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Alloy/layer double hydroxide interphasic synergy via nano-heterointerfacing for highly reversible CO_(2)redox reaction in li-CO_(2)batteries

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Nano Research 2024年第6期17卷 5206-5215页

作者： Tianzhen Jian Wenqing ma Jiagang Hou jianping ma Xianhong {3. Haiyang Gao Caixia Xu Hong {3.u Institute for Advanced Interdisciplinary Research(iAIR) Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of ShandongSchool of Chemistry and Chemical EngineeringUniversity of JinanJinan 250022China Kyiv college at Qilu university of Technology Qilu University of Technology(Shandong Academy of Sciences)Jinan 250353China State Key Laboratory of Crystal materials Shandong UniversityJinan 250100China Shandong Sacred Sun Power Sources Co. Ltd.Qufu 273100China

li-CO_(2)batteries are among the most intriguing techniques for balancing the carbon cycle,but are challenged by the annoyed thermodynamic barrier of the li_(2)CO_(3.decomposition ***,we demonstrate the electrocatalytic performances of two-dimensional(2D)CoAl-layer double hydroxide(LDH)nanosheets can be significantly improved by trans-dimensional crosslinking with three-dimensional(3.)multilevel nanoporous(MP)-RuCoAl alloy(MP-RuCoAl alloy⊥CoAl-LDH).The MP-RuCoAl alloy⊥CoAl-LDH with multiscale pore channels and abundant nano-heterointerface is directly prepared by controllable etching Al from a Ru-Co-Al master alloy along with simultaneous partial oxidization of Al and Co *** MP-RuCoAl is composed of various intermetallic compounds and Ru with abundant grain boundaries,and forms numerous heterointerface with 2D CoAl-LDH *** multiscale porous metallic network benefits mass and electron transportation as well as discharge product storage and enables a rich multiphase reaction *** situ differential electrochemical mass spectrometry shows that the mass-to-charge ratio in the charging process is~0.73. which is consistent with the theoretical value of 3.4,stating that the reversible co-decomposition of li_(2)CO_(3.and C can be achieved with the MP-RuCoAl alloy⊥*** Ketjen black(KB)/MP-RuCoAl⊥CoAl-LDH battery demonstrates a high cyclability for over 2270 h(227 cycles)with a lower voltage gap stabilized at~1.3.V at 200 ma·g^(−1).Our findings here provide useful guidelines for developing high efficiency transition metal based electrocatalysts by coupling with conductive porous substrate for impelling the development of practical li-CO_(2)battery systems.

关键词： heterojunction interface nanoporous li-CO_(2)battery dealloying

The underappreciated role of fugitive VOCs in ozone formation and health risk assessment emitted from seven typical industries in China

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Journal of Environmental sciences 2024年第2期136卷 647-657页

作者： Zhiling liang Yunjiang Yu Bingbing Sun Qian Yao Xihua lin Yongsheng Wang {3. Zhang Yingzi li Xuefeng Wang Zhengzheng Tang Shexia ma college of Environmental and Chemical Engineering Shanghai University of Electric PowerShanghai 200090China State Environmental Protection Key Laboratory of Environmental Protection Health Risk Assessment South China Institute of Environmental SciencesMinistry of Ecology and EnvironmentGuangzhou 510535China Henan Jiyuan Ecological Environment Testing Center Jiyuan 454650China Ecological Environment Bureau of Jiyuan Production City Integration Demonstration Zone Jiyuan 454650China

Fugitive emission from industrial sources may result in ozone formation and health risk,while the exact contribution of this source remains incompletely *** this study,emission characteristics,ozone formation potential(OFP)and health risk of fugitive VOCs in7 representative industries were *** material industry was the dominant contributor to VOCs of fugitive emission in comparison with other *** OFP of VOCs from fugitive emission was in the range of 1.45×10^(3.-3.98×10^(5)μg/m^(3.,with a higher value than that of organized emission in seven industries except for the coking industry and the chemical material industry,suggesting that fugitive VOCs should be taken into account while developing control ***,m,p-xylene,n-nonane,ethylene,vinyl chloridethe and other high OFP-contributing species were the major reactive species that should be *** risk assessment investigated non-cancer and cancer risks of fugitive VOCs in 7 industries were all above safe level(HR>1 and LCR>1×10^(-4)),posing remarkable health threats to human *** were the main contributor to non-cancer risk,while halohydrocarbons and aromatics contributed most to cancer risks,posing remarkable health threat on human *** findings high{13.ghted the contribution of fugitive VOCs on ozone formation and health risk was underestimated,indicating which should be considered in emission control strategies of industrial sources.

关键词： Industrial sources Volatile organic compounds Fugitive emission Ozone formation potential Health risk assessment

Application of the Conditional Nonlinear Local Lyapunov Exponent to Second-Kind Predictability

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Advances in atmospheric sciences 2024年第9期41卷 1769-1786页

作者： Ming ZHANG Ruiqiang DING Quanjia ZHONG jianping li Deyu LU State Key Laboratory of Earth Surface Processes and Resource Ecology(ESPRE)/Key Laboratory of Environmental Change and Natural Disasters of Chinese Ministry of EducationBeijing Normal UniversityBeijing 100875China Department of Ocean Science Hong Kong University of Science and TechnologyHong KongChina college of Oceanic and atmospheric sciences/Frontiers Science Center for Deep Ocean Multispheres and Earth System(DOMES)/Key Laboratory of Physical Oceanography Ministry of Education/Academy of the Future Ocean/Center for Ocean Carbon NeutralityOcean University of ChinaQingdao 266100China Laoshan Laboratory Qingdao 266237China State Key Laboratory of Numerical Modeling for atmospheric sciences and Geophysical Fluid Dynamics(LASG) Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China college of Earth Science University of Chinese Academy of SciencesBeijing 100049China

In order to quantify the influence of external forcings on the predictability limit using observational data,the author introduced an algorithm of the conditional nonlinear local Lyapunov exponent(CNLLE)*** effectiveness of this algorithm is validated and compared with the nonlinear local Lyapunov exponent(NLLE)and signal-to-noise ratio methods using a coupled Lorenz *** results show that the CNLLE method is able to capture the slow error growth constrained by external forcings,therefore,it can quantify the predictability limit induced by the external *** this basis,a preliminary attempt was made to apply this method to measure the influence of ENSO on the predictability limit for both atmospheric and oceanic variable *** spatial distribution of the predictability limit induced by ENSO is similar to that arising from the initial conditions calculated by the NLLE *** similarity supports ENSO as the major predictable signal for weather and climate *** addition,a ratio of predictability limit(RPL)calculated by the CNLLE method to that calculated by the NLLE method was *** RPL larger than 1 indicates that the external forcings can significantly benefit the long-term predictability *** instance,ENSO can effectively extend the predictability limit arising from the initial conditions of sea surface temperature over the tropical Indian Ocean by approximately four months,as well as the predictability limit of sea level pressure over the eastern and western Pacific ***,the impact of ENSO on the geopotential height predictability limit is primarily confined to the troposphere.

关键词： conditional nonlinear local Lyapunov exponent second-kind predictability coupled Lorenz model ENSO

A study on the simulation of carbon and water fluxes of Dangxiong alpine meadow and its response to climate change

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atmospheric and Oceanic Science Letters 2024年第5期17卷 22-27页

作者： lingyun He Lei Zhong Yaoming ma Yuting Qi jie liu Peizhen li School of Earth and Space sciences University of Science and Technology of ChinaHefeiChina CAS Center for Excellence in Comparative Planetology HefeiChina Jiangsu Collaborative Innovation Center for Climate Change NanjingChina Key Laboratory of Tibetan Environment Changes and Land Surface Processes Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijingChina college of Earth and Planetary sciences University of Chinese Academy of SciencesBeijingChina college of atmospheric sciences Lanzhou UniversityLanzhouChina Qomolangma atmospheric and Environmental Observation and Research Station TingriChina Kathmandu Center for Research and Education Chinese Academy of Sciences-Tribhuvan UniversityBeijingChina China-Pakistan Joint Research Center on Earth sciences IslamabadPakistan

The alpine meadow ecosystem accounts for 27%of the total area of the Tibetan Plateau and is also one of the most important vegetation *** Dangxiong alpine meadow ecosystem,located in the south-central part of the Tibetan Plateau,is a typical *** understand the carbon and water fluxes,water use efficiency(WUE),and their responses to future climate change for the alpine meadow ecosystem in the Dangxiong area,two parameter estimation methods,the Model-independent Parameter Estimation(PEST)and the Dynamic Dimensions Search(DDS),were used to optimize the Biome-BGC ***,the gross primary productivity(GPP)and evapotranspiration(ET)were *** results show that the DDS parameter calibration method has a better *** annual GPP and ET show an increasing trend,while the WUE shows a decreasing ***,ET and GPP reach their peaks in July and August,respectively,and WUE shows a“dual-peak”pattern,reaching peaks in may and ***,according to the simulation results for the next nearly 100 years,the ensemble average GPP and ET exhibit a significant increasing trend,and the growth rate under the SSP5–8.5 scenario is greater than that under the SSP2–4.5 *** shows an increasing trend under the SSP2–4.5 scenario and a significant increasing trend under the SSP5–8.5 *** study has important scientific significance for carbon and water cycle prediction and vegetation ecological protection on the Tibetan Plateau.

关键词： Carbon and water flux Water use efficiency Alpine meadow Biome-BGC model Climate change

Nonlinear local Lyapunov exponent and atmospheric predictability research

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Science China Earth sciences 2006年第10期49卷 1111-1120页

作者： CHEN Baohua1, li jianping1,2 & DING Ruiqiang2.1. {3. of atmospheric {3., lanzhou university, lanzhou 73.000, China 2. State Key Laboratory of Numerical Modeling for atmospheric Science and Geophysical Fluid Dynamics (LASG), Institute of atmospheric Physics, Chinese Academy of {3., Beijing 100029, China college of atmospheric sciences Lanzhou University Lanzhou China State Key Laboratory of Numerical Modeling for atmospheric Science and Geophysical Fluid Dynamics (LASG) Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

Because atmosphere itself is a nonlinear system and there exist some problems using the linearized equations to study the initial error growth, in this paper we try to use the error nonlinear growth theory to discuss its evolution, based on which we first put forward a new concept: nonlinear local Lyapunov exponent. It is quite different from the classic Lyapunov exponent because it may characterize the finite time error local average growth and its value depends on the initial condition, initial error, variables, evolution time, temporal and spatial scales. Based on its definition and the at-mospheric features, we provide a reasonable algorithm to the exponent for the experimental data, obtain the atmospheric initial error growth in finite time and gain the maximal prediction time. Lastly, taking 500 hPa height field as example, we discuss the application of the nonlinear local Lyapunov exponent in the study of atmospheric predictability and get some reliable results: atmospheric predictability has a distinct spatial structure. Overall, predictability shows a zonal distribution. Prediction time achieves the maximum over tropics, the second near the regions of Antarctic, it is also longer next to the Arctic and in subtropics and the mid-latitude the predictability is lowest. Particularly speaking, the average prediction time near the equation is 12 days and the maximum is located in the tropical Indian, Indonesia and the neighborhood, tropical eastern Pacific Ocean, on these regions the prediction time is about two weeks. Antarctic has a higher predictability than the neighboring latitudes and the prediction time is about 9 days. This feature is more obvious on Southern Hemispheric summer. In Arctic, the predictability is also higher than the one over mid-high latitudes but it is not pronounced as in Antarctic. Mid-high latitude of both Hemispheres (3.°S―60°S, 3.°―60°N) have the lowest predictability and the mean prediction time is just 3.4 d. In addition, predictab

关键词： nonlinear, local, Lyapunov exponent, atmospheric predictability, maximal prediction time.

Acidic electroreduction CO_(2)to formic acid via interfacial modification of Bi nanoparticles at industrial-level current

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Nano Research 2024年第7期17卷 5817-5825页

作者： Tian Dong Hongdong li Zhenhui Wang Yanling Geng Rui Chang Xiaofeng Tian jianping Lai Shouhua Feng Lei Wang Key Laboratory of Eco-Chemical Engineering International Science and Technology Cooperation Base of Eco-Chemical Engineering and Green ManufacturingCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Engineering Research Center for marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

Electrocatalytic CO_(2)reduction reaction(CO_(2)RR)in acidic media is a promising approach to overcome the unavoidable formation of carbonates in alkaline or neutral ***,the proton-rich environment near the catalyst surface favors hydrogen evolution reactions(HER),leading to lower energy efficiency of the desired products,especially in industrial-level current ***,quaternary ammonium cationic surfactant(cetyltrimethylammonium bromide(CTAB))was introduced into acidic electrolyte to modulate the interfacial microenvironment,which greatly enhanced CO_(2)electroreduction to formic acid(HCOOH)at the Bi/C nanoparticles *** a Bi/C nanoparticles electrode with CTAB added,constant production of formic acid was enabled with a cathodic energy efficiency of>40%and maximum FE_(HCOOH)(FE=Faradaic efficiency)of 86.2%at−400 ma·cm^(−2)over 24 *** with in-situ attenuated total reflection Fourier transform infrared spectroscopy,the concentration of*OCHO intermediates significantly increased after CTAB modification,confirming that the hydrophobic interface microenvironment formed by dynamic adsorption of positively charged long alkyl chains on Bi/C nanoparticle electrodes inhibited HER and improved the selectivity of CO_(2)RR to HCOOH.

关键词： acidic media CO_(2)electrolysis electrolyte additive hydrophobic interfacial microenvironment industrial-level current

Polysulfide modified PtCu intermetallic nanocatalyst with enrichment realizes efficient electrooxidation ethanol to CO_(2)

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Nano Research 2024年第4期17卷 2320-2327页

作者： Shuanglong Zhou Zheng Lv liang Zhao Dan Zhang Zuocao Wang Yu Dai Bin li Olga Starostenko jianping Lai Lei Wang Key Laboratory of Eco-chemical Engineering Ministry of EducationTaishan scholar advantage and characteristic discipline team of Eco-chemical process and technologyLaboratory of Inorganic Synthesis and Applied ChemistryCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China college of Foreign Languages Qingdao City UniversityQingdao 266106China college of materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China Institute of macromolecular Chemistry of the National Academy of sciences of Ukraine Kyiv 02160Ukraine Shandong Engineering Research Center for marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

The main problem faced by ethanol oxidation reaction(EOR)includes low activity,poor selectivity,and *** the study,we found that polysulfide modified on the surface of PtCu intermetallic(IM)/C can simultaneously enrich hydroxyl and ethanol,which could effectively improve the catalytic activity,CO_(2) selectivity,and durability of *** mass activity and the specific activity of the product in 1 M KOH electrolyte reached 17.83.A·mgPt^(-1) and 24.67 ma·cm^(-2).The CO_(2) selectivity of polysulfide modified product achieved 93.5%,which was 3. folds higher than Pt/*** addition,the catalyst showed high catalytic *** mechanism study demonstrates that the surface modified polysulfide could significantly boost the enrichment effect of ethanol and hydroxyl species,accelerating C–C bond cleavage and CO oxidation.

关键词： Pt CO_(2) selectivity enrichment effect ethanol oxidation reaction(EOR) electrocatalyst

A Study on the Assessment and Integration of Multi-Source Evapotranspiration Products over the Tibetan Plateau

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Advances in atmospheric sciences 2024年第3期41卷 435-448页

作者： Ming CHENG Lei ZHONG Yaoming ma Han ma Yaoxin CHANG Peizhen li Meilin CHENG Xian WANG Nan GE School of Earth and Space sciences University of Science and Technology of ChinaHefei 230026China CAS Center for Excellence in Comparative Planetology Hefei 230026China Jiangsu Collaborative Innovation Center for Climate Change Nanjing 210023China Frontiers Science Center for Planetary Exploration and Emerging Technologies University of Science and Technology of ChinaHefei 230026China Land-Atmosphere Interaction and its Climatic Effects Group State Key Laboratory of Tibetan Plateau Earth SystemResources and Environment(TPESRE)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China college of Earth and Planetary sciences University of Chinese Academy of SciencesBeijing 100049China college of atmospheric Science Lanzhou UniversityLanzhou 730000China National Observation and Research Station for Qomolongma Special atmospheric Processes and Environmental Changes Dingri 858200China Kathmandu Center of Research and Education Chinese Academy of SciencesBeijing 100101China China-Pakistan Joint Research Center on Earth sciences Chinese Academy of SciencesIslamabad 45320Pakistan

Evapotranspiration(ET)is a crucial variable in the terrestrial water,carbon,and energy *** present,a large number of multi source ET products *** to sparse observations,however,great challenges exist in the evaluation and integration of ET products in remote and complex areas such as the Tibetan Plateau(TP).In this paper,the applicability of the multiple collocation(MC)method over the TP is evaluated for the first time,and the uncertainty of multisource ET products(based on reanalysis,remote sensing,and land surface models)is further analyzed,which provides a theoretical basis for ET data *** results show that 1)ET uncertainties quantified via the MC method are lower in RS-based ET products(5.95 vs.7.06 mm month^(-1))than in LSM ET products(10.22 vs.17.97 mm month^(-1))and reanalysis ET estimates(7.27 vs.12.26 mm month-1).2)A multisource evapotranspiration(MET)dataset is generated at a monthly temporal scale with a spatial resolution of 0.25°across the TP during *** has better performance than any individual product.3.Based on the fusion product,the total ET amount over the TP and its patterns of spatiotemporal variability are clearly *** annual total ET over the entire TP is approximately 3.0.60 ***,an increasing trend of 1.59±0.85 mm yr^(-1)over the TP is shown during *** study provides a basis for future studies on water and energy cycles and water resource management over the TP and surrounding regions.

关键词： evapotranspiration data fusion multiple collocation the Tibetan Plateau

Cooling History of Mesozoic magmatism and Implications for Large-Scale Gold Mineralization in the Jiaodong Peninsula, East China: Constraints from T-t Paths Determined by U-Pb Thermochronology of Zircon and Apatite

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Journal of Earth Science 2024年第3期35卷 878-889页

作者： Guangyan Zhou Mingchun Song Long li Yan Luo DGraham Pearson Jianbo Zhou Zhengjiang Ding Xuefeng Yu Yingxin Song jie li Shiyong li Faculty of Earth sciences China University of GeosciencesWuhan 430074China Department of Earth&atmospheric sciences University of AlbertaEdmontonAlberta T6G 2E3Canada Hebei Key Laboratory of Strategic Critical Mineral Resources Hebei GEO UniversityShijiazhuang 050031China Shandong Provincial No.6 Exploration Institute of Geology and Mineral Resources Weihai 264209China college of Earth sciences Jilin UniversityChangchun 130061China Ministry of Natural Resources Key Laboratory of Gold Mineralization Processes and Resources Utilization Key Laboratory of Metallogenic-Geologic Processes and Comprehensive Utilization of Minerals Resources in Shandong ProvinceShandong Institute of Geological SciencesJinan 250013China Shandong Nuclear Industry Geological Group 273 Yantai 264006China

The Mesozoic intrusions of the Jiaodong Peninsula,eastern China,host giant gold *** the genesis of these deposits requires the determination of the source of the parental auriferous fluid and the timing of gold mineralization,which are strongly influenced by the cooling/uplift histories of the hosting *** performed an integrated U-Pb geochronology study on both zircon and apatite from four {3.jor {3.g{3.tic episodes of the Jiaodong *** zircon and apatite U-Pb ages are 156.9±1.2.and 13..2±2.4 {3. for the linglong intrusion,129.9±1.0 and 125.0±3.8 {3. for the Qujia intrusion,119.5±0.7 and 117.2.1.8 {3. for the liulinzhuang intrusion,118.6±1.0 and 111.6±1.6 {3. for the Nansu intrusion,*** coupled zircon and apatite data of these granitoids indicate a slow cooling rate(11.9°C/{3.)in the Late Jurassic,and rapid uplift and cooling(3..8-29.2°C/{3.)in the Early *** dra{3.tically increased uplift and cooling period in the Early Cretaceous are contemporaneous with large-scale gold mineralization in the Jiaodong *** implies that ther{3.l upwelling of asthenosphere and related tectonic extension played an important role in gold remobilization and precipitation.

关键词： magmatism geochronology zircon apatite gold deposits Jiaodong Peninsula