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New Applications of Zirconium Phosphate Nanomaterials

Accounts of Materials Research 2021年第9期2卷 793-803页

作者： mario v.ramos-garcés Julissa González-villegas Aleannette López-Cubero Jorge L.Colón Cain Department of Chemical Engineering Louisiana State UniversityBaton RougeLouisiana 70803United States Department of Chemistry University of Puerto RicoSan JuanPuerto Rico 00925-2537United States

CONsPECTUs:The 2-D layers of the inorganic ion exchangerα-zirconium phosphate(Zr(HPO_(4))2·H_(2)O,α-ZrP)make this compound particularly stable to low pH,high temperature,and ionizing *** studied for its ion exchange properties,once the conditions for its synthesis in crystalline form was accomplished by James stynes and Abraham Clearfield in 1964,numerous other types of studies and applications *** studies in the 1960s and 1970s on the thermodynamics of ion exchange led to insights into the intercalation mechanism of this *** Clearfield group solved the crystal structure in 1968 and refined it in *** methods were pioneered by the Clearfield group to solve the structure of this type of *** 1968 Giulio Alberti reported means to prepare zirconium phosphonates expanding the chemistry of these layered *** phases of ZrP were also discovered(e.g.,γ,θ,λ,τ)and the applications ranged from heterogeneous catalysis to intercalation chemistry and solid-state proton *** to exfoliate the layers of ZrP were developed in the 1990s as interest grew in new applications of these types of *** example,protein and enzyme intercalation was accomplished starting in the 1990s by the McLendon,Mallouk,and Kumar *** the early 2000s,the Colon group pioneered the use of théθphase of ZrP for the direct intercalation of large inorganic metal complexes that could not be directly intercalated into theα*** studies in the Colon group ranged from applications of these directly intercalated ZrP derivatives in photophysics and photochemistry,́amperometric biosensors,vapochromism,and *** the past decade,new applications of these materials have been developed in anticancer drug delivery and electrocatalysis of the oxygen evolution reaction(OER).ZrP has now proven to be a promising drug nanocarrier and its unique chemical microenvironment provided by theα-type layers and the interlay

关键词： properties zirconium inorganic

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Geochemistry and mineralogy of beach sediments in the northern Gulf of Mexico,Tamaulipas state,Mexico:implication for provenance

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Journal of Palaeogeography 2024年第3期13卷 375-400页

作者： Mayank shukla sanjeet K.verma Mayla A.ramos-vázquez John s.Armstrong-Altrin Karla R.Hernández-Martínez sumit Mishra vivek P.Malviya Héctor Hernández-Mendoza Posgrado de la Division de Geociencias Aplicadas Instituto Potosino de Investigacion Científica y Tecnologica(IPICYT)Camino a la Presa San José2055San Luis Potosí78216Mexico Division de Geociencias Aplicadas Instituto Potosino de Investigación Científica y Tecnologica(IPICYT)Camino a la Presa San Jose 2055San Luis Potosí78216Mexico Universidad Nacional Autonoma de México Instituto de Ciencias del Mar y LimnologíaUnidad de ProcesosOceanicos y CosterosCiudad UniversitariaCiudad de México 04510Mexico Department of Marine sciences Bharathidasan UniversityTiruchirappalli620024Tamil NaduIndia Instituto de Geociencias Universidad Nacional Autonoma de MéxicoBoulevard Juriquilla 300176230JuriquillaQueretaroMexico Department of Applied Geology Dr.Harisingh Gour Central UniversitySagar470002Madhya PradeshIndia Instituto de Investigacion de Zonas Desérticas Universidad Autònoma de San Luis PotosíAltair 200CP 78377San LuisS.L.P.Mexico Universidad del Centro de Mexico Capitán Caldera 75CP 78250San LuisS.L.P.Mexico

Geochemical and mineralogical studies were performed in the La Pesca(LP)and Tesoro Altamira(TA)beach sediments,located in the Tamaulipas state,northern Gulf of *** main aim of this study is to infer the weathering history and provenance and to discriminate the tectonic environment of the beach *** sediments are composed of quartz with small amounts of accessory minerals such as plagioclase,calcite,orthoclase,microcline,and *** beach sediments are classified as fine-grained and very well sorted,however LP has coarse skewed and leptokurtic sediments,whereas TA has fine-skewed and very leptokurtic *** chemical index of weathering(CIW’)indicates intense weathering in the source *** quartz grain microtextures in the LP and TA are classified into mechanical,chemical,and mechanical/chemical *** features such as fractures,pits,percussion marks,abrasion fatigue,and v-shaped marks favor high-energy littoral,fluvial,subaqueous-marine,and aeolian *** chemical features indicate solution pits and crystalline overgrowth,which suggests a silica saturated marine *** mechanical/chemical features display adhering particles and elongated depressions suggest formation in a sub-aqueous nearshore marine *** and trace elements-based provenance discrimination diagrams indicate a felsic source derived from the Mesa Central(MC),sierra Madre Oriental(sMOr)and Oaxaquia *** major and trace element concentrations imply a passive margin setting for the northern Gulf of Mexico,which is consistent with the general geology.

关键词： Beach sediments Geochemistry Mineralogy Provenance Tamaulipas Tectonic setting

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Influence of cardiorespiratory fitness and body composition on resting and post-exercise indices of vascular health in young adults

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sports Medicine and Health science 2024年第1期6卷 54-62页

作者： Rian Q.Landers-ramos Kathleen Dondero Ian Imery Nicholas Reveille Hannah A.Zabriskie Devon A.Dobrosielski Towson University Department of KinesiologyTowsonMDUSA University of Maryland school of Medicine Department of Physical Therapy and Rehabilitation SciencesBaltimoreMDUSA Johns Hopkins University Department of Cell BiologyBaltimoreMDUSA University of Florida Department of Applied Physiology and KinesiologyGainesvilleFLUSA

Poor cardiorespiratory fitness may mediate vascular impairments at rest and following an acute bout of exercise in young healthy *** study aimed to compare flow mediated dilation(FMD)and vascular augmentation index(AIx75)between young adults with low,moderate,and high levels of cardiorespiratory fitness before and after an acute bout of aerobic ***-three participants(22 men;21 women)between 18 and 29 years of age completed the *** were classified into low,moderate,and high health-related cardiorespiratory fitness groups according to age-and sex-based relative maximal oxygen consumption(v_O2 max)percentile *** was performed using Doppler ultrasound and AIx75 was performed using pulse wave analysis at baseline and 60-min after a 30-min bout of treadmill running at 70%v_O2 max.A significant interaction(p=0.047;ηp 2=0.142)was observed,with the moderate fitness group exhibiting a higher FMD post-exercise compared with baseline([6.7%3.1%]vs.[8.5%2.8%],p=0.028;d=0.598).We found a significant main effect of group for AIx75(p=0.023;ηp 2=0.168),with the high fitness group exhibiting lower AIx75 compared to low fitness group([10%10%]vs.[2%10%],respectively,p=0.019;g=1.07).This was eliminated after covarying for body fat percentage(p=0.489).Our findings suggest that resting FMD and AIx75 responses are not significantly influenced by cardiorespiratory fitness,but FMD recovery responses to exercise may be enhanced in individuals with moderate cardiorespiratory fitness levels.

关键词： Cardiorespiratory fitness Flow mediated dilation Augmentation index vascular Acute exercise Body composition

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Plant growth and metabolism of exotic and native Crotalaria species for mine land rehabilitation in the Amazon

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Journal of Forestry Research 2024年第1期35卷 143-154页

作者： Hemelyn soares das Chagas Rafael silva Guedes Markus Gastauer Paula Godinho Ribeiro Allan Klynger da silva Lobato Cecílio Frois Caldeira Fabrício William deÁvila AndréRodrigues dos Reis silvio Junio ramos Instituto Tecnológico vale Rua Boaventura da Silva955BelémPA 66055-090Brazil Universidade Federal do sul e sudeste do Pará XinguaraPABrazil Núcleo de Pesquisa vegetal Básica e Aplicada Universidade Federal Rural da AmazôniaParagominasPABrazil Departamento de Engenharia Florestal Universidade Estadual do Centro-Oeste/UNICENTROIratiPRBrazil school of sciences and Engineering São Paulo State University(UNESP)TupãSP.CEP 17602-496Brazil

Despite its enormous benefits,mining is respon-sible for intense changes to vegetation and soil ***,after extraction,it is necessary to rehabilitate the mined areas,creating better conditions for the establishment of plant species which is *** study evaluated mineral and organic fertilization on the growth,and carbon and nitrogen(N)metabolism of two Crotalaria species[Cro-talaria spectabilis(exotic species)and Crotalaria maypu-rensis(native species from Carajás Mineral Province(CMP)]established on a waste pile from an iron mine in CMP.A control(without fertilizer application)and six fertilization mixtures were tested(i=NPK;ii=NPK+micronutrients;iii=NPK+micronutrients+organic compost;iv=PK;v=PK+micronutrients;vi=PK+micronutrients+organic compost).Fertilization contributed to increased growth of both species,and treatments with NPK and micronutrients had the best results(up to 257%***),while organic fertilization did not show *** Crotalaria had a greater number of nodules,higher nodule dry mass,chlorophyll a and b contents and showed free ammonium as the predominant N form,reflecting greater increments in biomass compared to native *** having lower growth,the use of this native species in the rehabilitation of mining areas should be considered,mainly because it has good development and meets current government legislation as an opportunity to restore local biodiversity.

关键词： Biological nitrogen fixation Mining Nitrogen metabolism Plant nutrition

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增材制造Ti6Al4v合金的闪速等离子体电解氧化与在生理介质中的电化学行为

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Transactions of Nonferrous Metals society of China 2024年第4期34卷 1150-1166页

作者： H.MORA-sANCHEZ C.ramos M.MOHEDANO B.TORREs R.ARRABAL E.MATYKINA Departamento de Ingeniería Química y de Materiales Facultad de Ciencias QuímicasUniversidad Complutense de Madrid28040 MadridSpain CIDETEC Basque Research and Technology Alliance(BRTA)Po.Miramón 19620014 Donostia-San SebastiánSpain Departamento Matemática Aplicada Ciencia e Ingeniería de Materiales y Tecnología ElectrónicaUniversidad Rey Juan CarlosC/Tulipán s/nMóstoles 28933MadridSpain

研究激光粉末床熔融增材制造(AM)(又称直接金属激光烧结)技术制备的Ti6Al4v合金等离子体电解氧化(PEO)处理及其电化学行为。通过短时间(<120 s)PEO处理(也称闪速PEO),在AM合金和传统合金表面制备了3~10μm厚、含Ca和P的涂层。然后在改... 详细信息

研究激光粉末床熔融增材制造(AM)(又称直接金属激光烧结)技术制备的Ti6Al4v合金等离子体电解氧化(PEO)处理及其电化学行为。通过短时间(s)PEO处理(也称闪速PEO),在AM合金和传统合金表面制备了3~10μm厚、含Ca和P的涂层。然后在改良的α-MEM溶液中,通过动电位极化曲线和电化学阻抗谱(EIs)评估了合金的电化学行为。与传统合金相比,AM合金中形成了细小的层片状α显微组织和层间小尺寸的β相颗粒,这促使了火花的产生,从而促进了PEO涂层的生长。闪速PEO涂层提高了传统合金和AM合金的耐腐蚀性,最薄的涂层(v由于其高的晶界密度,易受局部缝隙腐蚀的影响。而即使短至35 s的闪速PEO处理也足以成功避免这种情况。

关键词：增材制造激光粉末床熔融等离子体电解氧化闪速PEO 钛缝隙腐蚀 α-MEM

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Enhancement of the benthic communities around an isolated island in the Antarctic Ocean

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Acta Oceanologica sinica 2013年第6期32卷 47-55页

作者： José I saiz Nuria Anadón Javier Cristobo Oscar garcía-Alvarez Gerardo garcía-Castrillo Eduardo López Cruz Palacín Jesús s Troncoso Ana ramos Department of Zoology and Animal Cell Biology University of the Basque CountryBilbao 48080 Spain Department of Organisms and systems Biology (Zoology) Rodrigo Uría s/n University of OviedoOviedo 33071 Spain spanish Institute of Oceanography Gijón Oceanographic Centre Príncipe de Asturias 70bisGijón 33212 Spain Department of Zoology and Physical Anthropology University of Santiago de CompostelaSouth Campus Santiago de Compostela 15706 Spain Cantabrian Maritime Museum San Martín de Bajamar s/nSantander 39004 Spain Department of Biology Faculty of Sciences Autonomous University of MadridMadrid 28049 Spain Department of Animal Biology University of BarcelonaAvinguda Diagonal 645 Barcelona 08028 Spain Department of Ecology and Animal Biology Marine Sciences Faculty University of VigoVigo 36310 Spain spanish Institute of Oceanography Subida a Radio Faro 50-52Vigo 36390 Spain

Insular marine biotas are often richer in faunal diversity than those from the open sea in the same geo- graphical region. The existence of particular island effects were tested under polar conditions by compar- ing infaunal benthic assemblages on Peter I Island with those of similar latitudes in the open ocean at the Bellingshausen sea and also from the coast of the Antarctic Peninsula. sampling was carried out aboard the R/v Hesperides during the expedition named BENTART-2003 from 24 January to 3 March 2003. Benthic samples were collected at 18 stations ranging from 90 to 2 044 m depth, using an UsNEL-type box corer （BC） dredge. Representatives of 32 higher taxa of invertebrates were found. Univariate and multivariate analyses revealed various patterns in the data. First, significant differences in polychaete abundance were detected between the stations located in the open sea and the remaining sites （island plus mainland sites）. Bivalve abundances were also distinct between island and mainland sampling sites. sediment columns taken from the island seafloor exhibited the highest rate of bioturbation by the infauna. These findings confirm the model that islands develop distinct assemblages characterized by the enhancement of the benthic commu- nities even in cold waters. several abiotic factors were measured simultaneously at the seafloor and along the water column to investigate faunal distribution patterns. significant correlations were found between the benthic assemblages and a combination of two environmental variables：＂island effect＂（measured as a categorical variable） and the redox state of sediments. Richer and more complex benthic assemblages were found in Peter I Island＇s sea bottom, whereas the more depauperate bottoms remained in the open sea.

关键词： Antarctica Bellingshausen sea benthos Peter I Island PRIMER

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Provenance of sediments from Barra del Tordo and Tesoro beaches, Tamaulipas state, northwestern Gulf of Mexico

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Journal of Palaeogeography 2021年第3期10卷 382-398页

作者： Mayla A.ramos-vazquez John s.Armstrong-Altrin Posgrado en Ciencias del Mar y Limnologpa Universidad Nacional Autonoma de MexicoCiudad UniversitariaCiudad de Mexico 04510Mexico Universidad Nacional Autonoma de Mexico Instituto de Ciencias del Mar y LimnologiaUnidad de Procesos Oceanicos y CosterosCiudad UniversitariaCiudad de Mexico 04510Mexico

The mineralogy, bulk sediment geochemical composition, and U–Pb ages of detrital zircons retrieved from the Barra del Tordo(Tordo) and Tesoro beach sediments in the northwestern Gulf of Mexico were analyzed to determine their provenance. The beach sediments are mainly composed of quartz, ilmenite, magnetite, titanite,zircon, and anorthite. The weathering proxies such as the Chemical Index of Alteration(CIA), Chemical Index of Weathering(CIW), and Plagioclase Index of Alteration(PIA), reveal a moderate-to-high intensity of weathering in the source area. The chondrite-normalized rare earth element(REE) patterns are similar to felsic igneous rocks, with large negative europium anomaly(Eu/Eu^(*)= ~ 0.47–0.80 and ~ 0.57–0.67 in the Tordo and Tesoro beach sediments,respectively).Three major zircon U–Pb age groups are identified in the Tordo and Tesoro beach sediments, i.e., Proterozoic(~2039–595 Ma), Mesozoic(~ 244–70.3 Ma), and Cenozoic(~ 65.9–1.2 Ma). The differences of the zircon age spectrum between the Tordo and Tesoro beach sediments are not significant. The comparison of zircon U–Pb ages in this study with ages of potential source terranes suggests that the Mesozoic and Cenozoic zircons of the studied Tordo and Tesoro beach sediments were derived from the Eastern Alkaline Province(EAP) and Mesa Central Province(MCP). similarly, the likely sources for the Proterozoic zircons were the sierra Madre Oriental(sMOr) and Oaxaquia in the northwestern Gulf of Mexico. The results of this study further indicate that the sediments delivered to the beaches by rivers and redistributed by longshore currents were crucial in determining the sediment provenance.

关键词： Geochemistry sedimentary provenance Zircon U–Pb Beach sediment Rare earth elements Mexico

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Feasibility of the 2-point method to determine the load-velocity relationship variables during the countermovement jump exercise

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Journal of sport and Health science 2023年第4期12卷 544-552,F0003页

作者： Alejandro Pérez-Castilla Rodrigo Ramirez-Campillo John F.T.Fernandes Amador garcía-ramos Department of Physical Education and sport Faculty of Sport SciencesUniversity of GranadaGranada 18011Spain Human Performance Laboratory Department of Physical Activity SciencesUniversidad de Los LagosSantiago 5170000Chile Centro de Investigacion en Fisiologıa del Ejercicio Facultad de CienciasUniversidad MayorSantiago 8580745Chile Higher Education sport Hartpury UniversityHartpury GL193BEUK Department of sports sciences and Physical Conditioning Faculty of EducationUniversidad Catolica de la Santısima ConcepcionConcepcion 4090541Chile

Purpose:This study aimed to examine the reliability and validity of load-velocity(L-v)relationship variables obtained through the 2-point method using different load combinations and velocity ***:Twenty men performed 2 identical sessions consisting of 2 countermovement jumps against 4 external loads(20 kg,40 kg,60 kg,and80 kg)and a heavy squat against a load linked to a mean velocity(Mv)of 0.55 m/s(load_(0.55)).The L-v relationship variables(load-axis intercept(L_(0)),velocity-axis intercept(v_(0)),and area under the L-v relationship line(A_(line)))were obtained using 3 velocity variables(Mv,mean propulsive velocity(MPv),and peak velocity)by the multiple-point method including(20-40-60-80-load_(0.55))and excluding(20-40-60-80)the heavy squat,as well as from their respective 2-point methods(20-load_(0.55)and 20-80).Results:The L-v relationship variables were obtained with an acceptable reliability(coefncient of variation(Cv)≤7.30%;intra-class correlation coefficient>0.63).The reliability of L_(0)and v_(0)was comparable for both methods(Cv_(ratio)(calculated as higher value/lower value):1.11-1.12),but the multiple-point method provided Al_(ine)with a greater reliability(Cv_(ratio)=1.26).The use of a heavy squat provided the L-v relationship variables with a comparable or higher reliability than the use of a heavy countermovement jump load(Cv_(ratio):1.06-1.19).The peak velocity provided the load-velocity relationship variables with the greatest reliability(Cv_(ratio):1.15-1.86)followed by the Mv(Cv_(ratio):1.07-1.18),and finally the *** 2-point methods only revealed an acceptable validity for the Mv and MPv(effect size≤0.19;Pearson s product-moment correlation coefficient≥0.96;Lin's concordance correlation coefficient≥0.94).Conclusion:The 2-point method obtained from a heavy squat load and Mv or MPv is a quick,safe,and reliable procedure to evaluate the lower-body maximal neuromuscular capacities through the L-v relationship.

关键词： Force-velocity relationship Mean velocity Multiple-point method Peak velocity velocity-based training

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Non-Canonical Functions of the E2F/DP Pathway with Emphasis in Plants

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Phyton-International Journal of Experimental Botany 2021年第2期90卷 307-330页

作者： víctor A.sánchez-Camargo samantha Romero-Rodríguez Jorge M.vázquez-ramos Facultad de Química Departamento de BioquímicaUniversidad Nacional Autónoma de MéxicoAvenida Universidad y CopilcoCiudad de México04510México Plant Development and(Epi)Genetics Group Swammerdam Institute for Life SciencesUniversiteit van AmsterdamAmsterdam1098XHNetherlands

The E2F/DP pathway is a widely conserved regulatory mechanism in pluricellular *** family of E2F and DP transcription factors was originally described having a role in the transition from the G1 to the s phase of the cell ***,the discovery of hundreds of possible gene targets and their involvement in many other biochemical processes,soon showed that they participated in cell development and differentiation,chromatin remodeling,DNA repair and *** E2F/DP transcription factors can act as either activators or repressors of transcription depending on their association to other regulatory proteins,particularly the retinoblastoma protein,or even depending to their protein structure that can define their *** plants the E2F/DP pathway also regulates endoreduplication,a process present along the life cycle,from organ elongation to root differentiation and *** transcription factors also help plant cells to respond to environmental disturbances such as those caused by different types of radiation,or by *** review focuses on the“so called”non-canonical functions of the E2F/DP family proteins in animal and plant cells,that are in fact essential activities that connect regulatory circuits among multiple metabolic pathways by means of their atypical functions.

关键词： E2F DP transcription factors atypical functions plant cells

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High-speed silicon photonic electro-optic Kerr modulation

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Photonics Research 2024年第1期12卷 51-60页

作者： JONATHAN PELTIER WEIWEI ZHANG LEOPOLD vIROT CHRIsTIAN LAFFORGUE LUCAs DENIEL DELPHINE MARRIs-MORINI GUY AUBIN FARAH AMAR DENH TRAN XINGZHAO YAN CALLUM G.LITTLEJOHNs CARLOs ALONsO-ramos KE LI DAvID J.THOMsON GRAHAM REED LAURENT vIvIEN University Paris-saclay CNRSCentre for Nanoscience and Nanotechnology(C2N)Palaiseau 91120France University Grenoble Alpes CEALETIGrenoble 38000France Optoelectronics Research Centre Zepler Institute for Photonics and NanoelectronicsFaculty of Engineering and Physical SciencesUniversity of SouthamptonSouthampton SO171BJUK

silicon-based electro-optic modulators contribute to easing the integration of high-speed and low-power consumption circuits for classical optical communications and data *** the plasma dispersion modulation,an alternative solution in silicon is to exploit the DC Kerr effect,which generates an equivalent linear electro-optical effect enabled by applying a large DC electric *** some theoretical and experimental studies have shown its existence in silicon,limited contributions relative to plasma dispersion have been achieved in high-speed modulation so *** paper presents high-speed optical modulation based on the DC Kerr effect in silicon PIN *** contributions of both plasma dispersion and Kerr effects have been analyzed in different waveguide configurations,and we demonstrated that the Kerr induced modulation is dominant when a high external DC electric field is applied in PIN ***-speed optical modulation response is analyzed,and eye diagrams up to 80 Gbit/s in NRZ format are obtained under a *** of 30 *** work paves the way to exploit the Kerr effect to generate high-speed Pockels-like optical modulation.

关键词： waveguide dispersion effect

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