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Metal-Organic Framework-Based Solid Acid Materials for Biomass Upgrade

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Transactions of Tianjin University 2021年第6期27卷 434-449页

作者： Yutian Qin Jun Guo Meiting Zhao Tianjin Key Laboratory of Molecular Optoelectronic Sciences Institute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China School of Chemistry Tiangong UniversityTianjin 300387China

Biomass is a green and producible source of energy and chemicals.Hence,developing high-efficiency catalysts for biomass utilization and transformation is urgently demanded.Metal-organic framework(MOF)-based solid acid materials have been considered as promising catalysts in biomass transformation.In this review,we first introduce the genre of Lewis acid and Brønsted acid sites commonly generated in MOFs or MOF-based composites.Then,the methods for the generation and adjustment of corresponding acid sites are overviewed.Next,the catalytic applications of MOF-based solid acid materials in various biomass transformation reactions are summarized and discussed.Furthermore,based on our personal insights,the challenges and outlook on the future development of MOF-based solid acid catalysts are provided.We hope that this review will provide an instructive roadmap for future research on MOFs and MOF-based composites for biomass transformation.

关键词： Metal-organic framework Solid acid Catalysis Biomass Glucose

Combining metal-organic frameworks(MOFs)and covalentorganic frameworks(COFs):Emerging opportunities for new materials and applications

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Nano Research 2022年第4期15卷 3514-3532页

作者： Zhixi Li Jun Guo Yue Wan Yutian Qin Meiting Zhao Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China School of Chemistry Tiangong UniversityTianjin 300387China

In the past decades,metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)basically enjoy the coordination chemistry and covalent chemistry,respectively,and such uniqueness has become the major obstacle hampering their further scope diversity and application multi-functionalization.Inspired from the principle of organic retrosynthesis,combining coordination bond and covalent bond together offers additional opportunities for constructing novel MOFs,COFs and MOF@COF hybrids as well as confer on them superior performances in versatile application fields.In this review,we firstly classify and summarize the recently reported synthesis strategies based on the integration of metal-ligand coordination and dynamic covalent bonds.Then,the application performances of as-constructed MOFs,COFs as well as MOF@COF hybrids are discussed and highlighted in the fields of adsorption,separation,catalysis,biosensing,energy storage and so on.Last,our personal insights of the remaining challenges and further prospects are also provided,in order to trigger much more inspirations and endeavors for this hot research field.

关键词： metal-organic frameworks(MOFs) covalent organic frameworks(COFs) hybrids coordination chemistry covalent chemistry applications

Controllable NO Release for Catheter Antibacteria from Nitrite Electroreduction over the Cu-MOF

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天津大学学报:英文版 2023年第4期29卷 275-283页

作者： Yibo Wang Yutian Qin Wei Li Yuting Wang Lina Zhu Meiting Zhao Yifu Yu Institute of Molecular Plus Department of ChemistrySchool of ScienceTianjin UniversityTianjin 300072China Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China College of Chemistry Nankai UniversityTianjin 300071China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

Implant-associated infections caused by biomedical catheters severely threaten patients'health.The use of electrochemical control on NO release from benign nitrite equipped in the catheter can potentially resolve this issue with excellent biocompatibility.Inspired by nitrite reductase,a Cu-BDC(BDC:benzene-1,4-dicarboxylic acid)catalyst with coordinated Cu(Ⅱ)sites was constructed as a heterogeneous electrocatalyst to control nitrite reduction to nitric oxide for catheter antibacteria.The combined results of in situ and ex situ tests unveil the key function of interconversion between Cu(Ⅱ)and Cu(Ⅰ)species in NO_(2)^(-)reduction to NO.After being incorporated into the actual catheter,the Cu-BDC catalyst exhibits high electrocatalytic activity toward NO_(2)^(-)reduction to NO and excellent antibacteria efficacy with a sterilizing rate of 99.9%,paving the way for the development of advanced metal-organic frameworks(MOFs)electrocatalysts for catheter antibacteria.

关键词： Heterogeneous electrocatalysis Nitrite electroreduction NO-releasing catheter Antibacterial MOF material

Dark Forest Algorithm:A Novel Metaheuristic Algorithm for Global Optimization Problems

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Computers, Materials & Continua 2023年第5期75卷 2775-2803页

作者： Dongyang Li Shiyu Du Yiming Zhang Meiting Zhao Faculty of Electrical Engineering and Computer Science Ningbo UniversityNingbo315000China Engineering Laboratory of Advanced Energy Materials Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo315000China School of Material and Chemical Engineering Ningbo UniversityNingbo315000China

Metaheuristic algorithms,as effective methods for solving optimization problems,have recently attracted considerable attention in science and engineering fields.They are popular and have broad applications owing to their high efficiency and low complexity.These algorithms are generally based on the behaviors observed in nature,physical sciences,or humans.This study proposes a novel metaheuristic algorithm called dark forest algorithm(DFA),which can yield improved optimization results for global optimization problems.In DFA,the population is divided into four groups:highest civilization,advanced civilization,normal civilization,and low civilization.Each civilization has a unique way of iteration.To verify DFA’s capability,the performance of DFA on 35 well-known benchmark functions is compared with that of six other metaheuristic algorithms,including artificial bee colony algorithm,firefly algorithm,grey wolf optimizer,harmony search algorithm,grasshopper optimization algorithm,and whale optimization algorithm.The results show that DFA provides solutions with improved efficiency for problems with low dimensions and outperforms most other algorithms when solving high dimensional problems.DFAis applied to five engineering projects to demonstrate its applicability.The results show that the performance of DFA is competitive to that of current well-known metaheuristic algorithms.Finally,potential upgrading routes for DFA are proposed as possible future developments.

关键词： Metaheuristic algorithm global optimization

Dynamically modulated synthesis of hollow metal-organic frameworks for selective hydrogenation reactions

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Nano Research 2023年第8期16卷 11334-11341页

作者： Liyun Xiao Chuanqi Cheng Zhixi Li Chaoyang Zheng Jing Du Meina Song Yue Wan Shaopeng Li Guo Jun Meiting Zhao Department of Chemistry Institute of Molecular Aggregation ScienceTianjin Key Laboratory of Molecular Optoelectronic SciencesTianjin UniversityTianjin 300072China Institute of New Energy Materials School of Materials Science and EngineeringTianjin UniversityTianjin 300072China State Key Laboratory of Separation Membranes and Membrane Processes School of ChemistryTiangong UniversityTianjin 300387China

Hollow metal-organic frameworks(MOFs)have attracted increasing attention in the field of catalysis in recent years due to their unique cavity structure with fast mass-diffusion rates and easily accessible active sites.Here,we report the use of dynamic modulators,which are formed by the in-situ imine condensation reaction of 4-aminobenzoic acid and 4-formylbenzoic acid,to regulate the growth of MOFs to synthesize well-defined hollow thioether functionalized UiO-67(denoted as H-UiO-67-S)single crystals.After supporting Pd nanoparticles,the designed catalysts Pd@H-UiO-67-S show excellent conversion(>99.9%),selectivity(>99.9%),and stability(10 cycles)in the selective hydrogenation of nitrobenzenes with other reducible groups.Density functional theory calculations and the experimental results reveal that Pd nanoparticles not only selectively adsorb the nitro-groups on nitrobenzene,but also restrict the adsorption of the aniline product,due to the interaction of thioether with Pd in the confined pores of H-UiO-67-S,finally result in a significant increase in selectivity of nitro-hydrogenation.

关键词： hollow structure metal-organic frameworks(MOFs) dynamically modulated synthesis selective hydrogenation nitrobenzene

Advanced photocatalysts based on metal nanoparticle/metalorganic framework composites

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Nano Research 2021年第7期14卷 2037-2052页

作者： Jun Guo Yue Wan Yanfei Zhu Meiting Zhao Zhiyong Tang Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

Photocatalysis,via conversion of light into valuable chemicals,is an economic and effective way to utilize inexhaustible solar energy for the sustainable development of our human society.Aiming at killing two birds with one stone,metal nanoparticle(MNP)/metal-organic framework(MOF)composites via integration of the individual advantages of MNP and MOF have been becoming a versatile photocatalyst.Moreover,owing to the synergist effect between each component,MNP/MOF composite photocatalysts usually show greatly promoted catalytic activity,selectivity and long-term recyclability.In this review,first of all,the widely adopted synthesis strategies of MNP/MOF composite are introduced comprehensively,and then their recent advances in photocatalysis including photocatalytic hydrogen production,carbon dioxide reduction,organic transformation reactions and photodegradation of pollutants are summarized and highlighted.Finally,challenges and perspectives among MNP/MOF based photocatalysis are also proposed and discussed for advancing further development in this hot research field.

关键词： metal nanoparticles metal-organic frameworks composite photocatalysis

Temperature Gradient Analyses of a Tubular Solid Oxide Fuel Cell Fueled by Methanol

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Transactions of Tianjin University 2023年第1期29卷 14-30页

作者： Qidong Xu meiting Guo Lingchao Xia Zheng Li Qijiao He Dongqi zhao Keqing Zheng Meng Ni Department of Building and Real Estate Research Institute for Sustainable Urban Development(RISUD)&Research Institute for Smart Energy(RISE)The Hong Kong Polytechnic UniversityHong Kong 999077China School of Artifi cial Intelligence and Automation Key Laboratory of Image Processing and Intelligent ControlHuazhong University of Science and TechnologyWuhan 430074China School of Low-Carbon Energy and Power Engineering China University of Mining and TechnologyXuzhou 221116China

Thermal management in solid oxide fuel cells(SOFC)is a critical issue due to non-uniform electrochemical reactions and convective fl ows within the cells.Therefore,a 2D mathematical model is established herein to investigate the thermal responses of a tubular methanol-fueled SOFC.Results show that unlike the low-temperature condition of 873 K,where the peak temperature gradient occurs at the cell center,it appears near the fuel inlet at 1073 K because of the rapid temperature rise induced by the elevated current density.Despite the large heat convection capacity,excessive air could not eff ectively eliminate the harmful temperature gradient caused by the large current density.Thus,optimal control of the current density by properly selecting the operating potential could generate a local thermal neutral state.Interestingly,the maximum axial temperature gradient could be reduced by about 18%at 973 K and 20%at 1073 K when the air with a 5 K higher temperature is supplied.Additionally,despite the higher electrochemical performance observed,the cell with a counter-fl ow arrange-ment featured by a larger hot area and higher maximum temperature gradients is not preferable for a ceramic SOFC system considering thermal durability.Overall,this study could provide insightful thermal information for the operating condition selection,structure design,and stability assessment of realistic SOFCs combined with their internal reforming process.

关键词： Solid oxide fuel cell Modeling Methanol fuel Temperature gradient Internal reforming

Ultra-thin metal-organic framework nanoribbons

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National Science Review 2020年第1期7卷 46-52页

作者： Bingqing Wang Meiting Zhao Liuxiao Li Ying Huang Xiao Zhang Chong Guo Zhicheng Zhang Hongfei Cheng Wenxian Liu Jing Shang Jing Jin Xiaoming Sun Junfeng Liu Hua Zhang State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Center for Programmable Materials School of Materials Science and Engineering Nanyang Technological University Department of Chemistry City University of Hong Kong

Structure engineering of metal-organic frameworks(MOFs) at the nanometer scale is attracting increasing interest due to their unique properties and new functions that normally cannot be achieved in bulk MOF crystals. Here, we report the preparation of ultra-thin MOF nanoribbons(NRBs) by using metal-hydroxide nanostructures as the precursors. Importantly, this general method can be used to synthesize various kinds of ultra-thin MOF NRBs, such as MBDC(M = Co, Ni; BDC = 1,4-benzenedicarboxylate), NiCoBDC,CoTCPP(TCPP = tetrakis(4-carboxyphenyl)porphyrin) and MIL-53(Al) NRBs. As a proof-of-concept application, the as-prepared ultra-thin Co BDC NRBs have been successfully used as a fluorescent sensing platform for DNA detection, which exhibited excellent sensitivity and selectivity. The present strategy might open an avenue to prepare MOF nanomaterials with new structures and unique properties for various promising applications.

关键词： metal-organic frameworks nanoribbons metal-hydroxide nanostructures structure engineering DNA detection

Size engineering of 2D MOF nanosheets for enhanced photodynamic antimicrobial therapy

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中国化学快报:英文版 2023年第9期34卷 219-224页

作者： Baoli Xue Xiwen Geng Haohao Cui Huiying Chen Zhikang Wu Hong Chen Hai Li Zhan Zhou Meiting Zhao Chaoliang Tan Jingguo Li Henan Provincial People’s Hospital People’s Hospital of Zhengzhou UniversityZhengzhou 450003China College of Chemistry and Chemical Engineering Henan Key Laboratory of Function-Oriented Porous MaterialsLuoyang Normal UniversityLuoyang 471934China Luoyang Key Laboratory of Organic Functional Molecules College of Food and DrugLuoyang Normal UniversityLuoyang 471934China Institute of Advanced Materials(IAM)and Key Laboratory of Flexible Electronics(KLoFE) Nanjing Tech University(NanjingTech)Nanjing 211816China Department of Chemistry Institute of Molecular Aggregation ScienceTianjin Key Laboratory of Molecular Optoelectronic SciencesTianjin UniversityTianjin 300072China Department of Chemistry and Center of Super-Diamond and Advanced Films(COSDAF) City University of Hong KongHong Kong 999077China Shenzhen Research Institute City University of Hong KongShenzhen 518057China Pharmaceutical Sciences Laboratory Abo Akademi UniversityTurku 20520Finland

Although porphyrin-based metal-organic frameworks(MOFs)have been widely explored as photosensitizers for photodynamic therapy,how the size will affect the light-induced catalytic activity for generation of reactive oxygen species(ROS)still remain unclear.Herein,we first report the size-controlled synthesis of two-dimensional(2D)porphyrin-based PCN-134 MOF nanosheets by a two-step solvothermal method to explore the size effect on its PDT performance,thus yielding enhanced photodynamic antimicrobial therapy.By simply controlling the reaction temperature in the synthesis process,the bulk PCN-134 crystal,large PCN-134(L-PCN-134)nanosheets with a lateral size of 2–3μm and thickness of 33.2–37.5 nm and small PCN-134 nanosheets(S-PCN-134)with a lateral size of 160–180 nm and thickness of 9.1–9.7 nm were successfully prepared.Interestingly,the S-PCN-134 nanosheets exhibit much higher photodynamic activity for ROS generation than that of the bulk 3D PCN-134 crystal and L-PCN-134 nanosheets under a660 nm laser irradiation,suggesting that the photodynamic activity of PCN-134 MOF increases when the size reduces.Therefore,the S-PCN-134 nanosheets show much enhanced performance when used as a photosensitizer for photodynamic antimicrobial activity and wound healing.

关键词： 2D nanosheets PCN-134 MOFs Size effect Photodynamic therapy Antibacterial