by logging,livestock and *** remains of laurel forests are currently protected in the Canary Islands(Spain).However,we miss basic information needed for their restoration and adaptive management,such as tree longevity,growth potential and responsiveness to natural and anthropogenic *** dendrochronological methods,we studied how forest dynamic is related to land-use change and windstorms in two well-preserved laurel forests on Tenerife *** cores were collected from over 80 trees per stand at three stands per *** used ring-width series to estimate tree ages and calculate annual basal area increments(BAI),cumulative diameter increases,and changes indicative of released and suppressed *** tree species were found in all stands,with Laurus novocanariensis,Ilex canariensis and Morella faya being the most common *** some individuals were over 100 years old,61.8%-88.9% of the trees per stand established between 1940 and 1970,coinciding with a post-war period of land abandonment,rural exodus and the onset of a tourism *** trees have shown growth rates larger than 1 cm diameter per year and most species have had increasing BAI trends over the past *** growth releases occurred after windstorms at both sites,but the effects of windstorms were site-dependent,with the 1958 storm affecting mainly the eastern tip of the island(Anaga massif)and the 1991 storm the western tip(Teno massif).Given the great ability of laurel forest trees to establish after land use cessation and to increase growth after local disturbances such as windstorms,passive restoration may be sufficient to regenerate this habitat in currently degraded areas.

关键词： Canary islands Dendroecology Disturbance Forest structure Macaronesia Management cessation Tree rings

Asthma, bronchiectasis, and chronic obstructive pulmonary disease: the Bermuda Triangle of the airways

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Chinese Medical Journal 2022年第12期135卷 1390-1393页

作者： miguel Angel Martinez garcia Joan B.Soriano Pneumology Department Hospital Universitario y Politecnico la Fe de ValenciaSpain CIBERES de enfermedades respiratorias Instituto de salud Carlos IIIMadridSpain Servicio de Neumologia Hospital Universitario de la PrincesaMadridSpain Facultad de Medicina Universidad Autonoma de MadridMadridSpain

Also known as the Devil's Triangle or Hurricane Alley,the Bermuda Triangle is an area of the Atlantic Ocean with vertices in Miami,San Juan de Puerto Rico,and Bermuda,which has been credited for causing mass disappear... 详细信息

关键词： airway obstructive Atlantic

Optimal Design of Hybrid Microgrid in Isolated Communities of Ecuador

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Journal of Modern Power Systems and Clean Energy 2024年第2期12卷 488-499页

作者： Luis A.Pesantes Ruben Hidalgo-León Johnny Rengifo miguel Torres Jorge Aragundi JoséCordova-garcia Luis F.Ugarte Facultad de Ingeniería en Electricidad y Computación of Escuela Superior Politécnica del Litoral(ESPOL)University GuayaquilEcuador Department of Electrical Engineering at Universidad Técnica Federico Santa María SantiagoChile IEEE

In rural territories, the communities use energy sources based on fossil fuels to supply themselves with electricity, which may address two main problems: greenhouse gas emissions and high fuel prices. Hence, there is an opportunity to include renewable resources in the energy mix. This paper develops an optimization model to determine the optimal sizing, the total annual investment cost in renewable generation, and other operating costs of the components of a hybrid microgrid. By running a k-means clustering algorithm on a meteorological dataset of the community under study, the hourly representative values become input parameters in the proposed optimization model. The method for the optimal design of hybrid microgrid is analyzed in six operating scenarios considering:(1) 24-hour continuous power supply;(2) load shedding percentage;(3) diesel power generator(genset) curtailment;(4) the worst meteorological conditions;(5) the use of renewable energy sources including battery energy storage systems(BESSs);and(6) the use of genset. A mathematical programming language(AMPL) tool is used to find solutions of the proposed optimization model. Results show that the total costs of microgrid in the scenarios that cover 100% of the load demand(without considering the scenario with 100% renewables) increase by over 16% compared with the scenario with genset operation limitation. For the designs with power supply restrictions, the total cost of microgrid in the scenario with load shedding is reduced by over 27% compared with that without load shedding.

关键词： Battery energy storage system(BESS) isolated community microgrid renewable energy optimization

Candelilla Wax as Natural Slow-Release Matrix for Fertilizers Encapsulated by Spray Chilling

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Journal of Renewable Materials 2018年第3期6卷 226-236页

作者： Noe Navarro-Guajardo Edgar miguel garcia-Carrillo Carlos Espinoza-Gonzalez Ruben Tellez-Zablah Fatima Davila-Hernandez Jorge Romero-garcia Antonio Ledezma-Perez Jesus Alfonso Mercado-Silva Claudia Anahi Perez Torres Nicolaza Pariona Technological Institute of Saltillo Blvd.Venustiano Carranza 2400C.P.25280SaltilloCoahuilaMéxico Research Center for Applied Chemistry Sonomimetikos Research GroupBlvd.Enrique Reyna Hermosillo 140C.P.25294SaltilloCoahuilaMéxico Research Center for Applied Chemistry National Laboratory of GrapheneBlvd.Enrique Reyna Hermosillo 140C.P.25294SaltilloCoahuilaMéxico CONACyT–Institute of Ecology A.C. Carretera antigua a Coatepec 351El HayaC.P.91070XalapaVeracruzMéxico Network for Advanced Molecular Studies Institute of Ecology A.C.Carretera antigua a Coatepec 351El HayaC.P.91070XalapaVeracruzMéxico

Efforts to improve crop yields with efficient use of fertilizers are needed to guarantee global food *** slow-release fertilizer systems(SRFs)encapsulated in biodegradable matrices are being developed to address this global *** a wide range of strategies for SRFs development,we explored a natureinspired solution based on the plant cuticle model and its function as a membrane for water and nutrient transport ***,Candelilla wax,extracted from Candelilla wild plants(Euphorbia antisyphilitica),is studied as a renewable slow-release matrix for fertilizers encapsulated by a modified spray chilling *** this process,microencapsulates containing 40 wt%of phosphorus fertilizer are obtained with distinctive sizes and chemical characteristics,presenting a slow-release *** the abovementioned features,novel insights into fertilizer release mechanisms based on plant cuticle models are discussed.

关键词： Candelilla wax encapsulation phosphorus slow-release fertilizers(SRFs) spray chilling

Bronchiectasis and COVID-19 infection:a two-way street

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Chinese Medical Journal 2022年第20期135卷 2398-2404页

作者： Grace Oscullo Jose DanieGómez-Olivas Thais Beauperthuy AminaBekki Alberto garcia-Ortega Maria Gabriella Matera Mario Cazzola miguel Angel Martinez-garcia Department of Pneumology Hospital Universitario y Politécnico la Fe de ValenciaValencia 46012Spain Department of Experimental Medicine University of Campania“Luigi Vanvitelli”Naples 80121Italy Department of Experimental Medicine University of Rome Tor VergataRome 00185Italy CIBERES de enfermedades respiratorias Instituto de Salud Carlos IIIMadrid 41263Spain

Bronchiectasis(BE)has been linked to past viral infections such as influenza,measles,or *** years ago,a new pandemic viral infection severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)broke out and it still persists today,and a significant proportion of surviving patients have radiological and clinical sequelae,including *** aim was to thoroughly review the information available in the literature on the bidirectional relationship between SARS-CoV-2 infection and the development of BE,as well as the impact of this infection on patients already suffering from *** information indicates that only a small percentage of patients in the acute phase of coronavirus disease 2019(COVID-19)pneumonia develop BE,although the latter is recognized as one of the radiological sequelae of COVID-19 pneumonia,especially when it is caused by *** severity of the initial pneumonia is the main risk factor for the development of future BE,but during the COVID-19 pandemic,exacerbations in BE patients were reduced by approximately 50%.Finally,the impact of BE on the prognosis of patients with COVID-19 pneumonia is not yet known.

关键词： Bronchiectasis Coronavirus COVID-19 SARS-CoV-2

Environmental Pollution and Economic Growth in China: A Test of the Environmental Kuznets Curve

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Journal of Geoscience and Environment Protection 2017年第10期5卷 92-100页

作者： Jiaqi Hu Adrian Hernandez-del-Valle miguel A. Martinez-garcia SEPI-ESE-Instituto Politécnico Nacional Mexico City Mexico

We apply a two pronged approach to analyze the presence of Environmental Kuznets Curve, EKC, in three types of emissions in the People’s Republic of China from 1994 to 2014: a structural breakpoint analysis and a model based test. We apply it to PM2.5, industrial waste and domestic water pollution time series, and find evidence of EKC in all three types of emissions that require appropriate policy.

关键词： Economic Growth Environmental Kuznets Curve PM2.5 Domestic Water Pollution Industrial Waste China

Antimicrobial Activity, Structural, Crystallographic and Thermal Characteristics of Alpha-Titanium Phosphate Promoted by Silver Ions

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Materials Sciences and Applications 2024年第8期15卷 253-269页

作者： Enzo Erbisti garcia Agnes Maria Cupertino Fernandes Araujo Gerson Alberto Valencia Albitres Daniela de França da Silva Freitas Danielle Mattos Mariano Carlos Magno Fialho Soares Sibele Piedade Cestari Marco Antônio Lemos miguel Luis Claudio Mendes Institute of Macromolecules Professora Eloisa Mano Federal University of Rio de Janeiro Avenida Horacio Macedo 2030 Centro de Tecnologia Bloco J Ilha do Fundo Rio de Janeiro Brazil Institute of Microbiology Paulo de Ges Federal University of Rio de Janeiro Centro de Ciencias da Saude Bloco I Ilha do Fundo Rio de Janeiro Brazil Innovation in Polymer Engineering (PIEP) University of Minho Guimares Portugal

The recent global spread of the pandemic underscores the necessity of seeking new materials effective against microorganisms. Nanotechnology offers avenues for developing multifunctional materials. In this study, alpha-titanium phosphate (α-TiP) nanoparticles were synthesized and treated with silver salt to enhance their antimicrobial properties. The physicochemical characteristics and antimicrobial activity were evaluated. It was revealed by X-ray diffraction analysis that the structural integrity of α-TiP was influenced by ethylenediamine and silver ions. Distinct degradation profiles for each chemical modification were shown by thermogravimetric analysis. Infrared spectroscopy detected shifts and new absorption peaks in the spectra depending on the type of modification. Energy dispersive spectroscopy confirmed the disaggregation of α-TiP galleries following the addition of silver salt, which increased their effectiveness against microorganisms. Notably, only the sample treated with silver ions exhibited antimicrobial action. Antimicrobial activity was tested against the bacteria of medical importance Escherichia coli, Salmonella Enteritidis, Pseudomonas aeruginosa, Staphylococcus aureus, Bacillus cereus, Listeria momocytogenes and the yeast Candida albicans. All microorganisms were inhibited by sample containing silver. Minor inhibition was observed against the Gram-positive bacteria L. monocytogenes and Bacillus cereus, while the greatest inhibition occurred against the fungus (yeast) C. albicans. The results revealed a potential application of the nanoparticles for control of microorganisms in public health.

关键词： Titanium Phosphate Silver Nitrate Antimicrobial Action

Adenomyomatosis of the gallbladder in childhood: A systematic review of the literature and an additional case report

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World Journal of Clinical Pediatrics 2016年第2期5卷 223-227页

作者： Filippo Parolini Giuseppe Indolfi miguel garcia Magne Marianna Salemme Maurizio Cheli Giovanni Boroni Daniele Alberti Department of Paediatric Surgery "Spedali Civili" Children's Hospital Department of Paediatrics "Meyer" Children’s University Hospital Department of Pathology "Spedali Civili" Hospital Department of Paediatric Surgery "Papa Giovanni XXⅢ" Hospital Clinical and Experimental Sciences University of Brescia

AIM: To investigate the diagnostic and therapeutic assessment in children with adenomyomatosis of the gallbladder(AMG).METHODS: AMG is a degenerative disease characterized by a proliferation of the mucosal epithelium which deeply invaginates and extends into the thickened muscular layer of the gallbladder, causing intramural diverticula. Although AMG is found in up to 5% of cholecystectomy specimens in adult populations, this condition in childhood is extremely uncommon. Authors provide a detailed systematic review of the pediatric literature according to PRISMA guidelines, focusing on diagnostic and therapeutic assessment. An additional case of AMG is also presented. RESULTS:Five studies were finally enclosed, encompassing 5 children with AMG. Analysis was extended to our additional 11-year-old patient, who presented diffuse AMG and pancreatic acinar metaplasia of the gallbladder mucosa and was successfully managed with laparoscopic cholecystectomy. Mean age at presentation was 7.2 years. Unspecific abdominal pain was the commonest symptom. Abdominal ultrasound was performed on all patients, with a diagnostic accuracy of 100%. Five patients underwent cholecystectomy, and at follow-up were asymptomatic. In the remaining patient, completely asymptomatic at diagnosis, a conservative approach with monthly monitoring via ultrasonography was undertaken. CONCLUSION: Considering the remote but possible degeneration leading to cancer and the feasibility of laparoscopic cholecystectomy even in small children, evidence suggests that elective laparoscopic cholecystectomy represent the treatment of choice. Preoperative evaluation of the extrahepatic biliary tree anatomy with cholangio-MRI is strongly recommended.

关键词： Adenomyomatosis Children Gallbladder Laparoscopy Ultrasound