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Organophosphate pesticides an emerging environmental contaminant: Pollution, toxicity, bioremediation progress, and remaining challenges

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Journal of Environmental Sciences 2023年第5期127卷 234-250页

作者： Himanshu mali Chandni Shah B.H.Raghunandan Anil S.Prajapati Darshan H.Patel Ujjval Trivedi R.B.Subramanian P.G.Department of Biosciences UGC-Centre of Advanced StudiesSatellite CampusSardar Patel UniversitySardar Patel MaidanBakrol-Vadtal RoadBakrol 388315GujaratIndia Charotar Institute of Paramedical Sciences Charotar University of Science and Technology(CHARUSAT)Changa 388421GujaratIndia

Organophosphates(OPs)are an integral part of modern agriculture;however,due to overexploitation,OPs pesticides residues are leaching and accumulating in the soil,and groundwater contaminated terrestrial and aquatic food *** exposure to OPs could produce toxicity in insects,plants,animals,and *** are known for covalent inhibition of acetylcholinesterase enzyme in pests and terrestrial/aquatic organisms,leading to nervous,respiratory,reproductive,and hepatic *** pesticides also disrupt the growth-promoting machinery in plants by inhibiting key enzymes,permeability,and trans-cuticular diffusion,which is crucial for plant *** use of OPs,directly/indirectly affecting human/environmental health,raise a thoughtful global *** a safe,reliable,economical,and eco-friendly methods for removing OPs pesticides from the environment is thus *** techniques coupled with microbes or microbial-biocatalysts are emerging as promising antidotes for OPs ***,we comprehensively review the current scenario of OPs pollution,their toxicity(at a molecular level),and the recent advancements in biotechnology(modified biocatalytic systems)for detection,decontamination,and bioremediation of OP-pesticides in polluted ***,the review focuses on onsite applications of OPs degrading enzymes(immobilizations/biosensors/others),and it also highlights remaining challenges with future approaches.

关键词： Organophosphorus compounds Toxicity Bioremediation Microorganisms Enzymes Biosensors

A survey on communication protocols and performance evaluations for Internet of Things

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Digital Communications and Networks 2022年第6期8卷 1094-1104页

作者： Cüneyt Bayılmış mali Ebleme ÜnalÇavuşoğlu Kerem Küçük Abdullah Sevin Department of Computer Engineering Sakarya UniversitySerdivanSakaryaTurkey Institute of Natural Science Sakarya UniversitySakaryaTurkey Department of Software Engineering Sakarya UniversitySerdivanSakaryaTurkey Department of Software Engineering Kocaeli UniversityKocaeliTurkey

The Internet of Things (IoT) is a large-scale network of devices capable of sensing, data processing, and communicating with each other through different communication protocols. In today's technology ecosystem, IoT interacts with many application areas such as smart city, smart building, security, traffic, remote monitoring, health, energy, disaster, agriculture, industry. The IoT network in these scenarios comprises tiny devices, gateways, and cloud platforms. An IoT network is able to keep these fundamental components in transmission under many conditions with lightweight communication protocols taking into account the limited hardware features (memory, processor, energy, etc.) of tiny devices. These lightweight communication protocols affect the network traffic, reliability, bandwidth, and energy consumption of the IoT application. Therefore, determining the most proper communication protocol for application developers emerges as an important engineering problem. This paper presents a straightforward overview of the lightweight communication protocols, technological advancements in application layer for the IoT ecosystem. The survey then analyzes various recent lightweight communication protocols and reviews their strengths and limitations. In addition, the paper explains the experimental comparison of Constrained Applications Protocol (CoAP), Message Queuing Telemetry (MQTT), and WebSocket protocols, more convenient for tiny IoT devices. Finally, we discuss future research directions of communication protocols for IoT.

关键词： Internet of Things IoT application layer protocols IoT communicati on pr otocols Performance evaluation

Extended research of showing means of GIS in the development and management of oil and gas reservoir

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重庆邮电学院学报（自然科学版） 2004年第5期16卷 129-132页

作者： XIEQing JIANGYue mali InstituteofEconomic＆Management ChongqingUniversityofPostsandTelecommunicationsChongqing400065P.R.China InstituteofComputerScience＆Technology SouthwestUniversityforNationalitiesChengdu610041P.R.China

Owing to the close correlation of development of oil and gas reservoir and spatial geological place, the technique of GIS can be introduced into the process of development and management of oil and gas reservoir. But development of oil and gas reservoir has its particularity, development and management GIS of oil and gas reservoir should use the other techniques to extend the forms of representation to make up the shortages of GIS in representation. The development and management GIS of oil and gas reservoir will be perfect besides the basic functions of GIS. This paper expatiates how to use other techniques to extend GIS in development and management of oil and gas reservoir mainly from productive dynamic curve of well, layers of map piling up, 3 D geological model and replaying maps, etc. Through extended GIS in development and management of oil and gas reservoir, the forms of representation of geological information are enriched, representations of information are more direct and visual, spatial descriptive ability and forms of representation of GIS are built up and the single information system will be developed into a management and decision making system.

关键词： GIS 3-D地质模型油气池地理信息系统

Spatio-temporal breather dynamics in microcomb soliton crystals

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Light(Science & Applications) 2024年第11期13卷 2620-2633页

作者： Futai Hu Abhinav Kumar Vinod Wenting Wang Hsiao-Hsuan Chin James F.McMillan Ziyu Zhan Yuan Meng mali Gong Chee Wei Wong Fang Lu Mesoscopic Optics and Quantum Electronics Laboratory University of CaliforniaLos AngelesCAUSA State Key Laboratory of Precision Measurement Technology and Instruments Tsinghua UniversityBeijingChina

Solitons,the distinct balance between nonlinearity and dispersion,provide a route toward ultrafast electromagnetic pulse shaping,high-harmonic generation,real-time image processing,and RF photonic *** we uniquely explore and observe the spatio-temporal breather dynamics of optical soliton crystals in frequency microcombs,examining spatial breathers,chaos transitions,and dynamical deterministic switching–in nonlinear measurements and *** understand the breather solitons,we describe their dynamical routes and two example transitional maps of the ensemble spatial breathers,with and without chaos *** elucidate the physical mechanisms of the breather dynamics in the soliton crystal microcombs,in the interaction plane limit cycles and in the domain-wall understanding with parity symmetry breaking from third-order *** present maps of the accessible nonlinear regions,the breather frequency dependences on third-order dispersion and avoided-mode crossing strengths,and the transition between the collective breather spatio-temporal *** range of measurements matches well with our first-principles theory and nonlinear *** image these soliton ensembles and their breathers,we further constructed panoramic temporal imaging for simultaneous fast-and slow-axis two-dimensional mapping of the *** the phasedifferential sampling,we present two-dimensional evolution maps of soliton crystal breathers,including with defects,in both stable breathers and breathers with *** fundamental studies contribute to the understanding of nonlinear dynamics in soliton crystal complexes,their spatio-temporal dependences,and their stability-existence zones.

关键词： theory. soliton dynamics

Spatial coupling analysis of regional economic development and environmental pollution in China

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Journal of Geographical Sciences 2013年第3期23卷 525-537页

作者： mali JIN Fengjun SONG Zhouying LIU Yi Key Laboratory of Regional Sustainable Development Modeling of the Chinese Academy of Sciences Bei- jing 100101 China institute of Geographic Sciences and Natural Resources Research CAS Beijing 100101 China

Given the great number of studies focusing on the temporal interaction between economic and environmental subsystems, it is useful to perform a quantitative spatial as- sessment of these subsystems. In this paper, comprehensive assessment indicators for re- gional economic development and environmental pollution subsystems are constructed. Then the degree of coupling and coordination of the regional economy-environment system is calculated for 350 prefectural units in China. It is found that the economic development and environmental pollution in most prefectural units is still at a low level of coupling and coordi- nation. According to the coupling and coordination values, the Chinese territory can be di- vided into four types of area： economy-environment harmonious area, economy-environ- ment gearing area, economy-environment rivaling area and low coupling degree of econ- omy-environment area. Based on a structural analysis of the industrial sector in the four types of areas, there is a spatial relationship between the regional industrial sector structure and the coupling-coordination level. In the economy-environment harmonious area, the sectors of manufacturing of high-technology and high value-added products, such as com- munications, computer and electronic equipment, transport equipment and electrical ma- chinery, account for a large proportion of the value of local industrial output. The industrial value of the economy-environment gearing area is concentrated on the manufacturing of machinery and equipment, and. contains a few polluting sectors such as ferrous and non-ferrous metallurgy, chemical manufacturing and electricity generation. The econ- omy-environment rivaling area is the type of area where polluting sectors concentrate, such as iron and steel, petrifaction, coal mining, building materials and electricity generation. In the low coupling degree of economy-environment area, its industry is concentrated on the pro- duction and processing of primary

关键词： regional economy environmental pollution degree of coupling and coordination spatial pattern industrial sector structure characteristics

Self-assembly of CXCR4 antagonist peptide-docetaxel conjugates for breast tumor multi-organ metastasis inhibition

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Acta Pharmaceutica Sinica B 2023年第9期13卷 3849-3861页

作者： Chen Li Jiayan Lang Yazhou Wang Zhaoxia Cheng mali Zu Fenfen Li Jingyi Sun Yating Deng Tianjiao Ji Guangjun Nie Ying Zhao CAS Key Laboratory for Biomedical Effects of Nanomaterials&Nanosafety CAS Center of Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Pancreas Centre the First Affiliated Hospital of Nanjing Medical UniversityNanjing 210029China Green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou 450001China School of Basic Medical Sciences Zhengzhou UniversityZhengzhou 450001China

As a representative chemotherapeutic drug,docetaxel(DTX)has been used for breast cancer treatment for ***,the poor solubility of DTX limits its efficacy,and the DTX based therapy increases the metastasis risk due to the upregulation of C-X-C chemokine receptor type 4(CXCR4)expression during the ***,we conjugated CXCR4 antagonist peptide(CTCE)with DTX(termed CTCE-DTX)as an anti-metastasis agent to treat breast ***-DTX could selfassemble to nanoparticles,targeting CXCR4-upregulated metastatic tumor cells and enhancing the DTX ***,the CTCE-DTX NPs achieved promising efficacy on inhibiting both bonespecific metastasis and lung metastasis of triple-negative breast *** work provided a rational strategy on designing peptide-drug conjugates with synergistic anti-tumor efficacy.

关键词： Triple-negative breast cancer CXCR4 Docetaxel Drug delivery Peptide-drug conjugates Tumor metastasis Drug formulation

Spatiotemporal characterization of laser pulse amplification in double-pass active mirror geometry

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High Power Laser Science and Engineering 2020年第3期8卷 16-30页

作者： Tinghao Liu Qiang Liu Zhan Sui mali Gong Xing Fu Key Laboratory of Photonic Control Technology(Tsinghua University) Ministry of EducationBeijing 100084China State Key Laboratory of Precision Measurement Technology and Instruments Department of Precision InstrumentTsinghua UniversityBeijing 100084China Shanghai Institute of Laser Plasma China Academy of Engineering PhysicsShanghai 201800China

We present a spatiotemporal model of pulse amplification in the double-pass active mirror(AM)*** types of overlap condition are studied,and the spatiotemporal scaling under the four-pulse overlapping(4 PO)condition is fully characterized for the first time,by mapping the temporal and spatial segments of beam to the instantaneous gain ***,the influence of spatiotemporal overlaps on the amplified energy,pulse distortion and intensity profile is unraveled for both AM and zigzag *** model,verified by excellent agreement between the predicted and measured results,can be a powerful tool for designing and optimizing high energy multi-pass solid-state laser amplifiers with AM,zigzag and other geometries.

关键词： active mirror amplifier pulse overlap spatiotemporal characterization double-pass

Effect of Volume Fractions of Arc Sprayed Al Coatings on Tensile Properties of a Type 316 Steel Substrate

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材料热处理学报 2004年第05B期25卷 934-937页

作者： LIUGui-min mali-li KURZYDLOWSKIKrzysztofJan AcademyofArmoredForceEngineering BeijingChina FacultyofMaterialsScienceandEngineeringofWarsawUniversityofTechnology WarsawPoland

The effect of arc sprayed times, which are quantitatively described by the volume fraction of coatings, on the mechanical properties of type 316 steel, have been undertaken in the present work. Al wires were utilized as coatings materials. Tensile tests were carried out in the temperature range of Portevin-Le Chatelier (PLC) effect It has been found that grains at edges and corners of the 316 steel specimens have been dramatically constricted by grit blasting and spraying. Grit blasting has been found to exert a shot-peening effect on the mechanical properties of 316 steel specimens. Coatings with lower values of coating volume fraction strengthen the coated specimens in the very similar way as blasting. While if the volume fraction of coating, (Vv)c, exceeds a critical value, (VV)K, softens the specimens. Specimens with low values of (Vv)c, have high values of flow stress, as well as higher values of work-hardening coefficient, Calculations based on the experimental results show that the high thickness coatings have relatively lower contribution to the mechanical properties of specimens.

关键词：电弧喷镀层体积百分率 316型钢抗拉性能

A Method for Estimation of Wheat Yield Loss Caused by Drought in Northwestern China

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Agricultural Sciences in China 2004年第12期3卷 905-913页

作者： LIUJing WANGLian-xi mali-wen WUWan-li LIUYu-lan SUNYin-chuan NingxiaKeyLaboratoryforMeteorologicalDisasterPreventionandReduction Yinchuan750002P.R.China／／YinchuanMeteorologicalObservatoryYinchuan750002P.R.China

To develop a suitable method for monitoring wheat yield loss caused by drought for dry farming areas in northwestern China, daily ET0 and ETC were calculated using KC and FAO- PM from 1961 to 2000, and wheat evapotranspiration with an interval of 10 days was estimated with soil water balance equation for the mountainous areas in southern Ningxia, China. Actual water consumption and water requirements of wheat during growing season was calculated using soil water balance equation by correcting leakage of soil water and run-off of precipitation every year. A model for estimation of yield loss by drought was established based on crop growth-water consumption function and yield potential. The results show that it is an effective method for monitoring drought and estimating yield loss. This method is suitable for monitoring drought and estimating yield loss of wheat in dry farming areas in northwestern China.

关键词： Drought Monitor Yield loss estimation