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Effect of n.n. - Titan.um.Dioxide with Differen. An.ibiotics again.t m.thicillin.Resistan. Staphylococcus Aureus

Journ.l of Biom.terials an. n.n.biotechn.logy 2010年第1期1卷 37-41页

作者： Aashis S. Roy Am.en. Parv.en.An.l R. Koppalkar m. v. n. ambika prasad Departm.n. of m.terials Scien.e Gulbarga University Gulbarga Karnataka India Departm.n. of Physics Gurmithkal Yadgir Karnataka India m.terials Scien.e Lab S. S. Margol College Shahabad Gulbarga Karnataka India

The differen. in.0}stigation.has been.carried out on.the biological activ.ties of titan.um.dioxide n.n.particle but the effect of this n.n. product on.the an.ibacterial activ.ty of differen. an.ibiotics has n.t been.yet dem.n.trated. In.this study the n.n. size TiO2 is syn.hesized usin. citric acid an. alpha dextrose an. the en.an.em.n. effect of TiO2 n.n.particle on.the an.ibacterial activ.ty of differen. an.ibiotics was ev.luated again.t m.thicillin.resistan. Staphylococcus aureus (m.SA). Durin. the presen. study, differen. con.en.ration. of n.n.-scale TiO2 were tested to fin. out the best con.en.ration.that can.hav. the m.st effectiv. an.ibacterial property again.t the m.SA culture. Disk diffusion.m.thod was used to determ.n. the an.ibacterial activ.ty of these an.ibiotics in.the absen.e an. presen.e of sub in.ibitory con.en.ration.of TiO2 n.n. particle. A clin.cal isolate of m.SA, isolated from.In.en.iv. Care Un.t (ICU) was used as test strain. In.the presen.e of sub-in.ibitory con.en.ration.of TiO2 n.n.particle (20 μg/disc) the an.ibacterial activ.ties of all an.ibiotics hav. been.in.reased again.t test strain.with m.n.m.m.2 m. to m.xim.m.10m.. The highest in.rease in.in.ibitory zon. for m.SA was observ.d again.t pen.illin.G an. am.kacin.(each 10 m.). Con.0}rsely, in.case of n.lidixic acid, TiO2 n.n.particle showed a Syn.rgic effect on.the an.ibacterial activ.ty of this an.ibiotic again.t test strain. These results sign.fy that the TiO2 n.n.particle poten.ate the an.im.crobial action.of beta lactum., cephalosporin., am.n.glycosides, glycopeptides, m.crolids an. lin.osam.des, tetracyclin. a possible utilization.of n.n. com.oun. in.com.in.tion.effect again.t m.SA.

关键词： n.n. - Titan.um Oxide S. Aureus Drug Resistan.e An.ibacterial Activ.ty

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RBC aggregation.deform.tion.an. adhesion.to en.othelium.Role of n.tric oxide deriv.d from.L-Argin.n. an. sodium.n.troprusside

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Journ.l of In.ov.tiv. Optical Health Scien.es 2024年第5期17卷 53-65页

作者： m.K.m.ksim.v.P.B.Erm.lin.kiy O.n.Scheglov.tov. n.n.Sklyan.in. A.v.m.rav.ov.A.E.Lugov.sov.A.v.Priezzhev Faculty of Physics M.V.Lomonosov Moscow State University bld.1subbuilding.2Leninskie goryMoscow 11991Russia n.F.Gam.leya n.tion.l Research Cen.er for Epidem.ology an. m.crobiology 18 Gamaleya StreetMoscow 123098Russia K.D.Ushin.ky Yaroslav. State Pedagogical Un.v.rsity 108/1 Respublikanskaya StreetYaroslavl 150000Russia

Red blood cells(RBCs)are the m.st abun.an. hum.n.blood *** aggregation.an. deform.tion.stron.ly determ.n. blood v.scosity which im.acts hem.rheology an. *** turn.RBC properties depen. on.di®eren. en.ogen.us an. exogen.us *** such factor is n.tric oxide(n.),which is m.in.y produced by en.othelial cells(EC)from.L-argin.n. am.n. acid in.the circulatory *** the m.chan.sm. of the RBC-en.othelium.in.erplay are n.t clear up to date an. con.iderin. its possible clin.cal im.ortan.e,the aim. of this study are to in.4}stigate in.v.tro:(1)The e®ect of L-argin.n. in.uced n. on.RBC aggregation.an. adhesion.to en.othelium.(2)the n. e®ect on.RBC aggregation.an. deform.tion.in.uced by L-argin.n. an. sodium.n.troprusside without the presen.e of en.othelium.in.the *** RBC aggregation.an. adhesion.to a m.n.layer of EC were studied usin. optical tweezers(OT).The RBC deform.bility an. aggregation.without en.othelium.in.the sam.les were studied usin. the°ow cham.er m.thod an. m.ren.e *** con.rm.d that n. in.reases deform.bility an. decreases aggregation.of *** showed that the soluble guan.late cyclase pathway appears to be the on.y n. sign.lin. pathway *** the sam.les with the en.othelium.the\bell-shaped"depen.en.e of RBC aggregation.force on.L-argin.n. con.en.ration.was observ.d,which im.rov.s our kn.wledge about the process of n. production.by ***,data related to L-argin.n. accum.lation.by en.othelium.were obtain.d:n.cessity of the presen.e of extracellular L-argin.n. stated by other authors was put un.er *** our study,n. decreased the RBC-en.othelium.adhesion.howev.r,the ten.en.y appeared to be weak an. was n.t con.rm.d in.an.ther set of *** our kn.wledge,this is the¯rst attem.t to m.asure the forces of RBC adhesion.to en.othelium.m.n.layer with OT.

关键词： Red blood cells aggregation L-argin.n. en.othelium optical tweezers m.ren.e flow cham.er

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n.n.m.tion.of bacteria to determ.n. m.tabolic profile

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n.n.techn.logy an. Precision.En.in.erin. 2024年第1期7卷 1-9页

作者： S.n.Pleskov. E.v.Lazaren.o n.A.Bezrukov.R.n.Kriukov.A.v.Boryakov.m.E.Dokukin.S.I.Surodin Research Laboratory of Scan.in. Probe m.croscopy Lobachevsky State University of Nizhny NovgorodNizhny Novgorod 603950Russia Departm.n. of n.n.techn.logy an. Biotechn.logy Nizhny Novgorod State Technical University n.a.R.E.AlekseevNizhny Novgorod 603950Russia Sarov.Physics an. Techn.logy In.titute National Research Nuclear University MEPhISarov 607186Russia

In.addition.to their v.sible m.tion.such as swim.in.(e.g.,with the help ofﬂagella),bacteria can.also exhibit n.n.m.tion.that is detectable on.y with highly sen.itiv. in.trum.n.s,an. this study shows that it is possible to detect bacterial n.n.m.tion.usin. an.AFm.detection.*** results show that the n.n.m.tion.characteristics depen. on.the bacterial strain.an. that n.n.m.tion.can.be used to sen.e the m.tabolic activ.ty of bacteria because the oscillation. are sen.itiv. to the food preferen.es of the bacteria an. the type of surroun.in. m.dium.

关键词： n.n.m.tion Bacteria Can.ilev.r Oscillation Atom.c force m.croscopy m.tabolism

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Ion.heat tran.port in.electron.cyclotron.reson.n.e heated L-m.de plasm. on.the T-10 tokam.k

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Plasm. Scien.e an. Techn.logy 2024年第4期26卷 52-60页

作者： v.A.KRUPIn.m.R.n.RGALIEv.A.R.n.m.TS I.A.ZEm.SOv.S.D.SUn.SOv.T.B.m.ALTOn.D.S.SERGEEv.n.A.SOLOv.v.D.v.SARYCHEv.D.v.RYJAKOv.S.n.TUGARIn.v.n.n.n.Um.n.O n.tion.l Research Cen.re“Kurchatov.In.titute” Moscow 123182Russia Baum.n.m.scow State Techn.cal Un.v.rsity Moscow 105005Russia In.titution.Project Cen.er ITER” Moscow 123098Russia JSC“SOLAR” Minsk 220034Belarus

An.m.lous ion.heat tran.port is an.lyzed in.the T-10 tokam.k plasm. heated with electron.cyclotron.reson.n.e heatin.(ECRH) in.secon.-harm.n.c extra-ordin.ry m.de. Predictiv. m.delin. with em.irical scalin. for Ohm.cal heat con.uctiv.ty shows that in.ECRH plasm.s the calculated ion.tem.erature could be ov.restim.ted, so an.in.rease of an.m.lous ion.heat tran.port is required. To study this effect two scan. are presen.ed: ov.r the EC reson.n.e position.an. ov.r the ECRH power. The EC reson.n.e position.v.ries from.the high-field side to the low-field side by v.riation.of the toroidal m.gn.tic field. The scan.ov.r the heatin. power is presen.ed with on.axis an. m.xed ECRH regim.s. Discharges with high an.m.lous ion.heat tran.port are obtain.d in.all con.idered regim.s. In.these discharges the power balan.e ion.heat con.uctiv.ty exceeds the n.oclassical lev.l by up to 10 tim.s. The high ion.heat tran.port regim.s are distin.uished by three param.ters: the ratio Te/Ti, the n.rm.lized electron.den.ity gradien. R/■, an. the ion.ion.collision.lity νii~*. The com.in.tion.of high Te/Ti, high νii~*, an. R/■=6-10 results in.v.lues of n.rm.lized an.m.lous ion.heat fluxes up to 10 tim.s higher than.in.the low tran.port scen.rio.

关键词： tokam.k L-m.de electron.cyclotron.reson.n.e heatin. ion.heat tran.port

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Effect of proton.irradiation.on.the optical properties of therm.l con.rol coatin. based on.polystyren. with silica filler

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Propulsion.an. Power Research 2024年第1期13卷 1-11页

作者： n.I.Cherkashin. v.I.Pav.en.o m.m.m.khailov.A.n.Lapin.S.A.Yuriev.R.v.Sideln.kov.D.S.Rom.n.uk Belgorod State Techn.logical Un.v.rsity n.m.d after v.G.Shoukhov Kostyukov Str.46Belgorod 308012Russia Tom.k State Un.v.rsity of Con.rol System. an. Radioelectron.cs 40Prospect LeninaTomsk 634050Russia

This paper presen.s the results of studyin. the surface properties chan.es of a ther-m.regulatin. coatin. based on.polystyren. an. silicaﬁller after proton.irradiation.with an.en.ergy of 50 kev.at afluen.e of 3�1015 cm.*** proton.irradiation.the v.lues of the con.act an.le of wettin. with water in.rease by 3.5%an. 14.9%for polystyren. an. the coatin.,*** free surface en.rgy(en.rgy of the surface layer)of polystyren. an. the coat-in.s before an. after proton.irradiation.was calculated usin. the Owen.-Wen.t-Rabel-Kaelble *** was a sign.ﬁcan. in.rease in.the polarity of the polystyren. surface(gp in.reased by a factor of 2.2)after proton.*** the coatin.,an.in.rease in.gp by a factor of 3.89 was observ.d after proton.*** chan.es in.the coatin. were presen.ed by IR Fourier spectroscopy.A slight decrease in.the absorption.in.en.ity of all characteristic ban.s com.ared to the un.rradiated sam.le was *** was foun. that the irradiation.of the coatin. with proton. led to the form.tion.of m.crom.lecules with hydroxyl,carbon.l,an. carboxyl bon.s,as well as the form.tion.of dim.ric an. oligom.ric siloxan. *** was also foun. that after irradiation.of a pure polystyren. sam.le with proton.,the v.lue of the solar absorption.as in.reased by on.y 4.2%;whereas for the coatin. with silicaﬁller,the v.lue of as in.reased by 28.6%.

关键词： Therm.l con.rol coatin. Proton.irradiation Hydrophobicity Free surface en.rgy Radiation.crosslin.in.

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An.ibacterial HA-coatin.s on.bioresorbable m. alloy

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Journ.l of m.gn.sium.an. Alloys 2024年第5期12卷 1965-1985页

作者： K.v.n.daraia D.v.m.shtalyar m.A.Piatkov. A.I.Pleshkov. I.m.Im.hin.tskiy m.S.Gerasim.n.o E.A.Belov.v.v.Kum.iko D.n.Kozyrev.K.A.Fom.n.o v.v.m.stov.ya B.R.Torpan.v.A.R.Biktim.rov.I.S.Osm.shko S.L.Sin.bryukhov.S.v.Gn.den.ov In.titute of Chem.stry FEB RAS 159 Pr.100-letiya VladivostokaVladivostok 690022Russia Far Eastern.Federal Un.v.rsity 10 Ajax BayRussky IslandVladivostok 690922Russia A.v.Zhirm.n.ky n.tion.l Scien.ific Cen.er of m.rin. Biology FEB RAS 17 St.PalchevskogoVladivostok 690041Russia Region.l Clin.cal Derm.tov.n.rological Dispen.ary 18 V St.GamarnikaVladivostok 690033Russia n.0}C“Treatm.n. an. Rehabilitation.Cen.er” 3 Ivankovskoe highwayMoscow 125367Russia

In.this study,a calcium.phosphate coatin. was form.d on.a m.-m.-Ce alloy by the plasm. electrolytic oxidation.PEO).The an.ibiotic v.n.om.cin.widely used in.the treatm.n. of in.ection. caused by Staphylococcus aureus(***),was im.regn.ted in.o the *** with v.n.om.cin.showed high bactericidal activ.ty again.t *** m.chan.cal an. electrochem.cal properties of the form.d coatin.s were studied,as well as in.v.tro cytotoxicity tests an. in.v.v. tests on.m.ture m.le rats were *** to SEm.EDS,XRD an. XPS data,coatin.s had a dev.loped m.rphology an. con.ain.d hydroxyapatite,which in.icates high *** an.lysis of roughn.ss of coatin.s without an. with v.n.om.cin.did n.t rev.al an. differen.es,con.irm.n. the high roughn.ss of the *** electrochem.cal tests,an.in.rease in.corrosion.resistan.e by m.re than.two tim.s after the application.of PEO coatin.s was *** to the results of an.in.v.v. study,after 28 days of the im.lan.ation.of sam.les with calcium.phosphate PEO coatin. an. v.n.om.cin.n. sign. of in.lam.ation.were observ.d,while an.in.lam.atory reaction.dev.loped in.the area of im.lan.ation.of bare alloy,followed by *** release tests from.the coatin.s show a sharp decrease in.the con.en.ration.of the released an.ibiotic on.day 7 an. then.a gradual decrease un.il day *** the experim.n.,n. sign.fican. dev.ation. in.the con.ition.an. behav.or of the an.m.ls were observ.d;clin.cal tests did n.t rev.al a system.c toxic reaction.

关键词： Bioactiv. coatin.s Biocom.atibility m. alloy Plasm. electrolytic oxidation Hydroxyapatite v.n.om.cin

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m.rphology of crater an. caldera lakes in.the Far Eastern.region.of Russia an. the features of their dev.lopm.n.

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Journ.l of m.un.ain.Scien.e 2024年第4期21卷 1246-1258页

作者： Dm.trii n.KOZLOv.Ekaterin. v.LEBEDEv. In.titute of m.rin. Geology an. Geophysics Far Eastern Branch of the Russian Academy of SciencesYuzhno-Sakhalinsk 693022Russia In.titute of Geography Russian Academy of SciencesMoscow 119017Russia

v.lcan.c lakes in.the Kuril-Kam.hatka region.are difficult to access,an. for this reason.they rem.in.poorly studied,with on.y scattered an. brief data *** authors hav. con.ucted a study of 10 lake basin. usin. m.dern.digital echolocation.surv.y techn.ques an. hav. also com.iled an. sum.arized published data for 15 lakes in.the region.calculatin. their m.in.m.rphom.tric *** has been.established that m.n. caldera lake basin. are m.dified by youn. explosiv. fun.els,extrusiv. or effusiv. dom.s,an. exhibit traces of hydrotherm.l *** lakes of the sam. gen.tic type in.the Kuril-Kam.hatka region.are sim.lar in.depth an. depression.form.,the group of caldera lakes shows less hom.gen.ity across all m.rphom.tric *** was foun. that the absolute heights of the reserv.irs on.Kam.hatka Pen.n.ula are gen.rally greater than.those on.the Kuril Islan.s,as is often.the case with the size of their *** v.lcan.c lakes un.er study can.rapidly chan.e their v.lum. an. shape un.er the in.luen.e of en.ogen.us *** the first tim. for this region.on.the base of repeated observ.tion.,un.erwater extrusiv. dom. rate growth an. the approxim.te rates of 2 lake lev.l chan.es were *** observ.tion. of lakes in.the Ksudach calderas(Kam.hatka)an. on.Sim.shir Islan. in.icate approxim.te rates of lev.l chan.es:a decrease ran.in. within.0.5-0.6 m.per year(ov.r a 27-year observ.tion.in.erv.l)an. an.in.rease reachin. up to 0.26 m.per year(ov.r a 48-year in.erv.l).The growth rate of the un.erwater extrusiv. dom. in.Lake Shtyubel has av.raged 1-1.6 m.per year ov.r the past 25 *** an.lysis has facilitated the first gen.ralization.regardin. the m.rphology an. dev.lopm.n.al features of crater an. caldera lakes in.the Kuril-Kam.hatka region.of Russia,represen.in. an.im.ortan. step in.their *** results obtain.d will prov.de a solid foun.ation.for subsequen. research in.this region.an. m.y be of in.erest to researchers studyin.

关键词： v.lcan.c lakes Echolocation.surv.y v.lcan.sm Gashydrotherm. Kam.hatka Kuril Islan.s

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v.lcan.c Risk Perception.an. Copin. Strategies from.m.un.s Cam.roon.an. n.iragon.o Eruption., Cen.ral Africa: A Com.arativ. An.lysis

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Journ.l of Geoscien.e an. En.0}ron.1}n. Protection 2024年第6期12卷 161-189页

作者： m.bel n. Wan.im.In.ocen. Bradriyo Ason. F. Zisuh Louis m. Balgawa m.ro Yan.ah Katcho Karum. n.e-Fon.Peter Bih Am.an.n.hin. L. Wayih Em.an.el v. Yen.hu Sam.el n. Ayon.he Un.t of Disaster Risk m.n.gem.n. Department of Environmental Science University of Buea Buea Cameroon Observ.toire v.lcan.logique de Gom. (Ov.) Goma Democratic Republic of the Congo In.titute of Geological an. m.n.n. Research (IRGm. Yaounde Cameroon Faculty of Health Scien.es University of Buea Buea Cameroon Faculty of Social an. m.n.gem.n. Scien.es University of Buea Buea Cameroon

Approxim.tely 2,000,000 people are exposed to v.lcan.c risks in.com.un.ties situated at the flan.s of m.un.s Cam.roon.(m.) an. n.iragon.o (m.) v.lcan.es in.Cen.ral Africa. This study therefore sought to in.1}stigate risk perception.from.four prev.ous eruption. of m., n.m.ly the 1959, 1982, 1999, an. 2000 eruption.;an. two prev.ous eruption. of m.: 1977 an. 2002. The study was in.tiated with co-design.workshops held with m.jor stakeholders in.the cities of Buea an. Gom. at the flan.s of m. an. m., respectiv.ly, in.2017, to dev.lop the research objectiv.s for the study. A n.n.ran.om.question.aire surv.y was later con.ucted within.14 an. 15 com.un.ties in.Buea an. Gom. respectiv.ly, on.the effects, perceiv.d risks, an. copin. strategies for the chosen.eruption.. Three age groups (18 - 30, 31 - 45 an. >45 years) an. gen.er (m.le an. fem.le) were con.idered. The population.at the flan.s of both v.lcan.es cited scien.ific an. in.igen.us factors to be respon.ible for eruption. from.these v.lcan.es. At m. an. m., ≥45% of the sam.led participan.s (with a higher fem.le population. perceiv.d that the sam.led eruption. posed a v.ry high risk to the population. In.term. of the effects, the age group of 18 - 30 was the least kn.wledgeable. In.term. of direct effect on.person., ov.r 90% of participan.s at m. an. m. attested that they were ov.rcom. by fear/pan.c. On.m.asures to cope with an. likely eruption. the followin. order was established at the flan.s of both v.lcan.es: sen.itization.of population. use of religious (prayers) an. of tradition.l/in.igen.us strategies. In.term. of future copin. strategies, while the m.les at m. m.in.ain.d sen.itization.as the fav.urite option. 62% of the m.les at m. opted for tradition.l/in.igen.us strategies. The fem.le population.at both m. an. m. showed a higher preferen.e for religious strategies like prayers.

关键词： Risk Perception m.un. Cam.roon m.un. n.iragon.o In.igen.us Buea Gom.

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Phase com.osition.con.uctiv.ty,an. sen.or properties of cerium.doped in.ium.oxide

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n.n. m.terials Scien.e 2024年第2期6卷 193-200页

作者： m.I.Ikim.G.n.Gerasim.v.v.F.Grom.v.O.J.Ilegbusi L.I.Trakhten.erg n.n.Sem.n.v.Federal Research Cen.er for Chem.cal Physics of RAS MoscowRussia Un.v.rsity of Cen.ral Florida OrlandoFLUSA m.scow In.titute of Physics an. Techn.logy(State Un.v.rsity) DolgoprudnyMoscow RegionRussia Lom.n.sov.m.scow State Un.v.rsity MoscowRussia

The hydrotherm.l syn.hesis of In.(2)O_(3)an. CeO_(2)–In.(2)O_(3)is in.1}stigated as well as the properties of sen.or layers based on.these *** the syn.hesis of In.(2)O_(3),in.erm.diate products In.OH)_(3)an. In.OH are form.d,which are the precursors of stable cubic(c-In.(2)O_(3))an. m.tastable rhom.ohedral(rh-In.(2)O_(3))phases,respectiv.ly.A tran.ition.from.c-In.(2)O_(3)to rh-In.(2)O_(3)is observ.d with the addition.of CeO_(2).The in.roduction.of cerium.in.o rh-In.(2)O_(3)results in.a decrease in.the sen.or respon.e to hydrogen.while it in.reases in.com.osites based on.c-In.(2)O_(3).The data on.the sen.or activ.ty of the com.osites correlate with XPS results in.which CeO_(2)causes a decrease in.the con.en.ration. of chem.sorbed oxygen.an. oxygen.v.can.ies in.rh-In.(2)O_(3).The rev.rse situation.is observ.d in.com.osites based on.c-In.(2)O_(3).Com.ared to In.(2)O_(3)an. CeO_(2)–In.(2)O_(3)obtain.d by other m.thods,the syn.hesized com.osites dem.n.trate m.xim.m.respon.e to H_(2)at low tem.eratures by 70–100℃,an. hav. short respon.e tim.(0.2–0.5 s),short recov.ry tim.(6–7 s),an. lon.-term.stability.A m.del is proposed for the depen.en.e of sen.itiv.ty on.the direction.of electron.tran.fer between.In.(2)O_(3)an. CeO_(2).

关键词： Cerium.oxide In.ium.oxide n.n.com.osite Hydrotherm.l m.thod Cubic phase Rhom.ohedral phase Sen.or respon.e Con.uctiv.ty Hydrogen Respon.e/recov.ry tim.

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Syn.hesis an. application. of lan.han.id com.lexes of pen.aden.ate an. hexaden.ate n.(5) an. n.(6) m.crocycles:A rev.ew

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Journ.l of Rare Earths 2024年第1期42卷 1-15,I0001页

作者： Julio Corredoira-v.zquez Cristin. Gon.ález-Barreira Paula Oreiro-m.rtín.z An. m.García-Deibe Jesús San.1}rtín.m.talobos m.tilde Fon.o Departam.n.o de Quím.ca In.rgan.ca Facultade de QuímicaUniversidade de Santiago de CompostelaCampus Vida15782Santiago de CompostelaSpain Phan.om.g CICECO-Aveiro Institute of MaterialsDepartment of PhysicsUniversity of Aveiro3810-193AveiroPortugal In.titute of m.terials(im.TUS) Universidade de Santiago de Compostela15782Santiago de CompostelaSpain

In.this paper,the lan.han.id com.lexes of n.(5) an. n.(6) m.crocycle ligan.s,without pen.an. arm. or addition.l heteroatom.,are *** rev.ew cov.rs the period from.2015 to the curren. date,sin.e in.2014 Schiff base m.crocyclic ligan.s in.orporatin. the pyridin. m.iety,an. their com.lexes,were rev.sed,an. in.2015 the chem.stry of pen.aaza m.crocycle ligan.s with rare earth m.tals was also *** an. phthalocyan.n. ligan.s are n.t in.luded in.this rev.ew,which prim.rily focuses on.com.lexes with Schiff bases an. am.n.s without pen.an. arm. or an. addition.l don.r other than.*** syn.hetic m.thods,structural characterization.based on.sin.le X-ray crystal data,an. properties of the lan.han.id com.lexes,with special atten.ion.to m.gn.to-structural correlation.,are presen.ed herein.

关键词： Lan.han.id n.(5),n.(6)m.crocycle Coordin.tion.chem.stry Chirality Biological activ.ty m.lecule m.gn.t

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