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Micro-strain regulation strategy to stabilize perovskite lattice based on the categories and impact of strain on perovskite solar cells

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Journal of Energy Chemistry 2025年第1期100卷 578-604页

作者： Caixia Li Wenwu Liu Shiji Da lingbin kong Fen Ran State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050GansuChina

Photovoltaic metal halide perovskite solar cells(PSCs) convert light to electricity more efficiently than crystalline silicon cells, and the cost of materials used to make them is lower than that of silicon *** efficiency is not a core issue affecting the application of perovskite solar cells in special *** present, stability is the major technical encounters that hinders its further commercial development. Microstrain in PSCs is currently a significant factor responsible for the device's instability. Strain-induced ion migration is widely believed to accelerate perovskite degradation even when external stimuli are ***, it is imperative to study strain to enhance the stability of PSCs. This paper reviews recent developments to understand strain's origin and effect mechanisms on performance of PSCs, including ion migration,failure behavior, defect formation, and its effect on photoelectric properties, stability, and ***, several well-known strain management strategies are systematically introduced based on the strain effect mechanism and strain engineering on the film, providing more clues for further preparation with increased stability. The manipulation of external physical strain applied from films to entire devices has been extensively studied. Furthermore, recommendations for future research directions and chemical approaches have been provided. It is emphasized that strain engineering plays a crucial role in improving the efficiency and longevity of PSCs. Tensile strain causes rapid degradation, while moderate compressive strain and external strain control could improve properties and stability. Efforts should focus on controlling compressive strain to mitigate residual tensile strain and introducing it in a controlled manner. Future research endeavors may focus on exploring these pathways to improve the efficiency and lifespan of PSCs.

关键词： Halide perovskite solar cells Strain origins Strain effects Strain management

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Correlation between special brain area and blood perfusion in patients with cerebral infarction at convalescent period Feasibility for quantitative determination and estimation of learning and memory function

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Neural Regeneration Research 2007年第8期2卷 461-465页

作者： lingbin kong Rui An Zhiyin Yang Department of Nuclear Medicine Union Hospital Tongji Medical College Huazhong University of Science and Technology Wuhan430032 Hubei Province China Jining Medical College Shandong Institute for Behavioral Medicine Jining 272013 Shandong Province China

BACKGROUND： Presently, clinic memory scale is used to evaluate learning memory ability in most studies, and the influence of difference in measurement condition of individuals exists. OBJECTIVE： To study the correlation between regional cerebral blood flow （rCBF） perfusion and learning memory function in special brain regions of patients with cerebral infarction at convalescent period, and to try to find out a method which can quantitatively evaluate learning ability. DESIGN： Case observation, and correlation analysis. SETTINGS： Shandong Institute for Behavioral Medicine; the Affiliated Hospital of Jining Medical College. PARTICIPANTS： Totally 70 patients with cerebral infarction admitted to Department of Neurology, Jining Medical College between January 2004 and December 2005 were involved. The involved patients, 58 male and 12 female, were averaged （52±3） years, and they were all right handed. They all met the diagnosis criteria instituted by the Fourth National Conference on Cerebrovascular Disease, and were confirmed as cerebral infarction by skull CT or MRI. Informed consents of detected items were obtained from all the patients and relatives. METHODS： When the patients were at convalescent period, their learning and memory ability were measured with “ clinic memory scale （set A）”. The 18 patients whose total mark over 100 were regarded as good learning memory function group; The 23 cases whose total mark less than 70 were regarded as poor learning memory function group. RCBF of hippocampus, nucleus amygdalae, temporal cortex and prefrontal lobe of patients between two groups were measured and compared by single photon emission computed tomography （SPECT）. The total scores of the 18 good learning memory patients and 23 poor learning memory patients were taken as dependent variable Y, and their rCBFs of hippocampus, nucleus amygdale, temporal cortex and prefrontal lobe respectively as independent variable X for linear correlation analysis. MAIN OUTCOME MEASURES：

关键词： hippocampus nucleus amygdale temporal cortex, prefrontal lobe regional cerebral blood flow learning memory function relativity

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Facile synthesis of high electrical conductive CoP via solid-state synthetic routes for supercapacitors

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Journal of Energy Chemistry 2017年第1期26卷 49-55页

作者： Yumei Hu Maocheng Liu Qingqing Yang lingbin kong Long Kang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050GansuChina

Co-P precursor was prepared by a mechanical alloying method and then is controlled to synthesis of CoP phase through an annealing method. The optimal conditions of ball milling and annealing temperature are investigated. The CoP exhibits higher electrical conductivity than graphite and cobalt oxide, showing excellent pseudocapacitive properties due its high electrical conductivity which can result in a fast electron transfer in high rate charge-discharge possess. The as-obtained CoP electrode achieves a high specific capacitance of 447.5 Fig at 1 Aug, and displays an excellent rate capability as well as good cycling stability. Besides, the asymmetric supercapacitor (ASC) based on the CoP as the positive electrode and activated carbon (AC) as the negative electrode was assembled and displayed a high rate capability (60% of the capacitance is retained when the current density increased from 1 Aug to 12 Aug), excellent cycling stability (96.7% of the initial capacitance is retained after 5000 cycles), and a superior specific energy of 19 Wh/kg at a power density of 350.8 W/kg. The results, suggest that the CoP electrode materials have a great potential for developing high-performance electrochemical energy storage devices. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

关键词： CoP High electrical conductivity Pseudocapacitive properties Asymmetric supercapacitor

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The design and fabrication of Co3O4/Co3V2O8/Ni nanocomposites as high-performance anodes for Li-ion batteries

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Journal of Energy Chemistry 2017年第3期26卷 494-500页

作者： Yang Li lingbin kong Maocheng Liu Weibin Zhang Long Kang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050GansuChina

The CoO/CoVO/Ni nanocomposites were rationally designed and prepared by a two-step hydrothermal synthesis and subsequent annealing treatment. The one-dimensional（1D） CoOnanowire arrays directly grew on Ni foam, whereas the 1D CoVOnanowires adhered to parts of *** of the hybrid nanowires were inlayed with each other, forming a 3D hybrid nanowires *** a result, the discharge capacity of CoO/CoVO/Ni nanocomposites could reach 1201.8 mAh/g after100 cycles at 100 mA/g. After 600 cycles at 1 A/g, the discharge capacity was maintained at 828.1 mAh/***, even though the charge/discharge rates were increased to 10 A/g, it rendered reversible capacity of 491.2 mAh/g. The superior electrochemical properties of nanocomposites were probably ascribed to their unique 3D architecture and the synergistic effects of two active materials. Therefore, such CoO/CoVO/Ni nanocomposites could potentially be used as anode materials for high-performance Li-ion batteries.

关键词： Co3O4 Co3V2O8 Ni foam Nanocomposites Li-ion batteries

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Facile synthesis of MoS_2/graphite intercalated composite with enhanced electrochemical performance for sodium ion battery

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Journal of Energy Chemistry 2018年第4期27卷 1208-1213页

作者： Qingqing Yang Maocheng Liu Yumei Hu Yan Xu lingbin kong Long Kang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of Technology School of Materials Science and Engineering Lanzhou University of Technology

MoS2 is a promising anode material for sodium ion batteries owing to its two-dimensional layered structure and high specific capacity. But it still exhibits a poor cycle stability and limited rate capability for Na＋ storage because of its poor electrical conductivity and structural instability. In this work, MoS2/graphite composite is fabricated by mechanically delaminated and restacked MoS2 and graphite to form two-dimensional composite layers. The graphite sheets will improve electrical conductivity and prevent the aggregation as well as structure collapse of the MoS2 layers during charge-discharge process. The MoS2/graphite composite exhibits excellent Na＋ storage properties. It delivers a high discharge specific capacity of 358.2 mAh/g at a current density of 100 mA]g in the first discharge process and with capacity retention of 68.1% after 800 cycles （retains 244 mAh/g）. The average discharge specific capacities retain 250.9 and 225.4 mAh/g corresponding to the current densities of 100 and 1000 mA]g, showing excellent rate capability. The improved electrochemical performance is attributed to the improved electrical conductivity and structural stability after composition of graphite sheets. The study demonstrates a new research strategy for improving sodium ion storage properties of Mo52.

关键词： Sodium ion batteries Transition metal disulfides MoS2/graphite Anode materials

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Effects of special brain area regional cerebral blood flow abnormal perfusion on learning and memory function and its molecular mechanism in rats

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Frontiers in Biology 2008年第2期3卷 147-153页

作者： lingbin kong Zhiyin YANG Rui AN Shouhua DING Jining Medical College Shandong Institute of Behavioral Medical ScienceJining 272000China Department of Nuclear Medicine Union HospitalTongji Medical College of Huazhong University of Science and TechnologyWuhan 430030China

To study the effect of special brain area regional cerebral blood flow(rCBF)abnormal perfusion on learning and memory function and its molecular mechanism,64 adult male healthy Sprague-Dawley(SD)rats were randomly divided into two groups,the false operation group(control group)and the operation group(model group).After surgical operation,the operation group undertook bilateral common carotid artery permanent ligation,while the other group did *** and memory function were measured by Y-maze at 4 h,8 h,24 h and 3 d after surgical operation,*** rCBF of the right frontal lobe and hippocampus was also detected by the PerifluxPF model laser Doppler flowmetry,and the expressions of c-fos or c-jun or Bcl-2 and Bax were also measured by immune histochemistry S-P method *** showed that the rCBF of the right frontal lobe and hippocampus in the operation group was significantly lower than that in the false operation group(P,0.05).The learning indexes,error number(EN),day of reach standard and total reaction time(TRT)in the operation group,were significantly higher than that in the false operation group(P,0.05).However,the initiative evasion rate in the operation group was significantly lower than that in the false operation *** study also found that the rCBF was relatively more,the indexes(EN,the day of reach standard and TRT)relatively fewer,but the initiative evasion rate and the memory keeping rate were relatively *** positive expression and the average absorbency of Fos and Jun in the operation group were significantly higher than that in the false operation group(P<0.05).Furthermore,Bax and Bcl-2 positive cells were all increased over time in the operation group,and the expression ratio of Bax/Bcl-2 in the operation group was significantly higher than that in the false operation group(P<0.01).In conclusion,rCBF decrease can impair the learning and memory function in rats,which may be related to the increase of the expression

关键词： rCBF learning memory function correlation frontal lobe hippocampus molecular mechanism

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A bird nest-like manganese dioxide and its application as electrode in supercapacitors

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Journal of Energy Chemistry 2013年第6期22卷 928-934页

作者： Fen Ran Huili Fan Lingren Wang Lei Zhao Yongtao Tan Xuanxuan Zhang lingbin kong Long Kang State Key Laboratory of Gansu Advanced Non-Ferrous Metal Materials Lanzhou University of Technology Key Laboratory of Non-ferrous Metal Alloys and Processing of Ministry of Education Lanzhou University of Technology

A novel bird nest-like nanostructured MnO2(BNNS-MnO2) was prepared by a facile and cost-effective strategy. Their structures and morphologies were characterized by field emission scanning electron microscopy, transmission electron microscopy and powder X-ray diffraction. Capacitive behaviors were investigated by cyclic voltammetry and galvanostatic charge-discharge. The obtained nano-MnO2 possesses a well designed loose-assembled hierarchical nanoarchitecture with an appropriate crystallinity which gives rise to excellent performances as an electrode material for supercapacitors. A maximum specific capacitance of 917 F/g has been obtained at a current density of 5 mA/cm2 in 6 mol/L KOH aqueous solution, and a specific capacitance of 210 F/g has been maintained for 500 cycles. As the low cost of MnSO4 and KCr2O7 and the low reaction temperature, the present method avoids the requirements for complicated operations, time/energy-consuming and expensive reagents, and perhaps is ready for the industrialization of nano-MnO2 production.

关键词： energy storage nanostructured MnO2 supercapacitors electrochemical performance electrode material

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Vanadium Nitride Nanoparticles as Anode Material for Lithium Ion Hybrid Capacitor Applications

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Journal of Wuhan University of Technology(Materials Science) 2019年第6期34卷 1274-1278页

作者： LIU Wenchao ZHANG Weibin KANG Long kong lingbin State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China

A high production efficiency synthesis method was used to produce a stacked vanadium nitride nanoparticle structure with an inexpensive raw material as an anode material and high surface area polystyrene was used the cathode material for lithium ion hybrid capacitors. The Li-HCs cell displayed an excellent specific capacitance of 64.2 F·g^-1 at a current density of 0.25 A·g^-1 and a wide potential window of 0.01 to 3.5 V. Furthermore, the device exhibited a high energy density of 109.3 W·h·kg^-1 at a power density of 512.3 W·kg^-1 and retained an energy density of 69.2 W·h·kg^-1 at a high power density of 3 498.9 W· kg^-1 at 2 A·g^-1. Due to the short synthesis time and simple raw materials, this method is suitable for industrial production.

关键词： energy storage lithium ion capacitors anode materials vanadium nitride

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Prospect of the Seawater Desalination Technology

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Journal of Energy and Power Engineering 2017年第8期11卷 511-516页

作者： kong lingbin Luzhou Tianxu Tiancheng New Energy Co. Ltd. Luzhou City 646600 Sichuan Province China

This article classifies the seawater desalination technology into four types of hot method, membrane method, electric field method and solvent method. Electric field method and solvent method still remain experimental stage, while hot method and membrane method have been realized in commercialization but are difficult to be promoted. The problem lies in high water-producing cost. It is difficult for membrane method seawater desalination technology to reduce the water-producing cost. The heat utilization efficiency is not high for the current hot method seawater desalination technology and there is large amount of heat lost with the emission of concentrated seawater. The new hot method seawater desalination technology and new solar-powered seawater desalination technology can divide the seawater into fresh water and solid salt without any emission of concentrated seawater so that the heat utilization efficiency can reach theoretical limit to multiply reduce the water-producing cost. They will become the mainstream technology for seawater desalination and can totally eliminate the global water crisis.

关键词： Seawater desalination membrane method hot method solar energy.

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Validation of MODIS C6 AOD Products Retrieved by the Dark Target Method in the Beijing–Tianjin–Hebei Urban Agglomeration,China

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Advances in Atmospheric Sciences 2017年第8期34卷 993-1002页

作者： Jie ZHANG Jinyuan Xin Wenyu ZHANG Shigong WANG Lili WANG Wei XIE Guojie XIAO Hela PAN lingbin kong College of Atmospheric Sciences Chengdu University of Information Technology Plateau Atmosphere and Envilvnment Key Laboratory of Sichuan Province Chengdu 610225 China Key Laboratory of Arid Climatic Change and Reducing Disaster of Gansu Province College of Atmospheric Sciences Lanzhou University Lanzhou 730000 China State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China

The quality of the MODIS C6 3-km and 10-km aerosol optical depth（AOD） products retrieved by the Dark Target（DT）method is discussed using ground-based observations in the Beijing–Tianjin–Hebei region from 1 August 2007 to 31 July2008. Good consistency exists between the 3-km and 10-km products and ground-based observations. The retrieval accuracy of the two products both show distinctive seasonality. The percentage falling within the expected error（EE） is largest in the winter, moderate in the spring and autumn, and smallest in the summer. A worse overestimation appears in the spring and summer（27%–66%）. However, the 3-km and 10-km products over different surfaces still exhibit obvious deviations. The 10-km product performs better in the large cities, while the 3-km product has advantages in the suburbs. In urban areas, the percentage falling within EE of the 3-km AOD product（18%–59%） is lower than that for the 10-km AOD product（31%–69%）. However, in suburban areas, the percentage falling within EE of the 3-km AOD product（61%–84%） is higher than for the 10 km AOD product（54%–83%）.The percentages falling within EE differ considerably when the AOD is greater than1.5（73% and 63% for the 3-km and 10-km products, respectively）. On the whole, the 3-km（10-km） AOD product performs better in suburban（urban） areas.

关键词： aerosol urban agglomeration MODIS AOD

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