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Anisotropic Plasmon Resonance Enables Spatially Controlled Photothermal and Photochemical Effects in Hot Carrier-Driven Catalysis

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Chinese Journal of Chemistry 2024年第16期42卷 1877-1885页

作者： Jiaqi Wang Zhijie Zhu Kai Feng Shuang Liu Yuxuan Zhou Ifra Urooj Jiari He Zhiyi Wu Jiahui Shen Xu Hu Zhijie Chen Xudong Dong manzar sohail Yanyun Ma Jinxing Chen Chaoran Li Xingda An Le He Institute of Functional Nano&Soft Materials(FUNSOM) Soochow UniversitySuzhouJiangsu 215123China Jiangsu Key Laboratory ofAdvanced Negative Carbon Technologies Soochow UniversitySuzhouJiangsu 215123China Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices Soochow UniversitySuzhouJiangsu 215123China Department of Chemistry School of Natural SciencesNational University of Sciences and TechnologyIslamabad 44000Pakistan

Localized surface plasmon resonance has been demonstrated to provide effective photophysical enhancement mechanisms in plasmonic ***,it remains highly challenging for distinct mechanisms to function in synergy for a collective gain in catalysis due to the lack of spatiotemporal control of their ***,the anisotropic plasmon resonance nature of Au nanorods was exploited to achieve distinct functionality towards synergistic *** and photochemical effects were enabled by the longitudinal and transverse plasmon resonance modes,respectively,and were enhanced by partial coating of silica nanoshells and epitaxial growth of a reactor *** excitation leads to a synergistic gain in photothermal-mediated hot carrier-driven hydrogen evolution *** approach provides important design principles for plasmonic photocatalysts in achieving spatiotemporal modulation of distinct photophysical enhancement *** also effectively broadens the sunlight response range and increases the efficacy of distinct plasmonic enhancement pathways towards solar energy harvesting and conversion.

关键词： Plasmon resonance Photothermal effect Photochemistry Photocatalysis Metal nanoparticles Charge carrier injection Heterogeneous catalysis Photoelectrochemistry

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Sudden Collapse of a Newborn Infant Following Delivery Complicated by Shoulder Dystocia

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Maternal-Fetal Medicine 2024年第3期6卷 201-202页

作者： Shabih manzar Department of Pediatrics Louisiana State University Health Sciences CenterShreveportLouisiana 71103United States

To editor:Shoulder dystocia(SD)constitutes an obstetric emergency,bearing associations with maternal and neonatal morbidity due to its unique *** a comprehensive series involving 228,438 women,SD occurred in 2159 patients,accounting for 1.7%of the total.1 Various techniques have been described to facilitate successful delivery in SD patients;2 however,these maneuvers are not without associated complications.3 This correspondence highlights a case of a newborn experiencing a collapse following such a *** guardian granted written and informed consent for the publication of the patient’s clinical information and associated images.

关键词： Collapse therapy Fetal shoulder dystocia Obstetric Vacuum-assisted vaginal delivery

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The Persisting Value of Autopsies on Extremely Preterm Infants in the 21^(st)Century

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Maternal-Fetal Medicine 2023年第4期5卷 203-205页

作者： Shabih manzar Department of Pediatrics Louisiana State University Health Sciences CenterShreveportLA 71103USA

An autopsy is performed with the primary objective of finding the definitive cause of death(COD).Historically,it was done to know more about the anatomical details and pathological findings of the *** preterm(EP)infan... 详细信息

关键词： Infant premature Autopsy Ethics

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Phage capsid nanoparticles as multivalent inhibitors of viral infections

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Science Bulletin 2020年第24期65卷 2050-2052,M0004页

作者： manzar Abbas Muhammad Ovais Chunying Chen Institute for Molecules and Materials Radboud UniversityNijmegen 6525 AJthe Netherlands CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China GBA Research Innovation Institute for Nanotechnology Guangzhou 510700China

In the present time, coronavirus disease COVID-19 has become prevalent across the globe and declared as a pandemic by the world health organization(WHO) [1]. As of now, many vaccines and medicines are in the approval process or at different stages of preclinical investigations to coup with the COVID-19 [2]. Coronavirus has a spike protein, which tends to bind with receptors present in the lung tissues, and that helps in its entry to the cells and replication inside [3]. Therefore, we are in need to design the multivalent nanomaterials, which can act as receptors to bind with spike protein of virus and stop its replication(Fig. 1).

关键词：病毒感染衣壳 lung

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Self-assembly of biomimetic light-harvesting complexes capable of hydrogen evolution

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Green Energy & Environment 2017年第1期2卷 58-63页

作者： Kai Liu manzar Abass Qianli Zou Xuehai Yan State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences University of Chinese Academy of Sciences Center for Mesoscience Institute of Process EngineeringChinese Academy of Sciences

Biomimetics provides us a new perspective to understand complex biological process and strategy to fabricate functional materials. However,a great challenge still remains to design and fabricate biomimetic materials using a facile but effective method. Here, we develop a biomimetic light harvesting architecture based on one-step co-assembly of amphiphilic amino acid and porphyrin. Amphiphilic amino acid can self-assemble into nanofibers via π-stacking and hydrogen binding interactions. Negatively charged porphyrin adsorbs on the surface of the assembled nanofibers through electrostatic force, and the nanofibers further organize into porous urchin-like microspheres induced presumably by hydrophobic interaction. The assembled amphiphilic amino acid nanofibers work as a template to tune the organization of porphyrin with an architecture principle analogous to natural light harvesting complex. The co-assembled microspheres exhibit enhanced light capture due to the light reflection in the porous structure. Reaction center(platinum nanoparticles) can be effectively coupled with the light harvesting microspheres via photoreduction. After visible light illumination, hydrogen evolution occurs on the hybrid microspheres.

关键词： Light-harvesting Amino acid Porphyrin Co-assembly Hydrogen evolution

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Suicide bomb attack causing penetrating craniocerebral injury

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Chinese Journal of Traumatology 2013年第1期16卷 51-53页

作者： manzar Hussain Muhammad Ehsan Bari Department of Neurosurgery Dow University of HealthSciences Karachi 75300 Pakistan

Penetrating cerebral injuries caused by foreign bodies are rare in civilian neurosurgical trauma, al- though there are various reports of blast or gunshot injuries in warfare due to multiple foreign bodies like pellets and nails. In our case, a 30-year-old man presented to neurosurgery clinic with signs and symptoms of right-sided weakness after suicide bomb attack. The skull X-ray showed a single intracranial nail. Small craniotomy was done and the nail was removed with caution to avoid injury to surrounding normal brain tissue. At 6 months＇ follow-up his right- sided power improved to against gravity.

关键词： Head injury, penetrating Bombs Nails

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Electronic and Optical Properties of Spinel GeMg2O4 and GeCd2O4

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Chinese Physics Letters 2013年第12期30卷 134-138页

作者： A.manzar G.Murtaza R.Khenata S.Muhammad Hayatullah Department of Physics Hazara University MansehraKPKPakistan Materials Modeling Lab Department of PhysicsIslamia College UniversityPeshawarPakistan LPQ3M Laboratory Institute of Science and TechnologyUniversity of MascaraAlgeria

Oxide spinels have potential applications in optoelectronics and optics *** this work the electronic band structure and optical properties of GeMg2O4 and GeCd2O4 are calculated by first principles technique based on the new potential approximation known as the modified Becke-Johnson exchange potential approximation(mBJ).The local density and generalized gradient approximations significantly underestimate the direct band gap values compared to the *** band gap dependent optical parameters such as dielectric constant,refractive index,reflectivity and optical conductivity are calculated and *** replacement of the cation is observed and analyzed for the compounds studied and a prominent change is *** replacement of the cation Mg by Cd reduces the band gap and its dependent optical *** device fabrication in different regions of the spectrum this variation is strongly recommended.

关键词： approximation potential reflectivity

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Say no to drugs: wait and watch strategy for medications used in the neonatal intensive care unit (NICU)

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World Journal of Pediatrics 2020年第6期16卷 560-561页

作者： Hilary Tice Shabih manzar Nitin Walyat Kelsey Trimble University of Louisiana at Monroe.1501 Kings Highway Shreveport Campus1725 Claiborne Avenue.Shreveport.LA 71103USA Division of Neonatology Louisiana State University Health Sciences Shreveport1501 Kings HighwayShreveport.LA 71103USA Department of Pharmacy Ochsner-LSU Health Shreveport1541 Kings HighwayShreveportLA 71103USA

From the presentation of gray baby syndrome with chloramphenicol use to gasping baby syndrome with exposure from benzyl alcohol in bacteriostatic flushes,historical clinical precedence has shown that babies cared for in the neonatal intensive care unit(NICU)are at higher risk of adverse effects from medication administration than other populations[1,2].Historical precedence led to a discussion amongst the multi-disciplinary team questioning whether medications are used excessively in the NICU.A recent review paper by Hsieh et al.[3]has elaborated on this question in detail,in which a downward trend in the use of certain medications was shown.

关键词： medication drugs downward

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Impact of Customer Satisfaction on Brand Loyalty-an Empirical Analysis of Automobile Luxury and Security Products in Pakistan

Impact of Customer Satisfaction on Brand Loyalty-an Empirica...

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作者： manzar Rehman 河北地质大学

学位级别：硕士

Background and Significance: The main aim of the study was to determine the impact of customer satisfaction on brand loyalty in case of safety luxury products in automobile industry of *** firms selected were Toyota Indus,Honda and *** study holds significance because it will help to know why customer satisfaction is important and how it helps brands to grow and become more customer ***,the findings can be applied on the automobile industry of Pakistan which has not worked or designed any particular strategies for increasing brand *** Content: The method adopted by researcher was quantitative.275 questionnaires were received from ***,regression,descriptive statistics,customer satisfaction index and brand value analysis was *** findings revealed that customer expectation,customer perceived quality and customer perceived value had strong relationship with brand *** satisfaction index revealed that despite being large firms of Pakistan,still they are not able to make loyal customers due to their poor quality,high prices and poor ***: It was investigated that the automobile sector has played an important role in the development of the country for generating the revenue,creation of employment,transfer of technology,and foreign *** is recommended that loyalty of the customers mainly relies over the effective strategy to develop the customer communication in the journey with the *** dealers should provide excellent customer experience as they can use CRM data which would allow the customers to know the needs of the customer service.

关键词： brand satisfaction customer loyalty customer expectations customer perceived quality brand value customer satisfaction

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Electronic and Optic Properties of Cubic Spinel CdX2O4 （X=In, Ga, Al） through Modified Becke-Johnson Potential

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Chinese Physics Letters 2014年第6期31卷 186-189页

作者： A. manzar G. Murtaza R. Khenata Masood Yousaf S. Muhammad Hayatullah Department of Physics Hazara University Mansehra KPK Pakistan Materials Modeling Lab Department of Physics Islamia College University Peshawar Pakistan LPQ3M Laboratory Institute of Science and Technology University of Mascara Algeria Physics Department Faculty of Science Universiti Teknologi Malaysia Skudai81310 Johor Malaysia

A new potential approximation known as modified Becke-Johnson based on density functional theory is applied to compute the electronic band profile and optical response of CdIn2O4, CdGa2O4 and CDAl2O4 compounds. The direct band gap with common LDA, GGA and EV-GGA is drastically underestimated compared with modified 13ecke-Johnson approximation, whose results are significantly closer to the experimental findings. The optical properties like dielectric constant, refractive index, reflectivity, optical conductivity and absorption coefficient axe also computed. A unique characteristic associated with cation replacement is studied; the replacement of cation In by Ga and Ga by AI significantly reduces the direct energy band gap in these compounds. This variation is of crucial importance for band gap dependent optical properties of these compounds, which is also proof for applications of these compounds in optoelectronic devices.

关键词： ELECTRONIC apparatus & appliances OPTOELECTRONIC devices PHOTOELECTRON spectroscopy ELECTRONIC structure OPTICAL properties RESEARCH

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