Metal-Organic Framework-Based Solid Acid Materials for Biomass Upgrade

作     者：Yutian Qin Jun Guo Meiting Zhao Yutian Qin;Jun Guo;Meiting Zhao

作者机构：Tianjin Key Laboratory of Molecular Optoelectronic SciencesInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China School of ChemistryTiangong UniversityTianjin 300387China 

出 版 物：《Transactions of Tianjin University》 (天津大学学报（英文版）)

年 卷 期：2021年第27卷第6期

页      面：434-449页

核心收录：

学科分类：0820[工学-石油与天然气工程] 080703[工学-动力机械及工程] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：funded by the National Natural Sci-ence Foundation of China(No.21905195) Natural Science Foundation of Tianjin City(No.20JCYBJC00800) PEIYANG Young Scholars Program of Tianjin University(No.2020XRX-0023). 

主　　题：Metal-organic framework Solid acid Catalysis Biomass Glucose 

摘      要：Biomass is a green and producible source of energy and chemicals.Hence,developing high-efficiency catalysts for biomass utilization and transformation is urgently demanded.Metal-organic framework(MOF)-based solid acid materials have been considered as promising catalysts in biomass transformation.In this review,we first introduce the genre of Lewis acid and Brønsted acid sites commonly generated in MOFs or MOF-based composites.Then,the methods for the generation and adjustment of corresponding acid sites are overviewed.Next,the catalytic applications of MOF-based solid acid materials in various biomass transformation reactions are summarized and discussed.Furthermore,based on our personal insights,the challenges and outlook on the future development of MOF-based solid acid catalysts are provided.We hope that this review will provide an instructive roadmap for future research on MOFs and MOF-based composites for biomass transformation.